AU8605882A - An aqueous plastics dispersion, a process for its preparation and the use of this dispersion - Google Patents
An aqueous plastics dispersion, a process for its preparation and the use of this dispersionInfo
- Publication number
- AU8605882A AU8605882A AU86058/82A AU8605882A AU8605882A AU 8605882 A AU8605882 A AU 8605882A AU 86058/82 A AU86058/82 A AU 86058/82A AU 8605882 A AU8605882 A AU 8605882A AU 8605882 A AU8605882 A AU 8605882A
- Authority
- AU
- Australia
- Prior art keywords
- weight
- monomer
- mixture
- component
- emulsifier
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000006185 dispersion Substances 0.000 title abstract 7
- 229920003023 plastic Polymers 0.000 title abstract 3
- 239000004033 plastic Substances 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 abstract 12
- 239000000203 mixture Substances 0.000 abstract 8
- 239000003995 emulsifying agent Substances 0.000 abstract 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract 4
- 125000004432 carbon atom Chemical group C* 0.000 abstract 4
- 238000007334 copolymerization reaction Methods 0.000 abstract 4
- 229920001519 homopolymer Polymers 0.000 abstract 4
- 229920001577 copolymer Polymers 0.000 abstract 3
- 239000004094 surface-active agent Substances 0.000 abstract 3
- WAEOXIOXMKNFLQ-UHFFFAOYSA-N 1-methyl-4-prop-2-enylbenzene Chemical group CC1=CC=C(CC=C)C=C1 WAEOXIOXMKNFLQ-UHFFFAOYSA-N 0.000 abstract 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 2
- 125000000129 anionic group Chemical group 0.000 abstract 2
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 abstract 2
- 150000002148 esters Chemical class 0.000 abstract 2
- 239000011521 glass Substances 0.000 abstract 2
- 230000009477 glass transition Effects 0.000 abstract 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 2
- 125000005397 methacrylic acid ester group Chemical group 0.000 abstract 2
- 150000002763 monocarboxylic acids Chemical class 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 abstract 2
- 229920002554 vinyl polymer Polymers 0.000 abstract 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 1
- 125000005396 acrylic acid ester group Chemical group 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/066—Copolymers with monomers not covered by C09D133/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Colloid Chemistry (AREA)
Abstract
1. Claims for the Contracting states : BE, CH, DE, FR, GB, IT, LI, LU, NL, SE An aqueous plastics dispersion based on a copolymer of an acrylic monomer, a vinyl monomer and a functional monomer capable of crosslinking, containing at least one emulsifier consisting of a fluorinated surfactant, which dispersion is obtained by a radically initated emulsion copolymerization of a monomer mixture containing I) 20 to 80% by weight of a "hardening" component A from the group comprising methacrylic acid ester, the homopolymer of which has a glass transition temperature TG above + 50 degrees C, styrene, vinyltoluene or vinylxylene, or mixtures of these components, the aromatic vinyl monomer contributing not more than 50% by weight to the total amount of all monomers, II) 20 to 80% by weight of a "plasticizing" component B from the group comprising acrylic acid ester or methacrylic acid ester, the homopolymer of which has a glass transition temperature TG below + 50 degrees C, or mixtures of these components, III) in each case relative to the total of A + B = 100, 1) 3 to 18% by weight of a monoolefinic unsaturated monomer having a hydroxyl group and 2) 0,5 to 10% by weight of an alpha-, beta- unsaturated monocarboxylic acid and/or an unsaturated dicarboxylic acid, characterized in that the copolymerization was carried out in the pressence of an anionic fluorinated surfactant having a perfluoroalkyl radical of 2 to 20 C atoms or a perfluoroaralkyl radical of 7 to 30 C atoms as the emulsifier or as a component of the mixture of emulsifiers, and the particle diameters of the resulting dispersion copolymer are in the range of from 0,05 to 0,2 mu m. 1. Claims for the Contracting state : AT A process for the preparation of an aqueous plastics dispersion by copolymerization of a) 20 to 80% by weight of an ester of methacrylic acid, the homopolymer of which has a glass temperature TG above + 50 degrees C, or styrene, vinyltoluene or vinylxylene, or a mixture of these monomers, the aromatic monomer contributing not more than 50% by weight to the total amount of all monomers, as the hardening component, b) 20 to 80% by weight of an ester of acrylic acid or of methacrylic acid, the homopolymer of which has a glass temperature TG below + 50 degrees C, or a mixture of these monomers, as the plasticizing component, c) in each case relative to the total of A + B = 100, 1) 3 to 18% by weight of a monoolefinic unsaturated monomer having a hydroxyl group and 2) 0,5 to 10% by weight of an alpha-, beta- unsaturated monocarboxylic acid and/or an unsaturated dicarboxylic acid, in an aqueous medium in the presence of a radical-forming initiator and an emulsifier or a mixture of several emulsifiers, characterized in that the copolymerization is carried out in the presence of an anionic fluorinated surfactant having a perfluoralkyl radical of 2 to 20 C atoms or a perfluoraoaralkyl radical of 7 to 30 C atoms as the emulsifier or as a component of the mixture of emulsifier, and the particle diameters of the resulting dispersion copolymer are in the range of from 0.05 to 0.2 mu m.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19813128143 DE3128143A1 (en) | 1981-07-16 | 1981-07-16 | AQUEOUS COPOLYMERISAT DISPERSIONS, METHOD FOR THE PRODUCTION AND USE OF THE DISPERSIONS |
| DE31281435 | 1981-07-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AU8605882A true AU8605882A (en) | 1983-01-20 |
Family
ID=6137069
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU86058/82A Abandoned AU8605882A (en) | 1981-07-16 | 1982-07-15 | An aqueous plastics dispersion, a process for its preparation and the use of this dispersion |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP0070498B1 (en) |
| JP (1) | JPS5819303A (en) |
| AT (1) | ATE17739T1 (en) |
| AU (1) | AU8605882A (en) |
| BR (1) | BR8204135A (en) |
| DE (2) | DE3128143A1 (en) |
| DK (1) | DK318782A (en) |
| ES (1) | ES513837A0 (en) |
| FI (1) | FI822504L (en) |
| NO (1) | NO822456L (en) |
| PT (1) | PT75262B (en) |
| ZA (1) | ZA825033B (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3724858A1 (en) * | 1987-07-28 | 1989-02-09 | Texaco Ag | WAESSED PLASTIC DISPERSION |
| EP0529695A3 (en) * | 1989-05-31 | 1993-04-07 | Chemco Bausysteme Gesellschaft M.B.H. | Process for preparing a polymer dispersion |
| JP2001240791A (en) * | 2000-02-25 | 2001-09-04 | Nippon Paint Co Ltd | Method for forming composite coating film |
| WO2002020676A1 (en) * | 2000-09-07 | 2002-03-14 | Nederlandse Organisatie Voor Toegepast-Natuurwetenschappelijk Onderzoek Tno | Coating compositions containing perfluoropolyether surfactants |
| EP1342736B1 (en) * | 2002-02-28 | 2013-05-08 | Merck Patent GmbH | Prepolymer material, polymer material, imprinting process and their Use |
| DE102007058600A1 (en) | 2007-12-04 | 2009-06-10 | Merck Patent Gmbh | Use of phosphinic acids and / or phosphonic acids in polymerization processes |
| WO2013037707A1 (en) | 2011-09-14 | 2013-03-21 | Solvay Specialty Polymers Italy S.P.A. | Polymerization process |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3271341A (en) * | 1961-08-07 | 1966-09-06 | Du Pont | Aqueous colloidal dispersions of polymer |
| GB1574721A (en) * | 1976-03-03 | 1980-09-10 | Canadian Ind | Process for preparing aqueous copolymer emulsions |
-
1981
- 1981-07-16 DE DE19813128143 patent/DE3128143A1/en not_active Withdrawn
-
1982
- 1982-07-09 ES ES513837A patent/ES513837A0/en active Granted
- 1982-07-13 DE DE8282106241T patent/DE3268801D1/en not_active Expired
- 1982-07-13 AT AT82106241T patent/ATE17739T1/en not_active IP Right Cessation
- 1982-07-13 EP EP82106241A patent/EP0070498B1/en not_active Expired
- 1982-07-14 FI FI822504A patent/FI822504L/en not_active Application Discontinuation
- 1982-07-15 BR BR8204135A patent/BR8204135A/en unknown
- 1982-07-15 NO NO822456A patent/NO822456L/en unknown
- 1982-07-15 JP JP57122257A patent/JPS5819303A/en active Pending
- 1982-07-15 DK DK318782A patent/DK318782A/en not_active Application Discontinuation
- 1982-07-15 PT PT75262A patent/PT75262B/en unknown
- 1982-07-15 AU AU86058/82A patent/AU8605882A/en not_active Abandoned
- 1982-07-15 ZA ZA825033A patent/ZA825033B/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES8305015A1 (en) | 1983-04-01 |
| DE3268801D1 (en) | 1986-03-13 |
| NO822456L (en) | 1983-01-17 |
| JPS5819303A (en) | 1983-02-04 |
| EP0070498A1 (en) | 1983-01-26 |
| FI822504L (en) | 1983-01-17 |
| ATE17739T1 (en) | 1986-02-15 |
| BR8204135A (en) | 1983-07-12 |
| FI822504A0 (en) | 1982-07-14 |
| ES513837A0 (en) | 1983-04-01 |
| PT75262A (en) | 1982-08-01 |
| DE3128143A1 (en) | 1983-02-03 |
| PT75262B (en) | 1985-01-07 |
| ZA825033B (en) | 1983-06-29 |
| DK318782A (en) | 1983-01-17 |
| EP0070498B1 (en) | 1986-01-29 |
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