EP0168009B1 - Ausstattungselement für eine Armbanduhr - Google Patents
Ausstattungselement für eine Armbanduhr Download PDFInfo
- Publication number
- EP0168009B1 EP0168009B1 EP19850108437 EP85108437A EP0168009B1 EP 0168009 B1 EP0168009 B1 EP 0168009B1 EP 19850108437 EP19850108437 EP 19850108437 EP 85108437 A EP85108437 A EP 85108437A EP 0168009 B1 EP0168009 B1 EP 0168009B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- particles
- element according
- exterior element
- exterior
- watch
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 210000000707 wrist Anatomy 0.000 title claims abstract 3
- 239000002245 particle Substances 0.000 claims abstract description 41
- 239000000463 material Substances 0.000 claims abstract description 14
- 239000011230 binding agent Substances 0.000 claims abstract description 12
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 11
- 239000011707 mineral Substances 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 8
- 239000002131 composite material Substances 0.000 claims abstract description 7
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims abstract description 3
- 229920001519 homopolymer Polymers 0.000 claims abstract description 3
- 239000003086 colorant Substances 0.000 claims description 8
- 238000005498 polishing Methods 0.000 claims description 3
- 239000004033 plastic Substances 0.000 description 13
- 229920003023 plastic Polymers 0.000 description 13
- 239000011347 resin Substances 0.000 description 13
- 229920005989 resin Polymers 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 238000002347 injection Methods 0.000 description 5
- 239000007924 injection Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 150000001247 metal acetylides Chemical class 0.000 description 4
- 150000004767 nitrides Chemical class 0.000 description 4
- 238000005245 sintering Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 3
- 229920004943 Delrin® Polymers 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 238000004873 anchoring Methods 0.000 description 2
- 238000005452 bending Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- -1 oxides Chemical class 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910001347 Stellite Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- AHICWQREWHDHHF-UHFFFAOYSA-N chromium;cobalt;iron;manganese;methane;molybdenum;nickel;silicon;tungsten Chemical compound C.[Si].[Cr].[Mn].[Fe].[Co].[Ni].[Mo].[W] AHICWQREWHDHHF-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- COEZWFYORILMOM-UHFFFAOYSA-N sodium 4-[(2,4-dihydroxyphenyl)diazenyl]benzenesulfonic acid Chemical compound [Na+].OC1=CC(O)=CC=C1N=NC1=CC=C(S(O)(=O)=O)C=C1 COEZWFYORILMOM-UHFFFAOYSA-N 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44C—PERSONAL ADORNMENTS, e.g. JEWELLERY; COINS
- A44C5/00—Bracelets; Wrist-watch straps; Fastenings for bracelets or wrist-watch straps
-
- G—PHYSICS
- G04—HOROLOGY
- G04B—MECHANICALLY-DRIVEN CLOCKS OR WATCHES; MECHANICAL PARTS OF CLOCKS OR WATCHES IN GENERAL; TIME PIECES USING THE POSITION OF THE SUN, MOON OR STARS
- G04B37/00—Cases
- G04B37/22—Materials or processes of manufacturing pocket watch or wrist watch cases
- G04B37/225—Non-metallic cases
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49579—Watch or clock making
- Y10T29/49584—Watch or clock making having case, cover, or back
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/8305—Miscellaneous [e.g., treated surfaces, etc.]
Definitions
- the present invention relates to a clothing element for a wristwatch, such as a box or a bracelet, at least part of which is made of a composite material.
- the required mechanical properties are in fact only critical on the surface and in particular on surfaces exposed to attacks due to lines and shocks.
- the inclusion of microscopic particles has the effect of modifying the elastic properties of the plastic, especially with respect to stresses such as shear, compression, traction, bending, etc.
- these fillers have a less pronounced effect with respect to the surface hardness due to their microscopic size. Indeed, a sharp element can scratch the surface of such a charged plastic while passing between the particles because of their size. It therefore turns out that effective protection of the surface of a plastic part against rays does not only depend on the hardness of the particles used as filler and on the proportion of these particles.
- too high a proportion of microscopic fillers can have the consequence of making the resin more fragile to impact, which is obviously not desirable in the case of a watch case which notably includes edges capable of being chipped. if the box material is brittle.
- the object of the present invention is to at least partially remedy the aforementioned drawbacks.
- At least part of the clothing element is made of a material which comprises an organic binder and macroscopic particles of mineral substances contained in the binder.
- These particles are exposed on at least a visible surface portion of the element and occupy 60% to 95% of this portion.
- Such an element has the advantage of having excellent protection against lines and shocks in its surface thus formed, due to the macroscopic dimension of the inclusions and their sufficient density, without making the composite excessively fragile. It is thus possible to produce a watch case or a bracelet having inalterability properties close to those of boxes or bracelets covered with sintered carbides or nitrides, by an injection molding process.
- elements produced according to the invention have a new aesthetic appearance, in particular after polishing the surface which brings out the colors of the inclusions different from that of plastic, for example. Indeed, the inclusions of nitrides, oxides, carbides, etc., can have very diverse colors.
- any mineral material can be combined with resin, namely carbides, borides, nitrides, carbonitrides, oxides, etc., but also sintered agglomerates such as TiC bound with Ni, elements with a monocrystalline network such as ⁇ -A1 2 0 3 (corundum) or with an amorphous structure such as glass, particles of stellite or hard steel of the same type as those used for sintering.
- resin namely carbides, borides, nitrides, carbonitrides, oxides, etc.
- sintered agglomerates such as TiC bound with Ni
- elements with a monocrystalline network such as ⁇ -A1 2 0 3 (corundum) or with an amorphous structure such as glass, particles of stellite or hard steel of the same type as those used for sintering.
- the choice of resin is relatively limited.
- a technical plastic is chosen as the resin, in particular an acetal homopolymer resin, such as that sold by Du Pont under the trade name "Delrin” (registered trademark), of the 100 ST type, which has the advantage of having resistance. Izod impact (with notch) of 900 J / m, that is to say 7 to 30 times greater than that of the other "Delrin” which constitute one of the best ranges of technical plastics.
- This material is moldable by hot injection.
- Other materials such as polyamide 12 or polycarbonate can also be used.
- the watch element such as the middle part, the back, or the bezel, or even the back-middle part of a case, or the bracelet is placed in the mold cavity intended for molding the watch element, a charge of mineral particles which can comprise a mixture of the various abovementioned substances, but also consist of only one of these substances, depending on the decorative effect sought.
- the particle size can also be chosen to be uniform or, on the contrary, as diverse as possible.
- the smallest particle size is of the order of 0.1 mm; it can go up to several millimeters. When the particles are of different colors, one can for example choose the size according to the color.
- the proportion of particles in the volume can be variable, but it is generally made so that there is on the surface of the watch element intended to form a visible surface portion, and particularly the parts most exposed to the wear, as large a proportion as possible of mineral inclusions. Then, the mold is closed and the resin is injected under pressure. The element thus produced then has a mosaic structure formed of hard particles and resin which keeps these associated with each other. These particles occupy most of this portion. After cooling and demolding, the surfaces of the molded element intended to form the visible parts from the outside are advantageously polished with a diamond wheel to bring the inclusion particles perfectly flush with the surface of the resin. The latter tends to withdraw during cooling. This grinding also makes it possible to highlight the different colors of the particles which are flush with the surface of the element, since, to promote their anchoring in the resin, they are preferably used in the raw state. These particles can advantageously come from manufacturing waste, but they can also be produced specially.
- the charge of mineral material in the form of particles larger than or equal to 0.1 mm can be incorporated into the resin before its injection into the mold.
- this technique poses abrasion problems when the resin loaded with particles moves in the injection conduits.
- a third technique consists in including the mineral particles only at the surface and in particular on the visible surfaces.
- the resin is injection molded without filler.
- the particles are included as desired on the portions of desired surfaces, in particular the visible surfaces, by heating the particles to a temperature sufficient to locally soften the resin and allow their penetration.
- This technique offers in particular the advantage of being able to control the arrangement of the particles according to their dimensions and / or their colors, with a view to specially protecting certain parts of the surface, in particular the edges and / or creating decorative patterns which do not are not left to chance as in the variants described above.
- the portion of the visible surface and therefore exposed to attack of all kinds, covered by hard particles must be greater than the half the surface.
- it will be between 60% and 95%, and preferably around 85%.
- the hardness of the particles will generally be chosen at 1400 Hv. Some of the particles may even be made of transparent substances depending on the desired aesthetic appearance.
- the organic binder and the macroscopic particles have a very high wettability in order to ensure maximum fluidity of the binder and perfect anchoring of the particles.
- Processes are known in which particular elements are added to the organic binder to make it wetting.
- the particles they will be made wetting by a thorough cleaning which will rid them of all fats or other impurities.
- this treatment will prevent accidental formation of bubbles which could give rise to tears.
- the binder is an adhesive ensuring adhesion between the particles.
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Adornments (AREA)
- Powder Metallurgy (AREA)
- Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Physical Vapour Deposition (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT85108437T ATE34470T1 (de) | 1984-07-12 | 1985-07-08 | Ausstattungselement fuer eine armbanduhr. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH3382/84 | 1984-07-12 | ||
CH338284A CH658160GA3 (de) | 1984-07-12 | 1984-07-12 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0168009A1 EP0168009A1 (de) | 1986-01-15 |
EP0168009B1 true EP0168009B1 (de) | 1988-05-18 |
Family
ID=4254750
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19850108437 Expired EP0168009B1 (de) | 1984-07-12 | 1985-07-08 | Ausstattungselement für eine Armbanduhr |
Country Status (8)
Country | Link |
---|---|
US (1) | US4730288A (de) |
EP (1) | EP0168009B1 (de) |
JP (1) | JPS6157633A (de) |
KR (1) | KR880000223B1 (de) |
AT (1) | ATE34470T1 (de) |
CH (1) | CH658160GA3 (de) |
DE (1) | DE3562829D1 (de) |
HK (1) | HK56090A (de) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH686473B5 (fr) * | 1993-03-18 | 1996-10-15 | Boninchi Sa | Couronne à vis pour pièce d'horlogerie. |
GB9908498D0 (en) * | 1999-04-15 | 1999-06-09 | Thayer Andrew R | Improvements in or relating to jewellery or the like |
TW533105B (en) * | 1999-10-20 | 2003-05-21 | Injex Corp | Method of producing watchband parts |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3841848A (en) * | 1970-01-30 | 1974-10-15 | Suwa Seikosha Kk | HARD WATCH CASE COMPRISING TiN, T, AND AT LEAST ONE OF Mn, Al AND V |
GB1414864A (en) * | 1972-03-27 | 1975-11-19 | Suwa Seikosha Kk | Method of producing an externally visible part of a watch |
JPS5068163A (de) * | 1973-10-18 | 1975-06-07 | ||
JPS568898U (de) * | 1979-07-02 | 1981-01-26 | ||
US4495254A (en) * | 1981-05-18 | 1985-01-22 | Westinghouse Electric Corp. | Protectively-coated gold-plated article of jewelry or wristwatch component |
JPS5880586A (ja) * | 1981-11-10 | 1983-05-14 | Seiko Epson Corp | 時計用プラスチツクケ−スの製造方法 |
-
1984
- 1984-07-12 CH CH338284A patent/CH658160GA3/fr unknown
-
1985
- 1985-07-02 KR KR1019850004746A patent/KR880000223B1/ko not_active IP Right Cessation
- 1985-07-08 EP EP19850108437 patent/EP0168009B1/de not_active Expired
- 1985-07-08 AT AT85108437T patent/ATE34470T1/de not_active IP Right Cessation
- 1985-07-08 DE DE8585108437T patent/DE3562829D1/de not_active Expired
- 1985-07-11 JP JP60151466A patent/JPS6157633A/ja active Pending
-
1987
- 1987-01-08 US US07/004,788 patent/US4730288A/en not_active Expired - Fee Related
-
1990
- 1990-07-26 HK HK56090A patent/HK56090A/xx unknown
Also Published As
Publication number | Publication date |
---|---|
DE3562829D1 (en) | 1988-06-23 |
HK56090A (en) | 1990-08-03 |
ATE34470T1 (de) | 1988-06-15 |
EP0168009A1 (de) | 1986-01-15 |
KR880000223B1 (ko) | 1988-03-15 |
US4730288A (en) | 1988-03-08 |
KR860000840A (ko) | 1986-02-20 |
CH658160GA3 (de) | 1986-10-31 |
JPS6157633A (ja) | 1986-03-24 |
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Legal Events
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