EP0212284A2 - Nichtgewebtes elastisches Plissee - Google Patents

Nichtgewebtes elastisches Plissee Download PDF

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Publication number
EP0212284A2
EP0212284A2 EP86109998A EP86109998A EP0212284A2 EP 0212284 A2 EP0212284 A2 EP 0212284A2 EP 86109998 A EP86109998 A EP 86109998A EP 86109998 A EP86109998 A EP 86109998A EP 0212284 A2 EP0212284 A2 EP 0212284A2
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EP
European Patent Office
Prior art keywords
web
nonwoven
elastic web
nonwoven elastic
fibrous nonwoven
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP86109998A
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English (en)
French (fr)
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EP0212284B1 (de
EP0212284A3 (en
Inventor
Michael Tod Morman
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Kimberly Clark Corp
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Kimberly Clark Corp
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Publication date
Priority claimed from US06/760,445 external-priority patent/US4652487A/en
Priority claimed from US06/760,449 external-priority patent/US4657802A/en
Application filed by Kimberly Clark Corp filed Critical Kimberly Clark Corp
Publication of EP0212284A2 publication Critical patent/EP0212284A2/de
Publication of EP0212284A3 publication Critical patent/EP0212284A3/en
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    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/498—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres entanglement of layered webs
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/56—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving in association with fibre formation, e.g. immediately following extrusion of staple fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/50—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by treatment to produce shrinking, swelling, crimping or curling of fibres
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/559—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving the fibres being within layered webs
    • D—TEXTILES; PAPER
    • D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • D04H1/72—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
    • D04H1/724—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged forming webs during fibre formation, e.g. flash-spinning

Definitions

  • the field of the present invention encompasses a composite nonwoven elastic web which includes a nonwoven elastic web which is joined to a nonwoven gathered web and processes for forming such composite nonwoven elastic webs.
  • the field of the present invention also encompasses processes for forming a gathered nonwoven web exhibiting elastic properties by separating the gathered web from the nonwoven elastic web after gathering has been effected by retraction of the elastic web.
  • U.S. patent 2,957,512 to Wade discloses a method for producing an elastic composite sheet material in which a creped or corrugated flexible sheet material is bonded to, for example, an elastic meltblown material.
  • a fibrous web of elastomeric material may be stretched and bonded to the corrugated web at spaced points or areas and, upon allowing the fibrous elastomeric web to relax, the composite will assume the structure illustrated in Figure 7.
  • U.S. patent 3,316,136 to Pufahl Yet another method for forming a composite elastic fabric is disclosed in U.S. patent 3,316,136 to Pufahl.
  • the preferred method of fabrication of this fabric involves the utilization of an adhesive which is first applied in a predetermined pattern to an elastic backing material and the elastic backing material is then stretched to an elongated state. While the elastic material is in the stretched, elongated state an overlying fabric is placed in contact therewith and held in pressurized engagement with the elastic material for a time period sufficient to insure adhesion of the two layers. Thereafter, upon drying of the applied adhesive, the tension on the elastic backing material is released causing the overlying fabric to gather in the areas outlined by the adhesive.
  • U.S. Patent 3,485,706 to Evans at example 56 discloses the fabrication of an elongatable nonwoven, multilevel patterned structure having elasticity in one direction from an initially layered material.
  • the structure is composed of two webs of polyester staple fibers which have a web of spandex yarn located therebetween.
  • the webs are joined to each other by application of hydraulic jets of water which entangle the fibers of one web with the fibers of an adjacent web.
  • the spandex yarn is stretched 200 percent.
  • U.S. Patent 3,673,026 to Brown discloses a method for manufacturing a laminated fabric and specifically discloses a method for manufacturing a nonwoven laminated fabric of controlled bulk.
  • separate webs of nonwoven material e.g. creped tissue or bonded synthetic fiber
  • the bonded webs are thereafter relaxed so as to produce different degrees of contraction in each web with resultant separation of the webs in the unbonded regions and controlled bulk in the laminate.
  • the differential stretching includes the situation where only one web is actually stretched and the other web is maintained slack or nearly so.
  • U.S. patent 3,687,797 to Wideman discloses a method for producing a resilent cellulosic wadding product obtained by laminating a lower cellulosic wadding web to a prestretched polyurethane foam web.
  • the process involves applying adhesive in a desired pattern to either of the webs with the wadding web then being laminated to the prestretched polyurethane foam web.
  • the foam web is maintained in a stretched condition.
  • the tension on the prestretched polyurethane foam web is released to cause a contraction of the foam web.
  • the adhesive retains the wadding product and foam together while permitting bulking in areas between the adhesive zones. The stresses still remaining in the product after contraction may be further relieved by wetting.
  • U.S. patent 3,842,832 to Wideman is directed to a disposable stretch product such as a bandage and a method for production of the product.
  • the product is manufactured by passing a longitudinally oriented nonwoven material over a roller so as to apply an adhesive to one surface of the nonwoven material.
  • a polyurethane web is heated and longitudinally stretched and adhered to the nonwoven material.
  • a second nonwoven material is adhered to the other surface of the polyurethane web to form a laminate consisting of a stretched inner polyurethane core and outer unstretched nonwoven fabric layers adhered to the core by the adhesive.
  • the laminate is passed through a moistening device which results in a relaxing of the engagement between the nonwoven fabric outer layers and the adhesive connecting the outer layers to the stretched polyurethane core layer. This allows the stretched polyurethane layer to return to substantially its original length which results in the outer nonwoven layers being buckled or undulated to form wrinkles.
  • U.S. patent 4,104,170 to Nedza discloses a liquid filter having an improved extended polypropylene element. Fabrication of the polypropylene element is accomplished by forming a spunbonded underlayer of a continuous polypropylene fiber which adheres to itself as it is laid down in a random pattern. Thereafter, an overlayer of short polypropylene fibers is deposited onto the underlayer by, for example, meltblowing the overlayer onto an extended sheet of the underlayer.
  • a method for producing an elastic cloth structure which includes fibers of a synthetic, organic, relatively elastomeric polymer and fibers of a synthetic, organic, elongatable, but relatively nonelastic polymer is disclosed in U.S. patent 4,209,563 to Sisson.
  • the method includes the steps of forwarding the relatively elastic fibers and elongatable but relatively non-elastic fibers for a well dispersed random lay-down on a porous forming surface of an unbonded web having random fiber crossings.
  • U. S. Patent 4,296,163 to Emi et al. discloses a fibrous composite having a coalcesed assembly of (A) a sheet-like mesh structure composed of fibers of a synthetic elastomeric polymer, the individual fibers of which are interconnected at random in irregular relationship to form a number of meshes of different sizes and shape with the mesh structure having a recovery ratio after 10% stretch of at least 70% in two arbitrarily selected, mutually perpendicular directions on the plane of the mesh structure, and (B) a mat-, web- or sheet-like fiber structure composed of short or long fibers, with the fiber structure having a recovery ratio after 10% stretch of less than 50% in at least one arbitrarily selected direction.
  • the elastic composite is suitable as various apparel based materials and industrial materials such as filter cloths, absorbents, and heat insulating materials. Methods for forming the composite are described at column 6, line 64 et seq. and these methods include spun bonding, see column 9, lines 15 - 41.
  • U.S. patent 4,323,534 to DesMarais discloses an extrusion process for a thermoplastic resin composition for fabric fibers with exceptional strength and good elasticity.
  • meltblowing of a compounded resin comprising 79.13% KRATON G-1652, 19.78% stearic acid, 0.98% titanium dioxide and 0.1% Irganox 1010 antioxident is disclosed. It is stated that individual fibers were extruded from the meltblowing die.
  • U.S. patent 4,355,425 to Jones discloses a panty with a built-in elastic system to minimize gathering and to provide a comfortable, comforming fit and a method for assembling the panty. It is stated that a material made of meltblown KRATON rubber is well suited for the panty fabric material. It is also stated that a process for making meltblown KRATON fabrics is disclosed and shown schematically in figure 8 of the patent. The process which appears to utilize KRATON G-1652 is discussed starting at column 4, line 67 of the patent.
  • U.S. patent 4,379,192 to Wahlquist discloses a method for forming an impervious absorbent barrier fabric embodying film and fibrous webs where one or more meltblowing dies meltblow discontinuous fibers of small diameter as a mat directly on a prebonded web of continuous filaments.
  • meltblowing dies meltblow discontinuous fibers of small diameter as a mat directly on a prebonded web of continuous filaments.
  • U.S. patent 4,426,420 to Likhyani discloses hydraulically entangled spunlaced fabrics composed of a least two types of staple fibers and processes for their formation which include heat treating elastomeric fibers, which behave as ordinary staple fibers until they are heat treated, to impart improved stretch and resilience properties to the fabric.
  • the method includes the steps of drawing a potentially elastomeric fiber and allowing it to relax between the drawing and wind-up steps.
  • U.S. patent 4,446,189 to Romanek discloses a nonwoven textile fabric laminate which includes at least one layer of nonwoven textile fabric which is secured by needle punching to an elastic layer so that the nonwoven layer of textile fabric will be permanently stretched when the elastic layer is drafted within its elastic limits.
  • the elastic layer is allowed to relax and return to substantially its condition prior to being drafted the nonwoven fabric layer is stated to exhibit increased bulk as a result of its concurrent relaxation.
  • the nonwoven textile fabric laminate may be utilized to form wearing apparel which has enhanced freedom of movement.
  • the abstract of Japanese document number 47-43150 discloses a method for producing a nonwoven fabric having high tenacity with the method being carried out by (a) monoaxially stretching a sheet or film made of a mixture of incompatible polymers, (b) laminating this sheet or material with a layer of foamed polymer, (c) stretching the laminate at right angles to the direction of orientation of the substrate and then (d) stretching in the direction orientation of the substrate.
  • Preferred polymers are stated to include polyamides, linear polyesters, and polyolefins.
  • the upper layer is a polypropylene foam.
  • elastic and “elastomeric” are used interchangeably herein to mean any material which, upon application of a biasing force, is stretchable to a stretched, biased length which is at least about 125 percent, that is about one and one quarter, of its relaxed, unbiased length, and which will recover at least about 40 percent of its elongation upon release of the stretching, elongating force.
  • a hypothetical example which would satisfy this definition of an elastomeric material would be a one (1) inch sample of a material which is elongatable to at least 1.25 inches and which, upon being elongated to 1.25 inches and released will recover to a length of not more than 1.15 inches.
  • Many elastic materials may be stretched by much more than 25 percent of their relaxed length and many of these will recover to substantially their original relaxed length upon release of the stretching, elongating force and this latter class of materials is generally preferred for purposes of the present invention.
  • the term "recover” refers to a contraction of a stretched material upon termination of a biasing force following stretching of the material by application of the biasing force. For example, if a material having a relaxed, unbiased length of one (1) inch was elongated 50 percent by stretching to a length of one and one half (1.5) inches the material would have a stretched length that is 150 percent of its relaxed length. If this exemplary stretched material contracted, that is recovered, to a length of one and one tenth (1.1) inches, after release of the biasing and stretching force, the material would have recovered 80 percent (0.4 inch) of its elongation.
  • meltblown microfibers refers to small diameter fibers having an average diameter not greater than about 100 microns, preferably having a diameter of from about 0.5 microns to about 50 microns, more preferably having an average diameter of from about 4 microns to about 40 microns and which are made by extruding a molten thermoplastic material through a plurality of fine, usually circular, die capillaries as molten threads or filaments into a high velocity gas (e.g. air) stream which attenuates the filaments of molten thermoplastic material to reduce their diameter to the range stated above.
  • a high velocity gas e.g. air
  • meltblown microfibers are carried by the high velocity gas stream and are deposited on a collecting surface to form a web of randomly disbursed meltblown microfibers.
  • Such a process is disclosed, for example, in U.S. patent 3,849,241 to Butin and the disclosure of this patent is hereby incorporated by reference.
  • spunbonded microfibers refers to small diameter fibers having a diameter not greater than about 100 microns, preferably having a diameter of from about 10 microns to about 50 microns, more preferably having a diameter of from about 12 microns to about 30 microns and which are made by extruding a molten thermoplastic material as filaments through a plurality of fine, usually circular, capillaries of a spinnerete with the diameter of the extruded filaments then being rapidly reduced as by, for example, eductive drawing or other well known spunbonding mechanisms.
  • the production of spunbonded nonwoven webs is illustrated in U.S. patent 4,340,563 to Appel and the disclosure of this patent is hereby incorporated by reference.
  • nonwoven web includes any web of material which has been formed without use of textile weaving processes which produce a structure of individual fibers which are interwoven in an identifiable repeating manner.
  • specific examples of nonwoven webs would include, without limitation, a meltblown nonwoven web, a spunbonded nonwoven web, an apertured film, a microporous web or a carded web of staple fibers.
  • These nonwoven webs have an average basis weight of not more than about 300 grams per square meter.
  • the nonwoven webs have an average basis weight of from about 5 grams per square meter to about 100 grams per square meter. More preferably, the nonwoven webs have an average basis weight of from about 10 grams per square meter to about 75 grams per square meter.
  • the term "consisting essentially of” does not exclude the present of additional materials which do not significantly affect the elastomeric properties and characteristics of a given composition.
  • Exemplary materials of this sort would include, pigments, anti-oxidants, stabilizers, surfactants, waxes, flow promoters, solid solvents, particulates and materials added to enhance processability of the composition.
  • polystyrenic moiety means a monomeric unit represented by the formula:
  • polymer or “polymer resin” as used herein generally include, but are not limited to, homopolyers, copolymers, such as, for example, block, graft, random and alternating copolymers, terpolymers, etc. and blends and modifications thereof.
  • polymer or “polymer resin” shall include all possible geometrical configurations of the material. These configurations include, but are not limited to, isotactic, syndiotactic and random symmetries.
  • Another general object of the present invention is to provide a new process for forming a composite nonwoven elastic web which includes a nonwoven elastic web joined to a fibrous nonwoven gathered web where the fibrous nonwoven gathered web has been gathered as a result of the fibrous nonwoven gathered web having been directly formed, in a gatherable condition, on a surface of the nonwoven elastic web while the nonwoven elastic web is maintained in a stretched, biased condition and, thereafter, relaxing the nonwoven elastic web from its stretched, biased condition or length to a relaxed, unbiased condition or length.
  • Yet another object of the present invention is to provide a composite nonwoven elastic web which includes a nonwoven elastic web joined to a fibrous nonwoven gathered web where the fibrous nonwoven gathered web is formed, in a gatherable condition, on a surface of the nonwoven elastic web and simultaneously joined thereto.
  • a further object of the present invention is to provide the composite nonwoven elastic webs formed by the processes of the present invention.
  • One other object of the present invention is to provide a new process for forming a gathered nonwoven web possessing elastic characteristics solely from nonelastic materials.
  • Another object of the present invention is to provide a new process for forming a gathered nonwoven elastic web which process includes forming a nonwoven gatherable web directly on a surface of a nonwoven elastic web while the nonwoven elastic web is being maintained in a stretched, biased condition so as to separably join the gatherable web to the nonwoven elastic web and thereafter relaxing the nonwoven elastic web from its stretched, biased condition or length to a relaxed, unbiased condition or length so that the gatherable web is gathered and separating the gathered web from the elastic web to form a gathered web having elastic properties.
  • Yet another object of the present invention is to provide a new process for forming a gathered nonwoven elastic web which process includes forming a gatherable web directly on the surface of an extendable and retractable porous forming surface while the forming surface is being maintained in the extended condition so as to separably join the gatherable web to the extendable and retractable forming surface, retracting the forming surface to gather the gatherable web and thereafter separating the gathered web from the forming surface to form a gathered web having elastic properties.
  • a further object of the present invention is to provide the gathered nonwoven webs possessing elastic characteristics formed by the processes of the present invention.
  • the present invention is directed to a process for producing a composite nonwoven elastic web which is composed of a nonwoven elastic web that is joined to a fibrous nonwoven gathered web.
  • the process of the present invention produces a composite nonwoven elastic web which, in its relaxed, nonstretched state, is composed of a gathered nonwoven fibrous web that is joined to a nonwoven elastic web with the nonwoven elastic web having been relaxed from a stretched, biased length to a relaxed, unbiased, nonstretched length so as to gather the fibrous nonwoven gathered web.
  • An important feature of the process of the present invention is that the fibrous nonwoven gatherable web is formed directly onto a surface of the nonwoven elastic web while the nonwoven elastic web is maintained in a stretched, biased and elongated condition.
  • the nonwoven elastic web may be formed by, for example, a meltblowing process or any other process for forming a nonwoven elastic web.
  • the nonwoven elastic web could be an apertured web of an elastic film as opposed to a meltblown fibrous nonwoven elastic web.
  • the formed nonwoven elastic web has a normal relaxed, nonstretched, nonbiased length. Thereafter, the nonwoven elastic web is elongated by being stretched to a stretched, biased length.
  • a fibrous nonwoven gatherable web may be formed, for example, by either a meltblowing or spunbonding process or any other process for forming a fibrous nonwoven gatherable web, directly upon a surface of the nonwoven elastic web while the nonwoven elastic web is maintained at its elongated, stretched and biased length.
  • the nonwoven elastic web is maintained at a stretched length which is at least about 125 percent, that is at least about one and one quarter of the relaxed, unbiased length of the nonwoven elastic web.
  • the stretched, biased length of the nonwoven elastic web may be maintained in the range of from at least about 125 percent of the relaxed, unbiased length of the nonwoven elastic web to about 700 or more percent of the relaxed, unbiased length of the nonwoven elastic web.
  • the fibrous nonwoven gatherable web is joined to the nonwoven elastic web while the nonwoven elastic web is maintained at its elongated stretched, biased length. This results in the formation of a composite nonwoven elastic web which includes the nonwoven elastic web which is joined to the fibrous nonwoven gatherable web. Because the fibrous nonwoven gatherable web is formed directly onto the surface of the nonwoven elastic web while the nonwoven elastic web is being maintained at its stretched, biased length, the nonwoven elastic web is, at this stage in the process, elongated, stretched and biased and the fibrous nonwoven gatherable web is in an ungathered but gatherable condition.
  • joining of the fibrous nonwoven gatherable web to the nonwoven elastic web is achieved by heat-bonding to fuse the two webs to each other.
  • the heat-bonding may be carried out within the temperature range of from about 50 degrees centrigrade below the melt temperature of at least one of the materials utilized to form at least one of the two webs. At high through-put rates the heat-bonding can be carried out above the melt temperature of one or more of the materials utilized to form the webs.
  • the heat-bonding may also be carried out under appropriate conventional pressurized conditions. If desired, conventional sonic bonding techniques may be substituted for the heat-bonding steps.
  • joining of the fibrous nonwoven gatherable web to the stretched nonwoven elastic web is achieved solely by the entanglement of the individual fibers of the fibrous nonwoven gatherable web with the nonwoven elastic web during formation of the fibrous gatherable web on the surface of the elastic web.
  • the nonwoven elastic web is a fibrous nonwoven elastic web formed by, for example, meltblowing, entanglement of the individual fibers of the fibrous nonwoven gatherable web with the fibrous nonwoven elastic web is achieved by entanglement of the individual fibers of the fibrous gatherable web with the individual fibers of the fibrous elastic web.
  • the nonwoven elastic web is an apertured film, joining of the fibrous nonwoven web with the film is achieved by entanglement of the individual fibers of the fibrous gatherable web within the apertures of the film.
  • the joining of the two webs to each other is achieved by also forming the nonwoven elastic web out of a tacky elastic material.
  • joining of the two webs to each other may be further enhanced by applying pressure to the two webs after the gatherable web has been formed on the surface of the elastic web. Also, in any embodiment, joining of the two webs may be further improved by applying an adhesive material to the upper surface of the nonwoven elastic web prior to formation of the fibrous nonwoven gatherable web thereon.
  • the biasing force is removed from the composite nonwoven elastic web and the composite elastic web is allowed to relax to its normal relaxed, unbiased length. Because the fibrous nonwoven gatherable web is joined to the nonwoven elastic web while the nonwoven elastic web is stretched, relaxation of the composite nonwoven elastic web results in the gatherable web being carried with the contracting nonwoven elastic web and thus being gathered.
  • the composite nonwoven elastic web may be rolled up in rolls for storage and shipment.
  • the composite elastic web may thereafter be utilized to form a wide range of products, such as, for example, an outer cover for a diaper.
  • the gathered nonwoven web may be separated from the nonwoven elastic web subsequent to its being gathered by the retractive forces of the nonwoven elastic web.
  • the gathered nonwoven web can be utilized alone or in conjunction with a variety of other webs or film materials to form numerous different products.
  • the separated gathered nonwoven web retains a sustantial degree of its gathered configuration and also exhibits elastic properties.
  • the gathered nonwoven web may be formed, as discussed above, in a gatherable condition directly onto the surface of the elastic nonwoven web with the elastic nonwoven web being in an extended state.
  • the fibrous nonwoven gatherable web Upon its formation on the surface of the nonwoven elastic web, the fibrous nonwoven gatherable web is separably joined to the nonwoven elastic web while the nonwoven elastic web is maintained at its extended stretched, biased length. This results in the formation of a composite nonwoven elastic web which includes the nonwoven elastic web and the fibrous nonwoven gatherable web with the fibrous nonwoven gatherable web being separably joined to the nonwoven elastic web. Because the fibrous nonwoven gatherable web is formed directly onto the surface of the nonwoven elastic web while the nonwoven elastic web is being maintained at its extended stretched, biased length, the nonwoven elastic web is, at this stage in the process, extended, stretched and biased and the fibrous nonwoven gatherable web is in an ungathered but gatherable condition.
  • the separable joining of the fibrous nonwoven gatherable web to the extended, stretched nonwoven elastic web is achieved by the entanglement of the individual fibers of the fibrous nonwoven gatherable web with the nonwoven elastic web during formation of the fibrous nonwoven gatherable web on the surface of the nonwoven elastic web.
  • the nonwoven elastic web is a fibrous nonwoven elastic web formed by, for example, meltblowing
  • the separable joining of the fibrous nonwoven gatherable web to the fibrous nonwoven elastic web is achieved by entanglement of the individual fibers of the fibrous gatherable web with the individual fibers of the fibrous nonwoven elastic web.
  • the nonwoven elastic web is an apertured film
  • the separable joining of the fibrous nonwoven web with the nonwoven elastic web is achieved by entanglement of the individual fibers of the fibrous gatherable web within the apertures of the apertured film.
  • the biasing force is removed from the composite nonwoven elastic web and the composite elastic web is allowed to contract, due to contraction of the stretched nonwoven elastic web, to its normal contracted, unbiased length. Because the fibrous nonwoven gatherable web is separably joined to the nonwoven elastic web while the nonwoven elastic web is extended and stretched, contraction of the composite nonwoven elastic web results in the gatherable web being carried with the contracting nonwoven elastic web and thus being gathered on the surface of the nonwoven elastic web.
  • the gathered fibrous nonwoven web is separated from the nonwoven elastic web and the gathered web may, for example, be rolled up for storage. After separation of the fibrous nonwoven gathered web from the nonwoven elastic web, the nonwoven elastic web may be reused as a forming surface.
  • the fibrous nonwoven gathered web Upon its separation from the nonwoven elastic web, the fibrous nonwoven gathered web retains a gathered configuration and, upon application of a stretching and biasing force in the direction in which the fibrous nonwoven gatherable web was gathered, the gathered web extends to the extent that the gathers allow. Importantly, upon release of the stretching and biasing force the extended, fibrous nonwoven gathered web contracts substantially to the gathered configuration and length which it possessed after its separation from the nonwoven elastic web. That is, the fibrous nonwoven gathered web exhibits elastic characteristics and properties. The fact that the gathered web, upon its separation from the nonwoven elastic web, retains a gathered configuration is surprising.
  • the separated fibrous nonwoven gathered web upon being stretched to an extended length, exhibits elastic properties such as recovering at least about 40 percent of its elongation. That is, the separated fibrous nonwoven web exhibits elastic or elastomeric properties as defined herein. In fact, it has been found that the fibrous nonwoven gathered web exhibits these elastic properties even when the fibrous nonwoven gathered web was formed from a nonelastic material such as polypropylene.
  • the fibrous nonwoven gatherable web includes at least one meltblown fibrous nonwoven web.
  • Alternative methods which may be utilized in forming the fibrous nonwoven gatherable web include spunbonding or any other process for forming a fibrous nonwoven gatherable web.
  • the gathered fibrous nonwoven web may be formed entirely from one nonelastic material or from a blend of one or more nonelastic materials.
  • the gathered fibrous nonwoven may be formed from blends of one or more nonelastic materials with one or more elastic materials or from one or more elastic materials.
  • Nonelastic materials for forming the fibrous nonwoven gatherable web include nonelastic polyester materials, nonelastic polyolefin materials or blends of one or more nonelastic polyester materials with one or more nonelastic polyolefin materials.
  • An exemplary nonelastic polyester material is polyethylene terephthalate.
  • An examplary nonelastic polyolefin is a nonelastic polypropylene which may be obtained under the trade designation PF 301.
  • the necessity for the elastic nonwoven web can be eliminated by forming the gathered nonwoven web in a gatherable condition directly onto an extensible and contractable surface, such as, for example, an extendable and retractable mesh screen.
  • a tacky fibrous nonwoven elastic web is formed by, for example, meltblowing microfibers of a tacky elastic material such as, for example, an A-B-A' block copolymer or blends of such A-B-A' block copolymers with poly (alpha-methylstyrene) where A and A' are each thermoplastic polystyrene or polystyrene homologue end blocks and B is an elastic polyisoprene midblock.
  • A may be the same thermoplastic polystyrene or polystyrene homologue endblock as A'.
  • the tacky fibrous nonwoven elastic web is then elongated by being stretched to an elongated, stretched length and a fibrous nonwoven gatherable web is formed, for example, by meltblowing or spunbonding the fibrous nonwoven gatherable web, directly upon a surface of the tacky fibrous nonwoven elastic web while maintaining the fibrous nonwoven elastic web at its stretched length.
  • a fibrous nonwoven gatherable web is formed, for example, by meltblowing or spunbonding the fibrous nonwoven gatherable web, directly upon a surface of the tacky fibrous nonwoven elastic web while maintaining the fibrous nonwoven elastic web at its stretched length.
  • This embodiment results in the formation of a composite nonwoven elastic web having an ungathered fibrous gatherable web adhesively joined to the tacky fibrous nonwoven elastic web with the joining of the two webs to each other being achieved by the adhesive joining which occurs during formation of the fibrous nonwoven gatherable web on the surface of the fibrous nonwoven elastic web.
  • the adhesive joining of the two webs to each other may be increased upon application pressure to the composite nonwoven elastic web by passing the composite nonwoven elastic web through the nip between rollers, which may be unheated, after the composite web has been formed but before the fibrous tacky nonwoven elastic web is allowed to relax.
  • the adhesive joining may be further enhanced by application of an adhesive material to the surface of the tacky fibrous nonwoven elastic web prior to formation of the gatherable web thereon.
  • the composite nonwoven elastic web is then allowed to relax to its normal relaxed, unbiased length. Because the fibrous nonwoven gatherable web was joined to the tacky fibrous nonwoven elastic web while the tacky fibrous nonwoven elastic web was in a stretched condition, relaxation of the composite nonwoven elastic web and thus the tacky fibrous nonwoven elastic web results in the gatherable web being carried with the contracting fibrous nonwoven elastic web and thus being gathered.
  • the composite nonwoven elastic web may be rolled up in rolls for storage and shipment.
  • a second fibrous nonwoven gatherable web may be applied to the exposed surface of the fibrous nonwoven elastic web prior to the gathering step.
  • butcher paper may be applied, either before or after gathering of the gatherable web, to the exposed tacky surface of the tacky fibrous nonwoven elastic web and later removed prior to utilization of the composite nonwoven elastic web.
  • the composite elastic web may thereafter by utilized to form a wide variety of products.
  • the invention is also directed to a composite nonwoven elastic web composed of a nonwoven elastic web that is joined to a gatherable fibrous nonwoven web which has been gathered and with the composite web having been formed by any of the embodiments of the inventive process.
  • the composite nonwoven elastic web in its relaxed, nonstretched state, is composed of a nonwoven elastic web that is joined to a fibrous nonwoven gathered web which has been gathered as a result of the nonwoven elastic web having been relaxed from an elongated stretched, biased length to a relaxed, unbiased nonstretched length.
  • Exemplary elastomeric materials for use in formation of the fibrous nonwoven elastic web include polyester elastomeric materials, polyurethane elastomeric materials, and polyamide elastomeric materials.
  • Other elastomeric materials for use in formation of the fibrous nonwoven elastic web include (a) A-B-A' block copolymers, where A and A' are each a thermoplastic polymer endblock which includes a styrenic moiety and where A may be the same thermoplastic polymer endblock as A' , such as a poly (vinyl arene), and where B is an elastomeric polymer midblock such as a conjugated diene or a lower alkene or (b) blends of one or more polyolefins or poly (alpha-methyl styrene) with A-B-A' block copolymers, where A and A' are each a thermoplastic polymer endlbock which includes a styrenic moiety, where A may be the same
  • the A and A' endblocks may be selected from the group including polystyrene and polystyrene homologs and the B midblock may be selected from the group including polyisoprene, polybutadiene or poly (ethylene-butylene). If A and A' are selected from the group including polystyrene or polystyrene homologs and B is poly (ethylene-butylene), materials which may be blended with these block copolymers are polymers, including copolymers of ethylene, propylene, butene, other lower alkenes or one or more of these materials.
  • a and A' are selected from the group including polystyrene or polystyrene homologs and B is a polyisoprene midblock, a material for blending with this type of block copolymer is poly (alpha-methylstyrene).
  • the gatherable web includes at least one fibrous nonwoven web that includes nonelastic fibers which may be formed by meltblowing, spunbonding, or any other process for forming a fibrous nonwoven gatherable web.
  • Preferred materials for forming the gatherable web include polyester materials, polyolefin materials or blends of one or more polyester materials with one or more polyolefin materials.
  • An exemplary polyester material is polyethylene terephthalate.
  • An exemplary polyolefin material is polypropylene.
  • meltblown microfibers 10 which are formed by a conventional meltblowing die 12 are collected on a porous collecting screen 14 which is moving, as indicated by the arrows 16 in figure 1, about the rollers 18 and 20.
  • the material which is utilized to form the meltblown microfibers 10 is, for reasons which will hereinafter become clear, an elastomeric material.
  • the porous collection screen 14 is driven by the rotating rollers 18 and 20 which, in turn, are driven by a conventional drive arrangement (not shown). Also not shown for purposes of clarity is a conventional vacuum box located between the rollers 18 and 20 and beneath the lower surface of the upper portion of the screen 14.
  • the vacuum box assists in the retention of the microfibers 10 on the upper surface of the screen 14.
  • the meltblown microfibers 10 are deposited upon the moving collecting screen 14 they entangle and cohere to form a cohesive fibrous nonwoven elastic web 22.
  • the entangled cohesive fibrous nonwoven elastic web 22 is carried by the porous collecting screen 14 to the nip or gap 24 between the rotating roller 20 and a rotating nip roller 26.
  • the nip or gap 24 between the two rollers 20 and 26 is adjusted so that the rollers 20 and 26 firmly engage the fibrous nonwoven elastic web 22 without adversely affecting the web 22.
  • the rate of rotation of the rollers 20 and 26 is adjusted so that the peripheral surface speed of the rollers 20 and 26 is substantially the same as the speed of the moving porous collecting screen 14.
  • the cohesion of the microfibers 10 to each other may be improved by, for example, heat-bonding the microfibers 10 to each other by maintaining the roller 26 at an appropriate elevated temperature which will vary depending upon the degree of cohesion desired and the cohesive characteristics of the material utilized to form the microfibers 10.
  • Typical heat-bonding temperatures range from about 50 degrees centigrade below the melting temperature of at least one of the materials utilized to form the web 22 to about the melting temperature of at least one of the materials utilized to form the web 22. However, at high throughput rates temperatures exceeding the melting temperature of the material may be employed.
  • the fibrous nonwoven elastic web 22 is forwarded by the action of the rollers 20 and 26 into and passes through a second nip or gap 28 which is formed between a rotating roller 30 and a second rotating nip roller 32. Rotation of the rollers 30 and 32 is adjusted so that the peripheral surface speed of the rollers 30 and 32 is greater than the peripheral surface speed of the rollers 20 and 26.
  • the nip 28 between the two rollers 30 and 32 is adjusted so that the rollers 30 and 32 firmly engage the fibrous nonwoven elastic web 22 without adversely affecting the web 22.
  • a longitudinal or machine direction (MD) biasing force is placed on the fibrous nonwoven elastic web 22 and the webb 22 is stretched to an extended, stretched, biased length in the longitudinal or machine direction (MD).
  • the degree of stretching of the fibrous nonwoven elastic web 22 which occurs in the area 34 between the rollers 20 and 26 and the rollers 30 and 32 may be varied, for example, by varying the peripheral surface speed of the rollers 30 and 32 with respect to the peripheral surface speed of the rollers 20 and 26. For example, if the peripheral surface speed of the rollers 30 and 32 is twice that of the rollers 20 and 26, the fibrous nonwoven elastic web 22 will be stretched to a stretched length of substantially about twice, that is, about 200 percent, of its original relaxed unstretched, unbiased length. It is preferred that the fibrous nonwoven web 22 be stretched to a stretched length of at least about 125 percent of its original, relaxed, unbiased length.
  • the fibrous nonwoven web 22 is stretched to a preferred length of from at least about 150 percent of the relaxed, unbiased length of the fibrous nonwoven web 22 to about 700 or more percent of the relaxed, unbiased length of the fibrous nonwoven web 22.
  • the web 22 is passed onto a second porous collecting screen 36 which is moving as is indicated by the arrows 38 in figure 1.
  • the second porous collecting screen 36 moves about and is driven by the rotating roller 30 in conjunction with a rotating roller 40.
  • the rotating rollers 30 and 40 are, in turn, driven by a conventional driving arrangement (not shown) which may be the same arrangement that is driving the rotating rollers 18 and 20.
  • a conventional vacuum box located between the rollers 30 and 40 and beneath the lower surface of the upper portion of the screen 36. The vacuum box assists in the retention of the web 22 on the upper surface of the screen 36.
  • the stretched fibrous nonwoven elastic web 22 is carried by the second porous collecting screen 36 to a nip or gap 42 which is formed between the rotating roller 40 and a third rotating nip roller 44.
  • Rotation of the rotating roller 40 and the nip roller 44 is adjusted so that the peripheral surface speed of the two rollers 40 and 44 is substantially the same as the peripheral surface speed of the rollers 30 and 32.
  • the peripheral surface speed of the rollers 40 and 44 is maintained at substantially the same peripheral surface speed as that of the rollers 30 and 32 and because the nip 42 is adjusted so that the rollers 40 and 44 firmly retain the fibrous nonwoven elastic web 22, without adversely affecting the web 22, the stretched condition of the fibrous nonwoven elastic web 22 is maintained while the fibrous nonwoven elastic web 22 is being carried by the second porous collecting screen 36.
  • meltblown microfibers 46 formed by a conventional meltblowing die 48, are meltblown directly onto the upper surface of the stretched nonwoven elastic web 22 to form a cohesive fibrous nonwoven gatherable web 50 which is located on the upper surface of the stretched fibrous nonwoven elastic web 22.
  • meltblown microfibers 46 are collected on the upper surface of the fibrous nonwoven elastic web 22, they entangle and cohere with each other to form the cohesive fibrous nonwoven gatherable web 50.
  • the meltblown microfibers 46 may also mechanically entangle with the fibers of the elastic web 22.
  • the distance between the die tip of the meltblowing die 48 and the upper surface of the stretched fibrous nonwoven elastic web 22 is increased the mechanical entanglement of the fibers of the web 50 with the fibers of the web 22 decreases.
  • the distance between the die tip of the meltblowing die 48 and the upper surface of the web 22 should be no greater than about 25 inches.
  • the distance between the die tip of the meltblowing die 48 and the upper surface of the web 22 should range from about 6 inches to about 16 inches.
  • some adhesion of the fibers of the gatherable web 50 to the fibers of the elastic web 22 may also occur.
  • the materials which are appropriate for utilization in forming the fibrous nonwoven elastic web 22 are preferably selected after selection of the material or materials which will be utilized in formation of the fibrous nonwoven gatherable web 50 has occurred.
  • the material selected to form the fibrous nonwoven gatherable web 50 must be a material which forms a web 50 that is gatherable by the contracting force of the fibrous nonwoven elastic web 22. Because the contracting force of the web 22 will vary with the material selected for formation of the web 22, the material selected for formation of the web 22 will have to be selected so that the contracting force of the web 22 is capable of gathering the web 50.
  • Exemplary, materials for utilization in forming the webs 22 and 50 are disclosed hereinafter.
  • the two cohesive webs 22 and 50 may be joined to each other in a variey of ways. For example, if a relatively weak joining of the two webs 22 and 50 to each other is desired, the two webs 22 and 50 can be joined to each other solely by the entanglement of the individual meltblown fibers of the fibrous nonwoven gatherable web 50 with the individual meltblown fibers of the fibrous nonwoven elastic web 22 which occurs during formation of the web 50 on the stretched surface of the web 22.
  • the two webs 22 and 50 are separable from each other upon application of a relatively small amount of force such as, for example, a light picking or rubbing force applied by an individual's fingers.
  • a relatively small amount of force such as, for example, a light picking or rubbing force applied by an individual's fingers.
  • joining of the fibrous nonwoven gatherable web 50 to the fibrous nonwoven elastic web 22 can be achieved, while continuing to maintain the fibrous nonwoven elastic web 22 at its stretched length, by heat-bonding the two webs 22 and 50 to each other.
  • the heat-bonding can be achieved by, for example, passing the two webs 22 and 50 between the rollers 40 and 44 with the rollers 40 and 44 being arranged to apply appropriate heat-bonding temperatures and pressures to the two webs 22 and 50.
  • joining of the fibrous nonwoven gatherable web 50 to the fibrous nonwoven elastic web 22 may be achieved by heat-bonding of the two webs 22 and 50 to each other with the rollers 40 and 44 being maintained within the temperature range of from about 50 degrees centigrade below the melting point of at least one of the materials used to form the web 22 and 50 to about the melt temperature of at least one of the materials utilized to form the webs 22 and 50.
  • the heat-bonding can be carried out above the melt temperature of one or more the materials utilized to form the two webs 22 and 50 since the webs 22 and 50 will be exposed to the high temperature for a short time.
  • Pressurized heat-bonding of the two webs 22 and 50 to each other may be carried out at conventional, appropriate bonding pressures by adjusting the nip 42.
  • Other conventional alternatives to heat-bonding the two webs 22 and 50 to each other may be substituted for the heat-bonding steps.
  • a conventional sonic bonding arrangement (not shown) could be substituted for the heat-bonding arrangement 40 and 44.
  • the joining of the two webs 22 and 50 to each other is usually improved somewhat just by passage of the webs 22 and 50 through the nip 42 since such passage results in application of pressure to the two webs 22 and 50 and thus increased entanglement of the individual fibers of the two webs 22 and 50.
  • the biasing force on the fibrous nonwoven elastic web 22 is relaxed by, for example, passing the composite nonwoven elastic web 52, which includes both the fibrous nonwoven elastic web 22 and the fibrous nonwoven gatherable web 50, through the nip or gap 54 formed by a pair of rotating nip rollers 56 and 58.
  • the nip 54 is adjusted so that the rollers 56 and 58 firmly engage the composite web 52 without adversely affecting the composite web 52.
  • the rotation of the pair of nip rollers 56 and 58 is adjusted so that the peripheral surface speed of the nip rollers 56 and 58 allows the composite nonwoven elastic web 52 to relax and, as a result of its elastic properties, to contract to its relaxed, unbiased length.
  • the relaxing and contracting of the composite nonwoven elastic web 52 to its relaxed, unbiased length results in the fibrous nonwoven gatherable web 50, which is joined to the fibrous nonwoven elastic web 22, being carried along with, that is contracted, and thus gathered upon the upper surface of the contracting fibrous nonwoven elastic web 22.
  • the composite web 52 may be rolled up on a supply roller 60 for storage and shipment.
  • the composite nonwoven elastic web 52 may thereafter be utilized in the manufacture of wide variety of items such as, for example, an outer cover material for a diaper or other garment.
  • the gathered nonwoven web 50 is to be separated from the elastic nonwoven web 22
  • separation of the two webs 22 and 50 from each other is effected in this embodiment by passing the fibrous nonwoven gathered web 50 through the nip 62 between two rotating nip rollers 64 and 66 and passing the nonwoven elastic web 22 through the nip 68 between two rotating nip rollers 70 and 72.
  • the nips 62 and 68 are adjusted so that the rollers 64 and 66 engage the web 50 without adversely affecting the web 50 and the rollers 70 and 72 engage the web 22 without adversely affecting the web 22.
  • the two webs 22 and 50 are wound up on storage rolls 74 and 76, respectively.
  • the gathered fibrous nonwoven web 50 Upon its separation from the nonwoven elastic web 22 the gathered fibrous nonwoven web 50 exhibits a creped or gathered appearance. Accordingly, upon application of an extending force in the machine direction (i.e. is a direction substantially perpendicular to the lines of gathering) the web 50 is extended to the extent that the gathers allow, e.g. until the web 50 has assumed a generally planar configuration as opposed to a gathered configuration and, surprisingly, upon release of the extending force on the gathers, the gathered web 50 exhibits elastic characteristics as defined herein. The gathered web 50 exhibits elastic characteristics even when the web 50 was formed from a nonelastic material such as a polypropylene obtained from the Himont Corporation under the trade designation PF 301.
  • a nonelastic material such as a polypropylene obtained from the Himont Corporation under the trade designation PF 301.
  • the fibrous nonwoven elastic web 22 portion of the composite nonwoven elastic web 52 may be formed from any elastomeric material which may be formed into a fibrous nonwoven elastic web 22.
  • Exemplary elastomeric materials for use in formation of the fibrous nonwoven elastic web 22 include polyester elastomeric materials such as, for example, polyester elastomeric materials available under the trade designation Hytrel from E. I. DuPont DeNemours & Co., polyurethane elastomeric materials such as, for example, polyurethane elastomeric materials available under the trade designation Estane from B. F.
  • elastomeric materials for use in forming the fibrous nonwoven elastic web 22 include (a) elastomeric A-B-A' block copolymers, where A and A' are each a thermoplastic polymer endblock which includes a styrenic moiety and where A may be the same thermoplatic polymer endblock as A', for example, a poly (vinyl arene), and where B is an elastomeric polymer midblock such as conjugated diene or a lower alkene and (b) blends of one or more polyolefins or poly (alpha-methylstyrene) with elastomeric A-B-A' block copolymer materials, where A and A' are each polymer thermoplastic endblocks containing a styrenic moiety and where A may be the same
  • the A and A' materials may be selected from the group of materials including polystyrene or polystyrene homologs and the B material may be selected from the group of materials including polyisoprene, polybutadiene and poly (ethylene-butylene). Materials of this general type are disclosed in U.S. patents 4,323,534 to Des Marais and 4,355,425 to Jones and in the aforementioned Shell brochure.
  • elastomeric A-B-A' block copolymers having a saturated or essentially saturated poly (ethylene-butylene) midblock “B” represented by the formula: , where x, y and n are positive integers, and polystyrene endblocks A and A' represented by the formula: , where n is a positive integer which may be the same or different for A and A', are sometimes referred to as S-EB-S block copolymers and are available under the trade designation KRATON G, for example, KRATON G 1650, KRATON G 1652 and KRATON GX 1657, from the Shell Chemical Company.
  • elastomeric resins which may be utilized are A-B-A' block copolymers where A and A' are polystyrene endblocks, as defined above, and "B" is a polybutadiene midblock represented by the following formula: , where n is a positive integer.
  • This material is sometimes referred to as a S-B-S block copolymer and is available under the trade designation KRATON D, for example, KRATON D 1101, KRATON D 1102 KRATON D 1116, from the Shell Chemical Company.
  • KRATON D for example, KRATON D 1101, KRATON D 1102 KRATON D 1116
  • Another S-B-S block copolymer material may be obtained under the trade designation Solprene 418 from the Phillips Petroleum Company.
  • A-B-A' block copolymers where A and A' are polystyrene endblocks, as defined above, and B is a polyisoprene midblock where the midblock is represented by the formula: , where n is a positive integer.
  • block copolymers are sometimes referred to as S-I-S block copolymers and are available under the trade designation KRATON D, for example, KRATON D 1107, KRATON D 1111, KRATON D 1112 and KRATON D 1117, from the Shell Chemical Company.
  • meltblowing of the S-EB-S KRATON G block copolymers in pure, i.e. neat, form has proven to be difficult except at elevated temperatures and low through-puts such as from at least about 550 degrees Fahrenheit to about 625 degrees Fahrenheit or more and below at least about 0.14 grams per die capillary per minute.
  • elevated temperatures and low through-puts such as from at least about 550 degrees Fahrenheit to about 625 degrees Fahrenheit or more and below at least about 0.14 grams per die capillary per minute.
  • blending of certain materials with several of the different types of KRATON G materials has proven to provide a satisfactory meltblowable material.
  • blends of certain polyolefin materials with the S-EB-S block copolymer has resulted in a meltblowable material.
  • the polyolefin is preferably a polymer, including copolymers, of ethylene, propylene, butene, other lower alkenes or blends of one or more of these materials.
  • a particularly preferred polyolefin for blending with the KRATON G S-EB-S block copolymers is polyethylene and a preferred polyethylene may be obtained from U.S.I. Chemicals Company under the trade designation Petrothene Na601. (Also referred to herein as PE Na601 or Na601.)
  • the Na601 is a lower molecular weight, low density polyethylene for application in the areas of hot melt adhesives and coatings.
  • U.S.I. has also stated that the Na601 has the following nominal values: (1) a Brookfield Viscosity, cP at 150 degrees Centigrade of 8500 and at 190 degrees Centigrade of 3300 when measured in accordance with ASTM D 3236; (2) a density of 0.903 grams per cubic centimeter when measured in accordance with ASTM D 1505; (3) an equivalent Melt index of 2000 grams per ten minutes when measured in accordance with ASTM D 1238; (4) a ring and ball softening point of 102 degrees Centigrade when measured in accordance with ASTM E 28; (5) a tensile of 850 pounds per square inch when measured in accordance with ASTM D 638; (6) an elongation of 90 percent when measured in accordance with ASTM D 638; (7) a modulus of Rigidity, T F (45,000
  • the Na601 is believed to have a number average molecular weight (Mn) of about 4,600; a weight average molecular weight (Mw) of about 22,400 and a Z average molecular weight (Mz) of about 83,300.
  • Mn number average molecular weight
  • Mw weight average molecular weight
  • Mz Z average molecular weight
  • the polydisperisity of the Na601 (Mw/Mn) is about 4.87.
  • Blending polyolefins with the S-I-S and S-B-S block copolymers followed by meltblowing of the blend has, to date, proved to be unsatisfactory in that the blends appear to be incompatible.
  • a good material for blending with the S-I-S block copolymers is poly (alpha-methylstyrene) and a preferred poly (alpha-methylstyrene) may be obtained from Amoco under the trade designation 18-210.
  • the fibrous nonwoven gatherable web 50 portion of the composite nonwoven elastic web 52 formed by the process of the present invention may be formed from any gatherable material which may be formed into a fibrous nonwoven gatherable web 50.
  • the fibrous nonwoven gatherable web 50 could be formed from a blend of a nonelastic material with an elastic material, one or more nonelastic materials or a blend of one or more elastic materials with two or more nonelastic materials.
  • the fibrous nonwoven gatherable web 50 is formed from a fiber-forming meltblowable or spunbondable nonelastic gatherable material.
  • Exemplary fiber-forming materials for use in forming the fibrous nonwoven gatherable web are polyester materials, polyolefin materials or blends of one or more polyester materials with one or more polyolefin materials.
  • An exemplary polyester fiber-forming material is polyethylene terephthalate.
  • An exemplary fiber-forming polyolefin material is polypropylene. Preferred polypropylene materials may be obtained under the trade designation PC 973 and PF 301 from the Himont Company.
  • Typical characteristics of the Himont PC-973 polyproylene stated by Himont are a density of about 0.900 grams per cubic centimeter, measured in accordance with ASTM D 792; a meltflow rate obtained in accordance with ASTM D 1238, condition L, of 35 grams per ten (10) minutes; tensile of about 4,300 pounds per square inch (psi) measured in accordance with ASTM D 638; flex modulus of about 182,000 psi measured in accordance with ASTM D 790, B and a Rockwell hardness, R scale, of 93 measured in accordance with ASTM D 785 A.
  • the PC-973 is believed to have a number average molecular weight (Mn) of about 40,100; a weight average molecular weight (Mw) of about 172,000 and a Z average molecular weight of about 674,000.
  • Mn number average molecular weight
  • Mw weight average molecular weight
  • Z average molecular weight Z average molecular weight of about 674,000.
  • the polydispersity (Mw/Mn) of the PC-973) is about 4.29.
  • the gathered web 50 be capable of substantially returning to its gathered condition upon its separation from the elastic web 22.
  • the gathered condition e.g., configuration
  • the fibrous nonwoven gatherable web 50 exhibits upon its separation from the web 22 will be somewhat longer in the direction of gathering (i.e. machine direction) as compared to the length of the same amount of web 50 when the web 50 is separably joined to the elastic web 22.
  • the web 50 will extend somewhat in the direction of gathering after its separation from the web 22. Accordingly, the gathered, relaxed, unbiased length of the separated web 50 will be somewhat greater than or equal to the gathered, relaxed, unbiased length of the same amount of the web 50 while it is joined to the elastic web 22.
  • the composite nonwoven elastic web 52 is composed of a fibrous nonwoven elastic web 22 which is joined to a gatherable fibrous nonwoven web 50.
  • the composite nonwoven elastic web 52 of this embodiment differs from the composite nonwoven elastic web 52 of the above-described embodiments in that the joining of the two webs 22 and 50 of the composite nonwoven elastic web 52 is achieved without application of heat and/or pressure during the bonding step yet is stronger than the joining achieved by entanglement of the fibers of the nonwoven gatherable web 50 with the fibers of the nonwoven elastic web 22 during formation of the web 50 on the web 22.
  • the fibrous nonwoven elastic web 22 is formed from a tacky elastomeric material so that, upon its formation, the fibrous nonwoven elastic web 22 is tacky.
  • the tacky fibrous nonwoven elastic web 22 is formed by meltblowing the web 22 onto the porous collecting screen 14.
  • a tacky nonwoven elastic apertured film (not shown) could be substituted for the tacky fibrous nonwoven elastic web 22.
  • the tacky fibrous nonwoven elastic web 22 is stretched to a stretched length of at least about one and one quarter, that is at least about 150 percent of its relaxed, unbiased length by the combined action of the rollers 20 and 26 and 30 and 32.
  • the tacky fibrous nonwoven elastic web 22 is stretched to a length of from about 150 percent of the relaxed, unbiased length of the tacky fibrous nonwoven elastic web to about 700 or more percent of the relaxed, unbiased length of the tacky fibrous nonwoven web 22.
  • the tacky fibrous nonwoven elastic web 22 After the tacky fibrous nonwoven elastic web 22 has been stretched it is carried by the second porous collecting screen 36 to the nip or gap 42 between the rotating roller 40 and the rotating nip roller 44. While the web 22 is being carried by the second porous collecting screen 36, the fibrous nonwoven gatherable web 50 is formed directly on the upper surface of the tacky web 22 by either a conventional meltblowing or spunbonding process or by any other conventional method which may be utilized to form a fibrous nonwoven gatherable web 50, such as, for example, conventional carding apparatus for forming a carded web.
  • the tacky fibrous nonwoven elastic web 22 is maintained at its stretched, biased length by appropriately adjusting the peripheral surface speed of the rollers 40 and 44 with respect to the peripheral speed of the rollers 30 and 32.
  • an improved joining as compared to joining of the two webs solely by entanglement
  • a preferred tacky elastomeric material is an elastomeric A-B-A' block copolymer, where A and A' are each thermoplastic polystyrene endblocks and where B is a polyisoprene midblock.
  • Tri-block copolymer materials of this type are sometimes called S-I-S block copolymers and may be obtained under the trade designation KRATON D, for example, KRATON D 1107, KRATON D 1111, KRATON D 1112 and KRATON D 1117, from the Shell Chemical Company.
  • KRATON D for example, KRATON D 1107, KRATON D 1111, KRATON D 1112 and KRATON D 1117, from the Shell Chemical Company.
  • a blend of a S-I-S block copolymer and poly (alpha-methylstyrene) may be utilized
  • the materials which may be utilized to form the fibrous nonwoven gatherable web 50 of this embodiment may include any of the materials which were stated above with regard to the fibrous nonwoven gatherable web 50. That is, the fibrous nonwoven gatherable web may be formed from any gatherable material which may be formed into a fibrous nonwoven gatherable web 50.
  • the fibrous nonwoven gatherable web 50 could be formed from a blend of a nonelastic material with an elastic material, one or more nonelastic materials or a blend of one or more elastic materials with two or more nonelastic materials.
  • the fibrous nonwoven gatherable web 50 is formed from a fiber-forming meltblowable or spunbondable nonelastic gatherable material.
  • the fibrous nonwoven gatherable web 50 may be formed by depositing a carded web on the surface of the fibrous nonwoven elastic web 22 or by any other method which may be utilized to form a fibrous nonwoven gatherable web 50 on the surface of the web 22.
  • Exemplary fiber-forming materials for use in forming the fibrous nonwoven gatherable web 50 are polyester materials, polyolefin materials or blends of one or more polyester materials with one or more polyolefin materials.
  • An exemplary polyester fiber-forming material is polyethylene terephthalate.
  • An exemplary fiber-forming polyolefin material is polypropylene.
  • Preferred polypropylene materials may be obtained from the Himont Company under the trade designations PC 973 and PF 301.
  • one or more fibers such as cotton fibers, wood pulp fibers, polyester fibers or other particulates into one or both of the webs 22 and 50 during their formation. This may be accomplished by utilization of conventional coforming apparatus in conjunction with the meltblowing or spunbonding apparatus 12 and/or 48. Such coforming apparatus is well known to those in the art and is generally illustrated by the apparatus disclosed in U. S. patent 4,100,432 to Anderson.
  • the composite nonwoven elastic web 52 is passed through the rollers 40 and 44 which, for the reasons stated above, need not be heated or need not apply any excessive pressure to the composite elastic web 52. Thereafter, the stretching and biasing force on the tacky nonwoven elastic web 22 is released so as to relax and contract the composite nonwoven elastic web 52.
  • fibrous nonwoven gatherable web 50 is joined to the surface of the tacky fibrous nonwoven elastic 22 while the tacky fibrous nonwoven elastic web 22 is stretched, relaxing and contraction of the composite nonwoven tacky web 52 results in the fibrous nonwoven gatherable web 50 being carried with, contracted and thereby gathered into a soft batted or matted web 50 which is joined to the surface of the elastic web 22.
  • a fibrous nonwoven elastic web which had previously been formed by meltblowing a blend of 60 percent, by weight, of an A-B-A' block copolymer having polystyrene A and A' end blocks and a poly (ethylene-butylene) "B" midblock (obtained from the Shell Chemical Company under the trade designation KRATON GX 1657) and 40 percent, by weight, of a polyethylene (obtained from U.S.I. Chemical Company under the trade designation PE Na601) was provided in rolled-up form.
  • the prior meltblowing of the fibrous nonwoven elastic web was accomplished by extruding the blend of materials through a meltblowing die having thirty extrusion capillaries per lineal inch of die tip.
  • the capillaries each had a diameter of about 0.0145 inches and a length of about 0.113 inches.
  • the blend was extruded through the capillaries at a rate of about 0.52 grams per capillary per minute at a temperature of about 595 degrees Fahrenheit.
  • the extrusion pressure exerted upon the blend was measured as 73 pounds per square inch, gage in the capillaries.
  • the die tip configuration was adjusted so that is was recessed about 0.090 inches inwardly from the plane of the external surface of the air plates which form the forming air gaps on either side of the capillaries.
  • the air plates were adjusted so that the two forming air gaps, one on each side of the extrusion capillaries, formed air gaps of about 0.067 inches.
  • Forming air for meltblowing the blend was supplied to the air gaps at a temperature of about 600 degrees Fahrenheit and at a pressure of about 4 pounds per square inch, gage.
  • the meltblown fibers thus formed were blown onto a forming screen which was approximately 15 inches from the die tip.
  • the thus formed fibrous nonwoven elastic web was unrolled and stretched by applying a tensioning, i.e. biasing, force in the machine direction (MD) and a fibrous nonwoven gatherable web was formed on the surface of the elastic web by meltblowing polypropylene (obtained from the Himont Company under the trade designation PC 973) as microfibers onto the upper surface of the fibrous nonwoven elastic web while the fibrous nonwoven elastic web was maintained at its stretched length.
  • MD machine direction
  • Meltblowing of the fibrous nonwoven gatherable polypropylene web was accomplished by extruding the polypropylene through a meltblowing die having thirty extrusion capillaries per lineal inch of die tip.
  • the capillaries each had a diameter of about 0.0145 inches and a length of about 0.113 inches.
  • the polypropylene was extruded through the capillaries at a rate of about 0.38 grams per capillary per minute and at a temperature of about 590 degrees Fahrenheit.
  • the extrusion pressure exerted upon the polypropylene was measured as 29 pounds per square inch, gage in the capillaries.
  • the die tip configuration was adjusted so that it was about coplanar with the plane of the external surface of the air plates which form the forming air gaps on either side of the capillaries.
  • the air plates were adjusted so that the two forming air gaps, one on each side of the extrusion capillaries, formed air gaps of about 0.015 inches.
  • Forming air for meltblowing the polypropylene was supplied to the air gaps at a temperature of about 600 degrees Fahrenheit and at a pressure of about 4 pounds per square inch, gage.
  • the meltblown polypropylene microfibers thus formed were meltblown directly onto the upper surface of the fibrous nonwoven elastic web which was located approximately sixteen inches from the die tip. Because of these processing conditions the viscosity of the polypropylene was about 20 poise and very fine diameter polypropylene microfibers were formed on the surface of the fibrous nonwoven elastic web.
  • the tensioning, biasing force was reduced so as to allow the fibrous nonwoven elastic web to retract and for the meltblown polypropylene web to be gathered in the machine direction.
  • the composite nonwoven elastic web which was formed had inter-layer integrity which, apparently, resulted from the entanglement of the individual fibers of the two webs with each other since the webs were not otherwise joined by adhesives or heat-bonding.
  • Samples of the fibrous nonwoven elastic web, itself, and samples of the composite nonwoven elastic web were then stretched by an Instron tensile tester model 1122 which elongated each sample 100 percent, that is twice its unstretched length, and then allowed the sample to return to an unstretched condition. This procedure was then repeated three (3) times and then each sample was elongated to break. Each sample was two (2) inches wide by five (5) inches long and the initial jaw separation on the tester was set at one (1) inch. The samples were placed lengthwise in the tester and elongated at a rate of five (5) inches per minute. The machine direction data was obtained from samples having a machine direction length of five (5) inches and a transverse direction width of two (2) inches.
  • the transverse or cross machine direction measurements were obtained from samples having a length of five (5) inches in the tranverse machine direction and a width of two (2) inches in the machine direction.
  • the data which was obtained for the fibrous nonwoven elastic web is tabulated in Table III below and the data which was obtained for the composite elastic web is tabulated in Table IV below.
  • Tables III and IV disclose the total energy absorbed, in inch-pounds, the peak (maximum) load, in pounds, encountered during each repetition and the amount of each peak (maximum) elongation, in inches in stretching the samples in each repetition of the 100 percent elongation procedure and in elongating the sample to break. It can be seen that the total energy required to stretch the sample 100 percent in the machine direction at the peak load encountered in such stretching is about the same for the fibrous nonwoven elastic web and the composite nonwoven elastic web. This is to be expected since the meltblown polypropylene web is gathered in the machine direction and generally requires little energy to be elongated in the machine direction. Upon elongation to break, the peak load for the composite nonwoven elastic web increased over 70 percent indicating that the meltblown polypropylene web was contributing strength to the strength of the composite nonwoven elastic web.
  • the peak load for the initial stretch of the composite nonwoven elastic web is over 60 percent greater than the peak load for the fibrous nonwoven elastic web. This indicates that the meltblown polypropylene web contributes to the strength of the composite nonwoven elastic web even at low elongations. Additionally, the peak total energy absorbed for the composite nonwoven elastic web represents a 50 percent increase over that of the fibrous nonwoven elastic web for the first stretch and then actually decreases on subsequent stretchings. This indicates that the meltblown polypropylene web was substantially ruptured (torn) during the first stretch and is no longer contributing to total energy of the composite web.
  • the "breathability" of the composite nonwoven elastic web was still good as compared to the "breathability” of the fibrous nonwoven elastic web. Additionally, because of the thin web of meltblown polypropylene microfibers which have been applied to the surface of the fibrous nonwoven elastic web the composite web was more water repellent due to the water repellent characteristics of polypropylene. Moreover, application of the thin web of meltblown microfibers to the surface of the meltblown nonwoven elastic web changed the rubbery feel of the fibrous nonwoven elastic web to a soft, desirable feeling.
  • a fibrous nonwoven web which had previously been formed by meltblowing a blend of sixty percent (60%), by weight, of an A-B-A' block copolymer having polystyrene "A” and “A'” endblocks and a poly (ethylene-butylene) "B" midblock (obtained from the Shell Chemical Company under the trade designation KRATON GX 1657) and forty percent (40%) by weight, of a polyethylene (obtained from U.S.I. under the trade designation PE Na 601) was provided in rolled-up form.
  • the prior meltblowing of the fibrous nonwoven elastic web was accomplished by extruding the blend of materials through a meltblowing die having thirty extrusion capillaries per lineal inch of die tip.
  • the capillaries had a diameter of about 0.0145 inches and a length of about 0.113 inches.
  • the blend was extruded through the capillaries at a rate of about 0.50 grams per capillary per minute at a temperature of about 570 degrees Fahrenheit.
  • the extrusion pressure exerted upon the blend was measured as 144 pounds per square inch, gage in the capillaries. However, it is presently believed that this measurement was inaccurate due to a faulty pressure probe.
  • the die tip configuration was adjusted so that it was recessed about 0.110 inches inwardly from the plane of the external surface of the air plates which form the forming air gaps on either side of the capillaries.
  • the air plates were adjusted so that the two forming air gaps, one on each side of the extrusion capillaries, formed gaps of about 0.110 inches.
  • Forming air for meltblowing the blend was supplied to the air gaps at a temperature of about 614 degrees Fahrenheit and at a pressure of about 4 pounds per square inch, gage.
  • the meltblown microfibers were formed onto a forming screen which is believed to have been about 16 inches from the die tip. However, measurement of this distance was not actually taken.
  • the thus formed fibrous nonwoven elastic web was unrolled and stretched by applying a tensioning, i.e. biasing, force in the machine direction (MD) and a fibrous nonwoven gatherable web was formed on the surface of the elastic web by meltblowing polypropylene (obtained from the Himot Company under the trade designation PF 301) as microfibers on to the upper surface of the fibrous nonwoven elastic web while the fibrous nonwoven elastic web was maintained at its stretched length.
  • MD machine direction
  • Meltblowing of the fibrous nonwoven polypropylene gatherable web was accomplished by extruding the polypropylene through a meltblowing die having thirty extrusion capillaries per lineal inch of die tip.
  • the capillaries each had a diameter of about 0.0145 inches and a length of about 0.113 inches.
  • the polypropylene was extruded through the capillaries at a rate of about 0.75 grams per capillary per minute at a temperature of about 590 degrees Fahrenheit.
  • the extrusion pressure exerted upon the polypropylene was measured as about 186 pounds per square inch, gage in the capillaries.
  • the die tip configuration was adjusted so that it extended about 0.010 inches beyond the plane of the external surface of the air plates which form the forming air gaps on either side of the capillaries.
  • the air plates were adjusted so that the two forming air gaps, one on each side of the extrusion capillaries, formed air gaps of about 0.018 inches.
  • Forming air for meltblowing the polypropylene was supplied to the air gaps at a temperature of about 600 degrees Fahrenheit and at a pressure of about 2 pounds per square inch, gage.
  • the distance between the die tip and the surface of the fibrous nonwoven elastic web upon which the gatherable polypropylene web was formed was about 10 inches. Because of these processing conditions, the viscosity of the polypropylene was about 124 poise and larger diameter meltblown polypropylene microfibers were formed on the surface of the stretched fibrous nonwoven elastic web.
  • the tensioning, biasing force was reduced so as to allow the fibrous nonwoven elastic web to contract and for the meltblown polypropylene web to be gathered in the machine direction.
  • the composite nonwoven elastic web which was formed had inter-layer integrity which, apparently, resulted from the entanglement of the individual fibers of the two webs with each other since the webs were not otherwise joined by adhesives or heat-bonding.
  • Samples of this fibrous nonwoven elastic web, itself, and samples of the composite nonwoven elastic web were then stretched by an Instron tensile tester model 1122 which elongated each sample 100 percent, that is to twice its unstretched length, and then allowed the sample to return to an unstretched condition. This procedure was then repeated three (3) times and then each sample was elongated to break. Each sample was two (2) inches wide by five (5) inches long and the initial jaw separation on the tester was set at one (1) inch. The samples were placed lengthwise in the tester and elongated at a rate of five (5) inches per minute. The machine direction data was obtained from samples having a machine direction length of five (5) inches and a transverse direction width of two (2) inches.
  • the transverse or cross machine direction measurements were obtained from samples having a length of five (5) inches in the transverse direction and a width of two (2) inches in the machine direction.
  • the data which was obtained for the composite nonwoven elastic web formed by example 2 is tabulated in Table V below.
  • Table V illustrates that the, 100 percent, elongations required little energy or load in the machine direction while the total energy absorbed increased about seven (7) times and the peak load increased about three (3) times when the composite was stretched to break in the machine direction.
  • the initial, 100 percent elongation absorbed about three and one half (3.5) times as much total energy as the total energy absorbed to break and about four (4) to five (5) times as much energy as any of the subsequent, 100 percent stretchings.
  • the peak load for the first stretching in the transverse direction was about 40 percent higher than the peak load for any subsequent stretching in the transverse direction, including stretching to break.
  • the basis weight of the meltblown fibrous nonwoven elastic web utilized for example I was 67.3 grams per square meter and the basis weight of the meltblown gatherable polypropylene web which was formed on the surface of the fibrous nonwoven elastic web of example I was measured as being 12.2 grams per square meter.
  • the degree of relaxation or contraction of the composite nonwoven elastic web of example I was about 54 percent. This degree of relaxation of the composite was determined by taking a sample of the composite having a relaxed length of about 4.0 inches in the machine direction and elongating the sample, in the machine direction, until resistance to the elongation by the gathered polypropylene web was encountered. That is, just until the gathers in the polypropylene web were removed. At this point the 4.0 inch sample had been stretched to about 8.75 inches in the machine direction.
  • the basis weight of the fibrous nonwoven elastic web utilized in example II was about 66.2 grams per square meter and the basis weight of the fibrous nonwoven gatherable polypropylene web meltblown onto the surface of the elastic web in example II was measured at about 21.4 grams per square meter.
  • the degree of relaxation or contracting of the composite nonwoven elastic web of example II was determined to be about 42 percent. This degree of relaxation was determined by taking a sample of the composite having a relaxed length of about 12 inches in the machine direction and elongating the sample, in the machine direction, until resistance to the elongation by the gathered polypropylene web was encountered. That is, just until the gathers in the polypropylene web were removed. At this point the 12 inch sample had been stretched to about 20.7 inches.
  • the meltblown polypropylene web presented a creped, gathered, appearance with the lines of creping or gathering being generally transverse to the direction in which the fibrous nonwoven elastic web was stretched during formation of the meltblown polypropylene web on the surface of the fibrous nonwoven elastic web (i.e. transverse to the machine direction).
  • the fibrous nonwoven elastic web of the contracted and relaxed composite nonwoven elastic web exhibited lines of creping or gathering which were generally parallel to the direction of stretching of the fibrous nonwoven elastic web during formation of the meltblown polypropylene included on the surface thereof (i.e. the lines of creping or gathering of the fibrous nonwoven elastic web were generally parallel to the machine direction).
  • the two webbed composite included webs having transposed lines of gathering or creping which generally crossed each other generally at right angles. Formation of the lines of gathering or creping in the fibrous nonwoven gatherable polypropylene web would be expected in view of the gathering of that web in the machine direction. However, formation of lines of gathering or creping in the fibrous nonwoven elastic web and, in particular, formation of lines of gathering or creping in the fibrous nonwoven elastic which are generally at right angles with the lines gathering or creping of the fibrous nonwoven gatherable polypropylene webs was unexpected.
  • a portion of the composite nonwoven elastic web having an approximate machine direction (MD) length of about 5 and 7/8 inches and an approximate transverse direction (TD) dimension of about 4-1/2 inches was cut off of the composite nonwoven elastic web and the gathered fibrous nonwoven meltblown polypropylene web was separated from the fibrous nonwoven elastic web.
  • MD machine direction
  • TD transverse direction
  • the gathered fibrous nonwoven meltblown polypropylene web assumed a relaxed machine direction dimension of about 7 inches and retained its cross-direction dimension of about 4-1/2 inches.
  • the fibrous nonwoven gathered web substantially retained its creped or gathered configuration in the machine direction.
  • the separated gathered polypropylene web could be elongated in the machine direction upon application of a tensioning and biasing force in the machine direction and would, upon removal of the tensioning and biasing force, return, that is, contract, substantially to its relaxed and unbiased and untensioned gathered dimension (7 inches by 4-1/2 inches).
  • a tensioning and biasing force in the machine direction
  • return that is, contract
  • substantially to its relaxed and unbiased and untensioned gathered dimension 7.
  • the sample was measured and found to have a machine direction (MD) length of about 9-1/2 inches and a transverse direction (TD) dimension of about 4-1/2 inches.
  • fibrous nonwoven gatherable webs 50 could be bonded one on top of another in stacked configuration to give the fibrous nonwoven gatherable web additional thickness.
  • a fibrous nonwoven gatherable web 50 could be joined, either separably or otherwise as discussed herein, to both surfaces of the fibrous nonwoven elastic web 22 to form a composite nonwoven elastic web having the following three web sequence: fibrous nonwoven gatherable web/fibrous nonwoven elastic web/fibrous nonwoven gatherable web.
  • the three web sequence where the fibrous nonwoven elastic web is sandwiched between two fibrous nonwoven gatherable webs is especially preferred where the fibrous nonwoven elastic web 22 is formed from a tacky elastomeric material as described above because sandwiching of the tacky elastic web 22 between the two webs prevents the tacky web 22 from adhering to other portions of the web 52 upon rolling-up of the web 52 for storage.
  • the three web material could be formed by the process which is illustrated schematically in figure 3. This process is identical to the process schematically illustrated in figure 1 until the two layered composite nonwoven elastic web 52 exits rollers 40 and 42.
  • the composite web 52 passes through the nip or gap 78 between a rotating roller 80 and a rotating nip roller 82.
  • the composite web 52 is then carried by a third porous collecting screen 84 to the nip or gap 86 between a rotating nip roller 88 and a rotating roller 74.
  • the porous collecting screen 68 moves about and is driven by the rollers 80 and 84 in the direction indicated by the arrows 92 in figure 3.
  • Rotation of the rollers 80, 82, 88 and 90 is adjusted so that the peripheral surface speed of the rollers 80, 82, 88 and 90 is the same as the peripheral surface speed of the rollers 40 and 44. Accordingly, the fibrous nonwoven elastic web 22 is maintained at its stretched, biased length as it is carried by the porous collecting screen 84.
  • a conventional meltblowing die 94 (if desired, a conventional spunbonding die or carding apparatus can be utilized) forms a second nonwoven gatherable web 96 on the other surface of the stretched fibrous nonwoven elastic web 22 by meltblowing microfibers 98 directly onto the stretched upper surface of the nonwoven elastic web 22.
  • the materials which may be utilized to form the second gatherable web 96 may include any of the materials which were stated above as being utilizable to form the first fibrous nonwoven gatherable web 50. Particulate materials may also be incorporated within the web 96 as was stated above with regard to the webs 22 and 50.
  • the second fibrous nonwoven gatherable web 96 may be heat-bonded to the fibrous nonwoven elastic web 22 by the action of rollers 88 and 90 which are essentially equivalent to rollers 40, 44.
  • the heat-bonding of the second fibrous nonwoven gatherable web 96 to the fibrous nonwoven elastic web 22 can be carried out within the same temperature ranges and within the same pressure ranges as were stated above with regard to the heat-bonding of the first fibrous nonwoven gatherable web 50 to the fibrous nonwoven elastic web 22.
  • conventional sonic bonding techniques (not shown) may be substituted for the heat-bonding step.
  • the fibrous nonwoven elastic web 22 is tacky, as described above, heat bonding of the fibrous nonwoven gatherable web 96 to the fibrous nonwoven elastic web will not be required since the second fibrous nonwoven gatherable web 96 will be simultaneously formed upon and joined to the surface of the fibrous nonwoven elastic web 22.
  • the second fibrous nonwoven gatherable web 96 may be separably joined to the surface of the fibrous nonwoven elastic web 22 by entanglement of the individual fibers of the web 96 with the individual fibers of the web 22 during formation of the web 96 on the surface of the web 22.
  • the fibrous nonwoven gatherable web 96 is simultaneously formed upon and joined to the fibrous nonwoven elastic web 22.
  • improved joining of the webs 50 and 96 to the web 22 can be effected by application of a coating of an adhesive material to the surface of the elastic web 22 prior to formation of the webs 50 and 96 upon the stretched surface of the web 22.
  • Application of such an adhesive coating to the surface of web 22 may be conventionally readily effected by the nip rollers 32 and 82.
  • the adhesive material could be conventionally applied to the surface of the rollers 32 and 82 so that the rollers 32 and 82 would transfer the adhesive onto the surface of the web 22 as the web 22 passes through the nips 28 and 78.
  • the adhesive may be applied onto the surface of the web 22 in a configuration of spots.
  • the biasing force on the web 22 is relaxed by passing the three webbed composite 100 through the nip or gap 102 between two rotating nip rollers 104 and 106. Rotation of the rollers 104 and 106 is adjusted so that the peripheral surface speed of the rollers 104 and 106 allows the composite web 100 to relax and, as a result of its elastic properties, to contract to its relaxed, unbiased length.
  • the relaxing and contracting of the web 100 to its relaxed, unbiased length results in both of the fibrous nonwoven gatherable webs 50 and 96 being gathered by the relaxing and contracting of the fibrous nonwoven elastic web 22.
  • the composite web 100 can be rolled up and stored as is illustrated at 108. Since the tacky elastic web 22 is sandwiched between the webs 50 and 96 it will not adhere to other portions of the composite web 100 during storage. This material may be utilized to form a variety of products, such as, for example, diaper products.
  • the three webbed composite 100 discussed above with respect to a tacky nonwoven elastic web 22 could be formed without using a tacky material to form the web 22.
  • the other methods of joining for example, fibrous entanglement, heat-bonding or sonic bonding, the web 96 to the web 22 would have to be utilized.
  • FIG. 4 illustrates another embodiment of the present invention which avoids the requirement of forming the gathered nonwoven elastic web 50 of the embodiment of Figure 1 on the stretched, extended surface of the nonwoven elastic web 22.
  • the gathered nonwoven elastic web 50 is formed directly on the surface of a porous forming screen 110 which, itself, is extendable and retractable in the machine direction of movement as is indicated by the arrow 112.
  • the extendable and retractable porous collecting screen 100 could be formed from a continuous web of the nonwoven elastic web 22.
  • the extendable and retractable porous collecting screen 110 could be formed from a wire mesh screen 114 which is generally illustrated in Figure 5.
  • the wire mesh screen 114 could be formed from a plurality of substantially parallel springs 116 coiled and extending in the machine direction (MD) with the springs 116 being connected to each other in the transverse machine direction (TD) by a plurality of fine, generally parallel wires 118 extending in the transverse machine direction (TD).
  • the transverse direction wires 118 may be arranged very closely to each other so that, when the wire mesh screen 114 is in an unbiased, retracted or contracted configuration, the transverse direction wires 118 contact each other.
  • the coiled springs 116 Upon application of a tensioning or biasing force in the machine direction, the coiled springs 116 will extend, that is, stretch, in the machine direction and the fine transverse direction wires 118 will separate from each other to form the porous collecting surface 110.
  • This biased, stretched, extended configuration is generally illustrated in Figure 6.
  • the wire mesh screen 114 could be formed by a plurality of substantially parallel springs coiled and extending in the transverse machine direction (TD) with the springs being connected to each other in the machine direction (MD) by a plurality of fine, generally parallel wires extending in the machine direction (MD).
  • This configuration would be illustrated upon rotating Figures 5 and 6 90° and results in a configuration by which the gatherable web 96 could be gathered in the transverse machine direction (TD) as opposed to the machine direction (MD) as is illustrated in the figures. If gathering of the gatherable web 96 in the transverse direction is desired additional conventional arrangements (not shown) for extending and contracting the screen 114 in the transverse direction would replace the arrangement illustrated in the figures for extending and contracting the screen 114 in the machine direction (MD).
  • the nip 124 is adjusted so that the rollers 126 and 128 firmly engage the extendable and retractable or contractable porous collecting screen 110 without adversely affecting the screen 110.
  • Rotation of the rollers 126 and 128 is adjusted so that the peripheral surface speed of the rollers 126 and 128 is substantially the same as the peripheral surface speed of the rollers 120 and 122.
  • the extendable and retractable or contractable porous collecting screen 110 also passes through the nip 130 between another pair of rotating nip rollers 132 and 134 with the nip 130 being adjusted so that the rollers 132 and 134 firmly engage the porous collecting screen 110 without adversely affecting the porous collecting screen 110.
  • the rotaton of the rollers 132 and 134 is adjusted so that the peripheral surface speed of the rollers 132 and 134 is greater than the peripheral surface speed of the rollers 120 and 122.
  • a longitudinal or machine direction (MD) biasing and extending force is placed on the extendable and contractable porous collecting screen 110 and the screen 110 is extended to an extended, biased length in the longitudinal direction in the area 136.
  • the degree of extension of the porous collecting screen 110 which occurs in the area 136 between the rollers 126 and 128 and the rollers 132 and 134 may be varied, for example, by varying the peripheral surface speed of the rollers 132 and 134 with respect to the peripheral surface speed of the rollers 126 and 128. For example, if the peripheral surface speed of the rollers 132 and 134 is about twice that of the rollers 126 and 128, the extendable and retractable porous collecting screen 110 will be extended to an extended, biased length of substantially about twice, that is, about 200 percent, of its retracted, unbiased length.
  • the extendible and retractable porous collecting screen 110 is extended, in the area 136, to a length which is at least about 125 percent of its contracted, unbiased and unextended length.
  • the screen 110 is preferred for the screen 110 to be extended to an extended length, in the area 136, of from at least about 150 percent of its retracted, unbiased and unextended length.
  • the porous collecting surface 110 is preferred to be extended to an extended length of from at least about 150 percent of the retracted, unbiased and unextended length of the porous collecting surface 110 to about 700 or more percent of the retracted, unbiased and unextended length of the porous collecting surface 110.
  • meltblown microfibers 138 which are formed by a conventional meltblowing die 140 are meltblown onto the extended surface of the porous collecting screen 110.
  • meltblown microfibers 138 are deposited upon the extended porous collecting screen 110 they entangle and cohere to form a cohesive fibrous nonwoven gatherable web 96.
  • the entangled cohesive fibrous nonwoven gatherable web 96 is carried by the porous collecting screen 110 through the nip 130 and on to a nip 142 formed between the rotating roller 120 and a rotating nip roller 144.
  • the peripheral surface speed of the rotating nip roller 144 is adjusted so that it is substantially the same as the peripheral surface speed of the rotating roller 120 and the rollers 122 and 126 and 128. Because the peripheral surface speed of the rollers 144 and 120 is substantially the same as the peripheral surface speed of the rollers 122 and 126 and 128 the extending force is removed from the extended porous collecting screen 110 and the screen 110 is retracted, that is allowed to contract, as a result of its contractable properties, to its contracted, unbiased length.
  • the relaxing and contracting of the porous collecting screen 110 to its contracted, unbiased length results in the fibrous nonwoven gatherable web 96, which was formed on the surface of the screen 110 while the screen 110 was being maintained in its extended configuration, being carried along with, and retracted and thus gathered upon the upper surface of the retracting porous collecting screen 110.
  • the gathering of the fibrous nonwoven gatherable web 96 accordingly, occurs in the area 146 between the pairs of rollers 132 and 134 and 120 and 144.
  • the fibrous nonwoven gatherable web 96 may be rolled up on a supply roller 148 for storage and shipment.
  • the rate of rotation of the supply roller 148 should be controlled so that the gathered fibrous nonwoven 96 is stored in substantially an untensioned state. This may be accomplished by adjusting the rate of rotation of the roller 148 so that the peripheral surface speed of the roller 148 is substantially equal to or just slightly greater than the peripheral surface speed of the rollers 120 and 144.
  • the fibrous nonwoven gathered webs 50 and 96 are separated from the fibrous nonwoven elastic web 22 by passing the web 50 through the nip 150 between two rotating nip rollers 152 and 154 and passing the web 96 through the nip 156 between two rotating nip rollers 158 and 160.
  • the webs 50 and 96 are then wound-up for storage and later used on their respective storage rolls 162 and 164.
  • the fibrous nonwoven gatherable webs 50 and 96 were formed by utilization of a conventional meltblowing die and meltblowing processes, conventional spunbonding dies and spundbonding processes may be substituted for the meltblowing dies and processes and the scope of the present invention is intended to include materials formed by the substitution of spunbonding dies and processes or any other apparatus and process for forming a nonwoven gatherable web for the meltblowing dies and processes 48 and 94.
  • the joining of one or more of the webs 50 and 96 to the web 22 is to be effected by heat-bonding (whether the webs 50 and 96 are spun bonded, meltblown or formed by other processes) care should be taken to allow the web 22 to relax and contract to substantially an untensioned, unbiased condition or configuration as soon as is pratical after the heat-bonding step has occurred because it is believed that the nonwoven elastic web 22 will lose its elasticity if it is maintained above its softening for any significant period of time. This loss of elasticity may result from the cooling elastic web 22 "setting" while in the stretched configuration if it is maintained in the stretched configuration for a significant period of time after heat-bonding.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
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EP86109998A 1985-07-30 1986-07-21 Nichtgewebtes elastisches Plissee Expired - Lifetime EP0212284B1 (de)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US06/760,445 US4652487A (en) 1985-07-30 1985-07-30 Gathered fibrous nonwoven elastic web
US760449 1985-07-30
US06/760,449 US4657802A (en) 1985-07-30 1985-07-30 Composite nonwoven elastic web
US760445 1985-07-30

Publications (3)

Publication Number Publication Date
EP0212284A2 true EP0212284A2 (de) 1987-03-04
EP0212284A3 EP0212284A3 (en) 1989-11-15
EP0212284B1 EP0212284B1 (de) 1993-09-22

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EP86109998A Expired - Lifetime EP0212284B1 (de) 1985-07-30 1986-07-21 Nichtgewebtes elastisches Plissee

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EP (1) EP0212284B1 (de)
JP (1) JPH0737703B2 (de)
KR (1) KR950006867B1 (de)
AU (1) AU580435B2 (de)
CA (1) CA1316651C (de)
DE (1) DE3689058T2 (de)
MX (2) MX166979B (de)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0337687A2 (de) * 1988-04-11 1989-10-18 E.I. Du Pont De Nemours And Company Mehrschichtige, elastische Steppstoffbahn
EP0341870A2 (de) * 1988-05-13 1989-11-15 Minnesota Mining And Manufacturing Company Absorbierender elastomerischer Wundverband
EP0333228A3 (en) * 1988-03-18 1990-05-02 Kimberly-Clark Corporation Nonwoven fibrous non-elastic material and method of formation thereof
US4957795A (en) * 1988-05-13 1990-09-18 Minnesota Mining And Manufacturing Company Absorbent elastomeric wound dressing
EP0432755A1 (de) * 1989-12-15 1991-06-19 Kimberly-Clark Corporation Vielseitig streckbares, elastisches Verbundmaterial und dessen Herstellungsverfahren
EP0432763A1 (de) * 1989-12-15 1991-06-19 Kimberly-Clark Corporation Vielseitig streckbares elastisches Verbundmaterial und sein Herstellungsverfahren
EP0420256A3 (en) * 1989-09-29 1992-02-12 Kimberly-Clark Corporation Increased pile density composite elastic material
EP0474123A1 (de) * 1990-09-06 1992-03-11 Kimberly-Clark Corporation Extrusionsbeschichteter Vliesschichtstoff, Verfahren zur Herstellung sowie dessen Verwendung
EP0548609A1 (de) * 1991-12-09 1993-06-30 Kimberly-Clark Corporation Elastisches Verbundmaterial mit einem anisotropischen Faserband sowie Verfahren zur Herstellung
WO1997030843A1 (en) * 1996-02-20 1997-08-28 Kimberly-Clark Worldwide, Inc. Fully elastic nonwoven fabric laminate
WO1997034037A1 (en) * 1996-03-14 1997-09-18 Kimberly-Clark Worldwide, Inc. Nonwoven fabric laminate with good conformability
US5939339A (en) * 1992-07-22 1999-08-17 3M Innovative Properties Company Absorbent self adhering elastic bandage
US6096668A (en) * 1997-09-15 2000-08-01 Kimberly-Clark Worldwide, Inc. Elastic film laminates
EP1186283A2 (de) * 2000-09-01 2002-03-13 Uni-Charm Corporation Elastisch dehnbares zusammengesetzte Blatt und tragender Wegwerfartikel mit diesem zusammengesetzten Blatt
US20100267914A1 (en) * 2009-04-21 2010-10-21 Alistair Duncan Westwood Method for Producing Temperature Resistant NonWovens
US8183429B2 (en) 2006-11-28 2012-05-22 Uni-Charm Corporation Composite sheet and absorbent article comprising composite sheet
EP3215084A1 (de) * 2014-11-06 2017-09-13 The Procter and Gamble Company Vorgespannte laminate und verfahren zur herstellung davon

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4775579A (en) * 1987-11-05 1988-10-04 James River Corporation Of Virginia Hydroentangled elastic and nonelastic filaments
CA1339061C (en) * 1988-09-23 1997-07-29 Michael Tod Morman Composite elastic necked-bonded material
US4965122A (en) * 1988-09-23 1990-10-23 Kimberly-Clark Corporation Reversibly necked material
EP0803602A4 (de) * 1995-01-12 2002-06-26 Japan Absorbent Tech Inst Elastischer verbundkörper mit mehrstüfiger dehnnbarkeit und verfahren zu ihrer herstellung
EP1876277B8 (de) * 2005-04-25 2012-04-25 Kao Corporation Stretchvliesstoff und herstellungsverfahren dafür
KR101484114B1 (ko) * 2006-11-28 2015-01-19 유니 참 코포레이션 복합 시트 및 복합 시트를 사용한 흡수성 물품
JP5783951B2 (ja) * 2012-04-27 2015-09-24 ユニ・チャーム株式会社 複合シートおよび複合シートの製造方法
EP4335420A3 (de) 2017-02-16 2024-05-29 The Procter & Gamble Company Saugfähige artikel mit substraten mit sich wiederholenden mustern von öffnungen mit mehreren wiederholungseinheiten

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2957512A (en) * 1953-12-24 1960-10-25 American Viscose Corp Method of producing elastic composite sheet material
US4100324A (en) * 1974-03-26 1978-07-11 Kimberly-Clark Corporation Nonwoven fabric and method of producing same
WO1980000676A1 (en) * 1978-09-22 1980-04-17 Fuller H B Co Hot melt adhesive for elastic banding and method for utilizing the same

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3687797A (en) * 1970-09-28 1972-08-29 Kimberly Clark Co Resilient cellulosic wadding product
JPS5347360B2 (de) * 1971-08-19 1978-12-20
JPS4910309A (de) * 1972-05-31 1974-01-29
US4418123A (en) * 1978-12-06 1983-11-29 H. B. Fuller Company Extrudable self-adhering elastic and method of employing same
JPS58124636A (ja) * 1982-01-21 1983-07-25 三洋化成工業株式会社 積層繊維材料の伸縮性複合体製造方法
JPS58132157A (ja) * 1982-01-31 1983-08-06 ユニ・チヤ−ム株式会社 植毛不織布及びその製造方法
JPS59201846A (ja) * 1983-04-30 1984-11-15 日本バイリ−ン株式会社 伸縮テ−プ及びその製造法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2957512A (en) * 1953-12-24 1960-10-25 American Viscose Corp Method of producing elastic composite sheet material
US4100324A (en) * 1974-03-26 1978-07-11 Kimberly-Clark Corporation Nonwoven fabric and method of producing same
WO1980000676A1 (en) * 1978-09-22 1980-04-17 Fuller H B Co Hot melt adhesive for elastic banding and method for utilizing the same

Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0333228A3 (en) * 1988-03-18 1990-05-02 Kimberly-Clark Corporation Nonwoven fibrous non-elastic material and method of formation thereof
EP0337687A3 (en) * 1988-04-11 1990-08-01 E.I. Du Pont De Nemours And Company Quilted elastic composite fabric
EP0337687A2 (de) * 1988-04-11 1989-10-18 E.I. Du Pont De Nemours And Company Mehrschichtige, elastische Steppstoffbahn
EP0341870A2 (de) * 1988-05-13 1989-11-15 Minnesota Mining And Manufacturing Company Absorbierender elastomerischer Wundverband
EP0341870A3 (en) * 1988-05-13 1990-01-10 Minnesota Mining And Manufacturing Company Absorbent elastomeric wound dressing absorbent elastomeric wound dressing
US4957795A (en) * 1988-05-13 1990-09-18 Minnesota Mining And Manufacturing Company Absorbent elastomeric wound dressing
EP0420256A3 (en) * 1989-09-29 1992-02-12 Kimberly-Clark Corporation Increased pile density composite elastic material
EP0432755A1 (de) * 1989-12-15 1991-06-19 Kimberly-Clark Corporation Vielseitig streckbares, elastisches Verbundmaterial und dessen Herstellungsverfahren
EP0432763A1 (de) * 1989-12-15 1991-06-19 Kimberly-Clark Corporation Vielseitig streckbares elastisches Verbundmaterial und sein Herstellungsverfahren
US5116662A (en) * 1989-12-15 1992-05-26 Kimberly-Clark Corporation Multi-direction stretch composite elastic material
EP0474123A1 (de) * 1990-09-06 1992-03-11 Kimberly-Clark Corporation Extrusionsbeschichteter Vliesschichtstoff, Verfahren zur Herstellung sowie dessen Verwendung
EP0548609A1 (de) * 1991-12-09 1993-06-30 Kimberly-Clark Corporation Elastisches Verbundmaterial mit einem anisotropischen Faserband sowie Verfahren zur Herstellung
AU655081B2 (en) * 1991-12-09 1994-12-01 Kimberly-Clark Worldwide, Inc. A composite elastic material including an anisotropic elastic fibrous web and process to make the same
US5939339A (en) * 1992-07-22 1999-08-17 3M Innovative Properties Company Absorbent self adhering elastic bandage
WO1997030843A1 (en) * 1996-02-20 1997-08-28 Kimberly-Clark Worldwide, Inc. Fully elastic nonwoven fabric laminate
WO1997034037A1 (en) * 1996-03-14 1997-09-18 Kimberly-Clark Worldwide, Inc. Nonwoven fabric laminate with good conformability
AU705599B2 (en) * 1996-03-14 1999-05-27 Kimberly-Clark Worldwide, Inc. Nonwoven fabric laminate with good conformability
US6096668A (en) * 1997-09-15 2000-08-01 Kimberly-Clark Worldwide, Inc. Elastic film laminates
EP1186283A2 (de) * 2000-09-01 2002-03-13 Uni-Charm Corporation Elastisch dehnbares zusammengesetzte Blatt und tragender Wegwerfartikel mit diesem zusammengesetzten Blatt
SG89417A1 (en) * 2000-09-01 2002-06-18 Uni Charm Corp Elastically stretchable composite sheet and disposable wearing article using this composite sheet
EP1186283A3 (de) * 2000-09-01 2002-09-04 Uni-Charm Corporation Elastisch dehnbares zusammengesetzte Blatt und tragender Wegwerfartikel mit diesem zusammengesetzten Blatt
US8183429B2 (en) 2006-11-28 2012-05-22 Uni-Charm Corporation Composite sheet and absorbent article comprising composite sheet
AU2007326554B2 (en) * 2006-11-28 2012-07-26 Uni-Charm Corporation Composite sheet and absorbent article comprising composite sheet
US20100267914A1 (en) * 2009-04-21 2010-10-21 Alistair Duncan Westwood Method for Producing Temperature Resistant NonWovens
US9168718B2 (en) * 2009-04-21 2015-10-27 Exxonmobil Chemical Patents Inc. Method for producing temperature resistant nonwovens
EP3215084A1 (de) * 2014-11-06 2017-09-13 The Procter and Gamble Company Vorgespannte laminate und verfahren zur herstellung davon
US10786401B2 (en) 2014-11-06 2020-09-29 The Procter & Gamble Company Apertured topsheets and methods for making the same
US10973705B2 (en) 2014-11-06 2021-04-13 The Procter & Gamble Company Apertured webs and methods for making the same
US11090202B2 (en) 2014-11-06 2021-08-17 The Procter & Gamble Company Apertured webs and methods for making the same
US11135103B2 (en) 2014-11-06 2021-10-05 The Procter & Gamble Company Apertured webs and methods for making the same
EP3215084B1 (de) * 2014-11-06 2022-01-05 The Procter & Gamble Company Vorgespannte laminate und verfahren zu deren herstellung

Also Published As

Publication number Publication date
MX9205896A (es) 1994-04-29
EP0212284B1 (de) 1993-09-22
JPS6228456A (ja) 1987-02-06
DE3689058T2 (de) 1994-01-13
EP0212284A3 (en) 1989-11-15
KR950006867B1 (ko) 1995-06-23
AU580435B2 (en) 1989-01-12
JPH0737703B2 (ja) 1995-04-26
DE3689058D1 (de) 1993-10-28
MX166979B (es) 1993-02-17
CA1316651C (en) 1993-04-27
AU6048786A (en) 1987-02-05
KR870001351A (ko) 1987-03-13

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