EP0300041A1 - Fine particle-containing fibers and process for their production - Google Patents

Fine particle-containing fibers and process for their production Download PDF

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Publication number
EP0300041A1
EP0300041A1 EP87903430A EP87903430A EP0300041A1 EP 0300041 A1 EP0300041 A1 EP 0300041A1 EP 87903430 A EP87903430 A EP 87903430A EP 87903430 A EP87903430 A EP 87903430A EP 0300041 A1 EP0300041 A1 EP 0300041A1
Authority
EP
European Patent Office
Prior art keywords
fiber
finely divided
divided particles
fibers
wool
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP87903430A
Other languages
German (de)
French (fr)
Other versions
EP0300041A4 (en
Inventor
Nobukazu Muto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jf Corp KK
NAKAMURA Masahiro
Original Assignee
Jf Corp KK
NAKAMURA Masahiro
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jf Corp KK, NAKAMURA Masahiro filed Critical Jf Corp KK
Publication of EP0300041A1 publication Critical patent/EP0300041A1/en
Publication of EP0300041A4 publication Critical patent/EP0300041A4/en
Withdrawn legal-status Critical Current

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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters

Definitions

  • the present invention relates to finely divided particles-containing fiber wherein characteristic features belonging to the finely divided particles are suitably selected and applied to the fiber without damaging essential characteristic features thereof and a process for preparing the same. More particularly, the invention relates to finely divided particles-containing fiber which can maintain the above described characteristic features for a long period of time and an easy process for preparing the same which comprises immersing fiber in a prescribed processing solution which has been heated and pressurized, and solid-dissolving finely divided particles into molecular spacing or micelles involved in the resulting swelled monofilaments of said fiber.
  • wool consists of a number of cells, which is classified into cuticle, cortex, and core sections.
  • Cuticle consists of scalelike cells, constructions of cuticle and core are independent respectively and nonuniform, so that wool provide favourable crimp, besides wool has good elastic recovery. Accordingly, wool possesses very good properties as fiber for clothing.
  • synthetic fiber exhibits beautiful appearance peculiar thereto, moderate elasticity and strength while satisfying a demand corresponding to consumption of such synthetic fiber.
  • an object of the present invention is to provide finely divided particles-containing fiber and the process for preparing the same both of which involve no disadvantages being accompanied with conventional natural or synthetic fiber wherein finely divided particles are merely adhesive bonded to surface of the fiber, to which fiber is added characteristic features belonging to the finely divided particles without damaging essential characteristic features belonging to the very fiber, and such advantageous characteristic features of the finely divided particles-containing fiber can maintain for a long period of time.
  • Another object of the present invention is to suitably select and add characteristic features in response to quality required to the products manufactured from the above described fiber.
  • fibers are immersed in a prescribed processing solution which has been heated and pressurized, and finely divided particles are solid-dissolved in spacings defined between molecules or micelles of these swelled fibers to close the spacings or micelles.
  • Fig. 1 is a scanning electron micrograph of a wool surface portion showing a state where ceramic particles are solid-dissolved in micelles of wool fiber.
  • the present fiber and the process for preparing the same will be particularly described in connection with wool as its major component.
  • wool consists of a number of cells, and since the construction thereof is nonuniform, wool exhibits ample crimps as well as characteristic features adapting easily to the environment such as good elastic recovery and so on.
  • the present invention utilizes such characteristic features as described above.
  • a surface of wool monofilament has scalelike micelles as its cuticle. When these micelles are immersed in an aqueous solution, they swell rapidly under the environment in the aqueous solution, and as a result, the extreme end portion thereof expands from its spindle-like cortex being the main body of monofilament.
  • Fig. 1 is a scanning electron micrograph showing a state where ceramic particles are solid-dissolved in micelles of wool fiber, and from which a situation where the white ceramic particles are solid-dissolved in stratified micelles in the surface of the wool fiber is well understood.
  • this wool fiber has solid-dissolved ceramic having a very high porosity (for example, 90% or more), it is excellent in its thermal insulating properties. More specifically, yarn consisting of a solid such as the porous silicon ceramic and gas as in the present invention reduces not only such conduction and heat transfer propagating through the fiber itself, but also heat transfer and radiating heat transmission between the fiber and space. Thus, the yarn has very excellent thermal insulating properties, so that clothing and the like fabricated from such wool fiber as described above does not absorb heat from the outside.
  • ceramic having a high porosity adsorbs easily moisture due to capillarity of pores in the ceramic, and such ceramic is sensitive to moisture absorption from the outside, so that the ceramic existing inside the micelles makes moisture absorption easy.
  • the ceramic absorbs rapidly, in turns, moisture in the core inside the cortex of wool so that a moisture content of the wool main body is elevated. This moisture content tends to adapt to the outer environment as natural characteristic features of wool. When the environment dries, environmental adaptability is added to wool characteristic features by releasing moisture to the surface of the wool.
  • a sweater made from the ceramic wool has superior water absorption properties than those of conventional wool manufactured goods.
  • ceramic exhibits various characteristic features dependent upon ingredients thereof.
  • translucent ceramic being transparent in infrared region exhibits high selective absorption with respect to infrared rays.
  • a metallic oxide MgO ceramics, Sio 2 ceramics, Al 2 O 3 ceramics or the like
  • an article to be heated for example, human body and the like
  • far infrared rays 25 - 10 ⁇ m
  • Such synthetic fiber in which a disperse dye is solid-dissolved as described above can provide a stable dyed fiber which has not been heretofore.
  • the finely divided particles-containing fiber and the process for preparing the same according to the present invention are not limited to the above described embodiments, but any fiber gaps of which existing on the surface of the fiber may be expanded and finely divided particles may be solid-dissolved as well as the process for preparing the same are involved in the present invention. Therefore, the present invention can provide fiber having characteristic features which have never heretofore been dependent on combinations of a type of fiber and that of finely divided particles.
  • the finely divided particles-containing fiber and the process for preparing the same according to the present invention selects and adds arbitrarily characteristic features involved in the finely divided particle without damaging characteristic features of an original fiber.
  • the process for the preparation according to the present invention is useful for preparing the fiber having characteristic features to be added, and particularly it is suitable for solid-dissolving ceramic finely divided particles in natural fiber.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

Fine particle-containing stable fibers with a wide applicability. They are produced by dipping fibers into a given heated and pressured treatment bath and allowing fine particles to dissolve as solid within micelles or keeping them in molecular gaps of the swollen fibers. Thus, selected properties of the fine particles can be suitably imparted to the fibers in addition to the properties of the fibers themselves.

Description

    TECHNICAL FIELD
  • The present invention relates to finely divided particles-containing fiber wherein characteristic features belonging to the finely divided particles are suitably selected and applied to the fiber without damaging essential characteristic features thereof and a process for preparing the same. More particularly, the invention relates to finely divided particles-containing fiber which can maintain the above described characteristic features for a long period of time and an easy process for preparing the same which comprises immersing fiber in a prescribed processing solution which has been heated and pressurized, and solid-dissolving finely divided particles into molecular spacing or micelles involved in the resulting swelled monofilaments of said fiber.
    • TECHNICAL BACKGROUND
  • It has been conventionally known that quality of textile goods depends upon that of fiber from which the corresponding textile good is manufactured, so that fiber must be selected on the basis of characteristic features involved in the fiber dependent upon functions and applications of the objective textile goods.
  • For example, wool consists of a number of cells, which is classified into cuticle, cortex, and core sections. Cuticle consists of scalelike cells, constructions of cuticle and core are independent respectively and nonuniform, so that wool provide favourable crimp, besides wool has good elastic recovery. Accordingly, wool possesses very good properties as fiber for clothing. On one hand, with development of recent petrochemical industry, consumption of synthetic fiber increases, and under these circumstances, synthetic fiber exhibits beautiful appearance peculiar thereto, moderate elasticity and strength while satisfying a demand corresponding to consumption of such synthetic fiber.
  • On the other hand, such trial that finely divided particles are adhesive bonded to surfaces of respective fiber has been effected in order to extend applications and functions of fiber which have been limited to peculiar properties of the fiber itself by adding characteristic features involved in the other fiber to the very individual fiber.
  • For instance, there have been such fiber wherein the fiber is immersed in a particulate material solution containing a binder to adhesive bond said particulate material on the surface of the fiber, or such textile which is obtained by either blending fiber to which is adhesive bonded the particulate material or twisting and uniting the fiber, and the like textile or fiber.
  • In case of applying a dyestuff to a synthetic fiber, such colored synthetic fiber wherein coloring matter has been adhesive bonded between finely divided particles of the coloring matter and the surface of the synthetic fiber by means of an adhesive as its medium, and the like fiber have heretofore been proposed.
  • However, such synthetic fiber as described above wherein finely divided particles are merely adhesive bonded to the surface of the fiber, so that characteristic features of the finely divided particles could not be maintained for a long period of time dependent upon use and applications for products manufactured from said fiber. Even in mix-spun or twisted union cloth, such cloth could not maintain essential property of union cloth due to differences in stretchability and the like of both of the fiber.
  • Accordingly, an object of the present invention is to provide finely divided particles-containing fiber and the process for preparing the same both of which involve no disadvantages being accompanied with conventional natural or synthetic fiber wherein finely divided particles are merely adhesive bonded to surface of the fiber, to which fiber is added characteristic features belonging to the finely divided particles without damaging essential characteristic features belonging to the very fiber, and such advantageous characteristic features of the finely divided particles-containing fiber can maintain for a long period of time.
  • Another object of the present invention is to suitably select and add characteristic features in response to quality required to the products manufactured from the above described fiber.
    • DISCLOSURE OF THE INVENTION
  • Namely, according to the present invention, fibers are immersed in a prescribed processing solution which has been heated and pressurized, and finely divided particles are solid-dissolved in spacings defined between molecules or micelles of these swelled fibers to close the spacings or micelles.
  • Thus, such characteristic features belonging to a finely divided particle are suitably selected therefrom and added to those of fiber which has been involved therein originally, whereby stable fiber which has not been conventionally is provided. Moreover, applications in conventional fiber are expanded.
    • BRIEF DESCRIPTION OF THE DRAWING
  • Fig. 1 is a scanning electron micrograph of a wool surface portion showing a state where ceramic particles are solid-dissolved in micelles of wool fiber.
    • BEST MODE FOR EMBODYING THE INVENTION
  • An embodiment of the present invention will be described in detail hereinbelow.
  • It is to be noted that the present fiber and the process for preparing the same will be particularly described in connection with wool as its major component. As described above, wool consists of a number of cells, and since the construction thereof is nonuniform, wool exhibits ample crimps as well as characteristic features adapting easily to the environment such as good elastic recovery and so on. The present invention utilizes such characteristic features as described above. In this connection, a surface of wool monofilament has scalelike micelles as its cuticle. When these micelles are immersed in an aqueous solution, they swell rapidly under the environment in the aqueous solution, and as a result, the extreme end portion thereof expands from its spindle-like cortex being the main body of monofilament.
  • Accordingly, for example, when a prescribed amount of silicon ceramic finely divided particles having a particle diameter of 7 millimicrons to 5 microns are mixed with a processing solution containing a non-surface active agent, and when the resulting mixture is heated at a temperature of less than 100°C and wool is immersed in the mixture for, e.g., about 45 minutes under a pressure of 3 - 5 kg/cm , the extreme ends of the micelles on the surface of the monofilament expand, and said silicon ceramic finely divided particles diffuse and are solid-dissolved in the expanded micelles. The resulting wool fiber in washed with water, thereafter when the wool fiber is left under a constant environment, the extreme end portions of the expanded micelles close, so that the ceramic particles are firmly enveloped therein.
  • ! Fig. 1 is a scanning electron micrograph showing a state where ceramic particles are solid-dissolved in micelles of wool fiber, and from which a situation where the white ceramic particles are solid-dissolved in stratified micelles in the surface of the wool fiber is well understood.
  • Since this wool fiber has solid-dissolved ceramic having a very high porosity (for example, 90% or more), it is excellent in its thermal insulating properties. More specifically, yarn consisting of a solid such as the porous silicon ceramic and gas as in the present invention reduces not only such conduction and heat transfer propagating through the fiber itself, but also heat transfer and radiating heat transmission between the fiber and space. Thus, the yarn has very excellent thermal insulating properties, so that clothing and the like fabricated from such wool fiber as described above does not absorb heat from the outside.
  • Furthermore, ceramic having a high porosity adsorbs easily moisture due to capillarity of pores in the ceramic, and such ceramic is sensitive to moisture absorption from the outside, so that the ceramic existing inside the micelles makes moisture absorption easy. Hence, the ceramic absorbs rapidly, in turns, moisture in the core inside the cortex of wool so that a moisture content of the wool main body is elevated. This moisture content tends to adapt to the outer environment as natural characteristic features of wool. When the environment dries, environmental adaptability is added to wool characteristic features by releasing moisture to the surface of the wool.
  • This means that applications of wool for summer clothing which have never been established become possible.
  • As described above, a sweater made from the ceramic wool has superior water absorption properties than those of conventional wool manufactured goods.
  • Furthermore, since ceramic has a crystalline structure of cubic or hexagonal system type and the like, when a part of the ceramic existing in micelles protrudes from the surface of the wool, coefficient of friction thereof becomes larger than that of original wool as a whole, and as a result, the touch of such wool becomes like hemp.
  • Moreover, ceramic exhibits various characteristic features dependent upon ingredients thereof. In this connection, translucent ceramic being transparent in infrared region exhibits high selective absorption with respect to infrared rays. For instance, when a metallic oxide (MgO ceramics, Sio2 ceramics, Aℓ2O3 ceramics or the like) is allowed to exist in fiber, an article to be heated (for example, human body and the like) is irradiated with far infrared rays (25 - 10 µm) being a kind of electromagnetic wave and exhibiting high thermal action from the outer environment through said translucent ceramic as thermal energy.
  • Accordingly, when such wool fiber containing the present ceramic exists on the surface of a human body, it is possible to absorb outer thermal energy. Next, in case of synthetic fiber, more specifically, when polyester fiber is treated with a processing solution prepared by solid-dissolving a disperse dye wherein a dispersant is added under the above-mentioned condition while heating and pressurizing the same to immerse the synthetic fiber, molecular spacing defined between molecules on the surface of the synthetic fiber expands, and dye molecules of the disperse dye of ultrafine particles diffuses into said spacing, and as a result the spacing is closed as mentioned above to solid-dissolve the disperse dye.
  • Thus, such synthetic fiber in which a disperse dye is solid-dissolved as described above can provide a stable dyed fiber which has not been heretofore.
  • The finely divided particles-containing fiber and the process for preparing the same according to the present invention are not limited to the above described embodiments, but any fiber gaps of which existing on the surface of the fiber may be expanded and finely divided particles may be solid-dissolved as well as the process for preparing the same are involved in the present invention. Therefore, the present invention can provide fiber having characteristic features which have never heretofore been dependent on combinations of a type of fiber and that of finely divided particles.
    • INDUSTRIAL APPLICABILITY
  • As described above, the finely divided particles-containing fiber and the process for preparing the same according to the present invention selects and adds arbitrarily characteristic features involved in the finely divided particle without damaging characteristic features of an original fiber. Moreover, the process for the preparation according to the present invention is useful for preparing the fiber having characteristic features to be added, and particularly it is suitable for solid-dissolving ceramic finely divided particles in natural fiber.

Claims (2)

  1. (1) Fiber containing finely divided particles characterized by containing fibers, gaps involved in said fibers or cuticle portions piled up on the surface of said fibers;
    allowing finely divided particles having a smaller diameter than that of the following expanded space to contain in said expanded space region which is formed by expanding said gaps or an end of said cuticle portions, such contained finely divided particles being closed by means of said gaps or cuticle portions.
  2. (2) A process for preparing fiber containing finely divided particles characterized by immersing fiber in a processing solution in which finely divided particles are incorporated and heating and pressurizing the processing solution to expand gaps existing on the surface of said fiber or cuticle portions, and
    diffusing said finely divided particles in said expanded portions and leaving said fiber in a constant condition, whereby the expanded portions are closed.
EP19870903430 1987-01-27 1987-05-28 Fine particle-containing fibers and process for their production Withdrawn EP0300041A4 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP16673/87 1987-01-27
JP1667387 1987-01-27

Publications (2)

Publication Number Publication Date
EP0300041A1 true EP0300041A1 (en) 1989-01-25
EP0300041A4 EP0300041A4 (en) 1990-09-12

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP19870903430 Withdrawn EP0300041A4 (en) 1987-01-27 1987-05-28 Fine particle-containing fibers and process for their production

Country Status (3)

Country Link
EP (1) EP0300041A4 (en)
AU (1) AU620018B2 (en)
WO (1) WO1988005477A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3891274T1 (en) * 1988-03-28 1990-04-05 J F Corp Kk FIBER CONTAINING CERAMICS AND A METHOD FOR THE PRODUCTION THEREOF
EP0364582A1 (en) * 1988-03-28 1990-04-25 Kabushiki Kaisha J.F. Corporation Ceramic-containing fiber and process for preparing the same
EP0417789A2 (en) * 1989-09-14 1991-03-20 Tadao Isshiki Animal fiber for use as wadding
WO2002014409A1 (en) * 2000-08-14 2002-02-21 Henkel Kommanditgesellschaft Auf Aktien Adhesive activated polymer fibre and preparation for the production thereof

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5049159A (en) * 1988-06-23 1991-09-17 Kohjin Co., Ltd. Deodorizing material and process for producing the same: cellulose fibers treated with copper hydroxide or zinc hydroxide colloid solution

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB313771A (en) * 1928-06-29 1929-06-20 Woldemar Fedorowitsch Haberkor Improvements in or relating to water-proofing, more especially for wool and silk goods
US3173803A (en) * 1961-02-06 1965-03-16 Deering Milliken Res Corp Shrink resistance of wool by coating with fibrous boehmite

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57192995U (en) * 1981-05-29 1982-12-07
MX169225B (en) * 1984-09-17 1993-06-24 Eltech Systems Corp COMPOSITE OF NON-ORGANIC FIBERS / POLYMER METHOD FOR PREPARING IT AND USING IT, INCLUDING A DIMENSIONALLY STABLE SEPARATOR
DE3443327C1 (en) * 1984-11-28 1985-09-05 Rosorius, Gerhard, 2085 Quickborn Process for improving the properties of textiles consisting of or containing native vegetable or animal fibers
JPH01246469A (en) * 1988-03-28 1989-10-02 J F Corp:Kk Ceramic-containing fiber and production thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB313771A (en) * 1928-06-29 1929-06-20 Woldemar Fedorowitsch Haberkor Improvements in or relating to water-proofing, more especially for wool and silk goods
US3173803A (en) * 1961-02-06 1965-03-16 Deering Milliken Res Corp Shrink resistance of wool by coating with fibrous boehmite

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of WO8805477A1 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3891274T1 (en) * 1988-03-28 1990-04-05 J F Corp Kk FIBER CONTAINING CERAMICS AND A METHOD FOR THE PRODUCTION THEREOF
EP0364582A1 (en) * 1988-03-28 1990-04-25 Kabushiki Kaisha J.F. Corporation Ceramic-containing fiber and process for preparing the same
EP0364582A4 (en) * 1988-03-28 1991-07-17 J F Corp Kk Ceramic-containing fiber and process for preparing the same
GB2224756B (en) * 1988-03-28 1992-03-04 J F Corp Kk Ceramic-containing fiber and process for preparing the same
EP0417789A2 (en) * 1989-09-14 1991-03-20 Tadao Isshiki Animal fiber for use as wadding
EP0417789A3 (en) * 1989-09-14 1992-11-25 Tadao Isshiki Animal fiber for use as wadding
WO2002014409A1 (en) * 2000-08-14 2002-02-21 Henkel Kommanditgesellschaft Auf Aktien Adhesive activated polymer fibre and preparation for the production thereof

Also Published As

Publication number Publication date
EP0300041A4 (en) 1990-09-12
AU7435587A (en) 1988-08-10
AU620018B2 (en) 1992-02-13
WO1988005477A1 (en) 1988-07-28

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