EP0172913A1

EP0172913A1 - Process and device for removing impurities contained in melted iron flowing from shaft furnace

Info

Publication number: EP0172913A1
Application number: EP85900768A
Authority: EP
Inventors: Kenzo Yamada; Katsuhiro Iwasaki; Mitsuru Ohtsuki; Haruo Ito
Original assignee: Nippon Kokan Ltd
Current assignee: JFE Engineering Corp
Priority date: 1984-02-04
Filing date: 1985-02-04
Publication date: 1986-03-05
Also published as: DE3590051T; EP0172913A4; IN165408B; DE3590051C2; EP0172913B1; GB2162860B; GB2162860A; GB8518758D0; BR8504996A; WO1985003525A1

Abstract

A slag trough (2N) for removing molten shaft furnace slag isolated from melted iron by a skimmer (3) is provided upstream from the skimmer (3) mounted in midway on a molten iron trough (1), and at least two partition walls (4a, 4b, 4c) are provided at a predetermined distance in the trough (1) downstream from the skimmer (3), the trough (1) is thus partitioned into at least two reaction zones (6a, 6b, 6c), lances (8a, 8b, 8c) for blowing particular flux for removing the impurities contained in the molten iron via carrier gas are disposed substantially vertically above the two reaction zones, the lower ends of the lances are isolated substantially vertically from the surface of the melted iron, and branch slag troughs (9a, 9b, 9c) are respectively provided with at least two reaction zones (6a, 6b, 6c).

Description

FIELD OF THE INVENTION

The present invention relates to an apparatus for removing at least two of such impurities as silicon, phosphorus and sulfur contained in molten pig iron in the middle of a hot-metal runner for directing molten pig iron tapped from a blast furnace into a hot-metal ladle.

BACKGROUND OF THE INVENTION

There is known methods for removing at least one of such impurities as silicon, phosphorus and sulfur contained in molten pig iron in the middle of a hot-metal runner for directing molten pig iron tapped from a blast furnace into a hot-metal ladle.
The above-mentioned conventional method commonly applied so far for removing impurities contained in molten pig iron tapped from the blast furnace in the middle of the hot-metal runner, comprises charging a granular flux for removing impurities contained in molten pig iron from a hopper arranged above the hot-metal runner into molten pig iron flowing through the hot-metal runner. This method has however the disadvantage of a low removing efficiency of impurities because of the insufficient contact between molten pig iron and the granular flux as a result of the fact that the charged granular flux floats on the surface of molten pig iron and does not sufficiently penetrate into molten pig iron.
As a method for efficiently removing impurities contained in molten pig iron tapped from a blast furnace, which solves the above-mentioned disadvantage and enables a sufficient contact between molten pig iron and a granular flux, there is known a method, disclosed in Japanese Patent Provisional Publication No.57-200,510 dated December 8, 1982, for removing silicon as one of impurities contained in molten pig iron tapped from a blast furnace, which comprises:
substantially vertically arranging a lance above a hot-metal runner for directing molten pig iron tapped from a blast furnace into a hot-metal ladle so that the lower end portion of said lance is immersed into molten pig iron flowing through said hot-metal runner; and blowing, through said lance, a granular flux for removing silicon as one of impurities contained in molten pig iron by means of a carrier gas, into molten pig iron flowing through said hot-metal runner, to cause said granular flux thus blown to combine with silicon contained in molten pig iron to form molten slag, thereby removing silicon from molten pig iron (hereinafter referred to as the "prior art 1").
The above-mentioned prior art 1 involves the following drawbacks:

(1) Since the lower end portion of the lance for blowing a granular flux by means of a carrier gas is immersed into molten pig iron, the lance is susceptible to a serious fusion. It is therefore necessary to frequently replace the lance, thus requiring much costs.
(2) Since the granular flux blown from the lance by means of a crrier gas into molten pig iron seriously hits the bottom of the hot-metal runner, the bottom of the hot-metal runner is damaged. It is therefore necessary to frequently repair the bottom of the hot-metal runner, thus requiring much costs.

As a method for efficiently removing impurities contained in molten pig iron tapped from a blast furnace, which solves the above-mentioned drawbacks in the prior art 1 and enables to avoid the fusion of the lance or damage to the bottom of the hot-metal runner, there is known a method, disclosed in Japanese Patent Provisional Publication No. 58-130,208 dated August 3, 1983, for removing impurities contained in molten pig iron tapped from a blast furnace, which comprises:
substantially vertically arranging a lance above a hot-metal runner for directing molten pig iron tapped from a blast furnace into a hot-metal ladle so that the lowermost end of said lance is spaced apart by a prescribed distance from the.surface of molten pig iron flowing through said hot-metal runner; and blowing, through said lance, a granular flux for removing impurities contained in molten pig iron by means of a carrier gas, into molten pig iron flowing through said hot-metal runner, to cause said granular flux thus blown to combine with impurities contained in molten pig iron to form molten slag, thereby removing said impurities from molten pig iron (hereinafter referred to as the "prior art 2").
The above-mentioned prior art 2 has the following drawbacks: In the prior art 2, there is only a single lance which is substantially vertically arranged above the hot-metal runner for blowing a granular flux. When both a granular flux for removing silicon and a granular flux for removing sulfur are blown through the single lance into molten pig iron in an attempt to simultaneously remove silicon and sulfur as impurities contained in molten pig iron, molten slag mainly comprising Si0₂ formed as a result of combination with silicon in molten pig iron reduces the removing efficiency of sulfur. Thus, at least two of impurities contained in molten pig iron cannot be removed efficiently by the application of the prior art 2.
Under such circumstances, there is a strong demand for the development of an apparatus for simultaneously and efficiently removing at least two impurities contained in molten pig iron, in which at least one lance is arranged above a hot-metal runner for directing molten pig iron tapped from a blast furnace into a hot-metal ladle so that the lowermost end of the at least one.lance is spaced apart by a prescribed distance from the surface of molten pig iron flowing through the hot-metal runner, and a granular flux for removing impurities contained in molten pig iron is blown through the at least one lance by means of a carrier gas into molten pig iron flowing through the hot-metal runner. However, such an apparatus has not as yet been proposed.

SUMMARY OF THE INVENTION

An object of the present invention is therefore to provide an apparatus for simultaneously and efficiently removing at least two impurities contained in molten pig iron, in which at least one lance is arranged above a hot-metal runner for directing molten pig iron tapped from a blast furnace into a hot-metal ladle so that the lowermost end of the at least one lance is spaced apart by a prescribed distance from the surface of molten pig iron flowing through the hot-metal runner, and a granular flux for removing impurities contained in molten pig iron is blown through the at least one lance by means of a carrier gas into molten pig iron flowing through the hot-metal runner. However, such an apparatus has not as yet been proposed.
In accordance with one of the features of the present invention, there is provided an apparatus for removing impurities contained in molten pig iron tapped from a blast furnace, which comprises:

a hot-metal runner for directing molten pig iron tapped from a blast furnace into a hot-metal ladle;
a skimmer, provided in the middle of said hot-metal runner, for damming up molten blast furnace slag floating on the surface of molten pig iron flowing through said hot-metal runner to separate molten blast furnace slag from molten pig iron, the lower end of said skimmer being immersed into molten pig iron flowing through said hot-metal runner and spaced apart from the bottom of said hot-metal runner by a distance sufficient to allow molten pig iron to pass through;
a slag runner, provided in the upstream of said skimmer relative to the flowing direction of molten pig iron in said hot-metal runner, for discharging molten blast furnace slag separated from molten pig iron by means of said skimmer; and
at least one lance, arranged substantially vertically above said hot-metal runner, for blowing, by means of a carrier gas, a granular flux for removing impurities contained in molten pig iron tapped from said blast furnace into molten pig iron flowing through said hot-metal runner, the lowermost end of said at least one lance being spaced apart by a prescribed distance from the surface of molten pig iron flowing through said hot-metal runner;
thereby causing combination of impurities contained in molten pig iron with said granular flux blown from said at least one lance into molten pig iron flowing through said hot-metal runner to form molten slag to remove said impurities;

at least two partitions (4a, 4b, 4c) are provided in said hot-metal runner (1) at prescribed intervals therebetween at right angles to the flowing direction of molten pig iron in said hot-metal runner (1) in the downstream of said skimmer (3) relative to the flowing direction of molten pig iron in said hot-metal runner (1), to divide said hot-metal runner (1) into at least two reaction zones (6a, 6b, 6c), the lower end of each of said at least two partitions (4a, 4b, 4c) being immersed into molten pig iron flowing through said hot-metal runner (1) and being spaced apart from the bottom (la) of said hot-metal runner (1) by a distance sufficient to allow molten pig iron to pass through;
said at least one lance (8a, 8b, 8c) is arranged for each of said at least two reaction zones (6a, 6b, 6c);
each of a plurality of branch slag runners (9a, 9b, 9c) is provided for each of said at least two reaction zones (6a, 6b, 6c);

BRIEF DESCRIPTION OF THE DRAWINGS

Fig. 1 is a schematic plan view illustrating a first embodiment of the apparatus of the present invention;
Fig. 2 is a sectional view illustrating the apparatus of the first embodiment of the present invention cut along the line A-A in Fig. 1;
Fig. 3 is a schematic plan view illustrating a second embodiment of the apparatus of the present invention;
Fig. 4 is a sectional view illustrating the apparatus of the second embodiment of the present invention cut along the line B-B in Fig. 3;
Fig. 5 is a schematic plan view illustrating a third embodiment of the apparatus of the present invention;
Fig. 6 is a sectional view illustrating the apparatus of the third embodiment of the present invention cut along the line C-C in Fig. 5;
Fig. 7 is a schematic plan view illustrating a fourth embodiment of the apparatus of the present invention;
Fig. 8 is a sectional view illustrating the apparatus of the fourth embodiment of the present invention cut along the line D-D in Fig. 7;
Fig. 9 is a schematic plan view illustrating a fifth embodiment of the apparatus of the present invention;
Fig. 10 is a schematic plan view illustrating a sixth embodiment of the apparatus of the present invention; and
Fig. 11 is a schematic cross-sectional view of a hot-metal runner illustrating blowing of a granular flux through a lance into molten pig iron in the apparatus of the present invention.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS

From the above-mentioned point of view, we carried out extensive studies to develop an apparatus for simultaneously and efficiently removing at least two impurities contained in molten pig iron, in which at least one lance is arranged above a hot-metal runner for directing molten pig iron tapped from a blast furnace into a hot-metal ladle so that the lowermost end of the at least one lance is spaced apart by a prescribed distance from the surface of molten pig iron flowing through the hot-metal runner, and a granular flux for removing impurities contained in molten pig iron is blown through the at least one lance by means of a carrier gas into molten pig iron flowing through the hot-metal runner.
As a result, we obtained the following finding:

it is possible to simultaneously and efficiently remove at least two impurities from molten pig iron tapped from a blast furnace by providing, in the downstream of a skimmer, which is provided in the middle of a hot-metal runner for directing molten pig iron tapped from a blast furnace into a hot-metal ladle and dams up molten blast furnace slag floating on the surface of molten pig iron flowing through the hot-metal runner to separate molten blast furnace slag from molten pig iron, relative to the flowing direction of molten pig iron in the hot-metal runner, at least two partitions at right angles to the flowing direction of molten pig iron in the hot-metal runner at prescribed intervals therebetween, of which the lower ends are immersed into molten pig iron with a distance from the bottom of the hot-metal runner sufficient to allow molten pig iron to pass through, to divide the hot-metal runner into at least two reaction zones; substantially vertically arranging at least one lance above each of the at least two reaction zones so that the lowermost end of the at least one lance is spaced apart from the surface of molten pig iron by a prescribed distance; blowing, through the at least one lance, a granular flux for removing impurities contained in molten pig iron into molten pig iron flowing through the at least two reaction zones by means of a carrier gas; providing each of a plurality of branch slag runners for each of the at least two reaction zones; damming up, by means of each of the at least two partitions, molten slag produced in each of the at least two reaction zones through combination of the granular flux with impurities contained in molten pig iron; separating the thus produced molten slag from molten pig iron; and discharging the thus produced molten slag from each of the at least two reaction zones through each of the branch slag runners.

The present invention was made on the basis of the above-mentioned finding. Now, the apparatus of the present invention is described with reference to the drawings.
Fig. 1 is a schematic plan view illustrating a first embodiment of the apparatus of the present invention, and Fig. 2 is a sectional view illustrating the apparatus of the first embodiment of the present invention cut along the line A-A in Fig. 1. As shown in Figs. 1 and 2, in the middle of a hot-metal runner 1 for directing molten pig iron 5 tapped from a blast furnace not shown into a hot-metal ladle not shown, a skimmer 3 for damming up molten blast furnace slag 7 floating on the surface of molten pig iron 5 flowing through the hot-metal runner 1 to separate molten blast furnace slag 7 from molten pig iron 5, is provided at right angles to the flowing direction of molten pig iron 5 between opposite side walls lb and lc of the hot-metal runner 1. The lower end of the skimmer 3 is immersed into molten pig iron 5 flowing through the hot-metal runner 1, and is spaced apart from the bottom la of the hot-metal runner 1 by a distance sufficient to allow molten pig iron 5 to pass through. A slag runner 2 for discharging molten blast furnace slag 7 separated from molten pig iron 5 by the skimmer, is provided in the hot-metal runner 1 in the upstream of the skimmer 3 relative to the flowing direction of molten pig iron 5 in the hot-metal runner 1.
A first partition 4a and a second partition 4b are provided in the hot-metal runner 1 at prescribed intervals therebetween at right angles to the flowing direction of molten pig iron 5 in the hot-metal runner 1 in the downstream of the skimmer 3 relative to the flowing direction of molten pig iron in the hot-metal runner 1 between the opposite side walls lb and lc of the hot-metal runner 1. The hot-metal runner 1 is divided by these two partitions 4a and 4b, from the upstream toward the downstream thereof, into a first reaction zone 6a and a second reaction zone 6b. The first reaction zone 6a is a reaction zone for removing silicon as one of impurities contained in molten pig iron,- and the second reaction zone 6b is a reaction zone for removing phosphorus or sulfur as one of impurities contained in molten pig iron. The lower end of each of the first partition 4a and the second partition 4b is immersed into molten pig iron 5 flowing through the hot-metal runner 1 and is spaced apart from the bottom la of the hot-metal runner 1 by a distance sufficient to allow molten pig iron 5 to pass through.
Above the first reaction zone 6a, two first lances 8a for blowing, by means of a carrier gas, a granular flux for removing silicon as one of impurities contained in molten pig iron into molten pig iron 5 flowing through the first reaction zone 6a, are substantially vertically arranged so as to pass through a cover 10 covering the first reaction zone 6a. Above the second reaction zone 6b, two second lances 8b for blowing, by means of a carrier gas, a granular flux for removing phosphorus.or sulfur as one of impurities contained in molten pig iron into molten pig iron 5 flowing through the second reaction zone 6b, are substantially vertically arranged so as to pass through the cover 10 also covering the second reaction zone 6b. The lowermost end of each of the first lances 8a and the second lances 8b is spaced apart from the surface of molten pig iron 5 by a prescribed distance. A first branch slag runner 9a is provided in the first reaction zone 6a, and a second branch slag runner 9b is provided in the second reaction zone 6b. The downstream end of each of the first branch slag runner 9a and the second branch slag runner 9b communicates with the slag runner 2. In Fig. 1, lla is a first tank for receiving a granular flux to be supplied through a conduit 11' to each of the two first lances 8a, and llb is a second tank for receiving a granular flux to be supplied through a conduit 11' to each of the two second lances 8b.
Molten blast furnace slag 7 floating on the surface of molten pig iron 5 which is tapped from the blast furnace not shown and flows through the hot-metal runner 1, is dammed up by the skimmer 3, separated from molten pig iron 5, and discharged through the slag runner 2. Molten pig iron 5 after the separation of molten blast furnace slag 7 by the skimmer 3, flows through the first reaction zone 6a and the second reaction zone 6b. A granular flux for removing silicon as one of impurities contained in molten pig iron is blown through the two first lances 8a by means of carrier gas into molten pig iron 5 flowing through the first reaction zone 6a. As a result, molten slag 7a is produced in the first reaction zone 6a through combination of the granular flux blown from the two frist lances 8a into molten pig iron 5 flowing through the first reaction zone 6a with silicon contained in molten pig iron, and thus silicon is removed from molten pig iron 5. Molten slag 7a thus produced is dammed up by the first partition 4a, separated from molten pig iron 5, and discharged through the first branch slag runner 9a from the first reaction zone 6a.
A granular flux for removing phosphorus or sulfur as one of impurities contained in molten pig iron is blown, in the second reaction zone 6b, through the two second lances 8b by means of a carrier gas into molten pig iron 5 from which silicon has been removed and molten slag 7a has been separated by the first partition 4a as described above. As a result, molten slag 7b is produced in the second reaction zone 6b through combination of the granular flux blown from the two second lances 8b into molten pig iron 5 flowing through the second reaction zone 6b with phosphorus or sulfur contained in molten pig iron, and thus phosphorus or sulfur is removed from molten pig iron 5. Molten slag 7b thus produced is dammed up by the second partition 4b, separated from molten pig iron 5, and discharged through the second branch slag runner 9b from the second reaction zone 6b.
Molten pig iron 5 from which silicon has thus been removed in the first reaction zone 6a, and then, phosphorus or sulfur has thus been removed in the second reaction zone. 6b, is directed through the hot-metal runner 1 into the hot-metal ladle not shown. On the other hand, molten slags 7a and 7b discharged respectively through the first branch slag runner 9a and the second branch slag runner 9b from the first reaction zone 6a and the second reaction zone 6b, are directed to the slag runner 2, and then further directed, together with molten blast furnace slag 7, through the slag runner 2 to a slag ladle or a slag disposal equipment not shown.
The following known fluxes are used as granular fluxes for removing impurities contained in molten pig iron:

(1) Granular flux for removing silicon:
- at least one flux selected from the group consisting of granular iron ore, granular ferro-manganese ore, iron sand and granular mill scale.
(2) Granular flux for removing phosphorus:
- Granular mixture of at least one flux selected from the group consisting of granular iron ore, granular ferro-manganese ore, iron sand and granular mill scale, on the one hand, and at least one flux selected from the group consisting of granular soda ash, granular calcined lime, granular limestone, granular converter slag and granular calcium carbide, on the other hand.
(3) Granular flux for removing sulfur:
- At least one flux selected from the group consisting of granular soda ash, granular calcined lime, granular limestone, granular converter slag and granular calcium carbide.

Fig. 11 is a schematic cross-sectional view of a hot-metal runner illustrating blowing of a granular flux through a lance into molten pig iron in the apparatus of the present invention. As shown in Fig. 11, the lowermost end of the first lance 8a, for example, is spaced apart by a prescribed distance from the surface of molten pig iron 5 flowing through the hot-metal runner 1. This arrangement makes it possible to blow.a granular flux 16 into molten pig iron 5 by means of a carrier gas without the fusion of the first lance 8a or damage to the bottom la of the hot-metal runner 1. In order to remove impurities contained in molten pig iron at a high and stable efficiency by means of such blowing of a granular flux through the lance, it is desirable to conduct blowing of a granular flux into molten pig iron so as to satisfy the following two Equations:
In Equations (1) and (2):

H : depth of molten pig iron in the hot-metal runner (mm),
Hp : penetration depth of the granular flux into molten pig iron in the hot-metal runner (mm),
M : flow rate of the granular flux (kg/minute),
G : flow rate of the carrier gas (Nm³/minute),
r : average particle size of the granular flux (mm),
D : inside diameter of the lance (mm), and
H_L : distance between the surface of molten pig iron in the hot-metal runner and the lowermost end of the lance (mm).

In the apparatus of the first embodiment, the two reaction zones may comprise, in addition to comprising the first reaction zone 6a for removing silicon as one of impurities contained in molten pig iron and the second reaction zone 6b for removing phosphorus or sulfur as one of impurities contained in molten pig iron as described above, the following reaction zones:

(1) The first reaction zone 6a is a reaction zone for removing sulfur as one of impurities contained in molten pig iron, and the second reaction zone 6b is a reaction zone for removing silicon as one of impurities contained in molten pig iron.
(2) In the case with a low silicon content in molten pig iron tapped from the blast furnace, the first reaction zone 6a is a reaction zone for removing phosphorus or sulfur contained in molten pig iron, and the second reaction zone 6b is a reaction zone for removing sulfur or phosphorus contained in molten pig iron.

When removing silicon and phosphorus as impurities contained in molten pig iron, it is necessary to remove silicon prior to removing phosphorus. More particularly, when silicon is present in molten pig iron, a granular flux blown into molten pig iron for removing phosphorus reacts preferentially with silicon, thus seriously reducing the removing efficiency of phosphorus.
Fig. 3 is a schematic plan view illustrating a second embodiment of the apparatus of the present invention, and Fig. 4 is a sectional view illustrating the apparatus of the second embodiment of the present invention cut along the line B-B in Fig. 3. As shown in Figs. 3 and 4, similarly to the apparatus of the first embodiment described with reference to Figs. 1 and 2, in the apparatus of the second embodiment, a first partition 4a and a second partition 4b are provided in the hot-metal runner 1 at prescribed intervals therebetween at right angles to the flowing direction of molten pig iron 5 in the hot-metal runner 1 in the downstream of the skimmer 3 relative to the flowing direction of molten pig iron in the hot-metal runner 1. The hot-metal runner 1 is divided by these two partitions 4a and 4b, from the upstream toward the downsteam thereof, into a first reaction zone 6a and a second reaction zone 6b.
In the apparatus of the second embodiment, the first reaction zone 6a is a reaction zone for removing phosphorus as one of impurities contained in molten pig iron, and the second reaction zone 6b is a reaction zone for removing sulfur as one of impurities contained in molten pig iron.
Above the first reaction zone 6a, two first lances 8a for blowing, by means of a carrier gas, a granular flux for removing phosphorus as one of impurities contained in molten pig iron into molten pig iron 5 flowing through the first reaction zone 6a, are substantially vertically arranged so as to pass through a cover 10 covering the first reaction zone 6a. Above the second reaction zone 6b, two second lances 8b for blowing, by means of a carrier gas, a granular flux for removing sulfur as one of impurities contained in molten pig iron into molten pig iron 5 flowing through the second reaction zone 6b, are substantially vertically arranged so as to pass through the cover 10 also covering the second reaction-zone 6b. The lowermost end of each of the first lances 8a and the second lances 8b is spaced apart from the surface of molten pig iron 5 by a prescribed distance. A first branch slag runner 9a is provided in the first reaction zone 6a, and a second branch slag runner 9b is provided in the second reaction zone 6b. The downstream end of each of the first branch slag runner 9a and the second branch slag runner 9b communicates with the slag runner 2.
In the apparatus of the second embodiment, two third lances 8c for blowing,by means of a carrier gas, a granular flux for removing silicon as one of impurities contained in molten pig iron into molten pig iron 5 flowing through the hot-metal runner 1, are substantially vertically arranged above the hot-metal runner 1 in the upstream of the skimmer 3 relative to the flowing direction of molten pig iron in the hot-metal runner 1 so as to pass through the cover 10 covering the hot-metal runner 1. The lowermost end of each of the third lances 8c is spaced apart from the surface of molten pig iron 5 by a prescribed distance. In Fig. 3, llc is a tank for receiving a granular flux to be supplied through a conduit 11' to each of the two third lances 8c.
A granular flux for removing silicon as one of impurities contained in molten pig iron is blown, in the upstream of the slag skimmer 3, through the two third lances 8c by means of a carrier gas into molten pig iron 5 tapped from a blast furnace not shown and flowing through the hot-metal runner 1. As a result, molten slag 7c is produced through combination of the granular flux blown from the two third lances 8c into molten pig iron 5 flowing through the hot-metal runner 1 with silicon as one of impurities contained in molten pig iron, and silicon is thus removed from molten pig iron 5. Molten slag 7c thus produced is dammed up by the skimmer 3, separated from molten pig iron 5, and discharged from the hot-metal runner 1 through the slag runner 2, together with molten blast furnace slag 7 separated from molten pig iron.
A granular flux for removing phosphorus as one of impurities contained in molten pig iron is blown, in the first reaction zone 6a, through the two first lances 8a by means of a carrier gas into molten pig iron 5 from which silicon has thus been removed and molten blast furnace slag 7 and molten slag 7c have thus been separated by the skimmer 3. As a result, molten slag 7a is produced in the first reaction zone 6a through combination of the granular flux blown from the two first lances 8a into molten pig iron 5 flowing through the first reaction zone 6a with phosphorus contained in molten pig iron, and phosphorus is thus removed from molten pig iron 5. Molten slag 7a thus produced is dammed up by the first partition 4a, separated from molten pig iron 5, and discharged through the first branch slag runner 9a from the first reaction zone 6a.
A granular flux for removing sulfur as one of impurities contained in molten pig iron is blown, in the second reaction zone 6b, through the two second lances 8b by means of a carrier gas into molten pig iron 5 from which phosphorus has thus been removed and molten slag 7a has thus been separated by the first partition 4a. As a result, molten slag 7b is produced in the second reaction zone 6b through combination of the granular flux blown from the two second lances 8b into molten pig iron 5 flowing through the second reaction zone 6b with sulfur contained in molten pig iron, and sulfur is thus removed from molten pig iron 5. Molten slag 7b thus produced is dammed up by the second partition 4b, separated from molten pig iron 5, and discharged from the second reaction zone 6b through the second branch slag runner 9b.
Molten pig iron 5 from which silicon has thus been removed in the hot-metal runner 1 in the upstream of the skimmer 3, then phosphorus has thus been removed in the first reaction zone 6a, and then sulfur has thus been removed in the second reaction zone 6b, is directed through the hot-metal runner 1 into the hot-metal ladle not shown. On the other hand, molten slags 7a and 7b discharged respectively through the first branch slag runner 9a and the second branch slag runner 9b respectively from the first reaction zone 6a and the second reaction zone 6b, are directed to the slag runner 2, and then further directed, together with molten blast furnace slag 7 and molten slag 7c, through the slag runner 2 to a slag ladle or a slag disposal equipment not shown. In the apparatus of the second embodiment, the first reaction zone 6a may be used as a reaction zone for removing sulfur as one of impurities contained in molten pig iron, and the second reaction zone 6b may be used as a reaction zone for removing phosphorus as one of impurities contained in molten pig iron.
In the apparatus of the second embodiment, as described above, the granular flux for removing silicon as one of impurities is blown through the two third lances 8c by means of the carrier gas into molten pig iron 5, on the surface of which molten blast furnace slag 7 floats, in the hot-metal runner 1 in the upstream of the skimmer 3. Because of the very high content of CaO, molten blast furnace slag 7 has a high basicity. Therefore, molten slag 7c mainly comprising Si0₂and having a low basicity, which has been produced through combination of the granular flux for removing silicon, blown.through the two third lances 8c by means of the carrier gas, with silicon contained in molten pig iron, is mixed with the above-mentioned molten blast furnace slag 7 having a high basicity. Molten slag 7c of which basicity has thus been increased, is improved in fluidity, and is smoothly discharged from the hot-metal runner 1 through the slag runner 2 together with molten blast furnace slag 7. Furthermore the reaction of the granular flux for removing silicon, blown through the third lances 8c, with silicon contained in molten pig iron becomes more active under the effect of molten blast furnace slag 7 having a high basicity. It is consequently possible to efficiently remove silicon from molten pig iron 5 flowing through the hot-metal runner 1.
Fig. 5 is a schematic plan view illustrating a third embodiment of the apparatus of the present invention, and Fig. 6 is a sectional view illustrating the apparatus of the third embodiment of the present invention cut along the line C-C in Fig. 5. As shown in Figs. 5 and 6, similarly to the apparatus of the first embodiment described with reference to Figs. 1 and 2, in the apparatus of the third embodiment, a first partition 4a and a second partition 4b are provided in the hot-metal runner 1 at prescribed intervals therebetween at right angles to the flowing direction of molten pig iron 5 in the hot-metal runner 1 in the downstream of the skimmer 3 relative to the flowing direction of molten pig iron in the hot-metal runner 1. The hot-metal runner 1 is divided by these two partitions 4a and 4b, from the upstream toward the downstream thereof, into a first reaction zone 6a and a second reaction zone 6b.
In the apparatus of the third embodiment, the first reaction zone 6a is a reaction zone for removing silicon and phosphorus as impurities contained in molten pig iron, and the second reaction zone 6b is a reaction zone for removing sulfur as one of impurities contained in molten pig iron.
Above the first reaction zone 6a, two first lances 8a for blowing, by means of a carrier gas, a granular flux for removing silicon as one of impurities contained in molten pig iron into molten pig iron 5 flowing through the first reaction zone 6a, and two second lances 8b positioned in the downstream of the two first lances 8a for blowing, by means of a carrier gas, a granular flux for removing phosphorus as one of impurities contained in molten pig iron, are substantially vertically arranged so as to pass through a cover 10 covering the first reaction zone 6a. Above the second reaction zone 6b, two third lances 8c for blowing, by means of a carrier gas, a granular flux for removing sulfur as one of impurities contained in molten pig iron into molten pig iron 5 flowing through the second reaction zone 6b, are substantially vertically arranged so as to pass through the cover 10 also covering the second reaction zone 6b. The lowermost end of each of the first lances 8a, the second lances 8b and the third lances 8c is spaced apart from the surface of molten pig iron 5 by a prescribed distance. A first branch slag runner 9a is provided in the first reaction zone 6a, and a second branch slag runner 9b is provided in the second reaction zone 6b. The downstream end of each of the first branch slag runner 9a and the second branch slag runner 9b communicates with the slag runner 2.
Molten blast furnace slag 7 floating on the surface of molten pig iron 5 which is tapped from a blast furnace not shown and flows through the hot-metal runner 1, is dammed up by the skimmer 3, separated from molten pig iron, and discharged through the slag runner 2.
A granular flux for removing silicon as one of impurities contained in molten pig iron is blown, in the first reaction zone 6a, through the two first lances 8a by means of a carrier gas, and a granular flux for removing phosphorus as one of impurities contained in molten pig iron is blown, also in the first reaction zone 6a, through the two second lances 8b by means of a carrier gas, into molten pig iron 5 from which molten blast furnace slag 7 has thus been separated by the skimmer 3. As a result, molten slag 7a is first produced in the first reaction zone 6a through combination of the granular flux blown from the two first lances 8a into molten pig iron 5 flowing through the first reaction zone 6a with silicon contained in molten pig iron, and silicon is thus removed from molten pig iron 5. Then, molten slag 7b is also produced in the first reaction zone 6a through combination of the granular flux blown from the two second lances 8b with phosphorus contained in molten pig iron, and phosphorus is thus removed from molten pig iron 5. Mixed molten slag comprising molten slag 7a and molten slag 7b is dammed up by the first partition 4a, separated from molten pig iron 5 and discharged from the first reaction zone 6a through the first branch slag runner 9a.
A granular flux for removing sulfur as one of impurities contained in molten pig iron is blown, in the second reaction zone 6b, through the two third lances 8c by means of a carrier gas into molten pig iron 5 from which silicon and phosphorus have been removed and molten slags 7a and 7b have been separated by the first partition 4a as described above. As a result, molten slag 7c is produced in the second reaction zone 6b through combination of the granular flux blown from the two third lances 8c into molten pig iron 5 flowing through the second reaction zone 6b with sulfur contained in molten pig iron, and sulfur is thus removed from molten pig iron 5. Molten slag 7c thus produced is dammed up by the second partition 4b, separated from molten pig iron 5, and discharged from the second reaction zone 6b through the second branch slag runner 9b.
Molten pig iron 5 from which silicon and phosphorus have thus been removed in the first reaction zone 6a and then sulfur has thus been removed in the second reaction zone 6b, is directed through the hot-metal runner 1 into the hot-metal ladle not shown. On the other hand, molten slags 7a, 7b and 7c discharged from the first reaction zone 6a and the second reaction zone 6b through the first branch slag runner 9a and the second branch slag runner 9b, are directed to the slag runner 2, and then further directed, together with molten blast furnace slag 7, through the slag runner 2 to a slag ladle or a slag disposal equipment not shown. In the apparatus of the third embodiment, the first reaction zone 6a may be used as a reaction zone for removing sulfur as one of impurities contained in molten pig iron, and the second reaction zone 6b may be used as a reaction zone for removing silicon and phosphorus as impurities contained in molten pig iron.
In the apparatus of the third embodiment, as described above, for example, the granular flux for removing silicon as one of impurities is blown, in the first reaction zone 6a, through the two first lances 8a by means of the carrier gas into molten pig iron 5, and then, the granular flux for removing phosphorus as one of impurities is blown, also in the first reaction zone 6a, through the two second lances 8b by means of carrier gas into molten pig iron 5. Molten slag 7b mainly comprising P₂0₅ has a high basicity, which molten slag 7b has been produced through combination of the granular flux for removing phosphorus, blown through the two second lances 8b by means of the carrier gas, with phosphorus contained in molten pig iron. Molten slag 7a mainly comprising Sio₂ and having a low basicity, which has been produced through combination of the granular flux for removing silicon, blown through the two first lances 8a by means of the carrier gas, with silicon contained in molten pig iron, is mixed with the above-mentioned molten slag 7b mainly comprising P₂0₅ and having a high basicity, to increase its basicity. Molten slag 7a of which basicity has thus been increased, is improved in fluidity, and is smoothly discharged from the first reaction zone 6a through the first branch slag runner 9a together with molten slag 7b. Furthermore, the reaction of the granular flux for removing silicon, blown from the first lances 8a, with silicon contained in molten pig iron becomes more active under the effect of molten slag 7b mainly comprising P₂0₅ and having a high basicity. It is consequently possible to efficiently remove silicon from molten pig iron 5 flowing through the hot-metal runner 1.
Fig. 7 is a schematic plan view illustrating a fourth embodiment of the apparatus of the present invention, and Fig. 8 is a sectional view illustrating the apparatus of the fourth embodiment of the present invention cut along the line D-D in Fig. 7. As shown in Figs. 7 and 8, in the apparatus of the fourth embodiment, a first partition 4a, a second partition 4b and a third partition 4c are provided in the hot-metal runner 1 at prescribed intervals therebetween at right angles to the flowing direction of molten pig iron 5 in the hot-metal runner 1 in the downstream of the skimmer 3 relative to the flowing direction of molten pig iron in the hot-metal runner 1 between the opposite side walls lb and lc of the hot-metal runner 1. The hot-metal runner 1 is divided by these three partitions 4a, 4b and 4c, from the upstream toward the downstream thereof, into a first reaction zone 6a, a second reaction zone 6b and a third reaction zone 6c.
The first reaction zone 6a is a reaction zone for removing silicon as one of impurities contained in molten pig iron, the second reaction zone 6b is a reaction zone for removing phosphorus as one of impurities contained in molten pig iron, and the third reaction zone 6c is a reaction zone for removing sulfur as one of impurities contained in molten pig iron. The lower end of each of the first partition 4a, the second partition 4b and the third partition 4c is immersed into molten pig iron 5 flowing through the hot-metal runner 1, and is spaced apart from the bottom la of the hot-metal runner 1 by a distance sufficient to allow molten pig iron 5 to pass through.
Above the first reaction zone 6a, two first lances 8a for blowing, by means of a carrier gas, a granular flux for removing silicon as one of impurities contained in molten pig iron into molten pig iron 5 flowing through the first reaction zone 6a, are substantially vertically arranged so as to pass through a cover 10 covering the first reaction zone 6a. Above the second reaction zone 6b, two second lances 8b for blowing, by means of a carrier gas, a granular flux for removing phosphorus as one of impurities contained in molten pig iron into molten pig iron 5 flowing through the second reaction zone 6b, are substantially vertically arranged so as to pass through the cover 10 also covering the second reaction zone 6b. Above the third reaction zone 6c, two third lances 8c for blowing, by means of carrier -gas, a granular flux for removing sulfur as one of impurities contained in molten pig iron into molten pig iron 5 flowing through the third reaction zone 6c, are substantially vertically arranged so as to pass through the cover 10 also covering the third reaction zone 6c.
The lowermost end of each of the first lances 8a, the second lances 8b and the third lances 8c is spaced apart from the surface of molten pig iron 5 by a prescribed distance. A first branch slag runner 9a is provided in the first reaction zone 6a, a second branch slag runner 9b is provided in the second reaction zone 6b, and a third branch slag runner 9c is provided in the third reaction zone 6c. The downstream end of each of the first branch slag runner 9a, the second branch slag runner 9b and the third branch slag runner 9c communicates with the slag runner 2.
Molten blast furnace slag 7 floating on the surface of molten pig iron 5 which is tapped from a blast furnace not shown and flows through the hot-metal runner 1, is dammed up by the skimmer 3, separated from molten pig iron, and discharged through the slag runner 2. Molten pig iron 5 from which molten blast furnace slag 7 has thus been separated by the skimmer 3 flows through the first reaction zone 6a, the second reaction zone 6b and the third reaction zone 6c.
A granular flux for removing silicon as one of impurities contained in molten pig iron is blown, in the first reaction zone 6a, through the two first lances 8a by means of a carrier gas into molten pig iron 5 flowing through the first reaction zone 6a. As a result, molten slag 7a is produced in the first reaction zone 6a through combination of the granular flux blown from the two first lances 8a into molten pig iron 5 flowing through the first reaction zone 6a with silicon contained in molten pig iron, and silicon is thus removed from molten pig iron 5. Molten slag 7a thus produced is dammed up by the first partition 4a, separated from molten pig iron 5, and discharged from the first reaction zone 6a through the first branch slag runner 9a.
A granular flux for removing phosphorus as one of' impurities contained in molten pig iron is blown, in the second reaction zone 6b, through the two second lances 8b by means of a carrier gas into molten pig iron 5 from which silicon has been removed and molten slag 7a has been separated by the first partition 4a as described above. As a result, molten slag 7b is produced in the second reaction zone 6b through combination of the granular flux blown from the two second lances 8b into molten pig iron 5 flowing through the second reaction zone 6b with phosphorus contained in molten pig iron, and phosphorus is thus removed from molten pig iron 5. Molten slag 7b thus produced is dammed up by the second partition 4b, separated from molten pig iron 5, and discharged from the second reaction zone 6b through the second branch slag runner 9b.
A granular flux for removing sulfur as one of impurities contained in molten pig iron is blown, in the third reaction zone 6c, through the two third lances 8c by means of a carrier gas into molten pig iron 5 from which phosphorus has been removed and molten slag 7b has been separated by the second partition 4b, as described above. As a result, molten slag 7c is produced in the third reaction zone 6c through combination of the granular flux blown from the two third lances 8c into molten pig iron 5 flowing through the third reaction zone 6c with sulfur contained in molten pig iron, and sulfur is thus removed from molten pig iron 5. Molten slag 7c thus produced is dammed up by the third partition 4c, separated from molten pig iron 5, and discharged from the third reaction zone 6c through the third branch slag runner 9c.
Molten pig iron 5 from which silicon has been removed in the first reaction zone 6a, then phosphorus has been removed in the second reaction zone 6b, and then, sulfur has been removed in the third reaction zone 6c, is directed through the hot-meral runner 1 into the hot-metal ladle not shown. On the other hand, molten slags 7a, 7b and 7c discharged respectively from the first reaction zone 6a, the second reaction zone 6b, and the third reaction zone 6c, respectively through the first branch slag runner 9a, the second branch slag runner 9b, and the third branch slag runner 9c, are directed to a slag runner 2, and further directed, together with molten blast furnace slag 7, through the slag runner 2 to a slag ladle or a slag disposal equipment not shown.
In the apparatus of the fourth embodiment, the three reaction zones comprise, as described above, the first reaction zone 6a for removing silicon as one of impurities contained in molten pig iron, the second reaction zone 6b for removing phosphorus as one of impurities contained in molten pig iron, and the third reaction zone 6c for removing sulfur as one of impurities contained in molten pig iron. These reaction zones may also be used as follows:

(1) The first reaction zone 6a is a reaction zone for removing silicon as one of impurities contained in molten pig iron, the second reaction zone 6b is a reaction zone for removing sulfur as one of impurities contained in molten pig iron, and the third reaction zone 6c is a reaction zone for removing phosphorus as one of impurities contained in molten pig iron.
(2) The first reaction zone 6a is a reaction zone for removing sulfur as one of impurities contained in molten pig iron, the second reaction zone 6b is a reaction zone for removing silicon as one of impurities contained in molten pig iron, and the third reaction zone 6c is a reaction zone for removing phosphorus as one of impurities contained in molten pig iron.

In the apparatus of the fourth embodiment, as described above, silicon is removed from molten pig iron 5 in the first reaction zone 6a after molten blast furnace slag 7 floating on the surface of molten pig iron flowing through the hot-metal runner 1 has been dammed up by the skimmer 3, separated from molten pig iron 5, and discharged through the slag runner 2. Then, phosphorus is removed from molten pig iron in the second reaction zone 6b, and then, sulfur is removed from molten pig iron in the third reaction zone 6c. When, for example, a granular flux for removing silicon (such as granular mill scale) is blown into molten pig iron from which molten blast furnace slag 7 is not yet separated, sulfur compound (CaS) contained in molten blast furnace slag 7 reacts with iron oxide (FeO) contained in the above-mentioned granular flux to form sulfur (S), and sulfur thus formed may return into molten pig iron. According to the apparatus of the fourth embodiment, however, since the granular flux for removing silicon is blown in the first reaction zone 6a into molten pig iron after separation of molten blast furnace slag 7, as described above, the above-mentioned problem is never posed.
Fig. 9 is a schematic plan view illustrating a fifth embodiment of the apparatus of the present invention. The apparatus of the fifth embodiment is identical with those of the above-mentioned embodiments except that the downstream end of each of the branch slag runners 9a, 9b, 9c is independent of the slag runner 2. Fig. 9 illustrates the apparatus of the fourth embodiment described above with reference to Figs. 7 and 8, of which the downstream end of each of the branch slag runners 9a, 9b, 9c is made independent of the slag runner 2. As shown in Fig. 9, slag ladles 12a, 12b and 12c for receiving molten slags discharged through the first branch slag runner 9a, the second branch slag runner 9b and the third branch slag runner 9c are arranged at respective ends of these branch slag runners. Therefore, molten slags discharged from individual reaction zones 6a, 6b, 6c are never mixed with molten blast furnace slag discharged from the hot-metal runner 1 through the slag runner 2. As a result, when manufacturing blast furnace slag as the by-Product by cooling and solidifying molten blast furnace slag, it is possible to prevent the above-mentioned mixture of molten slags from causing decrease in quality of the blast furnace slag.
Fig. 10 is a schematic plan view illustrating a sixth embodiment of the apparatus of the present invention. The apparatus of the sixth embodiment is identical with those of the above-mentioned embodiments except that a hot-metal separator 13 for separating molten pig iron entangled into molten slag produced in each of the reaction zones 6a, 6b, 6c from these molten slag is provided in the middle of the branch slag runners 9a, 9b, 9c. Fig. 10 illustrates the apparatus of the third embodiment described above with reference to Figs. 5 and 6, which is provided with the above-mentioned hot-metal separator 13. As shown in Fig. 10, the hot-metal separator 13 is provided in the middle of the first branch slag runner 9a for discharging molten slag produced in the first reaction zone 6a therefrom. The second branch slag runner 9b for discharging molten slag produced in the second reaction zone 6b therefrom is also connected to the hot-metal separator 13. The hot-metal separator 13 is connected to the second reaction zone 6b through a branch hot-metal runner 15 for returning molten pig iron separated by the hot-metal separator 13 into the downstream of the second reaction zone 6b. A skimmer 14 is provided at the upstream end of the branch hot-metal runner 15. The lower end of the skimmer is spaced apart by a prescribed distance from the bottom of the branch hot-metal runner 15 so as to allow molten pig iron separated from molten slags to pass through.
Therefore, molten slag discharged from the first reaction zone 6a, which is the mixture of molten slag produced through combination of the granular flux for removing silicon with silicon contained in molten pig iron, on the one hand, and molten slag produced through combination of the granular flux for removing phosphorus with phosphorus contained in molten pig iron, on the other hand, is directed to the hot-metal separator 13 through the first branch slag runner 9a. Molten slag discharged from the second reaction zone 6b, which is produced through combination of the granular flux for removing sulfur with sulfur contained in molten pig iron, is also directed to the hot-metal separator 13 through the second branch slag runner 9b. Molten pig iron entangled into these molten slags is separated from molten slags through precipitation in the hot-metal separator 13. Molten pig iron thus separated from molten slags is returned from the hot-metal separator 13 through the branch hot-metal runner 15 to the second reaction zone 6b. Molten pig iron thus returned joins molten pig iron from the first reaction zone 6a in the second reaction zone 6b, and sulfur contained in molten pig iron is removed. On the other hand, molten slags from which molten pig iron has been separated are directed from the hot-metal separator 13 through the downstream portion 9a' of the first branch slag runner 9a to the slag runner 2, and then further directed, together with molten blast furnace slag, through the slag runner 2 to a slag ladle or a slag disposal equipment not shown. According to the apparatus of the sixth embodiment, therefore, it is possible to recover molten pig iron entangled in molten slags which are produced in the reaction zones 6a, 6b, and discharged through the branch slag runners 9a, 9b.
In the apparatus of the present invention, the number of the reaction zones formed by dividing the hot-metal runner 1 is not limited to two or three as described above, but may be four or more, in response to the number of impurities to be removed from molten pig iron tapped from the blast furnace. By doing so, it is possible to remove impurities other than silicon, phosphorus and sulfur contained in molten pig iron tapped from the blast furnace.
According to the apparatus of the present invention, as described above in detail, it is possible to simultaneously and efficiently remove at least two of such impurities contained in molten pig iron as silicon, phosphorus and sulfur in the middle of the hot-metal runner for directing molten pig iron tapped from the blast furnace into the hot-metal ladle, without the risk of damaging the bottom of the hot-metal runner, thus providing industrially useful effects.

Claims

1. An apparatus for removing impurities contained in molten pig iron tapped from a blast furnace, which comprises:

a hot-metal runner for directing molten pig iron tapped from a blast furnace into a hot-metal ladle;

a skimmer, provided in the middle of said hot-metal runner, for damming up molten blast furnace slag floating on the surface of molten pig iron flowing through said hot-metal runner to separate molten blast furnace slag from molten pig iron, the lower end of said skimmer being immersed into molten pig iron flowing through said hot-metal runner and spaced apart from the bottom of said hot-metal runner by a distance sufficient to allow molten pig iron to pass through;

a slag runner, provided in the upstream of said skimmer relative to the flowing direction of molten pig iron in said hot-metal runner, for discharging molten blast furnace slag separated from molten pig iron by means of said skimmer; and

at least one lance, arranged substantially vertically above said hot-metal runner, for blowing, by means of a carrier gas, a granular flux for removing impurities contained in molten pig iron tapped from said blast furnace into molten pig iron flowing through said hot-metal runner, the lowermost end of said at least one lance being spaced apart by a prescribed distance from the surface of molten pig iron flowing through said hot-metal runner;

thereby causing combination of impurities contained in molten pig iron with siad granular flux blown from said at least one lance into molten pig iron flowing through said hot-metal runner to form molten slag to remove said impurities;

characterized in that:

at least two partitions (4a, 4b, 4c) are provided in said hot-metal runner (1) at prescribed intervals therebetween at right angles to the flowing direction of molten pig iron in said hot-metal runner (1) in the downstream of said skimmer (3) relative to the flowing direction of molten pig iron in said hot-metal runner (1), to divide said hot-metal runner (1) into at least two reaction zones (6a, 6b, 6c), the lower end of each of said at least two partitions (4a, 4b, 4c) being immersed into molten pig iron flowing through said hot-metal runner (1) and being spaced apart from the bottom (la) of said hot-metal runner (1) by a distance sufficient to allow molten pig iron to pass through;

said at least one lance (8a, 8b, 8c) is arranged for each of said at least two reaction zones (6a, 6b, 6c);

each of a plurality of branch slag runners (9a, 9b, 9c) is provided for each of said at least two reaction zones (6a, 6b, 6c);

whereby molten slag produced in each of said at least two reaction zones (6a, 6b, 6c) through combination of said granular flux blown from said at least one lance (8a, 8b, 8c) into molten pig iron flowing sequentially through said at least two reaction zones (6a, 6b, 6c) with impurities contained in molten pig iron, is dammed up by each of said at least two partitions (4a, 4b, 4c), separated from molten pig iron, and discharged through each of said plurality of branch slag runners (9a, 9b, 9c) from each of said at least two reaction zones (6a, 6b, 6c).

2. The apparatus as claimed in in Claim 1, characterized in that:

said at least two reaction zones comprise, from the upstream toward the downstream of said hot-metal runner (1), a first reaction zone (6a) and a second reaction zone (6b), said first reaction zone (6a) being a reaction zone for removing silicon as one of said impurities, and said second reaction zone (6b) being a reaction zone for removing phosphorus or sulfur as one of said impurities.

3. The apparatus as claimed in Claim 1, characterized in that:

said at least two reaction zones comprise, from the upstream toward the downstream of said hot-metal runner (1), a first reaction zone (6a) and a second reaction zone (6b), said first reaction zone (6a) being a reaction zone for removing sulfur as one of said impurities, and said second reaction zone (6b) being a reaction zone for removing silicon as one of said impurities.

4. The apparatus as claimed in Claim 1, characterized in that:

said at least two reaction zones comprise two reaction zones (6a, 6b), one of said two reaction zones (6a, 6b) being a reaction zone for removing phosphorus as one of said impurities, and the other of said two reaction zones (6a, 6b) being a reaction zone for removing sulfur as one of said impurities.

5. The apparatus as claimed in Claim 1, characterized in that:

said at least two reaction zones comprise two reaction zones (6a, 6b), one of said two reaction zones (6a, 6b) being a reaction zone for removing phosphorus as one of said impurities, and the other of said two reaction zones (6a, 6b) being a reaction zone for removing sulfur as one of said impurities, and said lance (8c) for blowing, by means of a carrier gas, a granular flux for removing silicon as one of said impurities is arranged above said hot-metal runner (1) in the upstream of said skimmer (3) relative to the flowing direction of molten pig iron in said hot-metal runner (1).

6. The apparatus as claimed in Claim 1, characterized in that:

said at least two reaction zones comprise two reaction zones (6a, 6b), one of said two reaction zones (6a, 6b) being a reaction zone for removing silicon and phosphorus as said impurities, the other of said two reaction zones (6a, 6b) being a reaction zone for removing sulfur as one of said impurities, and both said lance (8a) for blowing, by means of a carrier gas, a granular flux for removing silicon as one of said impurities and said lance (8b) for blowing, by means of a carrier gas, a granular flux for removing phosphorus as one of said impurities are arranged above said reaction zone for removing silicon and phosphorus as said impurities.

7. The apparatus as claimed in Claim 1, characterized in that:

said at least two reaction zones comprise, from the upstream toward the downstream of said hot-metal runner (1), a first reaction zone (6a), a second - reaction zone (6b) and a third reaction zone (6c), said first reaction zone (6a) being a reaction zone for removing silicon as one of said impurities, said second reaction zone (6b) being a reaction zone for removing phosphorus or sulfur as one of said impurities, and said third reaction zone (6c) being a reaction zone for removing sulfur or phosphorus as one of said impurities.

8. The apparatus as claimed in Claim 1, characterized in that:

said at least two reaction zones comprise, from the upstream toward the downstream of said hot-metal runner (1), a first reaction zone (6a), a second reaction zone (6b) and a third reaction zone (6c), said first reaction zone (6a) being a reaction zone for removing sulfur as one of said impurities, said second reaction zone (6b) being a reaction zone for removing silicon as one of said impurities, and said third reaction zone (6c) being a reaction zone for removing phosphorus as one of said impurities.

9. The apparatus as claimed in any one of Claims 1 to 8, characterized in that:

the downstream end of each of said plurality of branch slag runners (9a, 9b, 9c) provided for each of said at least two reaction zones (6a, 6b, 6c) is communicated with said slag runner (2).

10. The apparatus as claimed in any one of Claims 1 to 8, characterized in that:

the downstream end of each of said plurality of branch slag runners (9a, 9b, 9c) provided for each of said at least two reaction zones (6a, 6b, 6c) is independent of said slag runner (2).

11. The apparatus as claimed in any one of Claims 1 to 8, characterized in that:

a hot-metal separator (13) for separating molten pig iron entangled into molten slag which is produced in each of said at least two reaction zones (6a, 6b, 6c) and flows through each of said plurality of branch slag runners (9a, 9b, 9c) is provided in the middle of said plurality of branch slag runners (9a, 9b, 9c) respectively provided for said at least two reaction zones (6a, 6b, 6c).