EP0211909A1 - A double- or multi-walled thermos container of a ceramic material, and a method and a mould for producing it - Google Patents

A double- or multi-walled thermos container of a ceramic material, and a method and a mould for producing it

Info

Publication number
EP0211909A1
EP0211909A1 EP19860901362 EP86901362A EP0211909A1 EP 0211909 A1 EP0211909 A1 EP 0211909A1 EP 19860901362 EP19860901362 EP 19860901362 EP 86901362 A EP86901362 A EP 86901362A EP 0211909 A1 EP0211909 A1 EP 0211909A1
Authority
EP
European Patent Office
Prior art keywords
container
mould
ceramic
liquid
thermos
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP19860901362
Other languages
German (de)
French (fr)
Inventor
Kirsten Kampp
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of EP0211909A1 publication Critical patent/EP0211909A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/26Producing shaped prefabricated articles from the material by slip-casting, i.e. by casting a suspension or dispersion of the material in a liquid-absorbent or porous mould, the liquid being allowed to soak into or pass through the walls of the mould; Moulds therefor ; specially for manufacturing articles starting from a ceramic slip; Moulds therefor
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47JKITCHEN EQUIPMENT; COFFEE MILLS; SPICE MILLS; APPARATUS FOR MAKING BEVERAGES
    • A47J41/00Thermally-insulated vessels, e.g. flasks, jugs, jars
    • A47J41/02Vacuum-jacket vessels, e.g. vacuum bottles
    • A47J41/022Constructional details of the elements forming vacuum space
    • A47J41/024Constructional details of the elements forming vacuum space made of glass
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B28WORKING CEMENT, CLAY, OR STONE
    • B28BSHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
    • B28B1/00Producing shaped prefabricated articles from the material
    • B28B1/26Producing shaped prefabricated articles from the material by slip-casting, i.e. by casting a suspension or dispersion of the material in a liquid-absorbent or porous mould, the liquid being allowed to soak into or pass through the walls of the mould; Moulds therefor ; specially for manufacturing articles starting from a ceramic slip; Moulds therefor
    • B28B1/261Moulds therefor

Definitions

  • thermos container of a ceramic material and a method and a mould for producing it
  • the present invention relates to a double- or multi-walled and upwardly open thermos container of a ceramic material, consisting of two or more containers which are disposed within each other and are mutually separated, but conti ⁇ guous at least along the edge of the upper opening.
  • the invention also relates to a method of producing such a thermos container and a mould for use in the performance of the method.
  • Double-walled or multi-walled containers are widely used as thermos containers, which may have the shape of bowls, bottles, flasks, cups or jugs, e.g. for the storage of hot or cold beverages. If the space between the container walls is approximately evacuated, the container will have a great insulation capability so that the contents may maintain the temperature for a long period of time.
  • thermos containers are frequently made of glass by blowing of a glass mass softened in the heat.
  • Such thermos con ⁇ tainers must have rather thin walls in order to resist strong temperature effects, e.g. . when a boiling liquid is poured into a container at room temperature.
  • thermos containers are generally provided with a protective jacket, e.g. of metal, which is impact and shock resistant.
  • thermos containers and similar double- or multi-walled containers of ceramic materials such as clay, stoneware clay or china clay which are fired or sintered and optionally also- glazed.
  • Fired ceramic containers have also great resistance to temperature fluctuations and have a relatively great strength as well, so that, normally, they can be used without any protective jacket.
  • the mould used there consists of an outer mould part with a cavity corresponding to the outer wall of the container, as well as a core introduced into the cavity.
  • a liquid ceramic mass is introduced into the space between the inner side of the outer mould part and the core.
  • the plaster mould is porous and therefore absorbs water from the liquid ceramic mass, so that a layer of ceramic mass deposits on the mould inner sides, i.e. both on the core surface and on the inner side of the outer mould part. When this layer has reached a desired thickness, the still liquid part of the ceramic substance is poured out of the mould to provide a double-walled container with a cavity between the two walls.
  • the resulting double-walled ceramic container is dried, fired and glazed in the usual manner.
  • This known method has limited application because it must be possible, of course, to remove the core from the container opening. Therefore, this method does not allow manufacturing of containers in the form of bottles, flasks or jars whose opening has a smaller diameter than the interior of the container.
  • the object of the present invention is to provide a double- or multi-walled container of any desired shape, e.g. in the form of a bottle, flask or jar with an arbitrarily narrow neck or opening.
  • thermos container of the invention is characterized 5 by the sub ect-matter defined in the characterizing portion of claim 1.
  • the core consists of a first and pre-formed ceramic container which is to define the inner wall of the double- walled container.
  • the liquid moulding mass is introduced into the space between the inner side of a liquid-absorb-
  • the mould constructed as stated in claim 9, absorbs liquid from the liquid moulding mass, so that a layer will deposit on the inner side of the .mould to form the outer wall of the container.
  • the formed double-walled or multi-walled container is removed from the mould, dried, fired and glazed. Since 35 firing and glazing are effected at a high temperature, with development of i.a. water vapours because of ceramic reactions during the sintering process, practically any trace of air will be expelled from the space between the two container walls. During cooling, the glaze will solidify and form a gas-tight layer, so that a vacuum having a thermally insulating effect will prevail between the two or more container walls.
  • the mould used is preferably a mould of plaster, but, if desired, any other porous and liquid-absorbing material may be used, e.g. unglazed porous ceramic foam plastics or a fibre material, such as glass fibres, plant fibres or plastics fibres.
  • the first container which is to form the inner wall of the double-walled container, may be manufactured in a known manner, such as by throwing, pressing or moulding.
  • the first container may be moulded separately in a liquid-absorbing " "mould, e.g. of plaster, without a core, by introduction of liquid ceramic mass into the mould cavity so that a layer of the desired thickness will deposit on the inner side of said cavity.
  • a liquid-absorbing "mould e.g. of plaster
  • the first container After moulding of the first container, it may be expedient to impregnate or lacquer its outer side, so that it does not absorb liquid.
  • shellac or another lacquer may be used, or a metallic layer may be deposited.
  • the first container might be moulded with thin walls.
  • the wall thickness of the inner container would be increased at the same time.
  • Deposit of moulding mass on the outer side of the inner container may be controlled by adjusting the moisture content of the inner container wall when moulding in the second step is performed. Thus, if the first container has a high moisture content when introduced into the second mould, no or only little moulding mass will deposit on the outer side of the first container.
  • the first or inner container is given a lacquer finish on its exterior, a zone should be kept free at the opening of the container, so that the outer container can be moulded together with the inner container at that zone. If an organic resin is used for the lacquer finish, it will burn away during the firing and/or glazing of the container. In the event that the outer side of the inner container and optionally also the inner side of the outer container are provided with a heat-reflecting metallic coating, improved thermal insulation capability is obtained.
  • the ceramic moulding mass may be clay or stoneware clay to which sufficient water has been added to impart a liquid consistency to the mixture. Instead, an aqueous china clay solution may be used. In that case, finished containers of porcelain are obtained.
  • fig. 1 is a section through a mould for the making of a first ceramic container
  • fig. 2 is a cross-section of a mould for the making of another ceramic container around the first container.
  • the mould shown in fig. 1 consists of two mould parts 1 and 2 of a liquid-absorbing material, such as plaster, and has upwardly an opening in which a plug 4 is inserted
  • the plug has a through bore 5 and a guide face 9 mating with a guide face 8 in the opening of the mould.
  • the underside 14 of the plug 4 and the inner side 13 of the through bore 5 are given a shellak finish to avoid deposits of ceramic mass on these faces.
  • the mould is filled with a liquid ceramic moulding mass, such as an aqueous suspension of clay or porcelain.
  • the porous mould absorbs liquid from the liquid ceramic moulding mass, so that a layer 7 of the ceramic mass deposits along the inner side 6, 11, 12 of the mould. When this layer has reached a desired thickness, excess of liquid moulding mass is poured out.
  • the mould 1, 2 is separated, and the formed first con- tainer 7 with the plug 4 in the container opening is removed.
  • the outer side 16 of the container 7 is given a shellak finish, apart from a .zone 30 along the upper edge of the container.
  • the treated container 7 with the plug 4 in the opening is intTpduced into another mould 21, 22 likewise of a liquid-absorbing material.
  • the mould 21, 22 is inverted, and the mould is filled with liquid ceramic moulding mass through an opening 23 in the bottom of the mould. Owing to absorption of liquid in the mould, a layer 27 of ceramic mass deposits on the inner side 26 of the mould, whereas no layer deposits on the lacquered surface 16 of the first con ⁇ tainer 7, apart from the unlacquered zone 30.
  • the container After cooling, the container is glazed on the inside and the outside and fired again in a furnace. During the last firing, the glaze closes all pores. Prior to this, most of the volatile substances and gases have been expelled from the space 20 between the two container walls, and accordingly, a vacuum prevails in this space after cooling.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Food Science & Technology (AREA)
  • Cookers (AREA)
  • Packages (AREA)
  • Table Devices Or Equipment (AREA)
  • Thermally Insulated Containers For Foods (AREA)
  • Producing Shaped Articles From Materials (AREA)

Abstract

Un récipient isolant en matériau céramique à parois doubles ou multiples et produit par moulage d'une masse céramique liquide dans un moule absorbant de liquides dans lequel est inséré un récipient (7), pouvant avoir une ou plusieurs parois, pour servir de noyau. La masse liquide de moulage est introduite dans l'espace (20) entre le côté intérieur (26) du moule et le premier récipient (7) inséré dans le moule. Une couche de masse de moulage (27) se dépose sur le côté intérieur du moule pour former la paroi extérieure du moule. Le récipient est retiré du moule une fois que l'excédant de masse liquide de moulage a été évacué, puis achevé par séchage, cuisson et glaçage.An insulating container made of ceramic material with double or multiple walls and produced by molding a liquid ceramic mass in a liquid absorbent mold in which is inserted a container (7), which may have one or more walls, to serve as a core. The liquid molding mass is introduced into the space (20) between the interior side (26) of the mold and the first container (7) inserted in the mold. A layer of molding compound (27) is deposited on the inside of the mold to form the outside wall of the mold. The container is removed from the mold once the excess molding liquid mass has been removed, then completed by drying, baking and frosting.

Description

A double- or multi-walled thermos container of a ceramic material, and a method and a mould for producing it
The present invention relates to a double- or multi-walled and upwardly open thermos container of a ceramic material, consisting of two or more containers which are disposed within each other and are mutually separated, but conti¬ guous at least along the edge of the upper opening.
The invention also relates to a method of producing such a thermos container and a mould for use in the performance of the method.
Double-walled or multi-walled containers are widely used as thermos containers, which may have the shape of bowls, bottles, flasks, cups or jugs, e.g. for the storage of hot or cold beverages. If the space between the container walls is approximately evacuated, the container will have a great insulation capability so that the contents may maintain the temperature for a long period of time.
Thermos containers are frequently made of glass by blowing of a glass mass softened in the heat. Such thermos con¬ tainers must have rather thin walls in order to resist strong temperature effects, e.g.. when a boiling liquid is poured into a container at room temperature. To reduce the risk of cracking, thermos containers are generally provided with a protective jacket, e.g. of metal, which is impact and shock resistant.
There is a need for thermos containers and similar double- or multi-walled containers of ceramic materials, such as clay, stoneware clay or china clay which are fired or sintered and optionally also- glazed. Fired ceramic containers have also great resistance to temperature fluctuations and have a relatively great strength as well, so that, normally, they can be used without any protective jacket.
It is known from the US Patent Specification 2,839,209 to mould a double-walled ceramic container directly in a plaster mould and then fire and glaze the container in the usual manner. The mould used there consists of an outer mould part with a cavity corresponding to the outer wall of the container, as well as a core introduced into the cavity. During moulding, a liquid ceramic mass is introduced into the space between the inner side of the outer mould part and the core. The plaster mould is porous and therefore absorbs water from the liquid ceramic mass, so that a layer of ceramic mass deposits on the mould inner sides, i.e. both on the core surface and on the inner side of the outer mould part. When this layer has reached a desired thickness, the still liquid part of the ceramic substance is poured out of the mould to provide a double-walled container with a cavity between the two walls.
After separation of the mould, including removal of the core, the resulting double-walled ceramic container is dried, fired and glazed in the usual manner.
This known method has limited application because it must be possible, of course, to remove the core from the container opening. Therefore, this method does not allow manufacturing of containers in the form of bottles, flasks or jars whose opening has a smaller diameter than the interior of the container.
The object of the present invention is to provide a double- or multi-walled container of any desired shape, e.g. in the form of a bottle, flask or jar with an arbitrarily narrow neck or opening.
Ά
The thermos container of the invention is characterized 5 by the sub ect-matter defined in the characterizing portion of claim 1.
In the method of the invention, which is characterized by the features defined in the characterizing portion
10 of claim 7, comprising the use of a liquid-absorbing mould, the core consists of a first and pre-formed ceramic container which is to define the inner wall of the double- walled container. The liquid moulding mass is introduced into the space between the inner side of a liquid-absorb-
15 ing mould and the outer side of the first container introduced into the mould. The mould, constructed as stated in claim 9, absorbs liquid from the liquid moulding mass, so that a layer will deposit on the inner side of the .mould to form the outer wall of the container.
20 When this layer has reached the desired thickness, excess of liquid ceramic mass is poured out of the mould. This provides a cavity between the two walls of the container. If several layers or walls are desired, this process may be repeated by introducing the double-walled container
25 as a core, into another mould. Another layer will be formed along the mould inner side by introducing liquid moulding mass into the cavity between the inner side of this mould and the outer side of the inserted double- walled container. This results in the provision of a
30 multi-walled container with the number of layers or walls which are desired and useful in practice.
The formed double-walled or multi-walled container is removed from the mould, dried, fired and glazed. Since 35 firing and glazing are effected at a high temperature, with development of i.a. water vapours because of ceramic reactions during the sintering process, practically any trace of air will be expelled from the space between the two container walls. During cooling, the glaze will solidify and form a gas-tight layer, so that a vacuum having a thermally insulating effect will prevail between the two or more container walls.
The mould used is preferably a mould of plaster, but, if desired, any other porous and liquid-absorbing material may be used, e.g. unglazed porous ceramic foam plastics or a fibre material, such as glass fibres, plant fibres or plastics fibres.
The first container, which is to form the inner wall of the double-walled container, may be manufactured in a known manner, such as by throwing, pressing or moulding.
Thus, the first container may be moulded separately in a liquid-absorbing ""mould, e.g. of plaster, without a core, by introduction of liquid ceramic mass into the mould cavity so that a layer of the desired thickness will deposit on the inner side of said cavity.
After moulding of the first container, it may be expedient to impregnate or lacquer its outer side, so that it does not absorb liquid. To this end, e.g. shellac or another lacquer may be used, or a metallic layer may be deposited. This prevents deposit of ceramic mass on the first container during moulding of the other, outer container. Instead, the first container might be moulded with thin walls. When the outer container is moulded, the wall thickness of the inner container would be increased at the same time. Deposit of moulding mass on the outer side of the inner container may be controlled by adjusting the moisture content of the inner container wall when moulding in the second step is performed. Thus, if the first container has a high moisture content when introduced into the second mould, no or only little moulding mass will deposit on the outer side of the first container.
If the first or inner container is given a lacquer finish on its exterior, a zone should be kept free at the opening of the container, so that the outer container can be moulded together with the inner container at that zone. If an organic resin is used for the lacquer finish, it will burn away during the firing and/or glazing of the container. In the event that the outer side of the inner container and optionally also the inner side of the outer container are provided with a heat-reflecting metallic coating, improved thermal insulation capability is obtained.
The ceramic moulding mass may be clay or stoneware clay to which sufficient water has been added to impart a liquid consistency to the mixture. Instead, an aqueous china clay solution may be used. In that case, finished containers of porcelain are obtained.
An expedient embodiment of the invention will be explained more fully below with reference to the drawing, in which
fig. 1 is a section through a mould for the making of a first ceramic container, and
fig. 2 is a cross-section of a mould for the making of another ceramic container around the first container.
The mould shown in fig. 1 consists of two mould parts 1 and 2 of a liquid-absorbing material, such as plaster, and has upwardly an opening in which a plug 4 is inserted The plug has a through bore 5 and a guide face 9 mating with a guide face 8 in the opening of the mould. The underside 14 of the plug 4 and the inner side 13 of the through bore 5 are given a shellak finish to avoid deposits of ceramic mass on these faces. The mould is filled with a liquid ceramic moulding mass, such as an aqueous suspension of clay or porcelain. The porous mould absorbs liquid from the liquid ceramic moulding mass, so that a layer 7 of the ceramic mass deposits along the inner side 6, 11, 12 of the mould. When this layer has reached a desired thickness, excess of liquid moulding mass is poured out.
The mould 1, 2 is separated, and the formed first con- tainer 7 with the plug 4 in the container opening is removed. The outer side 16 of the container 7 is given a shellak finish, apart from a .zone 30 along the upper edge of the container. The treated container 7 with the plug 4 in the opening is intTpduced into another mould 21, 22 likewise of a liquid-absorbing material. The mould 21, 22 is inverted, and the mould is filled with liquid ceramic moulding mass through an opening 23 in the bottom of the mould. Owing to absorption of liquid in the mould, a layer 27 of ceramic mass deposits on the inner side 26 of the mould, whereas no layer deposits on the lacquered surface 16 of the first con¬ tainer 7, apart from the unlacquered zone 30.
When a suitable layer thickness 27 has deposited on the inner side of the mould 21, 22, most of the still liquid moulding mass is poured out. A porous plug is now inserted into the opening 23, and the mould is turned. The liquid moulding mass residue will settle on the bottom of the space 20, so that a layer of moulding mass deposits opposite the plug-closed opening 23 to close the bottom completely. The mould 21, 22 is separated, and the formed double-walled container is dried. The container is fired in a furnace at normal sintering temperature.
After cooling, the container is glazed on the inside and the outside and fired again in a furnace. During the last firing, the glaze closes all pores. Prior to this, most of the volatile substances and gases have been expelled from the space 20 between the two container walls, and accordingly, a vacuum prevails in this space after cooling.

Claims

P A T E N T C L A I M S
1. A double- or multi-walled and upwardly open thermos container of a ceramic material, consisting of two or more containers (7, 27) which are disposed within each other and are mutually separated, but contiguous at least along the edge (30) of the upper opening, c h a r a c t e r i z e d in that the outer container (27) is moulded around the inner container or containers (7) in a separate moulding process to form a closed space (20) between the outer container and the inwardly disposed container.
2. A thermos container according to claim 1, c h a r a c t e r i z e d in that the outer container has a constriction with an internal transverse dimension smaller than the largest external transverse dimension of the inner container in an area which is spaced more from the opening than the constriction.
3. A thermos container according to claim 1, c h a r a c t e r i z e d in that the closed space or spaces (20) defined between the container walls is approximately evacuated.
4. A thermos container according to claim 1, c h a r a c t e r i z e d in that the space or spaces (20). defined between the walls is filled with a porous insulation material.
5. A thermos container according to claim 1, where at least one of the walls is porous, c h a r a c t e r i z e d in that the container is covered with a gas-tight material, such as a glaze, on the inside and on the outside.
6. A thermos container according to any of claims 1-5, c h a r a c t e r i z e d in that at least one of the faces directed toward a space has a mirror coating.
7. A method of producing a thermos container according to claims 1-6 by moulding of a liquid ceramic mass in a liquid-absorbing mould equipped with a core, c h a r a c t e r i z e d in that the core consists of a first ceramic container inserted in the mould cavity so that the outer container is moulded together with the inserted first ceramic container along the edge of the upper opening.
8. A method according to claim 7, c h a r a c t e r i z e d by impregnating the first ceramic container prior to insertion into the mould with a liquid impermeable coating on the outer side, apart from the region or regions where the first ceramic container and the outer container are to be moulded together.
9. A mould for use in the performance of the method according to the claims 7 or 8, c h a r a c t e r i z e d in that it consists of a mould (21, 22) of a porous liquid-absorbing material which may be opened and has an opening provided with means (9, 28) for insertion and centering of a core (16).
10. A mould according to claim 9, c h a r a c t e r i z e d in that the opening is formed with a guide face (28), and that the means for inserting and centering the core consists of a plug (4) with a guide face (9) mating with the guide face (28) in the mould, as well as a face (11) fitting in the opening of the first container (7).
EP19860901362 1985-02-11 1986-02-10 A double- or multi-walled thermos container of a ceramic material, and a method and a mould for producing it Withdrawn EP0211909A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DK62585A DK161814C (en) 1985-02-11 1985-02-11 DOUBLE OR MULTIWAVE THERMO CONTAINER OF A CERAMIC MATERIAL AND PROCEDURE FOR THE PREPARATION OF SUCH THERMO CONTAINER AND FORM FOR USE IN PRACTICE OF THE PROCEDURE
DK625/85 1985-02-11

Publications (1)

Publication Number Publication Date
EP0211909A1 true EP0211909A1 (en) 1987-03-04

Family

ID=8095699

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19860901362 Withdrawn EP0211909A1 (en) 1985-02-11 1986-02-10 A double- or multi-walled thermos container of a ceramic material, and a method and a mould for producing it

Country Status (5)

Country Link
EP (1) EP0211909A1 (en)
DK (1) DK161814C (en)
ES (1) ES8702782A1 (en)
PT (1) PT82004B (en)
WO (1) WO1986004541A1 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2649630B2 (en) * 1992-05-29 1997-09-03 東陶機器株式会社 Casting method for ceramics
FR2907705B1 (en) * 2006-10-25 2009-01-16 Elmeceram Sa METHOD AND DEVICE FOR MANUFACTURING A CERAMIC CONTAINER
CN112497427B (en) * 2020-10-30 2021-12-31 高安罗斯福陶瓷有限公司 Utilize buoyancy to respond to automatic ceramic apparatus for producing of empting of mud consumption

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1305903A (en) * 1919-06-03 Heat-insulated eegeptaclb
US2839209A (en) * 1955-03-01 1958-06-17 Frank P Lester Ceramic structure and method for making same
EP0144168A3 (en) * 1983-11-21 1986-03-19 Yamamoto Seisakusho Ltd. Warmth keeping vessel made of ceramics or porcelain and method of producing the same

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO8604541A1 *

Also Published As

Publication number Publication date
PT82004A (en) 1986-03-01
DK62585D0 (en) 1985-02-11
ES8702782A1 (en) 1987-01-16
ES551803A0 (en) 1987-01-16
WO1986004541A1 (en) 1986-08-14
DK161814B (en) 1991-08-19
DK62585A (en) 1986-08-12
PT82004B (en) 1992-04-30
DK161814C (en) 1992-01-27

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