EP0199551A2 - Condensateur imprégné d'huile - Google Patents
Condensateur imprégné d'huile Download PDFInfo
- Publication number
- EP0199551A2 EP0199551A2 EP19860302885 EP86302885A EP0199551A2 EP 0199551 A2 EP0199551 A2 EP 0199551A2 EP 19860302885 EP19860302885 EP 19860302885 EP 86302885 A EP86302885 A EP 86302885A EP 0199551 A2 EP0199551 A2 EP 0199551A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- oil
- phenyl
- impregnated
- capacitor
- impregnated capacitor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003990 capacitor Substances 0.000 title claims abstract description 51
- 239000010735 electrical insulating oil Substances 0.000 claims abstract description 14
- 239000002985 plastic film Substances 0.000 claims abstract description 8
- 229920006255 plastic film Polymers 0.000 claims abstract description 8
- 238000004804 winding Methods 0.000 claims abstract description 5
- AOWVXBUUWBOTKP-UHFFFAOYSA-N 1-methyl-2-(1-phenylethyl)benzene Chemical compound C=1C=CC=C(C)C=1C(C)C1=CC=CC=C1 AOWVXBUUWBOTKP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000003921 oil Substances 0.000 claims description 11
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 8
- 239000004743 Polypropylene Substances 0.000 claims description 5
- -1 polypropylene Polymers 0.000 claims description 5
- 229920001155 polypropylene Polymers 0.000 claims description 5
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims 1
- BOKDBSJFKVOFBS-UHFFFAOYSA-N 1-methyl-4-(1-phenylethyl)benzene Chemical compound C=1C=C(C)C=CC=1C(C)C1=CC=CC=C1 BOKDBSJFKVOFBS-UHFFFAOYSA-N 0.000 abstract description 3
- 239000010408 film Substances 0.000 description 7
- 230000015556 catabolic process Effects 0.000 description 5
- 239000011888 foil Substances 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- QTKIQLNGOKOPOE-UHFFFAOYSA-N 1,1'-biphenyl;propane Chemical group CCC.C1=CC=CC=C1C1=CC=CC=C1 QTKIQLNGOKOPOE-UHFFFAOYSA-N 0.000 description 2
- IAUKWGFWINVWKS-UHFFFAOYSA-N 1,2-di(propan-2-yl)naphthalene Chemical compound C1=CC=CC2=C(C(C)C)C(C(C)C)=CC=C21 IAUKWGFWINVWKS-UHFFFAOYSA-N 0.000 description 2
- MXLKDEFRUKFRJE-UHFFFAOYSA-N C=1C=CC=CC=1C1(CC)C=CC=CC1C(C)C Chemical compound C=1C=CC=CC=1C1(CC)C=CC=CC1C(C)C MXLKDEFRUKFRJE-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WYYWMBKUPQWNRU-UHFFFAOYSA-N (2-methyl-1-phenylpropyl)benzene Chemical compound C=1C=CC=CC=1C(C(C)C)C1=CC=CC=C1 WYYWMBKUPQWNRU-UHFFFAOYSA-N 0.000 description 1
- GNPWYHFXSMINJQ-UHFFFAOYSA-N 1,2-dimethyl-3-(1-phenylethyl)benzene Chemical compound C=1C=CC(C)=C(C)C=1C(C)C1=CC=CC=C1 GNPWYHFXSMINJQ-UHFFFAOYSA-N 0.000 description 1
- ZZFUVPDOJGQTKI-UHFFFAOYSA-N 1-methyl-2-[(2-methylphenyl)methyl]benzene Chemical compound CC1=CC=CC=C1CC1=CC=CC=C1C ZZFUVPDOJGQTKI-UHFFFAOYSA-N 0.000 description 1
- QODLNWFFLYSPEP-UHFFFAOYSA-N 1-methyl-2-[1-(2-methylphenyl)ethyl]benzene Chemical compound C=1C=CC=C(C)C=1C(C)C1=CC=CC=C1C QODLNWFFLYSPEP-UHFFFAOYSA-N 0.000 description 1
- VVLCULKJFSUPHN-UHFFFAOYSA-N 1-methyl-3-(1-phenylethyl)benzene Chemical compound C=1C=CC(C)=CC=1C(C)C1=CC=CC=C1 VVLCULKJFSUPHN-UHFFFAOYSA-N 0.000 description 1
- AMBHHSBRXZAGDZ-UHFFFAOYSA-N 1-phenyl-2,3-di(propan-2-yl)benzene Chemical group CC(C)C1=CC=CC(C=2C=CC=CC=2)=C1C(C)C AMBHHSBRXZAGDZ-UHFFFAOYSA-N 0.000 description 1
- BSZXAFXFTLXUFV-UHFFFAOYSA-N 1-phenylethylbenzene Chemical compound C=1C=CC=CC=1C(C)C1=CC=CC=C1 BSZXAFXFTLXUFV-UHFFFAOYSA-N 0.000 description 1
- BUZMJVBOGDBMGI-UHFFFAOYSA-N 1-phenylpropylbenzene Chemical compound C=1C=CC=CC=1C(CC)C1=CC=CC=C1 BUZMJVBOGDBMGI-UHFFFAOYSA-N 0.000 description 1
- PMPBFICDXLLSRM-UHFFFAOYSA-N 1-propan-2-ylnaphthalene Chemical compound C1=CC=C2C(C(C)C)=CC=CC2=C1 PMPBFICDXLLSRM-UHFFFAOYSA-N 0.000 description 1
- MILSYCKGLDDVLM-UHFFFAOYSA-N 2-phenylpropan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)C1=CC=CC=C1 MILSYCKGLDDVLM-UHFFFAOYSA-N 0.000 description 1
- PLLCCSYEGQDAIW-UHFFFAOYSA-N 5-ethyl-1,6-dimethyl-5-phenylcyclohexa-1,3-diene Chemical compound C=1C=CC=CC=1C1(CC)C=CC=C(C)C1C PLLCCSYEGQDAIW-UHFFFAOYSA-N 0.000 description 1
- ZQISRDCJNBUVMM-YFKPBYRVSA-N L-histidinol Chemical compound OC[C@@H](N)CC1=CNC=N1 ZQISRDCJNBUVMM-YFKPBYRVSA-N 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical compound C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- JUFLTGRGLUCRCU-UHFFFAOYSA-N ethanediimidoyl dicyanide Chemical compound N#CC(=N)C(=N)C#N JUFLTGRGLUCRCU-UHFFFAOYSA-N 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000011104 metalized film Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G4/00—Fixed capacitors; Processes of their manufacture
- H01G4/002—Details
- H01G4/018—Dielectrics
- H01G4/20—Dielectrics using combinations of dielectrics from more than one of groups H01G4/02 - H01G4/06
- H01G4/22—Dielectrics using combinations of dielectrics from more than one of groups H01G4/02 - H01G4/06 impregnated
- H01G4/221—Dielectrics using combinations of dielectrics from more than one of groups H01G4/02 - H01G4/06 impregnated characterised by the composition of the impregnant
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31678—Of metal
- Y10T428/31681—Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
Definitions
- the present invention relates to an oil-impregnated capacitor. More particularly, it is concerned with a capacitor impregnated with aromatic hydrocarbons which contains 1-phenyl-1-methylphenylethane having a specific isomer ratio.
- CSV corona discharge start voltage
- CEV corona discharge extinction voltage
- the present invention resides in an oil-impregnated capacitor made by winding at least one plastic film impregnated with an electrical insulating oil comprising 1-phenyl-1-methylphenylethane in which 1-phenyl-1-(4-methylphenyl)ethane and 1-phenyl-1-(2-methylphenyl)ethane are present in amounts of not less than 70 percent and not more than 15 percent, respectively, based on the total weight of the 1-phenyl-1-methylphenylethane.
- the PTE prefferably has the following isomer composition; not less than 70 wt.% (in PTE) of 1-phenyl-1-(4-methylphenyl)ethane (hereinafter referred to as "p-isomer”) and not more than 15 wt.% (in PTE) of 1-phenyl-1-(2-methylphenyl)ethane (hereinafter referred to as "o-isomer").
- the typical composition is 70-90 wt.% of p-isomer, 2-15 wt.% of o-isomer and 2-30 wt.% of m-isomer.
- the electrical insulating oil of the present invention may contain aromatic hydrocarbons other than the PTE.
- the PTE content is preferably 30 to 100 wt.%, more preferably 30 to 80 wt.%, based on the total weight of the insulating oil.
- the aromatic hydrocarbon preferably used in combination with the PTE in the present invention is an aromatic hydrocarbon having two condensed or noncondensed type aromatic rings, except PTE.
- Examples are diarylalkanes, alkylbiphenyls and alkylnaphthalenes.
- diarylalkanes are mentioned 1-phenyl-1-(dimethylphenyl)ethane, 1,1-di(methylphenyl)-ethane, 1-phenyl-l-ethylphenylethane, 1-phenyl-1-isopropylphenylethane, 1-phenyl-2-isopropylphenylethane, diphenylmethane, methylphenyl-phenylmethane, di(methylphenyl)methane, dimethylphenyl-phenylmethane, ethylphenyl-phenylmethane, and isopropylphenyl- phenylmethane.
- alkylbiphenyls are mentioned monoisopropylbiphenyl and diisopropylbiphenyl.
- alkylnaphthalenes are mentioned monoisopropylnaphthalene and diisopropylnaphthalene.
- the capacitor of the present invention is made by winding both a metallic foil such as an aluminum foil as an electrode and a plastic film to form a capacitor element and then impregnating it with an electrical insulating oil in a known manner.
- plastic film there is used such a film as a polyester, polyvinylidene fluoride or polyolefin film.
- a polyolefin film and particularly preferred is a polypropylene film.
- An insulating paper may be used together with the plastic film.
- a metallized film capacitor made by winding a metallized plastic film with a metal such as zinc vapor-deposited thereon is also included in the present invention.
- the oil-impregnated capacitor of the present invention can have a sufficiently long service life and fulfill a superior performance even at a temperature as low as -50°C.
- the oil-impregnated capacitors thus obtained were each electrically charged at a.potential gradient of 70 V/p at a low temperature of -50°C, and the time until breakdown of each capacitor was determined. More specifically, with respect to one insulating oil there were prepared ten capacitors impregnated therewith and their breaking times were determined, then out of ten measured values obtained, the highest and lowest values were excluded and a mean value of the remaining eight measured values was used as a breaking time of the capacitor concerned. Results are as set out in Table 1. Experiment-II
- the insulating oil Nos. 6 and 9 in Table 2 is the same as the insulating oil Nos. 6 and 9 in Table 1.
- the viscosity of PTE is changed according to isomer ratios.
- the viscosity of No.6 oil in Table 1 and 2, for example, is 4.0 cst at 30°C.
- PTE having the same isomer ratio as that shown in No.6 in Table 3 was mixed in various ratios with PXE, monoisopropylbiphenyl (MIPB hereinafter, trade name: TANATEX CG, product of SYBRON Co., Ltd.), diisopropylnaphthalene (DISN hereinafter, trade name: KIS-400, a product of Kureha Chemical Industry Co., Ltd.) and 1-phenyl-2-isopropylphenylethane (PIPE hereinafter, trade name: KIS-1000, a product of Kureha Chemical Industry Co., Ltd.), to prepare electrical insulating oils.
- MIPB monoisopropylbiphenyl
- DISN diisopropylnaphthalene
- KIS-400 1-phenyl-2-isopropylphenylethane
- PIPE 1-phenyl-2-isopropylphenylethane
- capacitor element Two polypropylene films each 14 u thick were put one upon another and the resulting laminate was wound together with a 7 p thick aluminum'foil as an electrode to obtain a capacitor element.
- the capacitor element was impregnated with each of the above electrical insulating oils in a known manner to obtain oil-impregnated capacitors each having a capacity of about 0.4 ⁇ F.
- the oil-impregnated capacitors thus obtained were each electrically charged at a potential gradient of 70 V/u at a low temperature of -50°C, and the time until breakdown of each capacitor was determined. More specifically, with respect to one insulating oil there were prepared ten capacitors impregnated therewith and their breaking times were determined, then out of ten measured values obtained, the highest and lowest values were excluded and a mean value of the remaining eight measured values was used as a breaking time of the capacitor concerned.
Landscapes
- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Fixed Capacitors And Capacitor Manufacturing Machines (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP82179/85 | 1985-04-19 | ||
| JP8217885A JPS61241907A (ja) | 1985-04-19 | 1985-04-19 | 油浸コンデンサ− |
| JP8217985A JPS61241908A (ja) | 1985-04-19 | 1985-04-19 | 油含浸コンデンサ− |
| JP82178/85 | 1985-04-19 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| EP0199551A2 true EP0199551A2 (fr) | 1986-10-29 |
| EP0199551A3 EP0199551A3 (en) | 1988-04-13 |
| EP0199551B1 EP0199551B1 (fr) | 1991-06-05 |
Family
ID=26423190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP19860302885 Expired - Lifetime EP0199551B1 (fr) | 1985-04-19 | 1986-04-17 | Condensateur imprégné d'huile |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US4716084A (fr) |
| EP (1) | EP0199551B1 (fr) |
| CA (1) | CA1277131C (fr) |
| DE (1) | DE3679588D1 (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2720232A1 (fr) * | 2011-06-07 | 2014-04-16 | JX Nippon Oil & Energy Corporation | Composition d'huile d'isolation électrique présentant d'excellentes propriétés à basse température |
| EP2811488A4 (fr) * | 2012-02-03 | 2016-04-06 | Jx Nippon Oil & Energy Corp | Composition d'huile isolante électriquement dotée d'excellentes propriétés dans une large région de températures |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6585917B2 (en) | 2001-04-12 | 2003-07-01 | Cooper Industries, Inc. | Dielectric fluid |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4348713A (en) * | 1980-05-07 | 1982-09-07 | General Electric Company | Impregnants for metallized paper electrode capacitors |
| US4355346A (en) * | 1979-03-29 | 1982-10-19 | Mcgraw-Edison Company | Electrical apparatus having an improved dielectric system |
| US4506107A (en) * | 1983-12-03 | 1985-03-19 | Nippon Petrochemical Company, Limited | Electrical insulating oil and oil-filled electrical appliances |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1215001A (en) * | 1967-01-16 | 1970-12-09 | Shell Int Research | Improvements in or relating to insulating oils |
| GB2032950A (en) * | 1978-09-07 | 1980-05-14 | Kureha Chemical Ind Co Ltd | Electrical Insulating Oil |
| JPS5750710A (en) * | 1980-09-11 | 1982-03-25 | Nippon Petrochemicals Co Ltd | Electric insulating coil composition |
| JPS6044906A (ja) * | 1983-08-19 | 1985-03-11 | 呉羽化学工業株式会社 | 金属蒸着化プラスチックフイルムキャパシタ−用含浸油 |
-
1986
- 1986-04-15 CA CA 506723 patent/CA1277131C/fr not_active Expired - Lifetime
- 1986-04-17 EP EP19860302885 patent/EP0199551B1/fr not_active Expired - Lifetime
- 1986-04-17 DE DE8686302885T patent/DE3679588D1/de not_active Expired - Lifetime
- 1986-04-18 US US06/853,546 patent/US4716084A/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4355346A (en) * | 1979-03-29 | 1982-10-19 | Mcgraw-Edison Company | Electrical apparatus having an improved dielectric system |
| US4348713A (en) * | 1980-05-07 | 1982-09-07 | General Electric Company | Impregnants for metallized paper electrode capacitors |
| US4506107A (en) * | 1983-12-03 | 1985-03-19 | Nippon Petrochemical Company, Limited | Electrical insulating oil and oil-filled electrical appliances |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2720232A1 (fr) * | 2011-06-07 | 2014-04-16 | JX Nippon Oil & Energy Corporation | Composition d'huile d'isolation électrique présentant d'excellentes propriétés à basse température |
| EP2720232A4 (fr) * | 2011-06-07 | 2014-12-10 | Jx Nippon Oil & Energy Corp | Composition d'huile d'isolation électrique présentant d'excellentes propriétés à basse température |
| EP2811488A4 (fr) * | 2012-02-03 | 2016-04-06 | Jx Nippon Oil & Energy Corp | Composition d'huile isolante électriquement dotée d'excellentes propriétés dans une large région de températures |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1277131C (fr) | 1990-12-04 |
| EP0199551A3 (en) | 1988-04-13 |
| US4716084A (en) | 1987-12-29 |
| DE3679588D1 (de) | 1991-07-11 |
| EP0199551B1 (fr) | 1991-06-05 |
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