EP0291859A1 - Matériau anti-ballistique et procédé de fabrication à cet effet - Google Patents

Matériau anti-ballistique et procédé de fabrication à cet effet Download PDF

Info

Publication number
EP0291859A1
EP0291859A1 EP88107653A EP88107653A EP0291859A1 EP 0291859 A1 EP0291859 A1 EP 0291859A1 EP 88107653 A EP88107653 A EP 88107653A EP 88107653 A EP88107653 A EP 88107653A EP 0291859 A1 EP0291859 A1 EP 0291859A1
Authority
EP
European Patent Office
Prior art keywords
cellulose acetate
impregnated
material according
ethyl vinyl
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP88107653A
Other languages
German (de)
English (en)
Inventor
Augusto Alessi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Tat Sas Di Combi Maria Luisa & C
Original Assignee
Tat Sas Di Combi Maria Luisa & C
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from IT20568/87A external-priority patent/IT1204638B/it
Priority claimed from IT8722634A external-priority patent/IT8722634A0/it
Application filed by Tat Sas Di Combi Maria Luisa & C filed Critical Tat Sas Di Combi Maria Luisa & C
Publication of EP0291859A1 publication Critical patent/EP0291859A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/64Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
    • D04H1/645Impregnation followed by a solidification process
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4209Inorganic fibres
    • D04H1/4218Glass fibres
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4209Inorganic fibres
    • D04H1/4242Carbon fibres
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • D04H1/4326Condensation or reaction polymers
    • D04H1/4334Polyamides
    • D04H1/4342Aromatic polyamides
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/58Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
    • D04H1/587Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03Polysaccharides or derivatives thereof
    • D06M15/05Cellulose or derivatives thereof
    • D06M15/07Cellulose esters
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F41WEAPONS
    • F41HARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
    • F41H5/00Armour; Armour plates
    • F41H5/02Plate construction
    • F41H5/04Plate construction composed of more than one layer
    • F41H5/0471Layered armour containing fibre- or fabric-reinforced layers
    • F41H5/0485Layered armour containing fibre- or fabric-reinforced layers all the layers being only fibre- or fabric-reinforced layers

Definitions

  • the present invention concerns a bullet- and splinter- proof material.
  • bonded layers for this purpose each layer consisting of a fabric-type structure (woven or non-woven fabric, loose fibres, for example nylon, carbon or Kevlar, a Dupont registered trademark, or other aromatic polyammides or aramides) which is impregnated or in any event coated with plastic material.
  • a fabric-type structure woven or non-woven fabric, loose fibres, for example nylon, carbon or Kevlar, a Dupont registered trademark, or other aromatic polyammides or aramides
  • plastic material thus far in use there are difficulties in achieving a homogeneous material, as far as ballistic proofing characteristics are concerned, especially when manufacturing large items.
  • the material used up to now has a relatively high unit weight, rendering the items produced too heavy or too bulky. Normally anti-ballistic material is also difficult to form.
  • the aim of the present invention is to provide a material having high ballistic proofing over its entire surface, that also has a low unit weight and is preferably easy to process.
  • the above aims have been achieved with a material consisting of loose fibres, spun products, woven and non-woven fabrics, impregnated or coated with cellulose acetate butyrate or cellulose acetate propionate or ethyl vinyl acetate as such or plasticated or mixed with other resins the content of which is lower than 50%.
  • the above described material is preferably produced by immersing the base layer in a tank containing a solution or a dispersion of the above-mentioned resin and then subjecting it to heat treatment to allow the solvents or the water to evaporate.
  • the amount of product deposited on each layer is adjusted simply by changing the viscosity of the solution or the dispersion or by constantly squeezing the base. In this manner a high degree of evenness is easily achieved in the production of each layer. Heating is preferably carried out in a heated vertical tunnel through which the material is passed, an impregnated product being obtained that feels soft and is therefore easily shaped.
  • the material is heated to a higher temperature, 120-130°C, the result is a semi-rigid impregnated product suitable for flat shapes.
  • the material according to the invention offers a series of advantages. As far as its characteristics are concerned, it has a lower unit weight than other known materials having the same strength, its ballistic proofing is even and remains unchanged by time. As far as its formability is concerned, being produced with a thermoplastic resin the material lends itself to re-shaping and re-forming: all that is required is heating to make the hardened product become plastic again. As regards cost, the production cycle is economical because the process does not involve any critical step, thus it requires only limited supervision.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ceramic Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Laminated Bodies (AREA)
  • Reinforced Plastic Materials (AREA)
EP88107653A 1987-05-18 1988-05-12 Matériau anti-ballistique et procédé de fabrication à cet effet Withdrawn EP0291859A1 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
IT20568/87A IT1204638B (it) 1987-05-18 1987-05-18 Materiale a tenuta balistica e relativo procedimento di produzione
IT2056887 1987-05-18
IT8722634A IT8722634A0 (it) 1987-11-13 1987-11-13 Materiale a tenuta e relativo procedimento di produzione.
IT2263487 1987-11-13

Publications (1)

Publication Number Publication Date
EP0291859A1 true EP0291859A1 (fr) 1988-11-23

Family

ID=26327581

Family Applications (1)

Application Number Title Priority Date Filing Date
EP88107653A Withdrawn EP0291859A1 (fr) 1987-05-18 1988-05-12 Matériau anti-ballistique et procédé de fabrication à cet effet

Country Status (2)

Country Link
EP (1) EP0291859A1 (fr)
IL (1) IL86414A0 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991008895A2 (fr) * 1989-11-06 1991-06-27 Allied-Signal Inc. Article composite blinde presentant un systeme de matrice ameliore
US5196252A (en) * 1990-11-19 1993-03-23 Allied-Signal Ballistic resistant fabric articles
WO2002084202A1 (fr) * 2001-04-12 2002-10-24 E.I. Du Pont De Nemours And Company Article a resistance balistique
US8132494B1 (en) 1989-11-06 2012-03-13 Honeywell International, Inc. Ballistic resistant composite article having improved matrix system

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE541167C (de) * 1930-01-15 1932-01-05 I G Farbenindustrie Akt Ges Celluloseesterlacke zum UEberziehen nicht starrer Unterlagen
EP0169432A1 (fr) * 1984-07-18 1986-01-29 Val. Mehler AG Structure multicouche pour arrêter des projectiles
EP0221794A1 (fr) * 1985-09-27 1987-05-13 Hutchinson S.A. Dispositif de blindage souple et modulaire

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE541167C (de) * 1930-01-15 1932-01-05 I G Farbenindustrie Akt Ges Celluloseesterlacke zum UEberziehen nicht starrer Unterlagen
EP0169432A1 (fr) * 1984-07-18 1986-01-29 Val. Mehler AG Structure multicouche pour arrêter des projectiles
EP0221794A1 (fr) * 1985-09-27 1987-05-13 Hutchinson S.A. Dispositif de blindage souple et modulaire

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5330820A (en) * 1989-07-13 1994-07-19 Alliedsignal Inc. Ballistic resistant composition article having improved matrix system
WO1991008895A2 (fr) * 1989-11-06 1991-06-27 Allied-Signal Inc. Article composite blinde presentant un systeme de matrice ameliore
WO1991008895A3 (fr) * 1989-11-06 1991-09-05 Allied Signal Inc Article composite blinde presentant un systeme de matrice ameliore
US8132494B1 (en) 1989-11-06 2012-03-13 Honeywell International, Inc. Ballistic resistant composite article having improved matrix system
US5196252A (en) * 1990-11-19 1993-03-23 Allied-Signal Ballistic resistant fabric articles
WO2002084202A1 (fr) * 2001-04-12 2002-10-24 E.I. Du Pont De Nemours And Company Article a resistance balistique
US6610617B2 (en) 2001-04-12 2003-08-26 E. I. Du Pont De Nemours And Company Ballistic resistant article
AU2002247444B2 (en) * 2001-04-12 2006-07-06 E.I. Du Pont De Nemours And Company Ballistic resistant article
CN100402968C (zh) * 2001-04-12 2008-07-16 纳幕尔杜邦公司 柔性防弹物品
KR100848453B1 (ko) * 2001-04-12 2008-07-28 이 아이 듀폰 디 네모아 앤드 캄파니 탄도 저항 물품

Also Published As

Publication number Publication date
IL86414A0 (en) 1988-11-15

Similar Documents

Publication Publication Date Title
US2703774A (en) Glass fabric structure and method
US2723935A (en) Sheet material
US2372433A (en) Moldable plastics composition and method of preparing same
US3503784A (en) Smooth surfaced sheet materials and method of manufacturing the same
US5108458A (en) Sizing agent for carbon fiber
US5135591A (en) Process of making a phosphorescent fiber reinforced plastic article
CA2262935A1 (fr) Traitements chimiques de fibres et de fils de base composites enrobes, aux fins de moulage d'articles composites thermoplastiques a fibres renforcees
EP0573534B1 (fr) Procede de depot de poudre pour revetement electrostatique, en vue de produire des stratifies pour plaquettes a circuits imprimes et similaires
US2673824A (en) Process of producing vapor permeable fluid repellent fabrics
US2772995A (en) Leather replacement compositions and process
US2662044A (en) Coated fabrics
GB2168361A (en) Impregnating fibres reinforcement with polymer materials
DE2638792B2 (de) Verfahren zur Herstellung von Kunstleder
US2513268A (en) Glass fiber-resin composite product
EP0324714B1 (fr) Matériel textile plan
EP0291859A1 (fr) Matériau anti-ballistique et procédé de fabrication à cet effet
GB1241382A (en) Method for producing composite sheet substance composed of fibres and elastic materials
US3690911A (en) Process for preparing synthetic suede sheets
WO2010057478A2 (fr) Système composite flexible contenant un matériau à base de fibres de carbone, procédé pour le produire et son utilisation
CN1066417A (zh) 用针刺麻纤维毡制造汽车内饰件
US4010306A (en) Processes for impregnating and coating triaxial weave fabrics
US3962512A (en) Composite laminar structure and relative manufacturing process
ES418585A1 (es) Procedimiento para tratar ulteriormente hilos de poliureta-no.
US2802767A (en) Process of preparing fibrous, non-woven, porous sheets
DE69535124T2 (de) Verbundwerkstoff bestehend aus Kunstleder mit Mikrofasern und einem Kunststofffilm, das Herstellungsverfahren dazu und seine Verwendung zum Auskleiden von geformten Kunststoffartikeln

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH DE ES FR GB GR IT LI NL

17P Request for examination filed

Effective date: 19881005

17Q First examination report despatched

Effective date: 19890612

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN

18D Application deemed to be withdrawn

Effective date: 19900904