EP0182693A1 - Oxidant bleaching processes performed in an acid environment - Google Patents

Oxidant bleaching processes performed in an acid environment Download PDF

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Publication number
EP0182693A1
EP0182693A1 EP85402091A EP85402091A EP0182693A1 EP 0182693 A1 EP0182693 A1 EP 0182693A1 EP 85402091 A EP85402091 A EP 85402091A EP 85402091 A EP85402091 A EP 85402091A EP 0182693 A1 EP0182693 A1 EP 0182693A1
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Prior art keywords
vanadate
bleaching
bath
chlorite
hydrogen peroxide
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EP85402091A
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German (de)
French (fr)
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EP0182693B1 (en
Inventor
Jean Balland
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Manufacture de Produits Chimiques Protex SARL
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Manufacture de Produits Chimiques Protex SARL
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/0024—Dyeing and bleaching in one process
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3902—Organic or inorganic per-compounds combined with specific additives
    • C11D3/3905—Bleach activators or bleach catalysts
    • C11D3/3932—Inorganic compounds or complexes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
    • D06L4/00—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs
    • D06L4/10—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen
    • D06L4/12—Bleaching fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods; Bleaching leather or furs using agents which develop oxygen combined with specific additives

Definitions

  • the present invention relates to an improvement made to the oxidative bleaching processes carried out in an acid medium, by the action of hydrogen peroxide.
  • bleaching in an alkaline medium is not suitable for certain fibers, such as synthetic fibers.
  • other desiderata can rule out the use of an alkaline medium even with fibers, such as cellulosic fibers, which are not altered in such a medium. For example, we may want to keep the natural fats of fibers of vegetable or animal origin, fats which would be saponified in an alkaline medium.
  • the Applicant has therefore looked into the problem of industrial improvement of bleaching in an acid medium, by the action of hydrogen peroxide.
  • the Applicant has experimentally found that the introduction of a chlorite and a small amount of a vanadate into an aqueous and acid dilution of hydrogen peroxide makes it possible to greatly increase the whitening activity of the acid oxidizing solution and of industrially carry out bleaching under good pH and temperature conditions.
  • the present invention therefore relates to a process for bleaching fibers, using hydrogen peroxide in acid dilution, which is characterized in that the hydrogen peroxide is activated by the simultaneous presence of a chlorite and d 'an alkaline vanadate, in the bleaching bath.
  • the acid pH range of the bath can be between 3 and 6 and the temperatures between 30 and 130 ° C, preferably between 60 and 90 ° C.
  • the vanadate can be chosen from the family comprising vanadates of alkali metals and ammonium vanadate. Preference will be given among chlorites, to the use of sodium chlorite.
  • the necessary quantities of hydrogen peroxide will depend on the particularities of the bleaching process; these quantities could therefore be very variable and be, for example, between 1 and 100 g / l of a 35% hydrogen peroxide solution.
  • the necessary amounts of sodium chlorite will be between 0.1 and 10 g of chlorite per liter of the bath and preferably between 1 and 4 g / l.
  • the amounts of vanadate will be between 0.01 and 1 g per liter of bleaching bath and, preferably, between 0.1 and 0.4 g / 1.
  • sample bleached in bath c has a significantly higher whiteness level than that of samples from other baths with, in addition, good elimination of the shells of the fiber.
  • the temperature of the baths is brought to 80 ° C., this temperature is maintained for 20 minutes, then the temperature is brought to 110 ° C.
  • the sample from bath b has a weaker and duller coloration, the cellulosic fiber is not bleached and is heavily soiled by the dispersed dye.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Coloring (AREA)
  • Paper (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

Process for bleaching fibers by means of an acid solution of hydrogen peroxide. The acid solution is activated by means of a chlorite and a vanadate, simultaneously present in said solution.

Description

La présente invention concerne une amélioration apportée aux procédés de blanchiment oxydant réalisés en milieu acide, par l'action de peroxyde d'hydrogène.The present invention relates to an improvement made to the oxidative bleaching processes carried out in an acid medium, by the action of hydrogen peroxide.

On sait que l'efficacité blanchissante des dilutions de peroxyde d'hydrogène n'est pas très élevée en milieu acide et ne permet généralement pas de réaliser le blanchiment d'une fibre. C'est pour cette raison que le peroxyde d'hydrogène ou les peroxydes alcalins sont généralement utilisés en milieu alcalin.It is known that the bleaching efficiency of dilutions of hydrogen peroxide is not very high in an acid medium and generally does not allow the bleaching of a fiber. It is for this reason that hydrogen peroxide or alkaline peroxides are generally used in an alkaline medium.

Différents composés ont été préconisés pour accroître la stabilité et l'efficacité des peroxydes en milieu alcalin. L'emploi de silicates, de différents complexes de magnésium ou de divers autres sels est par exemple recommandé.Different compounds have been recommended to increase the stability and efficiency of peroxides in an alkaline medium. The use of silicates, different magnesium complexes or various other salts is for example recommended.

Cependant, le blanchiment en milieu alcalin ne convient pas à certaines fibres, telles que les fibres synthéthiques. Par ailleurs, d'autres désiderata peuvent faire écarter l'emploi d'un milieu alcalin même avec des fibres, comme les fibres cellulosiques, qui ne sont pas altérées dans un tel milieu. Par exemple, on peut vouloir conserver les graisses naturelles de fibres d'origine végétale ou animale, graisses qui seraient saponifiées en milieu alcalin.However, bleaching in an alkaline medium is not suitable for certain fibers, such as synthetic fibers. In addition, other desiderata can rule out the use of an alkaline medium even with fibers, such as cellulosic fibers, which are not altered in such a medium. For example, we may want to keep the natural fats of fibers of vegetable or animal origin, fats which would be saponified in an alkaline medium.

La demanderesse s'est donc penchée sur le problème de l'amélioration industrielle du blanchiment en milieu acide, par action de peroxyde d'hydrogène.The Applicant has therefore looked into the problem of industrial improvement of bleaching in an acid medium, by the action of hydrogen peroxide.

Des composés divers, tels que des sels métalliques dérivant par exemple du fer ou du cuivre, sont susceptibles d'accrol- tre la vitesse de décomposition de bains de peroxyde d'hydrogène en milieu acide. Il apparaît toutefois que ce type d'activation se traduit par la libération de molécules d'oxygène, ce qui est un processus pratiquement sans effet sur le blanchiment d'une fibre et ne peut donc être retenu.Various compounds, such as metal salts deriving for example from iron or copper, are capable of increasing the rate of decomposition of hydrogen peroxide baths in acid medium. However, it appears that this type of activation results in the release of oxygen molecules, which is a process which has practically no effect on the bleaching of a fiber and therefore cannot be retained.

L'emploi de divers autres composés a également été préconisé sans cependant jamais conduire à une efficacité blanchissante suffisante pour permettre véritablement de réaliser le blanchiment en milieu acide à l'aide de peroxyde d'hydrogène.The use of various other compounds has also been recommended without, however, ever leading to sufficient bleaching efficiency to truly allow bleaching in an acid medium using hydrogen peroxide.

La demanderesse a trouvé expérimentalement que l'introduction d'un chlorite et d'une faible quantité d'un vanadate dans une dilution aqueuse et acide de peroxyde d'hydrogène permet d'accroître fortement l'activité blanchissante de la solution oxydante acide et de réaliser industriellement le blanchiment dans de bonnes conditions de pH et de température.The Applicant has experimentally found that the introduction of a chlorite and a small amount of a vanadate into an aqueous and acid dilution of hydrogen peroxide makes it possible to greatly increase the whitening activity of the acid oxidizing solution and of industrially carry out bleaching under good pH and temperature conditions.

L'emploi de chlorite de sodium seul, sans vanadate, dans la solution acide de peroxyde d'hydrogène, ne permet pas d'accroître suffisamment l'activité blanchissante du milieu oxydant. Si l'on peut dans ce cas observer une amélioration de l'effet blanchissant, cette amélioration ne se manifeste cependant que d'une façon modérée et à la condition de réaliser le blanchiment à des températures relativement élevées de l'ordre de 120 à 130°C. Comparativement, la présence de vanadate permet d'enregistrer une efficacité nettement plus importante du pouvoir blanchissant, et ce, dans un domaine de température nettement plus acceptable, l'efficacité se manifestant déjà à partir de 40°C.The use of sodium chlorite alone, without vanadate, in the acid solution of hydrogen peroxide, does not make it possible to sufficiently increase the whitening activity of the oxidizing medium. If an improvement in the whitening effect can be observed in this case, this improvement only manifests itself in a moderate manner and on condition that the bleaching is carried out at relatively high temperatures of the order of 120 to 130 ° C. Comparatively, the presence of vanadate makes it possible to record a significantly greater efficiency of the bleaching power, and this, in a clearly more acceptable temperature range, the effectiveness manifesting itself already from 40 ° C.

De plus, il devient possible, comme l'a observé la demanderesse, de réaliser au cours d'une même opération, à la fois, le blanchiment et la teinture des fibres, en particulier des fibres de synthèse, dont la teinture s'effectue généralement dans un domaine de pH acide.In addition, it becomes possible, as observed by the applicant, to carry out, during the same operation, both bleaching and dyeing of fibers, in particular synthetic fibers, the dyeing of which takes place. generally in an acid pH range.

Divers autres avantages sont également offerts, tels que la possibilité de blanchir en milieu acide des articles tissés teints, en évitant le risque d'altération des divers coloris, ou la possibilité de réaliser le désencollage enzymatique au cours du processus de blanchiment, en éliminant, de façon économique, les produits d'encollage.Various other advantages are also offered, such as the possibility of bleaching dyed woven articles in an acid medium, avoiding the risk of alteration of the various colors, or the possibility of carrying out enzymatic desizing during the bleaching process, by eliminating, economically, sizing products.

La présente invention a donc pour objet un procédé de blanchiment de fibres, à l'aide de peroxyde d'hydrogène en dilution acide, qui se caractérise en ce que le peroxyde d'hydrogène est activé par la présence simultanée d'un chlorite et d'un vanadate alcalin, dans le bain de blanchiment.The present invention therefore relates to a process for bleaching fibers, using hydrogen peroxide in acid dilution, which is characterized in that the hydrogen peroxide is activated by the simultaneous presence of a chlorite and d 'an alkaline vanadate, in the bleaching bath.

Le domaine de pH acide du bain peut être compris entre 3 et 6 et les températures entre 30 et 130°C, de préférence entre 60 et 90°C.The acid pH range of the bath can be between 3 and 6 and the temperatures between 30 and 130 ° C, preferably between 60 and 90 ° C.

Le vanadate pourra être choisi dans la famille comprenant les vanadates des métaux alcalins et le vanadate d'ammonium. La préférence sera donnée parmi les chlorites, à l'emploi du chlorite de sodium.The vanadate can be chosen from the family comprising vanadates of alkali metals and ammonium vanadate. Preference will be given among chlorites, to the use of sodium chlorite.

Les quantités nécessaires de peroxyde d'hydrogène seront fonction des particularités du procédé de blanchiment ; ces quantités pourront donc être très variables et se situer, par exemple, entre 1 et 100g/l d'une solution de peroxyde d'hydrogène à 35 %.The necessary quantities of hydrogen peroxide will depend on the particularities of the bleaching process; these quantities could therefore be very variable and be, for example, between 1 and 100 g / l of a 35% hydrogen peroxide solution.

Les quantités nécessaires de chlorite de sodium seront comprises entre 0,1 et 10 g de chlorite par litre du bain et de préférence entre 1 et 4 g/l.The necessary amounts of sodium chlorite will be between 0.1 and 10 g of chlorite per liter of the bath and preferably between 1 and 4 g / l.

Les quantités de vanadate seront comprises entre 0,01 et 1 g par litre de bain de blanchiment et, de préférence, entre 0,1 et 0,4 g/1.The amounts of vanadate will be between 0.01 and 1 g per liter of bleaching bath and, preferably, between 0.1 and 0.4 g / 1.

Le procédé de l'invention permet de bénéficier d'avantages importants dans la préparation et la teinture des différentes fibres. Parmi ces avantages, on peut notamment retenir :

  • - La possibilité de blanchir à l'aide de peroxyde d'hydrogène l'ensemble des différentes fibres qui sont particulièrement sensibles au milieu alcalin, comme par exemple les fibres synthétiques.
  • - La possibilité de blanchir des articles tissés teints sans risque de dégradation des divers coloris.
  • - La réalisation simultanée du blanchiment et de la teinture.
  • - La réalisation d'un désencollage enzymatique au cours du procédé de blanchiment.
The process of the invention makes it possible to benefit from significant advantages in the preparation and dyeing of the different fibers. Among these advantages, we can notably note:
  • - The possibility of bleaching using hydrogen peroxide all the different fibers which are particularly sensitive to the alkaline medium, such as for example synthetic fibers.
  • - The possibility of bleaching dyed woven articles without risk of degradation of the various colors.
  • - Simultaneous bleaching and dyeing.
  • - Carrying out an enzymatic desizing during the bleaching process.

Les exemples suivants donnés à titre indicatif et non limitatif permettront d'illustrer de façon plus concrète les possibilités offertes par la présente invention.The following examples, given by way of non-limiting indication, will make it possible to illustrate in a more concrete way the possibilities offered by the present invention.

EXEMPLE 1 :EXAMPLE 1:

On traite un tissu de coton écru en opérant comparativement dans des bains ayant respectivement la composition suivante :

  • bain a : 4 cm3/l eau oxygénée à 35 % 2 cm3/l acide acétique
  • bain b : 4 cm3/1 eau oxygénée à 35 % 2 cm3/l acide acétique 2 g/1 chlorite de sodium
  • bain c : 4 cm3/1 eau oxygénée à 35 % 2 cm3/1 acide acétique 2 g/1 chlorite de sodium 0,2 g/1 vanadate de sodium
  • bain d : 4 cm3/1 eau oxygénée à 35 % 2 cm3/1 acide acétique 0,2 g/1 vanadate de sodium.
An unbleached cotton fabric is treated by operating comparatively in baths respectively having the following composition:
  • bath a: 4 cm 3 / l hydrogen peroxide at 35% 2 cm 3 / l acetic acid
  • bath b: 4 cm 3/1 to 35% hydrogen peroxide 2 cm 3 / l Acetic acid 2 g / 1 Sodium chlorite
  • bath c: 4 cm 3/1 hydrogen peroxide 35% 2 cm 3/1 acetic acid 2 g / 1 of sodium chlorite 0.2 g / 1 sodium vanadate
  • bath: 4 cm 3/1 to 35% hydrogen peroxide 2 cm 3/1 acetic acid 0.2 g / 1 sodium vanadate.

On adopte dans tous les cas les conditions suivantes :

  • Rapport de bain 1 à 10 - (entre le poids de fibre et le volume de bain)
  • Température 90°C
  • Durée 60 minutes.
The following conditions are adopted in all cases:
  • Bath ratio 1 to 10 - (between fiber weight and bath volume)
  • Temperature 90 ° C
  • Duration 60 minutes.

Après traitement, on rince puis sèche les différents échantillons.After treatment, the various samples are rinsed and then dried.

On observe que l'échantillon blanchi dans le bain c présente un niveau de blancheur nettement plus élevé que celui des échantillons issus des autres bains avec en outre une bonne élimination des coques de la fibre.It is observed that the sample bleached in bath c has a significantly higher whiteness level than that of samples from other baths with, in addition, good elimination of the shells of the fiber.

La détermination du degré de blancheur permet d'enregistrer les résultats suivants :

Figure imgb0001
The determination of the degree of whiteness makes it possible to record the following results:
Figure imgb0001

EXEMPLE 2 :EXAMPLE 2:

Un tissu constitué de fibres cellulosiques dont une partie a été préalablement teinte à l'aide de colorants réactifs afin de constituer un article tissu teint, est traité dans les bains de blanchiment respectifs ayant la composition suivante :

  • bain a : 3 cm3/1 eau oxygénée à 35 % 2 cm3/l acide acétique
  • bain b : 3 cm3/l eau oxygénée à 35 % 2 cm3/1 acide acétique 1,5 g/1 chlorite de sodium 0,2 g/1 vanadate de sodium
  • bain c : 3 cm3/1 eau oxygénée à 35 % 3 g/1 silicate de soude 2 cm3/l soude caustique à 30 %
A fabric consisting of cellulosic fibers, part of which has been dyed beforehand with reactive dyes in order to constitute a dyed fabric article, is treated in the respective bleaching baths having the following composition:
  • bath: 3 cm 3/1 to 35% hydrogen peroxide 2 cm 3 / l acetic acid
  • bath b: 3 cm 3 / l 35% hydrogen peroxide 2 cm 3/1 acetic acid 1.5 g / 1 of sodium chlorite 0.2 g / 1 sodium vanadate
  • bath c: 3 cm 3/1 hydrogen peroxide 35% 3 g / 1 sodium silicate 2 cm 3 / l sodium hydroxide solution 30%

On adopte les conditions opératoires suivantes :

  • Rapport de bain 1 à 10
  • Durée 1 heure
  • Température 80°C.
The following operating conditions are adopted:
  • Bath ratio 1 to 10
  • Duration 1 hour
  • Temperature 80 ° C.

On rince après traitement puis on sèche. On observe les résultats suivants pour les échantillons issus des divers bains :

  • bain a : blanchiment médiocre des fibres non teintes, avec une non élimination des coques de la fibre,
  • bain b : très bon degré de blan. Elimination totale des coques. On observe également que les divers coloris n'ont subi aucune dégradation.
  • bain c : bon degré de blan. Elimination totale des coques mais on observe une nette dégradation des coloris.
Rinse after treatment and then dry. The following results are observed for the samples from the various baths:
  • bath a: poor bleaching of undyed fibers, with non-elimination of the fiber shells,
  • bain b: very good degree of blan. Total elimination of hulls. We also observe that the various colors have not undergone any degradation.
  • bain c: good degree of blan. Total elimination of the hulls but there is a clear degradation of the colors.

EXEMPLE 3 :EXAMPLE 3:

On traite un tissu constitué de fibres de coton écru et de fibres de triacétate dans les bains de blanchiment ci-dessous, additionnés de colorants dispersés, afin de réaliser la teinture de la fibre de triacétate en même temps que le blanchiment de la fibre cellulosique.

  • bain a : 2 cm3/1 eau oxygénée à 35 % 0,75 g/1 chlorite de sodium 0,1 g/1 vanadate de sodium
  • bain a : 0,5 g/1 d'un colorant dispersé référencé dans le Color Index sous l'appela- tion de Disperse Red 60, 2 cm3/1 acide acétique
  • bain b : 0,5 g/1 de Disperse Red 60 2 cm3/1 acide acétique.
A fabric consisting of unbleached cotton fibers and triacetate fibers is treated in the bleaching baths below, containing dispersed dyes, in order to dye the triacetate fiber at the same time as the bleaching of the cellulosic fiber.
  • bath: 2 cm 3/1 hydrogen peroxide 35% 0.75 g / 1 of sodium chlorite 0.1 g / 1 sodium vanadate
  • bath: 0.5 g / 1 of a disperse dye present in the Color Index under the appela- tion of Disperse Red 60, 2 cm 3/1 acetic acid
  • bath b: 0.5 g / 1 of Disperse Red 60 2 cm3 / 1 acetic acid.

On adopte les conditions opératoires suivantes :

  • Rapport de bain 1 à 10.
The following operating conditions are adopted:
  • Bath ratio 1 to 10.

On porte la température des bains à 80°C, maintient cette température pendant 20 minutes, puis porte la température à 110°C.The temperature of the baths is brought to 80 ° C., this temperature is maintained for 20 minutes, then the temperature is brought to 110 ° C.

On maintient une température de 110°C pendant 30 minutes, refroidit puis rince la matière teinte.Maintaining a temperature of 110 ° C for 30 minutes, cooling and then rinsing the dyed material.

Après teinture, on observesur l'échantillon issu du bain a un excellent coloris sur la partie triacétate avec une fibre de coton blanchie et très peu salie par le colorant dispersé.After dyeing, we observe on the sample from the bath has an excellent color on the triacetate part with a cotton fiber bleached and very little soiled by the dispersed dye.

Comparativement, l'échantillon issu du bain b possède une coloration plus faible et plus terne, la fibre cellulosique n'est pas blanchie et se trouve fortement salie par le colorant dispersé.Comparatively, the sample from bath b has a weaker and duller coloration, the cellulosic fiber is not bleached and is heavily soiled by the dispersed dye.

EXEMPLE 4 :EXAMPLE 4:

On traite un tissu de coton écru et encollé de la façon suivante:

  • On imprègne ce tissu par foulardage dans un bain ayant la composition suivante :
    • 10 cm3/1 eau oxygénée
    • 5 g/1 chlorite de sodium
    • 0,3 g/1 vanadate de sodium
    • 1 cm3 acide acétique de façon à obtenir un pH de 5
    • 15 cm3/1 d'un produit enzymatique, commercialisé sous le nom d'Enzylase C, par la Société Diamalt.
We treat an unbleached and glued cotton fabric as follows:
  • This fabric is impregnated by padding in a bath having the following composition:
    • 1 0 cm 3/1 hydrogen peroxide
    • 5 g / 1 sodium chlorite
    • 0.3 g / 1 sodium vanadate
    • 1 cm 3 acetic acid so as to obtain a pH of 5
    • 15 cm 3/1 of an enzyme product sold under the name of Enzylase C, by Diamalt Company.

On exprime après imprégnation de façon à maintenir 90 % du bain d'imprégnation, met en rouleau puis porte ce rouleau dans une chambre de vaporisage pendant 90 minutes à la température de 80°C.It is expressed after impregnation so as to maintain 90% of the impregnation bath, rolls up and then carries this roll in a vaporization chamber for 90 minutes at a temperature of 80 ° C.

On rince après traitement puis sèche le tissu obtenu.Rinse after treatment and then dry the fabric obtained.

On observe après traitement un degré de blanc moyen avec une bonne élimination des coques de la fibre. On constate également un excellent désencollage de l'article blanchi qui correspond ainsi à un tissu parfaitement préparé pour subir toute autre opération de teinture ou finissage.After treatment, an average degree of white is observed, with good elimination of the fiber shells. There is also an excellent desizing of the bleached article which thus corresponds to a fabric perfectly prepared for undergoing any other dyeing or finishing operation.

Claims (10)

1. Procédé de blanchiment de fibres, au moyen d'une solution acide de peroxyde d'hydrogène,
caractérisé en ce que la solution acide est activée au moyen d'un chlorite et d'un vanadate, présents simultanément dans la solution acide.1. Process for bleaching fibers, using an acid solution of hydrogen peroxide,
characterized in that the acid solution is activated by means of a chlorite and a vanadate, present simultaneously in the acid solution. 2. Procédé selon la revendication 1, caractérisé en ce que la solution acide a un pH compris entre 3 et 6.2. Method according to claim 1, characterized in that the acid solution has a pH between 3 and 6. 3. Procédé selon la revendication 1 ou 2, caractérisé en ce que le vanadate est choisi dans la famille comprenant les vanadates de métaux alcalins et le vanadate d'ammonium.3. Method according to claim 1 or 2, characterized in that the vanadate is chosen from the family comprising vanadates of alkali metals and ammonium vanadate. 4. Procédé selon l'une des revendications 1 à 3, caractérisé en ce que le chlorite est le chlorite de sodium.4. Method according to one of claims 1 to 3, characterized in that the chlorite is sodium chlorite. 5. Procédé selon l'une des revendications 1 à 4, caractérisé en ce que la quantité de vanadate est comprise entre 0, 01 et 1 g de vanadate par litre de bain oxydant.5. Method according to one of claims 1 to 4, characterized in that the amount of vanadate is between 0.01 and 1 g of vanadate per liter of oxidizing bath. 6. Procédé selon la revendication 5, caractérisé en ce que la quantité de vanadate est comprise entre 0,1 et 0,4 g/1.6. Method according to claim 5, characterized in that the amount of vanadate is between 0.1 and 0.4 g / 1. 7. Procédé selon l'une des revendications 1 à 6, caractérisé en ce que la quantité de chlorite est comprise entre 0,1 et 10 g/l de bain.7. Method according to one of claims 1 to 6, characterized in that the amount of chlorite is between 0.1 and 10 g / l of bath. 8. Procédé selon la revendication 7, caractérisé en ce que la quantité de chlorite est comprise entre 1 et 4 g/1.8. Method according to claim 7, characterized in that the amount of chlorite is between 1 and 4 g / 1. 9. Procédé selon l'une des revendications 1 à 8, caractérisé en ce que le blanchiment est réalisé à une température comprise entre 30 et 130°C.9. Method according to one of claims 1 to 8, characterized in that the bleaching is carried out at a temperature between 30 and 130 ° C. 10. Procédé selon la revendication 9, caractérisé en ce que la température est comprise entre 60 et 90°C.10. Method according to claim 9, characterized in that the temperature is between 60 and 90 ° C.
EP85402091A 1984-10-31 1985-10-30 Oxidant bleaching processes performed in an acid environment Expired EP0182693B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR8416682 1984-10-31
FR8416682A FR2572430B1 (en) 1984-10-31 1984-10-31 IMPROVEMENT IN OXIDIZING BLEACHING PROCESSES CARRIED OUT IN AN ACID MEDIUM.

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EP0182693A1 true EP0182693A1 (en) 1986-05-28
EP0182693B1 EP0182693B1 (en) 1988-08-31

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EP85402091A Expired EP0182693B1 (en) 1984-10-31 1985-10-30 Oxidant bleaching processes performed in an acid environment

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EP (1) EP0182693B1 (en)
JP (1) JPS61502265A (en)
DE (1) DE3564713D1 (en)
FR (1) FR2572430B1 (en)
WO (1) WO1986002674A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19530786A1 (en) * 1995-08-22 1997-02-27 Hoechst Ag A bleaching composition containing polyoxometalates as a bleach catalyst
DE19942224A1 (en) * 1999-09-03 2001-03-08 Henkel Kgaa Use of transition metal complex compounds to enhance the bleaching effect of peroxygen compounds in acidic systems

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2471437A1 (en) * 1979-12-14 1981-06-19 Protex Manuf Prod Chimiq Bleaching of fibrous material by oxidn. - using hydrogen peroxide or alkali metal peroxide stabilised with an alkali(ne earth) chlorite

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2471437A1 (en) * 1979-12-14 1981-06-19 Protex Manuf Prod Chimiq Bleaching of fibrous material by oxidn. - using hydrogen peroxide or alkali metal peroxide stabilised with an alkali(ne earth) chlorite

Also Published As

Publication number Publication date
FR2572430B1 (en) 1987-01-23
DE3564713D1 (en) 1988-10-06
EP0182693B1 (en) 1988-08-31
FR2572430A1 (en) 1986-05-02
JPS61502265A (en) 1986-10-09
WO1986002674A1 (en) 1986-05-09
JPS6339704B2 (en) 1988-08-08

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