EP0198699B1 - Auslass für geschmolzenes Material - Google Patents

Auslass für geschmolzenes Material Download PDF

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Publication number
EP0198699B1
EP0198699B1 EP86302758A EP86302758A EP0198699B1 EP 0198699 B1 EP0198699 B1 EP 0198699B1 EP 86302758 A EP86302758 A EP 86302758A EP 86302758 A EP86302758 A EP 86302758A EP 0198699 B1 EP0198699 B1 EP 0198699B1
Authority
EP
European Patent Office
Prior art keywords
drip line
frusto
aperture
tap outlet
drip
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP86302758A
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English (en)
French (fr)
Other versions
EP0198699A3 (en
EP0198699A2 (de
Inventor
Bruce C. Peters
Richard M. Gross
Stanley R. Pearson
M. Dale Mayes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Chemical Co
Original Assignee
Dow Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Chemical Co filed Critical Dow Chemical Co
Publication of EP0198699A2 publication Critical patent/EP0198699A2/de
Publication of EP0198699A3 publication Critical patent/EP0198699A3/en
Application granted granted Critical
Publication of EP0198699B1 publication Critical patent/EP0198699B1/de
Expired legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/06—Continuous processes
    • C10J3/08—Continuous processes with ash-removal in liquid state
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/52—Ash-removing devices
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/74—Construction of shells or jackets
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S48/00—Gas: heating and illuminating
    • Y10S48/02—Slagging producer

Definitions

  • This invention concerns the gasification of finely divided solids, and more particularly, coal gasification plants of the kind in which coal or other carbonaceous fuel is introduced into a gasifying vessel and is converted at high temperature and in the presence of oxygen, to synthesis gas and an ash by-product.
  • U.S. Patent 4,312,637 discloses a structure for slag removal from a gasification generator which has three lines for dripping and these lines are located so that each lie in a different plane.
  • the slag removal is usually achieved by providing the gasifying vessel with a slag tap through which the molten material can pass.
  • the gasification industry recognizes that the configuration of and the material of construction for the tap are determinative of tap life. Selection of the materials of construction must be made dependent upon the high temperature environment in which the tap will be used and the errosive and corrosive nature of molten slag.
  • the tap configuration is important as it must provide for the flow of the molten slag through the tap without slag solidification around or within the tap to cause tap bridging and close-off.
  • the tap is configured to have a deep bore through which the molten slag must pass, then slag solidification will most likely occur as the slag within the bore is too far removed and/or cannot 'see' interior vessel temperatures which are above the slag melt point.
  • Various tap configurations have been suggested to reduce solidification. See, for example, U.S. 4,312,637 mentioned above.
  • This invention provides an outlet tap which resists close-off due to the solidification of molten material within thetap and/or adjacent its exterior mouth and which has a configuration which can be simply formed from conventional refractory materials.
  • This invention provides a tap outlet located in a floor of a vessel through which the liquid contents of the vessel may be drained, said tap outlet comprising:
  • the tap outlet is configured so as to reduce the liquid's passage time as it moves through the tap outlet. This particular feature is especially important when the liquid is molten as the chance of solidification of the molten liquid in the tap outlet or at its exterior mouth is greatly reduced.
  • the tap outlet provides an aperture having minimal depth.
  • the aperture would preferably have a depth less than about 4 inches (10 cm) to ensure that there is no solidification therewithin.
  • the aperture is preferably configured to be free of angular intersections within its bore as such intersections encourage liquid buildup at their locations. This buildup is best avoided as it can become so large that solidification of the liquid at the bottom of the buildup is facilitated. For this reason, curvilinear apertures are preferred, with circular apertures being most preferred.
  • the least distance across the aperture should be sufficiently large to allow the liquid to move through the aperture quickly. Determination of the least distance is best made empirically keeping in mind that aperture configuration, slag flow rate, viscosity and surface tension are all influential factors to be considered. It has been found that, for a circular aperture to be used in draining molten slag from a commercial 2400 to 3000°F (1300 to 1650°C) coal gasification reactor, the aperture diameter should be at least 6 inches (15 cm) and preferably within the range from about 12 to about 48 inches (30 to 120 cm).
  • a first drip line which circumscribes the aperture.
  • the drip line is radially spaced outward from the aperture so that the distances from any of the points on the drip line to their respective nearest points on the aperture are substantially equal. This relationship yields correspondence between the drip line configuration and the aperture bottom configuration with the former being dimensioned larger than the latter to effect the required circumscription. Under these preferred criteria, a circular aperture would be associated with a circular first drip line having a diameter larger than the diameter of the aperture.
  • the aperture is connected to the first drip line by way of a continuous surface.
  • the continuous surface would be an annular surface and preferably a frusto-conical surface.
  • the tap outlet also provides a second drip line which circumscribes the first drip line.
  • the second drip line is preferably configured similar to, even though larger than, the first drip line so that the various distances between the points on the second drip line and their respective nearest points on the first drip line will be equal.
  • the first drip line is circular so will be the second drip line, but with a larger diameter.
  • the first and second drip lines are substantially coplanar.
  • the degree to which the coplanar relationship can be achieved will be dependent upon the materials of construction and upon construction techniques. For example, if the tap outlet is circular and has a diameter of 24 inches (60 cm) and is made of refractory bricks then normally the relationship between the two drip lines may be 1 to 3 inches (2.5 to 8 cm) at variance with a true coplanar relationship.
  • the first and second drip lines are connected one to the other by a first hollow continuous surface.
  • This hollow surface is usefully comprised of two frusto-conical surfaces which intersect one another in a plane above the first and second drip lines. The intersection occurs between the base of one of the surfaces and the apex of the other surface. The angle of intersection is preferably obtuse with a 90° angle (right angle) most preferred.
  • the liquid contents pass quickly through the aperture due to its minimal depth. Should there be any liquid drip from the aperture, it will follow the first surface to the first drip line.
  • the edge configuration of the first drip line is such that it encourages the quick collection of the dripped liquid on it and so that the liquid will quickly obtain sufficient weight to overcome the adherence of the liquid to the drip line as a result of the liquid's surface tension.
  • the quick collection on and release from the drip line minimizes the chance of solidification on or about the drip line due to molten liquid cool down. Should the amount of liquid dripping from the aperture overwhelm the first drip line, the second drip line is provided to achieve the same quick collection and release of the liquid as does the first drip line.
  • drip lines circumscribing the two drip lines just described can be used for the tap outlet of the invention.
  • additional drip lines will be dependent on the extent of liquid drip at the aperture and upon the fluid properties of the liquid passing through the tap outlet.
  • additional drip lines may be useful from the standpoint of providing in-situ spare drip lines in the event inner drip lines are lost. The in-situ provision is beneficial as the reaction occurring in the vessel does not need to be brought down to effect drip line replacement.
  • the first drip line is also facilitated by locating the first drip line sufficiently close to the aperture so that the distance the dripped liquid has to travel from the aperture to the drip line is small.
  • the travel distance is optionally from about 2 to about 5 inches (5 to 13 cm).
  • the second drip line should not be too close to the first drip line so as to interfere with the drip from the first drip line but also not so far away as to delay the second dripping of the dripped liquid. Again, empirical determination of the location of the second drip line is necessary.
  • the second drip line it has been found useful for the second drip line to have a diameter which is about 6 to about 12 inches (15 to 30 cm) greater than that of the first drip line.
  • prefired brick Due to the novel configuration of the tap outlet of this invention, it is possible to make it from prefired brick as hereinafter described.
  • the use of fire brick gives an important advantage over other configurations which, due to their geometrical requirements, demand that non-prefired refractory materials such as ram mix, castable refractory or plastic refractory be utilized.
  • the use of prefired bricks is desirable as the bricks have a high density and a low porosity thereby giving them acceptable life for those applications where molten liquids such as molten slag are to be encountered.
  • the utilization of prefired bricks makes it most convenient to provide a circular aperture having so little depth that it may be referred to as a "knife edge" opening. Advantages of minimizing the depth of the tap outlet were previously discussed.
  • Vessel 10 having located in its interior a tap outlet of this invention, generally designated by the numeral 18.
  • Vessel 10 has an exterior wall 11 which, in most circumstances and for the embodiment shown in the drawings, is cylindrical in shape for at least that portion within which the tap outlet is located. This cylindrical shape is not required but rather is preferred.
  • Vessel 10 has a floor 12 having an opening at its center. This opening is circumscribed by flanges 14 and 16, the former being located on the bottom surface of floor 12 and the latter being located on the upper surface of the floor. These flanges are conventionally found to be beneficial to rigidify floor 12 about its central opening and to aid in support of tap outlet 18.
  • Tap outlet 18 is comprised of four courses of prefired refractory brick, such as Zirchrome-60, manufactured by Lafarge Refractairies of France, which all define frusto-conical surfaces.
  • the base course 20 overlies insulating and support granular material 28.
  • the apex of base course 20 is dimensioned so as to lie over and on flange 16.
  • the angle which the frusto-conical surface of base course 20 makes with its vertical axis will be duplicated by the overlying other courses.
  • the surface to vertical axis angle falls preferably within the range of from about 30° to about 60°. Some liquids, however, due to their viscosity, may be best handled with surface to vertical axis angles either above or below the just stated range.
  • Second course 22 Overlying base course 20 is second course 22.
  • the diameter of second course 22, at its apex, is smaller than the diameter of the apex of course 20.
  • the bricks which comprise second course 22 are staggered so that the joint lines of base course 20 and second course 22 do not overlie one another.
  • This staggering of mortar joints is a well known technique used in the art of constructing furnace floors from brick and has been proven helpful in maintaining floor integrity during furnace operation. Staggering of the mortar joints is also used for third course 24 and fourth course 26.
  • Third course 24 overlies second course 22 and has an apex diameter smaller than the apex diameter of second course 22.
  • Fourth course 26 overlays third course 24 and has an apex diameter which is the smallest of the apex diameters.
  • fourth course 26 provides at the inwardmost edge of its apex a circular aperture (30) which is defined by the upper end edges of the brick which define the apex of fourth course 26.
  • These bricks, especially prefired brick, provide sharp edges and thus, circular aperture 30 is knife-edged.
  • the bricks forming the apex of fourth course 26 also provide, with their lower end edges, circular drip line 32.
  • Circular drip line 32 is also knife-edged due to the sharp-edged configuration of the brick. This knife-edged configuration is beneficial as it provides very little surface for adherence of the liquid to the drip line thereby requiring very little liquid accumulation to effect release of the liquid therefrom.
  • the end faces of the bricks located about the apex of fourth course 26 also provide frusto-conical surface 36 which joins together circular aperture 30 and first circular drip line 32.
  • the distance between the circular aperture and circular drip line is the thickness of the brick. For most refractory bricks, this distance will be from about 2 to about 4 inches (5 to 10 cm). As can be appreciated, this distance is quite small and is beneficial in ensuring quick delivery of any dripped liquid to first circular drip line 32 so that the liquid can be quickly disengaged from the tap outlet. Other distances may be useful, so long as the distance that the dripped liquid from circular aperture 30 has to travel does not yield a travel time which will be conducive to liquid cool-off to the point of solidification before it drips from any of the circular drip lines.
  • Second course 24 provides, by way of the bricks forming its apex, second circular drip line 34.
  • circular drip line 34 is substantially coplanar with first circular drip line 32.
  • Second circular drip line 24 is configured similar to first circular drip line 32.
  • the first and second circular drip lines are connected to one another by way of a first hollow annular surface which, for the embodiment shown, is comprised of frusto-conical surface 38 and a frusto-conical surface 40.
  • Frusto-conical surface 38 intersects, at its base, the apex of frusto-conical surface 40 at an approximate 90° angle. This point of intersection 39 is located above the plane in which circular drip lines 32 and 34 lie.
  • a second hollow annular surface is provided.
  • the second hollow surface operates in the same manner and for the same reasons as the just-described first hollow surface.
  • the second annular hollow surface is comprised of frusto-conical surfaces 42 and 44.
  • the base of surface 42 intersects the apex of surface 44 to form intersection 43 which is above the plane(s) in which the first and second circular drip lines lie.
  • Any liquid which contacts frusto-conical surface 44 will be directed to flow onto the inner surfaces of flanges 14 and 16. If this liquid is originally molten, it may very well solidify on these surfaces as the surfaces do not have drip enhancing configurations.
  • first and second drip lines 32 and 34 may be provided to facilitate quick drip of the liquid from outlet tap 18.
  • the base to apex dimensions (width) of the various frusto-conical surfaces which make up the annular hollow surfaces are those which ensure quick liquid movement to the circular drip lines without being promotive of liquid bridging between the drip lines. Determination of the best widths for any particular application is dependent on many factors, e.g., the liquid's solidification temperature and its fluid properties, the rate of liquid cool-off, the drip line configuration and other similar well-known factors, and thus, is best made empirically. When refractory bricks are utilized to produce tap outlet 18, it is most convenient, for those frusto-conical surfaces formed by the brick end surfaces, e.g., surfaces 36, 40 and 44, to have their widths commensurate with the width dimensions of the brick surfaces ends.
  • frusto-conical surfaces formed by a portion of the under surface of the bricks e.g., surfaces 38 and 42
  • the preferred angle at intersections 39 and 43 is substantially a right angle (90°) as such angle is believed to result in maximized liquid flow without attendant liquid bridging between the two surfaces forming the annular hollow surface.
  • the tap outlet has the geometric configuration of the embodiment of Figures 1 and 2, but that the tap outlet be formed of materials other than refractory brick, e.g., castable refractory material.
  • Further modification of the configuration of the component parts of the illustrated outlet is contemplated herein.
  • the hollow annular surfaces may be configured so as to provide a semicircular or parabolic profile, when viewed in vertical-section, rather than the angular profile provided by the before-described frusto-conical surfaces.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)
  • Closures For Containers (AREA)
  • Gasification And Melting Of Waste (AREA)

Claims (14)

1. Abstichauslaß (18) in einem Boden (12) eines Kessels (10), durch welchen der flüssige Inhalt des Kessels abgelassen werden kann, wobei der Abstichauslaß umfaßt:
(a) eine Öffnung (30),
(b) eine erste Tropflinie (32), welche diese Öffnung umschreibt, wobei die erste Tropflinie mit der Öffnung durch eine erste kontinuierliche Oberfläche (36) verbunden ist und
(c) eine zweite Tropflinie (34), die die erste Tropflinie umschreibt, wobei die zweite Tropflinie
(i) im wesentlichen koplanar mit der ersten Tropflinie ist und
(ii) mit der ersten Tropflinie durch eine kontinuierliche hohle Verbindungsfläche (38, 40) verbunden ist.
2. Abstichauslaß nach Anspruch 1, worin die Öffnung (30) gekrümmt ist.
3. Abstichauslaß nach Anspruch 2 worin die gekrümmt Öffnung (30) eine im wesentlichen kreisförmige Öffnung ist.
4. Abstichauslaß nach Anspruch 3, worin die erste Tropflinie (32) im wesentlichen kreisförmig ist.
5. Abstichauslaß nach Anspruch 4, worin die Öffnung (30) im wesentlichen kreisförmig ist und eine Tiefe von nicht mehr als etwa 10 cm (4 inch) hat.
6. Abstichauslaß nach Anspruch 4 oder 5, worin die erste kontinuierliche Oberfläche (36) eine stumpfkegelförmige Oberfläche ist, die mit ihrem Scheitel zu der im wesentlichen ringförmigen Öffnung (30) und an ihrer Basis mit der im wesentlichen runden ersten Tropflinie (32) verbunden ist.
7. Abstichauslaß nach einem der vorhergehenden Ansprüche, worin die zweite Tropflinie (34) die hohle Verbindungsfläche (38, 40) und die zweite hohle Oberfläche (42, 44) begrenzt.
8. Abstichauslaß nach einem der vorhergehenden Ansprüche, worin die erste und die zweite Tropflinie (32, 34) im wesentlichen kreisförmig sind und die kontinuierliche hohle Verbindungsfläche zwei stumpf-kegelförmige Oberflächen (38, 40) umfaßt, eine der stumpf-kegelförmigen Oberflächen (38) an ihrer Scheitellinie mit der ersten Tropflinie (32) und an ihrer Basis mit der Scheitellinie der anderen der stumpf-kegelförmigen Oberflächen (40) verbunden ist und wobei die Verbindung der stumpf-kegelförmigen Oberflächen an einem Punkt (39) über der ersten und zweiten Tropflinie ist und die andere stumpf-kegelförmige Oberfläche an ihrer Basis mit der zweiten Tropflinie verbunden ist.
9. Abstichauslaß nach einem der vorhergehenden Ansprüche, worin die zweite Tropflinie (34) durch die hohle Verbindungsfläche (38, 40) und durch eine zweite hohle Verbindungsfläche (42, 44) verbunden ist, wobei die zweite hohle Oberfläche zwei weitere stumpf-kegelförmige Oberflächen (42, 44) umfaßt, wobei eine der stumpf-kegelförmigen Oberflächen (42) an ihrer Scheitellinie mit der zweiten Tropflinie (34) und an ihrer Basis mit der Scheitellinie der anderen der weiteren stumpf-kegelförmigen Oberflächen verbunden ist, und sich die Verbindung der weiteren stumpf-kegelförmigen Oberflächen an einem Punkt (43) oberhalb der zweiten Tropflinie befinden.
10. Abstichauslaß nach Anspruch 8 oder Anspruch 9, wobei die Verbindung(en) der stumpf-kegelförmigen Oberflächen im wesentlichen rechtwinklig ist.
11. Abstichauslaß nach einem der vorhergehenden Ansprüche, worin der Abstichauslaß (18) aus Materialien gebildet ist, die feuerfeste Steine (24, 26) und Mörtel umfassen.
12. Abstichauslaß nach Anspruch 11, worin die Öffnung (30) eine Tiefe aufweist, die gleich ist mit den Abmessungen der oberen Endekante der feuerfesten Steine (26), welche die Öffnung definieren.
13. Abstichauslaß nach Anspruch 12, worin die erste kontinuierliche Oberfläche (36) eine stumpf- kegelförmige Oberfläche mit einer Weite ist, die gleich mit der Abmessung der Endoberflächenweite der feuerfesten Steine (26) ist, welche die erste stumpf-kegelförmige Oberfläche definieren.
14. Kohlevergasungskessel, der in seinem Boden einen Abstichauslaß nach einem der vorhergehenden Ansprüche aufweist.
EP86302758A 1985-04-16 1986-04-14 Auslass für geschmolzenes Material Expired EP0198699B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US723769 1985-04-16
US06/723,769 US4653677A (en) 1985-04-16 1985-04-16 Vessel having a molten material outlet

Publications (3)

Publication Number Publication Date
EP0198699A2 EP0198699A2 (de) 1986-10-22
EP0198699A3 EP0198699A3 (en) 1987-05-06
EP0198699B1 true EP0198699B1 (de) 1989-09-20

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ID=24907596

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86302758A Expired EP0198699B1 (de) 1985-04-16 1986-04-14 Auslass für geschmolzenes Material

Country Status (12)

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US (1) US4653677A (de)
EP (1) EP0198699B1 (de)
JP (1) JPH0655952B2 (de)
KR (1) KR930011068B1 (de)
CN (1) CN1006897B (de)
AU (1) AU581505B2 (de)
CA (1) CA1250433A (de)
DE (1) DE3665733D1 (de)
IN (1) IN167381B (de)
NZ (1) NZ215763A (de)
TR (1) TR22479A (de)
ZA (1) ZA862843B (de)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018108698A1 (de) 2016-12-15 2018-06-21 Basf Se Verfahren zur herstellung von ethanolaminen und/oder ethylenaminen
WO2018224316A1 (de) 2017-06-09 2018-12-13 Basf Se Verfahren zur herstellung von ethylenaminen
WO2018224321A1 (de) 2017-06-09 2018-12-13 Basf Se Verfahren zur herstellung von ethylenaminen
WO2018224315A1 (de) 2017-06-09 2018-12-13 Basf Se Verfahren zur herstellung von ethylenaminen
WO2020178085A1 (en) 2019-03-06 2020-09-10 Basf Se Method for the production of ethyleneamines

Families Citing this family (9)

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Publication number Priority date Publication date Assignee Title
US4828579A (en) * 1988-03-07 1989-05-09 Becker Michael W Thermally insulated quench ring for a gasifier
US4979964A (en) * 1989-06-22 1990-12-25 Shell Oil Company Apparatus for preventing slag tap blockage
JP3118630B2 (ja) * 1995-09-22 2000-12-18 株式会社日立製作所 石炭ガス化炉
ES2247697T3 (es) * 1997-06-06 2006-03-01 Texaco Development Corporation Control de flujo de oxigeno para gasificacion.
US6313429B1 (en) 1998-08-27 2001-11-06 Retech Services, Inc. Dual mode plasma arc torch for use with plasma arc treatment system and method of use thereof
US6180911B1 (en) 1999-06-02 2001-01-30 Retech Services, Inc. Material and geometry design to enhance the operation of a plasma arc
US20060165582A1 (en) * 2005-01-27 2006-07-27 Brooker Donald D Production of synthesis gas
US7993131B2 (en) * 2007-08-28 2011-08-09 Conocophillips Company Burner nozzle
CN104403694B (zh) * 2014-10-16 2017-02-15 煤炭科学技术研究院有限公司 一种固定床气化炉的液态连续排渣器及排渣方法

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NL17586C (de) * 1922-02-06
GB2029946B (en) * 1978-09-08 1982-12-01 British Gas Corp Slag removal from coal gasification plant
US4312637A (en) * 1980-06-23 1982-01-26 Texaco Inc. Slag outlet for a gasification generator
AT387039B (de) * 1981-02-05 1988-11-25 Veitscher Magnesitwerke Ag Abstichvorrichtung fuer konverter
JPS589887A (ja) * 1981-07-11 1983-01-20 九州耐火煉瓦株式会社 溶融金属の流量制御用スライデイングノズルのプレ−トれんが及びその製造方法

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018108698A1 (de) 2016-12-15 2018-06-21 Basf Se Verfahren zur herstellung von ethanolaminen und/oder ethylenaminen
US10836704B2 (en) 2016-12-15 2020-11-17 Basf Se Method for producing ethanolamines and/or ethyleneamines
WO2018224316A1 (de) 2017-06-09 2018-12-13 Basf Se Verfahren zur herstellung von ethylenaminen
WO2018224321A1 (de) 2017-06-09 2018-12-13 Basf Se Verfahren zur herstellung von ethylenaminen
WO2018224315A1 (de) 2017-06-09 2018-12-13 Basf Se Verfahren zur herstellung von ethylenaminen
WO2020178085A1 (en) 2019-03-06 2020-09-10 Basf Se Method for the production of ethyleneamines

Also Published As

Publication number Publication date
ZA862843B (en) 1987-12-30
KR860008256A (ko) 1986-11-14
JPS61258894A (ja) 1986-11-17
CA1250433A (en) 1989-02-28
CN1006897B (zh) 1990-02-21
AU581505B2 (en) 1989-02-23
KR930011068B1 (ko) 1993-11-20
NZ215763A (en) 1988-07-28
CN86102609A (zh) 1986-12-17
TR22479A (tr) 1987-07-22
DE3665733D1 (en) 1989-10-26
IN167381B (de) 1990-10-20
EP0198699A3 (en) 1987-05-06
JPH0655952B2 (ja) 1994-07-27
US4653677A (en) 1987-03-31
AU5607086A (en) 1986-10-23
EP0198699A2 (de) 1986-10-22

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