EP0190892A3 - Process for the preparation of an aqueous dispersion of copolymeric latex polymer - Google Patents

Process for the preparation of an aqueous dispersion of copolymeric latex polymer Download PDF

Info

Publication number
EP0190892A3
EP0190892A3 EP86300668A EP86300668A EP0190892A3 EP 0190892 A3 EP0190892 A3 EP 0190892A3 EP 86300668 A EP86300668 A EP 86300668A EP 86300668 A EP86300668 A EP 86300668A EP 0190892 A3 EP0190892 A3 EP 0190892A3
Authority
EP
European Patent Office
Prior art keywords
beta
monomer
alpha
preparation
ethylenically unsaturated
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP86300668A
Other versions
EP0190892A2 (en
EP0190892B1 (en
Inventor
Ching-Jen Chang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rohm and Haas Co
Original Assignee
Rohm and Haas Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co
Priority to AT86300668T priority Critical patent/ATE69449T1/en
Publication of EP0190892A2 publication Critical patent/EP0190892A2/en
Publication of EP0190892A3 publication Critical patent/EP0190892A3/en
Application granted granted Critical
Publication of EP0190892B1 publication Critical patent/EP0190892B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/062—Copolymers with monomers not covered by C09D133/06
    • C09D133/064—Copolymers with monomers not covered by C09D133/06 containing anhydride, COOH or COOM groups, with M being metal or onium-cation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paints Or Removers (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Polymerisation Methods In General (AREA)
  • Coloring (AREA)
  • Paper (AREA)

Abstract

A process for the preparation of an aqueous dispersion of copolymeric latex polymer which may display enhanced thickening efficiency in aqueous solutions and compositions. The process comprises emulsion-polymerising alpha, beta-ethylenically unsaturated monomer in an aqueous medium, wherein at least some portion of the polymerization occurs in the presence of 3% to 20% by weight based on total monomer of at least one in-process additive having a solubility parameter having the valve of from between 1.64 x 10<-><2> (Jm <3>)<1/2 > to 2.46 x 10 <2> (Jm<-><3>)<1/2 >. The monomer comprises at least one copolymerizable alpha, beta-monoethylenically unsaturated surfactant comonomer, at least one copolymerizable alpha, beta-ethylenically unsaturated carbonoxylic acid comonomer, and at least one monomer selected from nonionic copolymerizable (C2-C12) alpha, beta-ethylenically unsaturated monomer.
EP86300668A 1985-02-04 1986-01-31 Process for the preparation of an aqueous dispersion of copolymeric latex polymer Expired - Lifetime EP0190892B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AT86300668T ATE69449T1 (en) 1985-02-04 1986-01-31 PROCESS FOR PREPARING AN AQUEOUS DISPERSION OF A COPOLYMER LATEX.

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US69782285A 1985-02-04 1985-02-04
US697822 1985-02-04

Publications (3)

Publication Number Publication Date
EP0190892A2 EP0190892A2 (en) 1986-08-13
EP0190892A3 true EP0190892A3 (en) 1989-05-31
EP0190892B1 EP0190892B1 (en) 1991-11-13

Family

ID=24802705

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86300668A Expired - Lifetime EP0190892B1 (en) 1985-02-04 1986-01-31 Process for the preparation of an aqueous dispersion of copolymeric latex polymer

Country Status (7)

Country Link
EP (1) EP0190892B1 (en)
JP (1) JPH0684403B2 (en)
AT (1) ATE69449T1 (en)
AU (1) AU593784B2 (en)
CA (1) CA1285685C (en)
DE (1) DE3682406D1 (en)
PH (1) PH24842A (en)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8813978D0 (en) * 1988-06-13 1988-07-20 Unilever Plc Liquid detergents
FR2633930B1 (en) * 1988-07-07 1991-04-19 Coatex Sa THICKENING AGENT FOR MODIFYING THE RHEOLOGICAL CHARACTERISTICS OF AQUEOUS LOADED AND / OR PIGMENTED, WHITE OR COLORED COMPOSITIONS
US5053448A (en) * 1989-07-21 1991-10-01 S. C. Johnson & Son, Inc. Polymeric thickener and methods of producing the same
US5192592A (en) * 1990-07-30 1993-03-09 Union Carbide Chemicals & Plastics Technology Corporation Method of coating substrates utilizing an alkali-functional associative thickner containing coating composition
DE69213384T2 (en) * 1991-09-30 1997-01-23 Nippon Zeon Co Acrylic copolymer elastomer and vulcanizable composition containing it
US5874495A (en) * 1994-10-03 1999-02-23 Rhodia Inc. Polymers useful as PH responsive thickeners and monomers therefor
DE19512882A1 (en) * 1995-04-06 1996-10-10 Basf Ag Aqueous polymer dispersion
DE19512883A1 (en) * 1995-04-06 1996-10-10 Basf Ag Aqueous polymer dispersion
DE19624281A1 (en) * 1996-06-18 1998-01-02 Basf Ag Process for the preparation of low-viscosity, aqueous polymer dispersions with polymer volume concentrations of at least 50% by volume
US5990233A (en) * 1996-08-16 1999-11-23 National Starch And Chemical Investment Holding Corporation Rheology modifiers for use in aqueous compositions
MX200986B (en) * 1997-07-29 2001-03-07 Rohm & Haas Solubilized hydrophobically-modified alkali-soluble emulsion polymers
GB9906149D0 (en) * 1999-03-18 1999-05-12 Ciba Spec Chem Water Treat Ltd Polymer composition
JP5130438B2 (en) * 2006-05-19 2013-01-30 サンノプコ株式会社 Viscosity improver
FR2917091B1 (en) * 2007-06-08 2009-08-28 Coatex S A S Soc Par Actions S PROCESS FOR PRODUCING AN AQUEOUS SOLUTION BASED ON SOLUTION OF AN ACRYLIC COMBED POLYMER AND ACRYLIC THICKENING EMULSION, FORMULATION OBTAINED AND USES THEREOF IN PAPER COATING
JP5086744B2 (en) * 2007-08-30 2012-11-28 関西ペイント株式会社 Water-based paint for automobiles containing viscosity improver
JP5456963B2 (en) * 2007-10-09 2014-04-02 共栄社化学株式会社 Thixotropic agent for aqueous dispersion composition
JP2009114348A (en) * 2007-11-07 2009-05-28 San Nopco Ltd Viscosity-improving agent
JP2009114351A (en) * 2007-11-07 2009-05-28 San Nopco Ltd Viscosity-improving agent
JP2009114347A (en) * 2007-11-07 2009-05-28 San Nopco Ltd Viscosity-improving agent
FR2956863B1 (en) * 2010-02-26 2013-02-08 Coatex Sas ASSOCIATIVE ACRYLIC EMULSION CONTAINING A MONOMER BASED ON OXO ALCOHOL, PROCESS FOR PRODUCING THE SAME, AND PROCESS FOR THICKENING AQUEOUS FORMULATION THEREFROM.
EP2716664A4 (en) * 2011-05-24 2014-12-10 Sumitomo Seika Chemicals (meth)acrylic acid-based copolymer
MX2020005522A (en) 2017-12-25 2020-10-15 Dow Global Technologies Llc Aqueous dispersion of multistage polymer.

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0013836A1 (en) * 1978-12-29 1980-08-06 Rohm And Haas Company Compositions containing acrylic emulsion copolymers and their use as thickeners
US4384096A (en) * 1979-08-27 1983-05-17 The Dow Chemical Company Liquid emulsion polymers useful as pH responsive thickeners for aqueous systems
US4421902A (en) * 1982-09-30 1983-12-20 Rohm And Haas Company Alkyl, poly(oxyethylene) poly(carbonyloxyethylene) acrylate emulsion copolymers for thickening purposes

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0011806B1 (en) * 1978-11-27 1983-11-23 The Dow Chemical Company Liquid emulsion polymers, process for preparing them and aqueous compositions thickened with these emulsions
ZA797050B (en) * 1978-12-29 1981-07-29 Rohm & Haas Methacrylic acid emulsion copolymers for thickening purposes

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0013836A1 (en) * 1978-12-29 1980-08-06 Rohm And Haas Company Compositions containing acrylic emulsion copolymers and their use as thickeners
US4384096A (en) * 1979-08-27 1983-05-17 The Dow Chemical Company Liquid emulsion polymers useful as pH responsive thickeners for aqueous systems
US4421902A (en) * 1982-09-30 1983-12-20 Rohm And Haas Company Alkyl, poly(oxyethylene) poly(carbonyloxyethylene) acrylate emulsion copolymers for thickening purposes

Also Published As

Publication number Publication date
DE3682406D1 (en) 1991-12-19
AU5285586A (en) 1986-08-07
JPH0684403B2 (en) 1994-10-26
PH24842A (en) 1990-10-30
CA1285685C (en) 1991-07-02
ATE69449T1 (en) 1991-11-15
EP0190892A2 (en) 1986-08-13
EP0190892B1 (en) 1991-11-13
JPS61228081A (en) 1986-10-11
AU593784B2 (en) 1990-02-22

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