EP0208985A3 - Process for coal hydrogenation using as a catalyst an oil soluble metal compound - Google Patents

Process for coal hydrogenation using as a catalyst an oil soluble metal compound Download PDF

Info

Publication number
EP0208985A3
EP0208985A3 EP86108967A EP86108967A EP0208985A3 EP 0208985 A3 EP0208985 A3 EP 0208985A3 EP 86108967 A EP86108967 A EP 86108967A EP 86108967 A EP86108967 A EP 86108967A EP 0208985 A3 EP0208985 A3 EP 0208985A3
Authority
EP
European Patent Office
Prior art keywords
metal compound
catalyst
soluble metal
oil soluble
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
EP86108967A
Other languages
German (de)
French (fr)
Other versions
EP0208985A2 (en
Inventor
Klaus Dr. Fuhrmann
Ulrich Dr. Graeser
Ludwig Dr. Merz
Heinz-Jürgen Dr. Klewer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Veba Oel Technologie und Automatisierung GmbH
Original Assignee
Veba Oel Technologie und Automatisierung GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Veba Oel Technologie und Automatisierung GmbH filed Critical Veba Oel Technologie und Automatisierung GmbH
Publication of EP0208985A2 publication Critical patent/EP0208985A2/en
Publication of EP0208985A3 publication Critical patent/EP0208985A3/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C10G1/08—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal with moving catalysts
    • C10G1/086—Characterised by the catalyst used

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Bei diesem Verfahren zur Kohlehydrierung unter Verwen­ dung einer öllöslichen Metallverbindung als Katalysator wird feingemahlene, getrocknete Kohle mit einem Anmaischöl ver­ setzt, auf den Verfahrensdruck gebracht und nach Zusatz eines wasserstoffhaltigen Gases und Aufheizung einem Sumpfphasereaktorsystem bei einer Hydriertemperatur von etwa 450 bis 500 °C zugegeben. Zwecks Verbesserung der Reaktionsführung wird der Katalysator in Form von eisenphe­ nolat- oder eisennaphthenathaltigen im Anmaischöl löslichen Formulierungen zugeführt. In this process for carbohydrate use formation of an oil-soluble metal compound as a catalyst finely ground, dried coal with a mashing oil sets, brought to the process pressure and after addition a hydrogen-containing gas and heating one Bottom phase reactor system at a hydrogenation temperature of about 450 to 500 ° C added. In order to improve the The reaction is carried out in the form of iron phe nolate or iron naphthenate-soluble in the mashing oil Formulations supplied.

EP86108967A 1985-07-09 1986-07-02 Process for coal hydrogenation using as a catalyst an oil soluble metal compound Ceased EP0208985A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3524449 1985-07-09
DE19853524449 DE3524449A1 (en) 1985-07-09 1985-07-09 METHOD FOR HYDROGENATING COAL

Publications (2)

Publication Number Publication Date
EP0208985A2 EP0208985A2 (en) 1987-01-21
EP0208985A3 true EP0208985A3 (en) 1988-08-31

Family

ID=6275294

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86108967A Ceased EP0208985A3 (en) 1985-07-09 1986-07-02 Process for coal hydrogenation using as a catalyst an oil soluble metal compound

Country Status (2)

Country Link
EP (1) EP0208985A3 (en)
DE (1) DE3524449A1 (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE525011A (en) *
DE648130C (en) * 1931-07-30 1937-08-02 I G Farbenindustrie Akt Ges Process for the extraction of valuable liquid hydrocarbons from solid carbonaceous starting materials or tars, mineral oils and the like. Like. By pressure hydrogenation
US3502564A (en) * 1967-11-28 1970-03-24 Shell Oil Co Hydroprocessing of coal
FR2356714A1 (en) * 1976-07-02 1978-01-27 Exxon Research Engineering Co COAL HYDROCONVERSION PROCESS
US4169041A (en) * 1978-04-05 1979-09-25 Exxon Research & Engineering Co. Fluid coking with the addition of dispersible metal compounds

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE707813C (en) * 1935-12-22 1941-07-04 I G Farbenindustrie Akt Ges Process for the pressure extraction of coal, peat, bituminous slate and the like like
US3532617A (en) * 1968-07-23 1970-10-06 Shell Oil Co Hydroconversion of coal with combination of catalysts

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE525011A (en) *
DE648130C (en) * 1931-07-30 1937-08-02 I G Farbenindustrie Akt Ges Process for the extraction of valuable liquid hydrocarbons from solid carbonaceous starting materials or tars, mineral oils and the like. Like. By pressure hydrogenation
US3502564A (en) * 1967-11-28 1970-03-24 Shell Oil Co Hydroprocessing of coal
FR2356714A1 (en) * 1976-07-02 1978-01-27 Exxon Research Engineering Co COAL HYDROCONVERSION PROCESS
US4169041A (en) * 1978-04-05 1979-09-25 Exxon Research & Engineering Co. Fluid coking with the addition of dispersible metal compounds

Also Published As

Publication number Publication date
EP0208985A2 (en) 1987-01-21
DE3524449A1 (en) 1987-02-05
DE3524449C2 (en) 1987-05-14

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RIN1 Information on inventor provided before grant (corrected)

Inventor name: GRAESER, ULRICH, DR.

Inventor name: MERZ, LUDWIG, DR.

Inventor name: FUHRMANN, KLAUS, DR.

Inventor name: KLEWER, HEINZ-JUERGEN, DR.