EP0237658A1 - Additif pour augmenter le rendement de combustion d'un matériau hydrocarbure liquide ainsi que son procédé de fabrication - Google Patents

Additif pour augmenter le rendement de combustion d'un matériau hydrocarbure liquide ainsi que son procédé de fabrication Download PDF

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Publication number
EP0237658A1
EP0237658A1 EP86301887A EP86301887A EP0237658A1 EP 0237658 A1 EP0237658 A1 EP 0237658A1 EP 86301887 A EP86301887 A EP 86301887A EP 86301887 A EP86301887 A EP 86301887A EP 0237658 A1 EP0237658 A1 EP 0237658A1
Authority
EP
European Patent Office
Prior art keywords
additive
liquid hydrocarbon
hydrocarbon material
alcohol
burning
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP86301887A
Other languages
German (de)
English (en)
Inventor
Ueki Giichi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to EP86301887A priority Critical patent/EP0237658A1/fr
Publication of EP0237658A1 publication Critical patent/EP0237658A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/02Use of additives to fuels or fires for particular purposes for reducing smoke development
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/06Use of additives to fuels or fires for particular purposes for facilitating soot removal
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/12Inorganic compounds
    • C10L1/1233Inorganic compounds oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1616Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy

Definitions

  • the present invention relates to an additive for increasing the rate of burning of a liquid hydrocarbon material, (such as petrol) that contributes greatly to the completeness of burning of the material and to a method of manufacturing such an additive.
  • a liquid hydrocarbon material such as petrol
  • added oxidizer or atomized water enhances the combustion rate by supplying an appropriate additional quantity of oxygen.
  • the present invention sets out to solve the above problems by producing a uniform admixture of a solution containing an organo germanium oxide and alcohols and liquid hydrocarbon materials as well as a surface active agent.
  • the invention consists in an additive for increasing the rate of burning of a liquid hydrocarbon material characterised by comprising a uniform mixture of a solution in water of an organo germanium oxide, at least one liquid alcohol, and liquid hydrocarbon material together with a surface active agent.
  • the liquid hydrocarbon material can be a heating oil or a fuel for a vehicle engine e.g. marine fuel oil, aviation fuel, diesel oil of differing grades or, most especially, leaded or unleaded petrol for automobiles.
  • a heating oil or a fuel for a vehicle engine e.g. marine fuel oil, aviation fuel, diesel oil of differing grades or, most especially, leaded or unleaded petrol for automobiles.
  • the alcohol is preferably an alkanol, and more especially those alcohols of lower molecular weight e.g. the C1 to C6 alkanols, preferably methanol and ethanol.
  • those alcohols of lower molecular weight e.g. the C1 to C6 alkanols, preferably methanol and ethanol.
  • a mixture of a major volume proportion of ethanol and a minor volume proportion of methanol e.g. 80:20 is particularly valuable.
  • a quantity of an organo germanium 32 oxide down to 1mg/l can be effective for the purpose of the invention. As the quantity is increased, it provides a corresponding effect. For practical purposes, however, the quantity may be increased up to 1000mg/l. The range between 50mg/l and 500mg/l is preferred in terms of cost efficiency.
  • the alcohol e.g. 20% of methyl alcohol and 80% of ethyl alcohol
  • the alcohol are preferably present in amounts from 900ml/ld to 300ml/l .
  • the preferred quantity may range from 50ml/l to 400ml/l, and for the surface active agent from 50ml/l and to 300ml/l.
  • the quantity of water is usually sufficient to allow the organo germanium oxide to be dissolved in the water. It may depend upon the quantity of the organic germanium, but usually ranges between 5ml/land 20ml/l.
  • the alcohols are added to increase the affinity of the mixture with the organo germanium.
  • the liquid hydrocarbon material is added to facilitate the admixture of the additive of the invention with the fuel.
  • the surface active agent is provided to improve the diffusion of the accelerator throughout the fuel, thereby allowing it to be mixed with the fuel rapidly and uniformly.
  • the amount of the additive actually to be used depends upon the kind or nature of the fuel. Usually the value of 100 ppm to 1000 ppm provides a satisfactory effect.For gasoline (petrol) to be used in a gasoline engine, an amount of approximately 500 ppm provides the desired effect.
  • the invention provides a method of increasing the rate of burning leaded or unleaded petrol for an automobile characterised in that it involves the essential step of adding to the petrol from 100 to 1000 ppm of the additive as described above.
  • the invention provides a method of manufacture of such an additive characterised in that (a) the organogermanium oxide is dissolved in the water (b) the alcohol or alcohols are added and mixed and (c) the liquid hydrocarbon material and surface active agent are added and uniformly mixed.
  • the organo germanium used in the present invention appears to contribute to reducing the fuel oil particles into finer particles, and thus increases the contact area between the fuel particles and oxygen.
  • the active oxygen contained in the organo germanium appears to lower the flash or firing point of the fuel,thereby accelerating the burning rate.
  • the additive can also improve the rates of atomizing, vaporization, and diffusion of the fuel.
  • the organo germanium oxide in the additive according to the present invention is easily dissolved in the water, and the resultant solution can uniformly diffuse throughout liquid hydrocarbon material without risk of segregation.
  • organo germanium oxide 100 mg is dissolved in 10ml of water, and 770ml of alcohol (20% v/v of methyl alchol and 80% of ethyl alcohol) is added to the resultant solution while it is being stirred. A uniform mixture is obtained. Then, 100ml of petrol and 100ml of a surface active agent are gradually added to that uniform mixture with stirring. The result is an additive according to the present invention, in an amount of 1000ml.
  • the present invention provides for easy admixture.
  • the additive incorporating the uniform mixture of the organo oxide can rapidly diffuse throughout the fuel whatever its quantity may be.
  • Fuel oil Gas oil No. 1 offered by Esso Oil. Calorie of 10,800: specific gravity of 0.8326.
  • Engine Model 6BD offered by Isuzu Motors Co. Capacity of 5785 c.c Output of 85ps/2100 rpm Maximum torque of 31 kgm/1500 rpm Test mode: conforms with JIS-D-1005

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Liquid Carbonaceous Fuels (AREA)
EP86301887A 1986-03-14 1986-03-14 Additif pour augmenter le rendement de combustion d'un matériau hydrocarbure liquide ainsi que son procédé de fabrication Withdrawn EP0237658A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP86301887A EP0237658A1 (fr) 1986-03-14 1986-03-14 Additif pour augmenter le rendement de combustion d'un matériau hydrocarbure liquide ainsi que son procédé de fabrication

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP86301887A EP0237658A1 (fr) 1986-03-14 1986-03-14 Additif pour augmenter le rendement de combustion d'un matériau hydrocarbure liquide ainsi que son procédé de fabrication

Publications (1)

Publication Number Publication Date
EP0237658A1 true EP0237658A1 (fr) 1987-09-23

Family

ID=8195933

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86301887A Withdrawn EP0237658A1 (fr) 1986-03-14 1986-03-14 Additif pour augmenter le rendement de combustion d'un matériau hydrocarbure liquide ainsi que son procédé de fabrication

Country Status (1)

Country Link
EP (1) EP0237658A1 (fr)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3006142A (en) * 1959-12-21 1961-10-31 Phillips Petroleum Co Jet engine combustion processes
US3491133A (en) * 1964-03-06 1970-01-20 Cities Service Res & Dev Co Metal organo phosphates and amine salts thereof
GB1237581A (en) * 1968-05-17 1971-06-30 Mobil Oil Corp Coordinated complexes of nitrogenous compounds
FR2241610A1 (en) * 1973-08-22 1975-03-21 Svenka Utvecklingsaktiebolaget Hydrocarbon fuels contg. water in micro-emulsion form - and soluble inorganic salts to increase octane ratings
FR2364260A1 (fr) * 1976-09-08 1978-04-07 Ciba Geigy Ag Combinaisons complexes, procede de preparation de ces combinaisons et utilisation de ces combinaisons

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3006142A (en) * 1959-12-21 1961-10-31 Phillips Petroleum Co Jet engine combustion processes
US3491133A (en) * 1964-03-06 1970-01-20 Cities Service Res & Dev Co Metal organo phosphates and amine salts thereof
GB1237581A (en) * 1968-05-17 1971-06-30 Mobil Oil Corp Coordinated complexes of nitrogenous compounds
FR2241610A1 (en) * 1973-08-22 1975-03-21 Svenka Utvecklingsaktiebolaget Hydrocarbon fuels contg. water in micro-emulsion form - and soluble inorganic salts to increase octane ratings
FR2364260A1 (fr) * 1976-09-08 1978-04-07 Ciba Geigy Ag Combinaisons complexes, procede de preparation de ces combinaisons et utilisation de ces combinaisons

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
PATENTS ABSTRACTS OF JAPAN, vol. 5, no. 148 (C-72)[820], 18th September 1981; & JP-A-56 81 393 (NOBORU HIGASHIDE) 03-07-1981 *
PATENTS ABSTRACTS OF JAPAN, vol. 9, no. 192 (C-296)[1915], 8th August 1985; & JP-A-60 63 288 (KITAMURA GOUKIN SEISAKUSHO K.K.) 11-04-1985 *

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