EP0310584A3 - Refining of raw gas - Google Patents

Refining of raw gas Download PDF

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Publication number
EP0310584A3
EP0310584A3 EP88850323A EP88850323A EP0310584A3 EP 0310584 A3 EP0310584 A3 EP 0310584A3 EP 88850323 A EP88850323 A EP 88850323A EP 88850323 A EP88850323 A EP 88850323A EP 0310584 A3 EP0310584 A3 EP 0310584A3
Authority
EP
European Patent Office
Prior art keywords
refining
raw gas
tar
catalytic
secondary stage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP88850323A
Other versions
EP0310584A2 (en
EP0310584B1 (en
Inventor
Clas Ekstrom
Bengt-Goran Espenas
Waclaw Kowalic
Erik Rensfelt
Lars Waldheim
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Studsvik Energiteknik AB
Original Assignee
Studsvik AB
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Studsvik AB filed Critical Studsvik AB
Priority to AT88850323T priority Critical patent/ATE88210T1/en
Publication of EP0310584A2 publication Critical patent/EP0310584A2/en
Publication of EP0310584A3 publication Critical patent/EP0310584A3/en
Application granted granted Critical
Publication of EP0310584B1 publication Critical patent/EP0310584B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/20—Purifying combustible gases containing carbon monoxide by treating with solids; Regenerating spent purifying masses
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
    • C10K3/023—Reducing the tar content
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0986—Catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Industrial Gases (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Control And Other Processes For Unpacking Of Materials (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Fats And Perfumes (AREA)
  • Artificial Filaments (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

The invention relates to a process for the refining of a raw gas produced from a carbonaceous material by means of a gasification process, refining taking place in a secondary stage separated from the gasifier. In order to reduce the gas contents of tar in the form of organic compounds condensible at lower temperatures, such as ambient temperatures, and of ammonia, the refining is carried out in a secondary stage being a fast circulating fluidized bed, the bed material of which at least mainly being an active material in the form of a material that is catalytic for tar and ammonia conversion, whereby a catalytic conversion of tar and ammonia contained in the raw gas is obtained. In order to decrease the content of hydrogen chloride in the gas, an active material that also can absorb chloride is used. Fresh catalytic and absorbing material is supplied in an amount sufficient to have the hydrogen chloride present in the raw gas absorbed on the material, a corresponding amount of the material containing absorbed chloride being discharged from the secondary stage.
EP88850323A 1987-10-02 1988-09-28 Refining of raw gas Expired - Lifetime EP0310584B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT88850323T ATE88210T1 (en) 1987-10-02 1988-09-28 CLEANING OF CRUDE GAS.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
SE8703816 1987-10-02
SE8703816A SE459584B (en) 1987-10-02 1987-10-02 PROCEDURES FOR PROCESSING OF RAAGAS MANUFACTURED FROM COAL CONTENTS

Publications (3)

Publication Number Publication Date
EP0310584A2 EP0310584A2 (en) 1989-04-05
EP0310584A3 true EP0310584A3 (en) 1990-03-14
EP0310584B1 EP0310584B1 (en) 1993-04-14

Family

ID=20369746

Family Applications (1)

Application Number Title Priority Date Filing Date
EP88850323A Expired - Lifetime EP0310584B1 (en) 1987-10-02 1988-09-28 Refining of raw gas

Country Status (15)

Country Link
EP (1) EP0310584B1 (en)
JP (1) JP2573681B2 (en)
AT (1) ATE88210T1 (en)
AU (1) AU612199B2 (en)
CA (1) CA1335694C (en)
DE (1) DE3880253T2 (en)
DK (1) DK175009B1 (en)
ES (1) ES2039698T3 (en)
FI (1) FI95924C (en)
GE (1) GEP19980893B (en)
LT (1) LT3842B (en)
LV (1) LV11188B (en)
NO (1) NO302422B1 (en)
SE (1) SE459584B (en)
WO (1) WO1989002909A1 (en)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5139756A (en) * 1989-10-05 1992-08-18 Nkk Corporation Catalytic oxidation of ammonia
JPH03122010A (en) * 1989-10-05 1991-05-24 Nkk Corp Catalytic oxidative degradation of ammonia
US5543390A (en) * 1990-11-01 1996-08-06 State Of Oregon, Acting By And Through The Oregon State Board Of Higher Education, Acting For And On Behalf Of The Oregon Health Sciences University Covalent microparticle-drug conjugates for biological targeting
US5827819A (en) * 1990-11-01 1998-10-27 Oregon Health Sciences University Covalent polar lipid conjugates with neurologically active compounds for targeting
DE4210003A1 (en) * 1992-03-27 1993-09-30 Ruhrkohle Ag Combined process for the production of metallurgical coke and sponge iron
FI96321C (en) * 1993-06-11 1996-06-10 Enviropower Oy Method and reactor for treating process gas
US5401282A (en) * 1993-06-17 1995-03-28 Texaco Inc. Partial oxidation process for producing a stream of hot purified gas
US5403366A (en) * 1993-06-17 1995-04-04 Texaco Inc. Partial oxidation process for producing a stream of hot purified gas
NL1001555C2 (en) * 1995-10-27 1997-05-02 Biomass Technology Group B V Catalytically producing combustible gases, e.g., for generating energy
DE19907901C2 (en) * 1999-02-24 2001-11-29 Mg Technologies Ag Process for the catalytic cracking of volatile higher hydrocarbons
UA65957U (en) * 2008-09-26 2011-12-26 Сименз Ваи Металз Текнолоджиз Гмбх Method for dry dust removal and dry cleaning of gas laden with dust and pollutants
DE102008049579A1 (en) * 2008-09-30 2010-04-01 Uhde Gmbh Hot gas cleaning
DE102010024429A1 (en) * 2010-06-21 2011-12-22 Technische Universität München Operating integrated gasification combined cycle power plant, comprises converting fuels in gasifier using adjuvants including oxygen, vapor, carbon dioxide and water, and cleaning raw gas from gasifier and treating gas in shift reactor
CA2808893C (en) 2010-08-16 2018-06-05 Energy & Environmental Research Center Foundation Sandwich gasification process for high-efficiency conversion of carbonaceous fuels to clean syngas with zero residual carbon discharge
DE102013008422A1 (en) * 2013-05-16 2014-11-20 Ecoloop Gmbh Process for the purification of synthesis gases
CN103820170B (en) * 2014-02-21 2015-09-02 陕西延长石油（集团）有限责任公司碳氢高效利用技术研究中心 The conversion system of the coal-tar middle oil component of a kind of raw gas and carbonaceous particles and method
JP6345139B2 (en) * 2015-03-13 2018-06-20 三菱日立パワーシステムズ株式会社 Gas engine system

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3807090A (en) * 1970-12-02 1974-04-30 Exxon Research Engineering Co Purifications of fuels
DE3404483A1 (en) * 1984-02-08 1985-08-08 Environment Protecting Engineers, Inc., Southfield, Mich. Process for purifying pyrolysis gases and apparatus for carrying out this process
GB2180849A (en) * 1985-09-25 1987-04-08 Skf Steel Eng Ab Producing clean gas containing hydrogen and carbon monoxide
FR2594140A1 (en) * 1986-02-13 1987-08-14 Goetaverken Energy Syst Ab Process for removing undesirable substances from a gas which is produced by pyrolytic gasification

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2824534A1 (en) * 1977-06-03 1978-12-07 Hitachi Ltd METHOD FOR PURIFYING HYDROGEN SULFUR AND AMMONIA CONTAINING HOT GASES
DE3017998C2 (en) * 1980-05-10 1994-05-26 Krupp Koppers Gmbh Process for the catalytic treatment of partial oxidation raw gas
DE3716199A1 (en) 1987-05-14 1988-11-24 Linde Ag METHOD AND DEVICE FOR PURIFYING RAW GAS WITH SIMULTANEOUS RECOVERY OF SYNTHESIS AND FUEL GAS

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3807090A (en) * 1970-12-02 1974-04-30 Exxon Research Engineering Co Purifications of fuels
DE3404483A1 (en) * 1984-02-08 1985-08-08 Environment Protecting Engineers, Inc., Southfield, Mich. Process for purifying pyrolysis gases and apparatus for carrying out this process
GB2180849A (en) * 1985-09-25 1987-04-08 Skf Steel Eng Ab Producing clean gas containing hydrogen and carbon monoxide
FR2594140A1 (en) * 1986-02-13 1987-08-14 Goetaverken Energy Syst Ab Process for removing undesirable substances from a gas which is produced by pyrolytic gasification

Also Published As

Publication number Publication date
WO1989002909A1 (en) 1989-04-06
LV11188B (en) 1996-10-20
FI901613A0 (en) 1990-03-30
LT3842B (en) 1996-04-25
EP0310584A2 (en) 1989-04-05
DE3880253D1 (en) 1993-05-19
SE8703816L (en) 1989-04-03
NO302422B1 (en) 1998-03-02
DK81090A (en) 1990-05-28
EP0310584B1 (en) 1993-04-14
LV11188A (en) 1996-04-20
ES2039698T3 (en) 1993-10-01
LTIP1598A (en) 1995-08-25
JP2573681B2 (en) 1997-01-22
AU2529788A (en) 1989-04-18
DK175009B1 (en) 2004-04-19
FI95924C (en) 1996-04-10
AU612199B2 (en) 1991-07-04
NO901393L (en) 1990-03-27
NO901393D0 (en) 1990-03-27
SE8703816D0 (en) 1987-10-02
JPH03500420A (en) 1991-01-31
SE459584B (en) 1989-07-17
GEP19980893B (en) 1998-04-10
DK81090D0 (en) 1990-03-30
DE3880253T2 (en) 1993-07-29
FI95924B (en) 1995-12-29
CA1335694C (en) 1995-05-30
ATE88210T1 (en) 1993-04-15

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