EP0191608A2 - Schmierfett für Steinbohrerspitzen und so geschmierte Bohrerspitzen - Google Patents

Schmierfett für Steinbohrerspitzen und so geschmierte Bohrerspitzen Download PDF

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Publication number
EP0191608A2
EP0191608A2 EP86300831A EP86300831A EP0191608A2 EP 0191608 A2 EP0191608 A2 EP 0191608A2 EP 86300831 A EP86300831 A EP 86300831A EP 86300831 A EP86300831 A EP 86300831A EP 0191608 A2 EP0191608 A2 EP 0191608A2
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EP
European Patent Office
Prior art keywords
grease
lubricating grease
acid
hydroxy
rock drill
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP86300831A
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English (en)
French (fr)
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EP0191608A3 (de
Inventor
Roy Dugmore Clarke
Robert Henry Newman
William Carill Pike
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP PLC
Original Assignee
BP PLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP PLC filed Critical BP PLC
Publication of EP0191608A2 publication Critical patent/EP0191608A2/de
Publication of EP0191608A3 publication Critical patent/EP0191608A3/de
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/06Mixtures of thickeners and additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M117/00Lubricating compositions characterised by the thickener being a non-macromolecular carboxylic acid or salt thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M125/00Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/22Compounds containing sulfur, selenium or tellurium
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/065Sulfides; Selenides; Tellurides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/06Metal compounds
    • C10M2201/065Sulfides; Selenides; Tellurides
    • C10M2201/066Molybdenum sulfide
    • CCHEMISTRY; METALLURGY
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/08Inorganic acids or salts thereof
    • C10M2201/084Inorganic acids or salts thereof containing sulfur, selenium or tellurium
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/106Carboxylix acids; Neutral salts thereof used as thickening agents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/1206Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms used as thickening agents
    • CCHEMISTRY; METALLURGY
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/14Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/1406Carboxylix acids; Neutral salts thereof having carboxyl groups bound to carbon atoms of six-membered aromatic rings used as thickening agents
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/16Naphthenic acids
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/18Tall oil acids
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/22Acids obtained from polymerised unsaturated acids
    • CCHEMISTRY; METALLURGY
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    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/26Overbased carboxylic acid salts
    • C10M2207/2613Overbased carboxylic acid salts used as thickening agents
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/26Overbased carboxylic acid salts
    • C10M2207/262Overbased carboxylic acid salts derived from hydroxy substituted aromatic acids, e.g. salicylates
    • C10M2207/2626Overbased carboxylic acid salts derived from hydroxy substituted aromatic acids, e.g. salicylates used as thickening agents
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    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04Phosphate esters
    • C10M2223/045Metal containing thio derivatives
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    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/02Groups 1 or 11
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    • C10N2010/00Metal present as such or in compounds
    • C10N2010/04Groups 2 or 12
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/30Refrigerators lubricants or compressors lubricants
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/32Wires, ropes or cables lubricants
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/34Lubricating-sealants
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/36Release agents or mold release agents
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/38Conveyors or chain belts
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/40Generators or electric motors in oil or gas winning field
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/42Flashing oils or marking oils
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/44Super vacuum or supercritical use
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    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/50Medical uses

Definitions

  • Rock drill bits used for drilling to a substantial depth into the earths crust normally consist of a number of cutter cones rotating on a stem.
  • the bearing surfaces between the cones and stem are lubricated by a grease.
  • the grease is sealed into the bit before use and it should provide lubrication for the lifetime of the bit, which may be several hundreds of hours.
  • the bit has to be replaced because of wear of the cutting surfaces but, since retrieving and replacing a bit is a time-consuming operation, it is desirable that the bit should last for the full lifetime of its cutting ability and should not fail prematurely through failure of its lubricating system.
  • the environment within which a rock drill bit operates can be severe. Heavy loads may be imposed on the rotating cutter cones, particularly when drilling through hard rock formations and high temperatures and pressures may exist in the vicinity of the bit. Further the bore of the hole being drilled may be filled with drilling mud containing abrasive particles.
  • a particularly suitable lithium complex soap may be formed from 12-hydroxy stearic acid, dodecanedioic acid, distilled tallow fatty acid and lithium hydroxide monohydrate.
  • compositions of the three greases and their characteristics were as shown in Table 1 below:
  • the EP wear properties were measured using the 4 Ball method (IP Test No 239).
  • the flow properties were measured in a suitable rheometer by applying a force (shear stress) to the greases and measuring the rate of flow (shear rate). The apparent viscosities shear stress were then calculated. shear rate
  • Thermo-mechanical analysis is a technique for comparing changes in consistency of a material over a temperature range.
  • a small probe 5 mm in diameter is loaded (0.3gm) against a small sample of grease in a hollow about 1 to 2 mm deep. Starting at room temperature, the assembly is heated at 10°C/minute up to 260°C. As the grease softens, the probe sinks further into the grease, ie the probe height is reduced. If any significant expansion occurs, the probe height increases. If hardening takes place, the probe height changes only slightly with temperature.
  • a commercial conventional lithium soap grease (C) starts to change at 120°C, expands up to 160°C, and then softens rapidly.
  • the commercial aluminium complex soap grease (A) starts to soften almost immediately and is softer than LXB3 up to 200°C.
  • the commercial calcium complex soap grease (B) shows no change in probe height indicating early and maintained hardening.
  • Commercial drill bit grease D1 shows expansion up to 120°C and then a gradual change consistent with hardening.
  • Commercial drill bit grease D2 starts to soften as soon as 80°C and thereafter increases rapidly in softness.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Lubricants (AREA)
  • Scissors And Nippers (AREA)
EP86300831A 1985-02-09 1986-02-06 Schmierfett für Steinbohrerspitzen und so geschmierte Bohrerspitzen Withdrawn EP0191608A3 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB858503382A GB8503382D0 (en) 1985-02-09 1985-02-09 Lubricating grease
GB8503382 1985-02-09

Publications (2)

Publication Number Publication Date
EP0191608A2 true EP0191608A2 (de) 1986-08-20
EP0191608A3 EP0191608A3 (de) 1988-07-27

Family

ID=10574239

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86300831A Withdrawn EP0191608A3 (de) 1985-02-09 1986-02-06 Schmierfett für Steinbohrerspitzen und so geschmierte Bohrerspitzen

Country Status (4)

Country Link
EP (1) EP0191608A3 (de)
JP (1) JPS61183393A (de)
GB (1) GB8503382D0 (de)
NO (1) NO860435L (de)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5015401A (en) * 1990-10-16 1991-05-14 Hughes Tool Company Bearings grease for rock bit bearings
US5589443A (en) * 1995-12-21 1996-12-31 Smith International, Inc. Rock bit grease composition
WO1997003152A1 (en) * 1995-07-11 1997-01-30 Shell Internationale Research Maatschappij B.V. Lubricating greases
US5668092A (en) * 1993-04-07 1997-09-16 Smith International, Inc. Rock bit grease composition
US5681799A (en) * 1988-08-01 1997-10-28 Exxon Chemical Patents Inc. Ethylene alpha-olefin/diene interpolymer-substituted carboxylic acid dispersant additives
US5891830A (en) * 1997-01-31 1999-04-06 Baker Hughes Incorporated Lubricating grease
US6056072A (en) * 1997-01-31 2000-05-02 Baker Hughes Inc. Lubricating grease
US9096814B2 (en) 2011-07-27 2015-08-04 Chevron U.S.A. Inc. Lubricating grease composition
CN108048186A (zh) * 2017-12-28 2018-05-18 东莞太平洋博高润滑油有限公司 一种复合锂基脂及其制备方法
CN111892984A (zh) * 2020-07-23 2020-11-06 中国石油化工股份有限公司 一种重载轴承润滑脂组合物及其制备方法

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE502608A (de) * 1950-04-20
US3223624A (en) * 1962-12-07 1965-12-14 Exxon Research Engineering Co Lubricating grease
US3396108A (en) * 1964-12-22 1968-08-06 Shell Oil Co Extreme pressure soap and complex thickened greases
US3705853A (en) * 1970-09-23 1972-12-12 Mobil Oil Corp Grease compositions
AU457980B2 (en) * 1970-11-18 1975-02-13 Esso Research And Engineering Company Lithium soap grease
US3791973A (en) * 1971-02-24 1974-02-12 Exxon Research Engineering Co Grease thickened with lithium soap of hydroxy fatty acid and lithium salt of aliphatic dicarboxylic acid
US3985662A (en) * 1975-02-28 1976-10-12 Exxon Research And Engineering Company High dropping point greases comprising a lithium soap of an epoxy-substituted and/or an ethylenically unsaturated fatty acid
US4358384A (en) * 1980-10-06 1982-11-09 Smith International Inc. Composite grease for rock bit bearings
EP0084910B1 (de) * 1982-01-21 1989-02-22 Shell Internationale Researchmaatschappij B.V. Lärmverhinderde Eigenschaften aufweisendes Lithium-Komplex-Fett mit hohem Tropfpunkt

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5681799A (en) * 1988-08-01 1997-10-28 Exxon Chemical Patents Inc. Ethylene alpha-olefin/diene interpolymer-substituted carboxylic acid dispersant additives
US5015401A (en) * 1990-10-16 1991-05-14 Hughes Tool Company Bearings grease for rock bit bearings
US5668092A (en) * 1993-04-07 1997-09-16 Smith International, Inc. Rock bit grease composition
CN1053214C (zh) * 1995-07-11 2000-06-07 国际壳牌研究有限公司 润滑脂
WO1997003152A1 (en) * 1995-07-11 1997-01-30 Shell Internationale Research Maatschappij B.V. Lubricating greases
GB2308382A (en) * 1995-12-21 1997-06-25 Smith International Rock bit greases
GB2308382B (en) * 1995-12-21 1999-10-20 Smith International Rock bit grease composition
US5589443A (en) * 1995-12-21 1996-12-31 Smith International, Inc. Rock bit grease composition
US5891830A (en) * 1997-01-31 1999-04-06 Baker Hughes Incorporated Lubricating grease
US6056072A (en) * 1997-01-31 2000-05-02 Baker Hughes Inc. Lubricating grease
US9096814B2 (en) 2011-07-27 2015-08-04 Chevron U.S.A. Inc. Lubricating grease composition
US9719046B2 (en) 2011-07-27 2017-08-01 Chevron U.S.A. Inc. Lubricating grease composition
CN108048186A (zh) * 2017-12-28 2018-05-18 东莞太平洋博高润滑油有限公司 一种复合锂基脂及其制备方法
CN111892984A (zh) * 2020-07-23 2020-11-06 中国石油化工股份有限公司 一种重载轴承润滑脂组合物及其制备方法
CN111892984B (zh) * 2020-07-23 2023-03-31 中国石油化工股份有限公司 一种重载轴承润滑脂组合物及其制备方法

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GB8503382D0 (en) 1985-03-13
EP0191608A3 (de) 1988-07-27
JPS61183393A (ja) 1986-08-16

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