EP0292910A2 - Composition de nettoyage pour surfaces dures - Google Patents

Composition de nettoyage pour surfaces dures Download PDF

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Publication number
EP0292910A2
EP0292910A2 EP88108207A EP88108207A EP0292910A2 EP 0292910 A2 EP0292910 A2 EP 0292910A2 EP 88108207 A EP88108207 A EP 88108207A EP 88108207 A EP88108207 A EP 88108207A EP 0292910 A2 EP0292910 A2 EP 0292910A2
Authority
EP
European Patent Office
Prior art keywords
composition
soap
amount
fatty acid
ranges
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP88108207A
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German (de)
English (en)
Other versions
EP0292910B1 (fr
EP0292910A3 (en
Inventor
Pierre Fonsny
Nicole Andries
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Colgate Palmolive Co
Original Assignee
Colgate Palmolive Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Colgate Palmolive Co filed Critical Colgate Palmolive Co
Publication of EP0292910A2 publication Critical patent/EP0292910A2/fr
Publication of EP0292910A3 publication Critical patent/EP0292910A3/en
Application granted granted Critical
Publication of EP0292910B1 publication Critical patent/EP0292910B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2075—Carboxylic acids-salts thereof
    • C11D3/2079—Monocarboxylic acids-salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0013—Liquid compositions with insoluble particles in suspension
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/37—Polymers
    • C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • This invention relates to liquid, aqueous, stable, effective, safe, non-scratching hard surface cleaning compositions commonly referred to as scouring cleansers.
  • the compositions are physically stable, do not separate, whereby the user is assured of the optimum performance to be expected from the various components and their amounts and ratios with respect to one another, are safe and do not scratch the usual surfaces to be cleaned, such as glass, porcelain, ceramic, plastic, metal, wood, painted wood (enamelled and lacquered).
  • U.S. Patent 4,005,027 describes compositions which include clay and insoluble abrasive. Only inorganic abrasives are shown. The compositions include surfactants which are bleach stable. Nonionics are not used. It is alleged that the products are physically stable and also do not "appreciably run along vertical surfaces" (column 10, lines 45-47). Such stability is a manifestation of a false body fluid formed when using the smectite and attapulgite clays necessary in such composi­tions. In U.S. Patent 4,116,849 the compositions are very similar to those in U.S. Patent 4,005,027. In addition, U.S.
  • Patent 4,116,849 discloses thickening agents instead of the preferred smectite and attapulgite clays, such as colloidal silica, polystyrenes, sulfonated polystyrenes, polyethylene, oxidized polyethylenes, polypropylene, copolymers of styrene with methacrylic acid, methyl or ethyl acrylate, vinyl acetate, among others; patentee states that "...ethoxylated nonionic surfactants are to be avoided.” Neither of these two patents disclose soaps or fatty acids as suitable materials as well.
  • U.S. Patent 4,240,919 describes compositions of multivalent stearate soap, water and water-insoluble abrasive.
  • abrasives are disclosed and among the “organic” types are “melamine, urea formaldehyde resins, ground rigid polymeric materials, such as polyurethane foam." (column 3, lines 10-12).
  • substantially any surfactant materials which are compatible with the other components in the composition of the present invention. These include water-soluble anionic, nonionic, amphoteric, cationic and zwitterionic surfactants.” (column 3, lines 57-62). Further reference is made to U.S.
  • Patents 4,051,056 (expanded perlite as abrasive), 4,457,856 (polyacrylate abrasive), German 1,956,616 (polyvinyl chloride as abrasive), 3,645,904 (skin cleanser containing polymer abrasive material) and 4,302,347.
  • a composition manifesting the optimum desiderata for a non-scratching, stable, effective and safe aqueous scouring cleanser has eluded the art.
  • the ability to remove most stains from all normally encountered hard surfaces and particularly plastic surfaces without damaging such delicate plastic materials as one might find as, for example, kitchen counter tops, anti-­stick coatings on metal pots, polystyrene, polymethyl methacrylate, polyvinyl chloride, nylon, polyester (e.g. fiberglass) and the like articles is the major thrust of this invention.
  • the composition should have good degreasing characteristics as well. Physical stability as demonstrated by the prior art cited above is a major problem and for good consumer acceptability is a must.
  • liquid non-scratching, aqueous, scouring cleansing composition comprises a fatty acid and/or fatty acid soap, non-soap anionic surfactant, nonionic surfactant, electrolyte and particulate abrasive.
  • the fatty acid component may be any fatty acid having a carbon chain of from about C6-C30 with C8-C20 preferred. Most preferred are C10-C18 and typically, naturally occuring materials, such as coconut oil, palm kernel oil, and animal tallow, serve admirably as sources for the fatty acids. A particularly preferred range of fatty acids is C12-C18 as one would find in coconut oil. A typical coconut oil fatty acid composition contains about 50% C12: 20% C14; 8.5% C16; and 10% C18 the balance other acid and even perhaps some neutral material, and is a liquid at 40°C.
  • the soaps used are the alkali metal and ammonium salts with sodium and potassium preferred.
  • the fatty acid may comprise from about 0.5 to 15% by weight and preferably 1 to 10% and, more preferably 1 to 7% of the compo­sition.
  • the non-stop anionic may be chosen from any of the conventional anionics, such as the alkyl benzene sulfonates, the alkyl sulfates, alcohol sulfates, the alcohol ether sulfates, olefin sulfonates, paraffin sulfonates, fatty acid monoglyceride sulfates, sarcosides, taurides and the like and their salts, such as alkali, alkaline, earth and ammonium salts. Of these, the sulfates and sulfonates are preferred.
  • the preferred non-soap anionic surfactants are the paraffin sulfonates (C10-C20); the linear alkyl benzene sulfonates, the alcohol and the alcohol ether sulfates.
  • the most preferred anionics are the C12-C18 paraffin sulfonates in the form of their alkali metal or ammonium salts; C8-C20 alkyl benzene sulfonates with C12-C16 being most highly preferred; the alkyl (i.e. alcohol) sulfates of C12-C18 and the corresponding ether sulfates with 3 to 50 (e.g. 3, 5, 10, 20, 30 or 50) moles of condensed ethylene oxide.
  • the most preferred salt forming cation is sodium.
  • the amount of the non-soap anionic may range from 1 to 15% by weight, preferably 1 to 10% and more preferably 1 to 5% by weight.
  • anionics are sodium lauryl sulfate, sodium paraffin (C14-C17) sulfonate, sodium decyl sulfate, sodium tridecyl sulfonate, sodium tallow alkyl sulfate, sodium coconut alkyl sulfate, sodium oxotridecyl-­(triethoxyl) [sulfate (sulfated - 3 E.O.
  • the nonionic surfactants which are usable herein are generally characterized by a long chain hydrophobe and a poly­(ethylene oxide) hydrophilic chain.
  • the hydrophobe may and preferably is from an alcohol (C6-C30, preferably C8-C18; most preferably C10-C16, typically a C13 alcohol, such as linear tridecyl alcohol), or a polypropylene backbone.
  • Other hydrophobes such as thioalcohols, acids, amines and the like, may also be used.
  • the preferred alcohol is a C10-C16 alcohol with 1 to less than 5 moles of ethylene oxide and most preferably 2 to 4 moles of ethylene oxide, typically 3 moles of ethylene oxide.
  • the level of nonionic in the formulation may vary from about 0.5% to about 15% by weight with preferred levels ranging from 1 to 10% and most preferred from about 3.5 to 6.5% typically and most highly preferred is 5%.
  • the electrolyte used herein is typically an alkaline, builder-type inorganic or organic salt.
  • the usual salts comprise the alkali metal bicarbonates, borates, carbonates, phosphates, polyphosphates and silicates among the inorganics and the polycarboxylates, such as polyacetates, tartrates, citrates, maleates, oxydiacetates, alkenyl succinates, carboxymethyloxy succinates, oxydisuccinates and the like, among the organics.
  • Polymeric builder salts such as the water-soluble salts of polymers of maleic acid, itaconic acid and the like, may be used as well as copolymers and interpolymers thereof with polymerizable ⁇ , ⁇ -ethylenically unsaturated compounds, such as vinyl ethers, esters, alkyl alcohol, acrylic and methacrylic acid and esters thereof, etc.
  • the electrolyte may vary over a considerable range from as little as 0.5% to 25% or more.
  • a preferred range is from about 2% to 15%; typically a mixture of carbonate and phosphate may total 5 to 10%; other convenient and preferred mixtures may comprise carbonate, polyphosphate and optionally some silicate in amounts of from 5 to 10% as well.
  • Specific electrolytes include sodium and potassium carbonate, sodium and potassium bicarbonate, sodium and potassium sesquicarbonate, sodium and potassium orthophosphates, pyro­phosphates, tripolyphosphate and hexametaphosphates, sodium and potassium tetraborate anhydrous, pentahydrate, decahydrate, sodium silicate (e.g. sodium metasilicate or other silicates with the Na2O to SiO2 ratio ranging from 3.5 to 1 to 1:1) as illustrative of the inorganics and ethylenediamine tetraacetic acid tetrasodium or potassium salt, trisodium nitrilotriacetate, disodium polymaleate, and the like, as merely illustrative of the organics.
  • sodium silicate e.g. sodium metasilicate or other silicates with the Na2O to SiO2 ratio ranging from 3.5 to 1 to 1:1
  • the abrasive may be any material derived from a polymeri­zable composition, such as polyethylene, polypropylene, poly­styrene, polyester, polyvinyl chloride, polyvinyl acetate, polymethyl methacrylate and various copolymers and interpolymers of the foregoing.
  • the criteria for suitability are that the material does not scratch polymethyl methacrylate and that the average particle size ranges from about 10 to 150 microns and preferably from 25 to 100 microns and most preferably from 30 to 75 microns, e.g. 60 microns.
  • a polyvinyl chloride abrasive powder whose average particle size is about 60 microns, with a major amount being within the range of 30 to 75 microns.
  • the molecular weight ranges of the polymeric abrasives may vary widely just so long as the physical properties set out above are met. Generally, milecular weights will range from several thousand (e.g. 2,000; 5,000; 20,000) to several hundred thousand (e.g. 125,000; 250,000; 400,000) and upwards of several million (e.g. 1,000,000; 2,000,000; 4,000,000; 6,000,000).
  • the amount of abrasive may range from about 2% to 30% or more (e.g. 40%; 50%).
  • a preferred range in the preferred formulations is from 5 to 25% and more preferred is a range of 5 to 15%, such as 7%; 10%; or 12%.
  • a large variety of optional ingredients may be included in the formulations of this invention. Some are even preferred, such as inorganic viscosity modifiers (e.g. montmorillonite clays, such as bentonite; attapulgites, etc.); organic ones, such as methylcellulose, carboxyl methylcellulose, hydroxy propylmethylcellulose. Such materials are particularly advan­tageous for a "cream” scouring cleanser where a "thickened” type of material is desired by the consumer. For such products it may be desirable to have viscosities ranging from several hundred (250 cps; 400 cps; 500 cps) to several thousand (e.g. 1,100 cps; 1,500 cps; 2,000 cps, etc.).
  • inorganic viscosity modifiers e.g. montmorillonite clays, such as bentonite; attapulgites, etc.
  • organic ones such as methylcellulose, carboxyl methylcellulose, hydroxy propy
  • the formulations of this invention exhibit unusual stability (i.e. lack of or minimum phase separation) in the absence of the viscosity "elevators," their major function as mentioned above to merely thicken.
  • the amount of the viscosity modifier may range from about 0.1 to 5 to 10%; usually 0.5 to 3%.
  • Other optional but, again, preferred additives include a hydrocarbon material, particularly a terpene, such as d-limonene. Such terpenes are readily available in many perfume materials which are generally added to most consumer cleaning products.
  • the amount of the hydrocarbon may vary from 0.05 to 5% and preferably from 0.1 to 2 to 3%.
  • Other additives which may be used include bleaches (liquid and solid hypochlorites, available, e.g.
  • auxiliary materials as NaOCl solution or calcium hypochlorite powder; chloramines, chlorinated di- and trisodium phosphates, sodium and potassium dichlorisocyanurate, trichlorocyanuric acid, and so forth); buffers, caustic soda; caustic potash; suds boosters; enzymes; preservatives; disinfectants; colorants; fragrances and the like, may be used where desired and compatible. Generally, minor amounts of such auxiliary materials are employed, e.g. 0.01 to 10% and often 0.1% to 5%.
  • compositions of this invention are alkaline and generally have a pH from about 10 to 12. It is generally preferred to add in the formulations the fatty acid in free acid form and neutralize in situ with caustic soda (NaOH) or caustic potash (KOH), at the same time adjusting the pH to the desired level.
  • CaOH caustic soda
  • KOH caustic potash
  • compositions of this invention are generally prepared by adding to the formula weight of hot water with stirring in a suitable mixer and homogenizer (at a temperature of about 50 to 80°C, e.g. 60°C) the following composition in the order given: fatty acid, nonionic, viscosity modifier (if used), abrasive polymer particles, and alkali for neutralization of fatty acid; at this point the temperature of the mixture is lowered to about room temperature and then the electrolyte (e.g.
  • composition is prepared in the manner described previously as preferred. To the formula weight of water at 60°C are added the fatty acid, nonionic, clay, abrasive and caustic potash with vigorous stirring. After a uniform mixture is obtained, it is cooled to room temperature (20°C) and the remaining components (in the order listed) are added with stirring. A creamy, stable product results; the pH is about 11 and the viscosity is about 1,100 cps.
  • Example I is repeated except that the following fatty acids are used in place of 2% distilled coconut fatty acid:
  • Example I is repeated using 5% sodium lauryl sulfate in place of the sodium paraffin sulfonate.
  • Examples I and III are repeated separately replacing the TKPP and K2CO3 with 4% soda ash (anhydrous Na2CO3).
  • Example I The product of Example I is used in a standarized test procedure to determine the degree of scratching against a plastic surface. This is compared with two commercial products.
  • the procedure involves the use of a reciprocating moving sponge (spontex) containing 1 g of test product which is applied to a plastic tile and after 200 strokes the plastic tile is washed and the gloss is compared with that of the original.
  • the tile used has an initial gloss reading of 79 and this is unchanged after the test with the product of Example I.
  • the two commercial products gave readings of 72 and 73 demonstrating thereby some damage to the tile by the commercial materials and none by the composition of this invention.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Fluid-Pressure Circuits (AREA)
EP88108207A 1987-05-28 1988-05-21 Composition de nettoyage pour surfaces dures Expired - Lifetime EP0292910B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US5497487A 1987-05-28 1987-05-28
US54974 1987-05-28

Publications (3)

Publication Number Publication Date
EP0292910A2 true EP0292910A2 (fr) 1988-11-30
EP0292910A3 EP0292910A3 (en) 1990-03-28
EP0292910B1 EP0292910B1 (fr) 1994-12-28

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP88108207A Expired - Lifetime EP0292910B1 (fr) 1987-05-28 1988-05-21 Composition de nettoyage pour surfaces dures

Country Status (6)

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EP (1) EP0292910B1 (fr)
AU (1) AU609482B2 (fr)
CA (1) CA1315636C (fr)
DE (1) DE3852571T2 (fr)
DK (1) DK293188A (fr)
NO (1) NO172592C (fr)

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0346994A2 (fr) * 1988-06-13 1989-12-20 Unilever N.V. Compositions détergentes liquides
EP0372427A2 (fr) * 1988-12-02 1990-06-13 Kao Corporation Composition détergente
EP0415395A2 (fr) * 1989-08-30 1991-03-06 Dow Corning Corporation Dispersions aqueuses nettoyantes utilisant des poudres polymériques adsorbantes et procédé pour leur utilisation
WO1991010718A1 (fr) * 1990-01-20 1991-07-25 Henkel Kommanditgesellschaft Auf Aktien Produits de nettoyage desemulsifiants et application
WO1992020776A1 (fr) * 1991-05-15 1992-11-26 Eftichios Van Vlahakis Composition de savon liquide pour les mains
WO1997039099A1 (fr) * 1996-04-12 1997-10-23 Reckitt & Colman Inc. Compositions de nettoyage stables contenant un agent blanchissant et des abrasifs doux
WO2003018737A1 (fr) * 2001-08-31 2003-03-06 Hydro Particles As Utilisation de particules polymeres spheriques et monodispersees dans des produits de nettoyage, et produits de nettoyage
EP1321514A1 (fr) * 2001-12-21 2003-06-25 Maclean S.A. Détergent liquide à action récurante contenant du polyéthylène particulaire
WO2004035720A1 (fr) 2002-10-16 2004-04-29 Henkel Kommanditgesellschaft Auf Aktien Produit de nettoyage abrasif transparent, notamment produit de nettoyage de vaisselle a la main
GB2398571A (en) * 2003-02-22 2004-08-25 Reckitt Benckiser Inc Acidic hard surface cleaning and/or disinfecting composition
US7119055B2 (en) 2001-08-31 2006-10-10 Reckitt Benckiser Inc. Hard surface cleaners comprising a thickening gum mixture
US7196046B2 (en) 2001-08-31 2007-03-27 Reckitt Benckiser Inc. Hard surface cleaner comprising a suspension of alginate beads
US7256167B2 (en) * 2001-08-31 2007-08-14 Reckitt Benckiser Inc. Hard surface cleaner comprising suspended particles and oxidizing agent
US7288512B2 (en) 2003-02-22 2007-10-30 Reckitt Benckiser Inc. Hard surface cleaning compositions comprising suspended alginate inclusions
US7291586B2 (en) 2003-02-22 2007-11-06 Reckitt Benckiser Inc. Hard surface cleaning compositions comprising suspended alginate inclusions
EP1965930A2 (fr) * 2005-12-30 2008-09-10 Lam Research Corporation Procédé et système d utilisation d un composé de nettoyage de substrat en deux phases
EP2035537A4 (fr) * 2006-05-26 2010-07-14 Gs Dev Ab Compartiment de lave-vaisselle pour lave-vaisselle à granules
EP3040408A1 (fr) * 2014-12-31 2016-07-06 Hayata Kimya Sanayi Anonim Sirketi Compositions de nettoyage liquide aqueux comprenant un agent de blanchiment et des particules abrasives
FR3046061A1 (fr) * 2015-12-23 2017-06-30 Oreal Composition comprenant deux acides gras neutralises, differents l'un de l'autre, et une argile particuliere
CN115975735A (zh) * 2022-12-28 2023-04-18 宁波坚锋新材料有限公司 一种用于废弃hips的塑料清洗剂

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4678596A (en) * 1986-05-01 1987-07-07 Rohm And Haas Company Rinse aid formulation
US20050176614A1 (en) 2002-10-16 2005-08-11 Heinz-Dieter Soldanski Transparent abrasive cleaning product, especially manual dishwashing liquid

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1534680A (en) * 1977-10-14 1978-12-06 Colgate Palmolive Co Cleaning compositions
EP0063472A2 (fr) * 1981-04-20 1982-10-27 Alcon Laboratories, Inc. Composition de nettoyage pour des surfaces optiques et procédé pour nettoyer une lentille de contact
US4655957A (en) * 1984-06-25 1987-04-07 Bausch & Lomb Incorporated Contact lens cleaning composition with polymeric beads
GB2181738A (en) * 1985-10-16 1987-04-29 Kao Corp Liquid abrasive detergent composition

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4240919A (en) * 1978-11-29 1980-12-23 S. C. Johnson & Son, Inc. Thixotropic abrasive liquid scouring composition

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1534680A (en) * 1977-10-14 1978-12-06 Colgate Palmolive Co Cleaning compositions
EP0063472A2 (fr) * 1981-04-20 1982-10-27 Alcon Laboratories, Inc. Composition de nettoyage pour des surfaces optiques et procédé pour nettoyer une lentille de contact
US4655957A (en) * 1984-06-25 1987-04-07 Bausch & Lomb Incorporated Contact lens cleaning composition with polymeric beads
GB2181738A (en) * 1985-10-16 1987-04-29 Kao Corp Liquid abrasive detergent composition

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0346994A2 (fr) * 1988-06-13 1989-12-20 Unilever N.V. Compositions détergentes liquides
EP0346994B1 (fr) * 1988-06-13 1996-03-06 Unilever N.V. Compositions détergentes liquides
EP0372427A2 (fr) * 1988-12-02 1990-06-13 Kao Corporation Composition détergente
EP0372427A3 (fr) * 1988-12-02 1991-07-03 Kao Corporation Composition détergente
EP0415395A2 (fr) * 1989-08-30 1991-03-06 Dow Corning Corporation Dispersions aqueuses nettoyantes utilisant des poudres polymériques adsorbantes et procédé pour leur utilisation
EP0415395A3 (en) * 1989-08-30 1991-07-17 Dow Corning Corporation Aqueous cleaning dispersions using adsorptive polymeric powder and method of using
WO1991010718A1 (fr) * 1990-01-20 1991-07-25 Henkel Kommanditgesellschaft Auf Aktien Produits de nettoyage desemulsifiants et application
WO1992020776A1 (fr) * 1991-05-15 1992-11-26 Eftichios Van Vlahakis Composition de savon liquide pour les mains
WO1997039099A1 (fr) * 1996-04-12 1997-10-23 Reckitt & Colman Inc. Compositions de nettoyage stables contenant un agent blanchissant et des abrasifs doux
US5821214A (en) * 1996-04-12 1998-10-13 Reckitt & Colman Inc. Stable bleach-containing cleansing compositions with soft abrasives
AU718606B2 (en) * 1996-04-12 2000-04-20 Reckitt Benckiser Inc. Stable bleach-containing cleansing compositions with soft abrasives
WO2003018737A1 (fr) * 2001-08-31 2003-03-06 Hydro Particles As Utilisation de particules polymeres spheriques et monodispersees dans des produits de nettoyage, et produits de nettoyage
US7196046B2 (en) 2001-08-31 2007-03-27 Reckitt Benckiser Inc. Hard surface cleaner comprising a suspension of alginate beads
US7119055B2 (en) 2001-08-31 2006-10-10 Reckitt Benckiser Inc. Hard surface cleaners comprising a thickening gum mixture
US7256167B2 (en) * 2001-08-31 2007-08-14 Reckitt Benckiser Inc. Hard surface cleaner comprising suspended particles and oxidizing agent
EP1321514A1 (fr) * 2001-12-21 2003-06-25 Maclean S.A. Détergent liquide à action récurante contenant du polyéthylène particulaire
WO2004035720A1 (fr) 2002-10-16 2004-04-29 Henkel Kommanditgesellschaft Auf Aktien Produit de nettoyage abrasif transparent, notamment produit de nettoyage de vaisselle a la main
GB2398571A (en) * 2003-02-22 2004-08-25 Reckitt Benckiser Inc Acidic hard surface cleaning and/or disinfecting composition
US7186676B2 (en) 2003-02-22 2007-03-06 Reckitt Benckiser Inc. Hard surface cleaning compositions comprising alginate materials and xanthan gum
US7288512B2 (en) 2003-02-22 2007-10-30 Reckitt Benckiser Inc. Hard surface cleaning compositions comprising suspended alginate inclusions
US7291586B2 (en) 2003-02-22 2007-11-06 Reckitt Benckiser Inc. Hard surface cleaning compositions comprising suspended alginate inclusions
EP1965930A2 (fr) * 2005-12-30 2008-09-10 Lam Research Corporation Procédé et système d utilisation d un composé de nettoyage de substrat en deux phases
EP1965930A4 (fr) * 2005-12-30 2012-09-26 Lam Res Corp Procédé et système d utilisation d un composé de nettoyage de substrat en deux phases
EP2035537A4 (fr) * 2006-05-26 2010-07-14 Gs Dev Ab Compartiment de lave-vaisselle pour lave-vaisselle à granules
EP3040408A1 (fr) * 2014-12-31 2016-07-06 Hayata Kimya Sanayi Anonim Sirketi Compositions de nettoyage liquide aqueux comprenant un agent de blanchiment et des particules abrasives
WO2016118096A1 (fr) * 2014-12-31 2016-07-28 Hayat Kimya Sanayi Anonim Sirketi Compositions aqueuses liquides de nettoyage contenant un agent de blanchiment et des particules abrasives
FR3046061A1 (fr) * 2015-12-23 2017-06-30 Oreal Composition comprenant deux acides gras neutralises, differents l'un de l'autre, et une argile particuliere
CN115975735A (zh) * 2022-12-28 2023-04-18 宁波坚锋新材料有限公司 一种用于废弃hips的塑料清洗剂

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DE3852571T2 (de) 1995-08-17
DK293188D0 (da) 1988-05-27
NO172592C (no) 1993-08-11
DK293188A (da) 1988-11-29
NO882339D0 (no) 1988-05-27
CA1315636C (fr) 1993-04-06
AU609482B2 (en) 1991-05-02
EP0292910B1 (fr) 1994-12-28
EP0292910A3 (en) 1990-03-28
NO882339L (no) 1988-11-29
DE3852571D1 (de) 1995-02-09
NO172592B (no) 1993-05-03
AU1666788A (en) 1988-12-01

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