EP0311454A1 - Atmosphere control device - Google Patents

Atmosphere control device Download PDF

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Publication number
EP0311454A1
EP0311454A1 EP88309431A EP88309431A EP0311454A1 EP 0311454 A1 EP0311454 A1 EP 0311454A1 EP 88309431 A EP88309431 A EP 88309431A EP 88309431 A EP88309431 A EP 88309431A EP 0311454 A1 EP0311454 A1 EP 0311454A1
Authority
EP
European Patent Office
Prior art keywords
container
gas
permeable material
active ingredient
box
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP88309431A
Other languages
German (de)
French (fr)
Inventor
Roger Philip Payne
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ALLEN DAVIES BUTLER (HOLDINGS) LIMITED
Original Assignee
ALLEN DAVIES BUTLER (HOLDINGS) Ltd
Allen Davies and Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ALLEN DAVIES BUTLER (HOLDINGS) Ltd, Allen Davies and Co Ltd filed Critical ALLEN DAVIES BUTLER (HOLDINGS) Ltd
Publication of EP0311454A1 publication Critical patent/EP0311454A1/en
Withdrawn legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D81/00Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
    • B65D81/24Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants
    • B65D81/26Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators
    • B65D81/266Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants
    • B65D81/268Adaptations for preventing deterioration or decay of contents; Applications to the container or packaging material of food preservatives, fungicides, pesticides or animal repellants with provision for draining away, or absorbing, or removing by ventilation, fluids, e.g. exuded by contents; Applications of corrosion inhibitors or desiccators for absorbing gases, e.g. oxygen absorbers or desiccants the absorber being enclosed in a small pack, e.g. bag, included in the package
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25DREFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
    • F25D17/00Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces
    • F25D17/04Arrangements for circulating cooling fluids; Arrangements for circulating gas, e.g. air, within refrigerated spaces for circulating air, e.g. by convection
    • F25D17/042Air treating means within refrigerated spaces

Definitions

  • This invention relates to an atmosphere control device which is suitable, for example, for emitting a component to, or extracting a component from, the surrounding atmosphere.
  • One specific use of a device in accordance with the present invention is to maintain the freshness of produce kept, for example in a refrigerator.
  • an atmosphere control device comprising an active ingredient packed in an enclosure, characterised in that the enclosure comprises a rigid container for the active ingredient, the container having an opening which is covered by a gas-permeable material.
  • the rigid wall of the container is made from a stiff, foldable material such as carton board.
  • the container may be elongate, with a square cross-section, with openings provided in one or more of the long sides. Each side may be provided with more than one of the openings.
  • the container may be made from plastics material which is formed to provide one or more cup-shaped recesses. The open end of the or each recess is covered by the air permeable material.
  • the active ingredient will be selected to provide an appropriate influence on the ambient surroundings. If the device is to be used to maintain the freshness of fruit in domestic refrigerators, the active ingredient may comprise potassium permanganate.
  • the potassium permanganate may, for example, be mixed with a suitable carrier, such as iron oxide, and formed into pellets.
  • Potassium permanganate absorbs ethylene, and consequently reduces deterioration of fruit and vegetables.
  • Other active ingredients may be used for different purposes.
  • calcium hydroxide will absorb not only ethylene but also carbon dioxide, and hygroscopic compounds will absorb moisture.
  • the device shown in Figure 1 comprises an elongate container of generally square cross-section.
  • the container is formed from the blank shown in Figure 2, which comprises two layers 2, 4 of material.
  • the layer 2 is relatively rigid and may, for example, comprise carton board, while the layer 4 is relative flimsy and gas-permeable and may comprise, for example, an unwoven fabric formed from natural or synthetic fibres.
  • the container as shown in Figure 1 has, on each of three sides, three oblong openings 6. These openings 6 are formed in the rigid layer 2, as shown in Figure 3, but are covered by the gas-permeable layer 4.
  • the gas-permeable layer 4 covers the entire extent of the rigid layer 2. However, it would be possible to apply the gas-­permeable layer only over that region of the blank shown in Figure 2 which is occupied by the openings 6.
  • the blank shown in Figure 2 comprises three panels 8 provided with the openings 6, and a fourth panel 10 which is continuous.
  • the blank also has a glue flap 12 and end tabs 14.
  • the flap 23 is glued to the inside surface of the panel 10, and the tabs 14 at one end are folded down and glued together to close that end.
  • the partially formed container is then filled with an active ingredient, such as potassium permanganate pellets or granules, and the tabs at the other end are then also folded down and glued.
  • the device For use, the device is placed in a refrigerator or other food storage cabinet. Air is able to pass through the material 4 covering the openings 6, and so circulates through the device with the result that ethylene gas is absorbed by the potassium permanganate. Ripening and subsequent deterioration of fruit is retarded in the absence of ethylene, and consequently produce in the refrigerator will keep longer in the presence of the device. Also, the active ingredient will absorb odours in the refrigerator or other storage cabinet and so prevent or reduce cross-tainting of produce. Thus, for example, mild-flavoured products, such as butter, will not become tainted with the flavour of more strongly flavoured products, such as cheese.
  • Figure 4 shows a package suitable for containing and displaying the device for retail sale.
  • the package comprises a box portion 16, which accommodates the device itself, and a panel 18 provided with a hole 20 suitable for suspending the package from a hook for display purposes.
  • the device is pre-packed in an airtight enclosure, for example in a flow-wrapping process using a flexible film, before insertion into the box portion 16. This avoids deterioration of the effectiveness of the active ingredient before the device is used by the purchaser.
  • FIG. 5 An alternative atmosphere control device is shown in Figures 5 and 6. This device is suitable for inclusion in a foodstuff package, for example in a box of fruit or vegetable produce, to retard ripening and/or deterioration of the produce.
  • the device comprises a container in the form of a tray 22 which has an array of relatively small recesses 24.
  • Each recess may have a depth slightly larger than 2mm, and will contain a small quantity of an active ingredient, such as potassium permanganate. If the active ingredient is supplied in the form of pellets 25, it is convenient for each recess 24 to contain a single pellet.
  • the tray is made from unplasticised poly(vinylchloride) (uPVC).
  • a layer 26 of air permeable material is bonded over the tray 22 to close the recesses 24.
  • the material is a bonded fibre material having a fusible polyethylene coating, and may be the material available under the designation "XPS125" with a weight of 15g/m2.
  • the layer 26 is welded to the tray 22 along lines 28 running between the recesses 24.
  • FIG 7 shows, diagrammatically, a process by which the device of Figures 5 and 6 may be formed.
  • uPVC is drawn from a roll 30 through heater boxes 32, where it is softened, and then through a forming head 34, which forms the recesses 24.
  • a dispenser 36 of potassium permanganate pellets (available under the name "ETHYSORB”) discharges the pellets over the surface of the tray 22.
  • a doctor blade 38 distributes the pellets evenly over the surface of the tray 22, so that each recess 24 receives a single pellet, excess pellets being returned to the dispenser 36.
  • the bonded fibre material 26 is drawn from a roll 40 on to the surface of the filled tray 22, and welded along the lines 28 by means of a welding head 42.
  • a cutting head 44 removes excess material from the sides of the tray 22, this excess material being received by a waste roll 46.
  • the resulting devices may be placed, for example, in the bottom of boxes intended to receive fresh fruit.
  • the size of the device which is used in any particular application will depend on the expected quantity of ethylene to be absorbed in order to keep the produce in a proper condition for the required length of time. Because the device is relatively thin and flat, it will not project significantly into the box, and consequently will not damage the produce subsequently placed into the box.

Landscapes

  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Mechanical Engineering (AREA)
  • Packages (AREA)
  • Packging For Living Organisms, Food Or Medicinal Products That Are Sensitive To Environmental Conditiond (AREA)
  • Disinfection, Sterilisation Or Deodorisation Of Air (AREA)

Abstract

An atmosphere control device comprises a container 22 having a rigid wall and an opening which is covered by a gas-permeable material (26). An active ingredient, such as potassium permanganate pellets (25) is retained in the container (22), for absorbing ethylene from the surroundings. The container (22) may comprise an array of recesses (24), each containing a single pellet (25) of the active ingredient. In use, the device may be included in a package of perishable produce, such as fruit. The device absorbs ethylene from the package, which retards ripening and deterioration of the produce.

Description

  • This invention relates to an atmosphere control device which is suitable, for example, for emitting a component to, or extracting a component from, the surrounding atmosphere. One specific use of a device in accordance with the present invention is to maintain the freshness of produce kept, for example in a refrigerator.
  • According to the present invention there is provided an atmosphere control device comprising an active ingredient packed in an enclosure, characterised in that the enclosure comprises a rigid container for the active ingredient, the container having an opening which is covered by a gas-permeable material.
  • In one embodiment, the rigid wall of the container is made from a stiff, foldable material such as carton board. The container may be elongate, with a square cross-section, with openings provided in one or more of the long sides. Each side may be provided with more than one of the openings.
  • In another embodiment, the container may be made from plastics material which is formed to provide one or more cup-shaped recesses. The open end of the or each recess is covered by the air permeable material.
  • The active ingredient will be selected to provide an appropriate influence on the ambient surroundings. If the device is to be used to maintain the freshness of fruit in domestic refrigerators, the active ingredient may comprise potassium permanganate. The potassium permanganate may, for example, be mixed with a suitable carrier, such as iron oxide, and formed into pellets.
  • Potassium permanganate absorbs ethylene, and consequently reduces deterioration of fruit and vegetables. Other active ingredients may be used for different purposes. For example, calcium hydroxide will absorb not only ethylene but also carbon dioxide, and hygroscopic compounds will absorb moisture.
  • For a better understanding of the present invention, and to show how it may be carried into effect, reference will now be made, by way of example, to the accompanying drawings, in which:
    • Figure 1 shows an atmosphere control device;
    • Figure 2 shows a blank from which the container of the device shown in Figure 1 is formed;
    • Figure 3 is a fragmentary sectional view of the material from which the blank of Figure 2 is formed;
    • Figure 4 shows packaging for the retail sale of the device of Figure 1;
    • Figure 5 is a plan view of an alternative form of atmosphere control device;
    • Figure 6 is a side view of the device of Figure 5; and
    • Figure 7 represents diagrammatically how the device of Figures 5 and 6 is made.
  • The device shown in Figure 1 comprises an elongate container of generally square cross-section. The container is formed from the blank shown in Figure 2, which comprises two layers 2, 4 of material. The layer 2 is relatively rigid and may, for example, comprise carton board, while the layer 4 is relative flimsy and gas-permeable and may comprise, for example, an unwoven fabric formed from natural or synthetic fibres.
  • The container as shown in Figure 1 has, on each of three sides, three oblong openings 6. These openings 6 are formed in the rigid layer 2, as shown in Figure 3, but are covered by the gas-permeable layer 4.
  • In the illustrated embodiment, the gas-permeable layer 4 covers the entire extent of the rigid layer 2. However, it would be possible to apply the gas-­permeable layer only over that region of the blank shown in Figure 2 which is occupied by the openings 6.
  • The blank shown in Figure 2 comprises three panels 8 provided with the openings 6, and a fourth panel 10 which is continuous. The blank also has a glue flap 12 and end tabs 14. To form the container, the flap 23 is glued to the inside surface of the panel 10, and the tabs 14 at one end are folded down and glued together to close that end. The partially formed container is then filled with an active ingredient, such as potassium permanganate pellets or granules, and the tabs at the other end are then also folded down and glued.
  • For use, the device is placed in a refrigerator or other food storage cabinet. Air is able to pass through the material 4 covering the openings 6, and so circulates through the device with the result that ethylene gas is absorbed by the potassium permanganate. Ripening and subsequent deterioration of fruit is retarded in the absence of ethylene, and consequently produce in the refrigerator will keep longer in the presence of the device. Also, the active ingredient will absorb odours in the refrigerator or other storage cabinet and so prevent or reduce cross-tainting of produce. Thus, for example, mild-flavoured products, such as butter, will not become tainted with the flavour of more strongly flavoured products, such as cheese.
  • Figure 4 shows a package suitable for containing and displaying the device for retail sale. The package comprises a box portion 16, which accommodates the device itself, and a panel 18 provided with a hole 20 suitable for suspending the package from a hook for display purposes. The device is pre-packed in an airtight enclosure, for example in a flow-wrapping process using a flexible film, before insertion into the box portion 16. This avoids deterioration of the effectiveness of the active ingredient before the device is used by the purchaser.
  • An alternative atmosphere control device is shown in Figures 5 and 6. This device is suitable for inclusion in a foodstuff package, for example in a box of fruit or vegetable produce, to retard ripening and/or deterioration of the produce.
  • The device comprises a container in the form of a tray 22 which has an array of relatively small recesses 24. Each recess may have a depth slightly larger than 2mm, and will contain a small quantity of an active ingredient, such as potassium permanganate. If the active ingredient is supplied in the form of pellets 25, it is convenient for each recess 24 to contain a single pellet. The tray is made from unplasticised poly(vinylchloride) (uPVC).
  • A layer 26 of air permeable material is bonded over the tray 22 to close the recesses 24. In the specific example shown, the material is a bonded fibre material having a fusible polyethylene coating, and may be the material available under the designation "XPS125" with a weight of 15g/m². The layer 26 is welded to the tray 22 along lines 28 running between the recesses 24.
  • Figure 7 shows, diagrammatically, a process by which the device of Figures 5 and 6 may be formed. uPVC is drawn from a roll 30 through heater boxes 32, where it is softened, and then through a forming head 34, which forms the recesses 24. A dispenser 36 of potassium permanganate pellets (available under the name "ETHYSORB") discharges the pellets over the surface of the tray 22. A doctor blade 38 distributes the pellets evenly over the surface of the tray 22, so that each recess 24 receives a single pellet, excess pellets being returned to the dispenser 36.
  • The bonded fibre material 26 is drawn from a roll 40 on to the surface of the filled tray 22, and welded along the lines 28 by means of a welding head 42. A cutting head 44 removes excess material from the sides of the tray 22, this excess material being received by a waste roll 46.
  • The resulting devices may be placed, for example, in the bottom of boxes intended to receive fresh fruit. The size of the device which is used in any particular application will depend on the expected quantity of ethylene to be absorbed in order to keep the produce in a proper condition for the required length of time. Because the device is relatively thin and flat, it will not project significantly into the box, and consequently will not damage the produce subsequently placed into the box.

Claims (11)

1. An atmosphere control device comprising an active ingredient packed in an enclosure, characterised in that the enclosure comprises a rigid container for the active ingredient, the container having an opening which is covered by a gas-permeable material (4,26).
2. A device as claimed in claim 1, characterized in that the container is in the form of a box, the opening being formed in a wall of the box.
3. A device as claimed in claim 2, in which the opening is one of a plurality of openings formed in different walls of the box.
4. A device as claimed in claim 2 or 3, characterised in that the box is formed from an apertured blank to which is bonded a layer of the gas-­permeable material.
5. A device as claimed in claim 1, characterised in that the container comprises a cup-shaped recess covered by a layer of the gas-permeable material.
6. A device as claimed in claim 5, characterised in that the container is in the form of a tray having a plurality of the recesses.
7. A device as claimed in claim 6, characterised in that all of the recesses of the tray are covered by a common layer of the gas-permeable material.
8. A device as claimed in claim 6 to 7, characterised in that the active ingredient is in pellet form, each recess of the tray containing a single pellet.
9. A device as claimed in any one of claims 5 to 8, characterised in that the gas-permeable material is a polyethylene coated bonded fibre material.
10. A device as claimed in any one of claims 5 to 9, characterised in that the gas-permeable material is welded to the container.
11. A package containing perishable produce and a device in accordance with any one of the preceding claims.
EP88309431A 1987-10-09 1988-10-10 Atmosphere control device Withdrawn EP0311454A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB878723717A GB8723717D0 (en) 1987-10-09 1987-10-09 Atmosphere control device
GB8723717 1987-10-09

Publications (1)

Publication Number Publication Date
EP0311454A1 true EP0311454A1 (en) 1989-04-12

Family

ID=10625037

Family Applications (1)

Application Number Title Priority Date Filing Date
EP88309431A Withdrawn EP0311454A1 (en) 1987-10-09 1988-10-10 Atmosphere control device

Country Status (3)

Country Link
EP (1) EP0311454A1 (en)
JP (1) JPH01230362A (en)
GB (2) GB8723717D0 (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001030658A1 (en) * 1999-10-25 2001-05-03 R-Tec Technologies, Inc. Container for odor remover and ethylene absorbent
WO2001056620A1 (en) * 2000-02-04 2001-08-09 The Procter & Gamble Company Air filtering device
WO2001056622A1 (en) * 2000-02-04 2001-08-09 The Procter & Gamble Company Apparatus and method for deodorizing air
FR2819990A1 (en) * 2001-01-26 2002-08-02 Solvay Device for controlling the ripening of fruit or vegetables includes potassium permanganate to inhibit ethylene-induced accelerated ripening
US6986806B2 (en) 2000-02-04 2006-01-17 The Procter & Gamble Company Air filtering device
US7005000B2 (en) 2000-02-04 2006-02-28 The Procter & Gamble Company Air deodorization device having a detachable cartridge member
EP1645812A2 (en) * 2004-10-08 2006-04-12 Propack S.p.A. Dehumidifier device
DE102006034602A1 (en) * 2006-05-30 2007-12-06 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Process for increasing the shelf life of ethylene-producing agricultural products during transport, sale, presentation and / or storage
EP1857753A3 (en) * 2006-05-18 2013-07-03 Liebherr-Hausgeräte Ochsenhausen GmbH Refrigeration and/or freezer device
US8664153B1 (en) 2013-03-15 2014-03-04 Sociedad Oxidquimica Limitada Activated carbon as an adsorbent composition
EP2772291A1 (en) * 2011-10-25 2014-09-03 Ozeano Urdina, S.l. Ethylene absorption filter for refrigerated spaces
WO2015110682A1 (en) * 2014-01-23 2015-07-30 Wang Yinan Gas absorption pocket for containers of perishable products
FR3077563A1 (en) * 2018-02-07 2019-08-09 Nano4 POLYMERIC FILM FOR FOOD PACKAGING
WO2021014047A1 (en) * 2019-07-24 2021-01-28 Greenkeeper Iberia Sl Tubular filter that absorbs ethylene or other gases, for refrigerated transport containers

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5624478A (en) * 1995-09-14 1997-04-29 Patapanian; Edward Ethylene absorption device
CN107600715A (en) * 2017-08-28 2018-01-19 安徽巢湖南方膜业有限责任公司 A kind of buffering packing film with ethylene absorption function

Citations (3)

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Publication number Priority date Publication date Assignee Title
US4235750A (en) * 1979-03-07 1980-11-25 Cazalet Michael F Container for prevention of postharvest decay, maturation and senescense of harvested crops
US4579223A (en) * 1983-01-28 1986-04-01 Mitsubishi Gas Chemical Company Inc. Oxygen absorbent packet
EP0230191A1 (en) * 1985-12-20 1987-07-29 Société civile de Recherches des Produits du Soleil RE.PRO.SOL Crate for the packaging of fruit or vegetables

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FR1398104A (en) * 1964-03-26 1965-05-07 Participations Et Procedes Ind desiccant elements and their manufacturing process
DE1757764B1 (en) * 1968-06-12 1970-09-03 Delbag Luftfilter Gmbh Plate-shaped disposable activated carbon filter
FR2158629A5 (en) * 1971-10-26 1973-06-15 Giffard L
GB2029256B (en) * 1978-07-14 1982-12-08 Marshall D Fluid filter
JPS5643457A (en) * 1979-09-18 1981-04-22 Japan Vilene Co Ltd Production of nonwoven fabric molded article
US4333752A (en) * 1980-01-14 1982-06-08 Michlin Chemical Corporation Adsorbent cartridge for the exhaust of diazo process machines
SE419630B (en) * 1980-01-16 1981-08-17 Zeidler Holmgren Handel STORAGE DEVICE FOR BODIES WHICH MUST BE EXPOSED TO THE ENVIRONMENT, LIKE HYGROSCOPIC BODIES FOR MOISTURE TAKING

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4235750A (en) * 1979-03-07 1980-11-25 Cazalet Michael F Container for prevention of postharvest decay, maturation and senescense of harvested crops
US4579223A (en) * 1983-01-28 1986-04-01 Mitsubishi Gas Chemical Company Inc. Oxygen absorbent packet
EP0230191A1 (en) * 1985-12-20 1987-07-29 Société civile de Recherches des Produits du Soleil RE.PRO.SOL Crate for the packaging of fruit or vegetables

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001030658A1 (en) * 1999-10-25 2001-05-03 R-Tec Technologies, Inc. Container for odor remover and ethylene absorbent
WO2001056620A1 (en) * 2000-02-04 2001-08-09 The Procter & Gamble Company Air filtering device
WO2001056622A1 (en) * 2000-02-04 2001-08-09 The Procter & Gamble Company Apparatus and method for deodorizing air
US6986806B2 (en) 2000-02-04 2006-01-17 The Procter & Gamble Company Air filtering device
US7005000B2 (en) 2000-02-04 2006-02-28 The Procter & Gamble Company Air deodorization device having a detachable cartridge member
FR2819990A1 (en) * 2001-01-26 2002-08-02 Solvay Device for controlling the ripening of fruit or vegetables includes potassium permanganate to inhibit ethylene-induced accelerated ripening
EP1645812A3 (en) * 2004-10-08 2010-12-01 Propack S.p.A. Dehumidifier device
EP1645812A2 (en) * 2004-10-08 2006-04-12 Propack S.p.A. Dehumidifier device
EP1857753A3 (en) * 2006-05-18 2013-07-03 Liebherr-Hausgeräte Ochsenhausen GmbH Refrigeration and/or freezer device
DE102006034602A1 (en) * 2006-05-30 2007-12-06 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Process for increasing the shelf life of ethylene-producing agricultural products during transport, sale, presentation and / or storage
EP2772291A1 (en) * 2011-10-25 2014-09-03 Ozeano Urdina, S.l. Ethylene absorption filter for refrigerated spaces
EP2772291A4 (en) * 2011-10-25 2015-04-15 Ozeano Urdina S L Ethylene absorption filter for refrigerated spaces
US8664153B1 (en) 2013-03-15 2014-03-04 Sociedad Oxidquimica Limitada Activated carbon as an adsorbent composition
WO2015110682A1 (en) * 2014-01-23 2015-07-30 Wang Yinan Gas absorption pocket for containers of perishable products
FR3077563A1 (en) * 2018-02-07 2019-08-09 Nano4 POLYMERIC FILM FOR FOOD PACKAGING
WO2019154860A1 (en) * 2018-02-07 2019-08-15 Nano4 Polymer film for food packaging
WO2021014047A1 (en) * 2019-07-24 2021-01-28 Greenkeeper Iberia Sl Tubular filter that absorbs ethylene or other gases, for refrigerated transport containers
ES2803824A1 (en) * 2019-07-24 2021-01-29 Greenkeeper Iberia S L TUBULAR ABSORBING FILTER OF ETHYLENE OR OTHER GASES FOR REFRIGERATED TRANSPORT CONTAINERS (Machine-translation by Google Translate, not legally binding)

Also Published As

Publication number Publication date
JPH01230362A (en) 1989-09-13
GB8823745D0 (en) 1988-11-16
GB8723717D0 (en) 1987-11-11
GB2210806A (en) 1989-06-21

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