EP0155254B1 - Lichtbogenplasmabrenner - Google Patents
Lichtbogenplasmabrenner Download PDFInfo
- Publication number
- EP0155254B1 EP0155254B1 EP85870025A EP85870025A EP0155254B1 EP 0155254 B1 EP0155254 B1 EP 0155254B1 EP 85870025 A EP85870025 A EP 85870025A EP 85870025 A EP85870025 A EP 85870025A EP 0155254 B1 EP0155254 B1 EP 0155254B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- anode
- intermediate electrode
- current source
- plasma torch
- plasma
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Images
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
- H05H1/3421—Transferred arc or pilot arc mode
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
- H05H1/3452—Supplementary electrodes between cathode and anode, e.g. cascade
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
- H05H1/3468—Vortex generators
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
- H05H1/38—Guiding or centering of electrodes
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/42—Plasma torches using an arc with provisions for introducing materials into the plasma, e.g. powder, liquid
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05H—PLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
- H05H1/00—Generating plasma; Handling plasma
- H05H1/24—Generating plasma
- H05H1/26—Plasma torches
- H05H1/32—Plasma torches using an arc
- H05H1/34—Details, e.g. electrodes, nozzles
- H05H1/3436—Hollow cathodes with internal coolant flow
Definitions
- the present invention relates to an electric arc plasma torch.
- Plasma torches also called torches or plasma burners, are devices well known per se, used to produce a gas jet in the plasma state.
- a plasma is an ionized gas which contains at least 10 15 charged corpuscles per cubic meter, and on average, very substantially as many electrons as positive ions.
- the arc In plasma arc torches, the arc is spouted between two electrodes between which a gas flows. The gas particles are ionized by the high energy of the arc and the gas turns into a plasma.
- Plasma electric arc torches can be further divided into two categories, depending on the type of cathode used, i.e. the hot cathode and the cold cathode.
- Called hot cathode a cathode brought to a sufficiently high temperature so that, by thermionic effect, it emits a number of electrons ensuring practically the arc current. Due to the high level of temperature necessary to carry out an electronic emission corresponding to an arc current intensity sufficient to reach the desired power and temperature, namely approximately 3000 ° C., the number of materials which can be used to manufacture such a cathode is very limited. Currently, practically only tungsten or some of its fittings are used. As a result, hot cathode arc plasma torches can only work with gases that are chemically inert to tungsten, such as hydrogen, nitrogen and rare gases (argon, xenon, etc ).
- the second type of plasma arc torch cold cathode torches
- a copper cathode which is strongly cooled to prevent it from reaching the thermionic emission temperature.
- aerodynamic or magnetic means are often used, or both simultaneously, to move the foot of the arc on the cathode at high speed, in order to limit the erosion of the latter.
- Cold cathode torches allow almost all gases to be used.
- the lifespan of these cathodes remains limited to a few hundred hours in the best cases currently known. These lifetimes are much shorter on the one hand, than those of hot cathodes, and on the other hand than those of anodes, which commonly reach one to a few thousand hours.
- US Pat. No. 4,002,466 discloses a plasma torch which can be used for the reduction of metal oxides, in particular for the direct reduction of iron ores.
- This torch of the prior art comprises a tungsten cathode and an anode, connected in a conventional manner respectively to the negative and positive terminals of an electric current source. Between the cathode and the anode is disposed an electrically insulated nozzle, intended in particular to stabilize the arc and to prevent the return of carbonaceous gas from the anode to the cathode.
- a torch for working with an arc comprising a hot cathode, an anode and an intermediate electrode permanently connected to the terminals of an electric current source.
- the intermediate electrode is the seat of a permanent electric arc, which adversely influences its lifespan.
- the possibility of using two current sources is also suggested, but the second source is intended to energize the workpiece, and not the intermediate electrode as provided by the present invention.
- the present invention relates to an arc plasma torch which combines the aforementioned advantages of hot and cold cathodes, without having the disadvantages, and which makes it possible to facilitate and improve the procedure for establishing the electric arc between the cathode. and the anode.
- the plasma torch may include means for connecting said hot cathode and said intermediate electrode to the terminals of a high-frequency current source having a voltage greater than the disruptive voltage between the hot cathode and the intermediate electrode , as well as current cut-off means for disconnecting said high frequency current source.
- the plasma torch comprises two chambers, separated by the ignition electrode and placed in communication with each other by an orifice formed in said ignition electrode, one of the two chambers, called cathode chamber, being equipped with the hot cathode (a) and means (d) for introducing an inert gas, and the other chamber, called the anode chamber, being formed in part by the anode (c) and being equipped with means (e) for introducing any plasma gas.
- the means for introducing gas into at least one of said chambers are arranged so as to give the gas a movement, preferably helical in said chamber.
- a particularly interesting variant of the present invention relates to a plasma torch allowing precisely the production of gaseous carbon from a solid fuel.
- this plasma torch includes an ignition electrode disposed between a hot cathode and an anode; it is further characterized in that it has at least one fuel supply duct, which opens into the space between the ignition electrode and the anode, and preferably immediately upstream of the section d entrance to the anode chamber.
- this duct is preferably parallel to the longitudinal axis of the plasma torch.
- its outlet is oriented so that its axis intersects the longitudinal axis of the anode downstream from the upstream end of the anode.
- the speed with which the fuel enters the anode chamber is adjusted so that it is not centrifuged by the plasma gas and that it does not obstruct the feed passages of the latter. This speed is adjusted as a function of the fuel and plasma gas flow rates. In no case, however, can the fuel speed be less than 5 m / s and that of the plasma gas 50 m / s.
- the plasma torch has several fuel supply conduits, these are advantageously uniformly distributed around the longitudinal axis of the torch, so as to ensure a balanced supply of fuel.
- the cathode (3) for example made of tungsten, is housed in a wall of the enclosure (1), preferably opposite the anode (2).
- These two electrodes (2) and (3) are respectively connected to the positive and negative poles of a rectified direct current source.
- the enclosure (1) is also provided with a passage (4) for introducing the plasma gas and the anode is pierced with an orifice allowing the plasma jet (5) to be ejected.
- the cathode can be made of tungsten, that is to say “hot”; it then requires the use of a chemically inert gas with respect to this element. It can also be “cold”, that is to say in cooled copper, with the drawbacks mentioned above with regard to the resistance to wear by erosion.
- FIG. 2 shows a plasma torch according to the invention, which does not have these drawbacks.
- This torch consists of an open enclosure (1) made of insulating material, extended by a copper anode (2).
- the whole is divided into two rooms (I) and (II) separated by an ignition electrode (6) disposed in the insulating enclosure, at a certain distance from the end of the latter.
- the chamber (1) called the cathode chamber, is equipped with a hot cathode (3) and provided with an orifice (8) for introducing a gas which is chemically inert with respect to tungsten.
- the chamber (II) or anode chamber is provided with at least one passage (4) for introducing the plasma gas, which can be any gas.
- This passage (4) is preferably formed in the part of the chamber (11) made of insulating material; it is oriented so as to give the gas a helical movement in the anode chamber.
- the ignition electrode is surrounded by at least one channel, preferably central (7), allowing the two chambers (I) and (II) to communicate; this channel is advantageously profiled in the form of a divergence.
- the distance between the cathode (3) and the ignition electrode (6) is adjustable and between 0 and 5 mm, the distance 0 corresponding to the contact of the cathode with the ignition electrode. The adjustment of this distance is preferably carried out by displacement of the cathode (3) along its longitudinal axis, for example by means of a screw device.
- the anode (2) is connected to the positive pole of a first, so-called main, current source; the ignition electrode (6) is connected simultaneously to the positive pole of the main current source and to the positive pole of a second current source, called ignition, of lower power.
- the power of this source is at least 5 kW and is preferably around 10 kW; its no-load voltage depends on the nature of the cathode gas. For example, it is at least 50 V for argon, 100 V for nitrogen and 200 V for hydrogen.
- the cathode (3) is connected simultaneously to the negative poles of these two sources of current, main and ignition.
- a third source of very low power (at least 50 W), high voltage and high frequency, is connected between the cathode and the ignition electrode.
- the voltage of this third source is greater than the disruptive voltage between the cathode and the ignition electrode (4 kV) and its frequency is produced by an oscillating discharge from an oscillating circuit or by a Tesla transformer.
- the plasma torch of the invention operates as follows. We open the arrival of cathode gas and plasma gas. The second and third current sources are switched on simultaneously. Switching on the third current source breaks the resistance of the gas flowing between the cathode (3) and the ignition electrode (6), allowing the establishment of a sufficiently high ignition current (100 400 A ) between the cathode and the ignition electrode. This ignition current gives rise to a jet of low power plasma which gushes into the anode chamber through the channel (7) of the ignition electrode (6). As soon as this plasma jet is established, the third current source is disconnected. We connect the main current source. Thanks to the plasma jet previously established, an electric current from this main source flows between the cathode (3) and the anode (2). The ignition current source is then disconnected, so that only the main current source remains in circuit.
- the plasma torch illustrated in FIG. 3 is, in principle, in accordance with the diagram in FIG. 2 and the corresponding parts are designated by the same numerical references.
- the description relating to FIG. 2 is also applicable to the torch of FIG. 3 and it is therefore not necessary to repeat it.
- the torch of FIG. 3 has several additional characteristics which it is interesting to specify.
- the hot cathode (3) has a pointed head, so as to allow easy lighting of the plasma torch.
- the cathode (3) is furthermore provided with a cooling duct (9) supplied with water in (10).
- the copper ignition electrode (6) is also cooled by water, by a circuit which can be put in series with that of the cathode; the cooling water is discharged through the outlet (II).
- the downstream end of the ignition electrode (6) carries a crown in which are formed several passages (4) in the form of conduits or channels, for the introduction of the plasma gas. These passages (4) are uniformly distributed in the crown, their outlet orifices, in the inner surface of the crown, are arranged very close to each other, and are preferably contiguous, so that the plasma gas forms a continuous jet over the entire inner periphery of the crown.
- passages (4) are also oriented substantially tangentially to the inner surface of the crown, so that the outgoing plasma gas is driven in a helical movement in the anode chamber (II).
- the speed of the plasma gas must be at least 50 m / s at the entrance to the anode chamber.
- the anode (2) is provided with a spiral peripheral cooling circuit, consisting of helical fins (12) capped by a tube (13); the cooling water arrives at (14) and is discharged at (15).
- the material of this ring is of current quality; it is for example made up of asbestos, silica, alumina or boron nitride.
- This ring is applied to the downstream end face of the ignition electrode (6), and, if necessary, it closes the channels (4) hollowed out in this face.
- the ring (16) is supported in a shoulder provided in the enclosure (1) and it constitutes the bearing surface of the inlet section of the anode (2).
- the inside diameter of the ring (16) is at least equal to that of the anode (2), and preferably equal to the inside diameter of the anode + 10 mm.
- a pipe (17) for supplying fuel, for example fine coal transported by a gas under pressure Through the body of the plasma torch is formed a pipe (17) for supplying fuel, for example fine coal transported by a gas under pressure.
- the outlet section (18) of this conduit passes through the ignition electrode (6) and opens out inside the ring (16).
- the outlet axis of this section (18) the longitudinal axis of the anode (2) at an angle of about 45 °.
- this torch functions in the same way as that of FIG. 2.
- a cathode gas inert with respect to tungsten for example, is introduced by (8) into the cathode chamber (1). nitrogen, hydrogen, rare gases or a mixture of these gases.
- the plasma gas is introduced at the entrance of the anode chamber (II), through the passages (4) formed in the crown of the ignition electrode (6).
- the fine carbon is introduced in (19) into the conduit (17, 18) and it is injected into the anode chamber (II) in which it passes into the vapor state under the effect of the high temperature, higher than 3500 ° C, prevailing in the plasma jet.
- fine charcoal is preferably used, of the so-called "boiler” quality, that is to say having about 70% of the grains less than 74 ⁇ m .
- the carbon-carrying gas is preferably air, possibly enriched in nitrogen for well-known explosion safety reasons.
- the injected carbon does not accumulate and does not obstruct the torch, it is almost completely sublimed and it is thus in the form of carbon gas which, injected for example in a blast furnace, reacts very quickly with minerals oxidized and with oxygen from the hot wind.
- the power of the plasma torches of the invention can be adjusted in three different ways.
- a first means consists in using cathode gases of a different nature. Thus, all other things being equal, the replacement of argon by nitrogen increases the power by about 20%.
- the power is indeed substantially proportional to the intensity of the arc current.
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- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Plasma & Fusion (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Plasma Technology (AREA)
- Discharge Heating (AREA)
Claims (9)
dadurch gekennzeichnet, daß er zwei Kammern (I, 11) enthält, die durch die genannte Zwischenelektrode (6) voneinander getrennt sind und mittels mindestens eines Durchlasses (7), der in der genannten Zwischenelektrode ausgespart wurde, miteinander in Verbindung stehen, wobei eine der beiden Kammern (I), genannt Kathodenkammer, mit der genannten Glühkathode (3) und mit Vorrichtungen (8) zur Einführung eines Schutzgases ausgestattet ist und die andere Kammer (11), genannt Anodenkammer, zum Teil aus der genannten Anode (2) besteht und mit Vorrichtungen (4) zur Einführung eines plasmaerzeugenden Gases ausgestattet ist.
dadurch gekennzeichnet, daß er wenigstens eine Leitung (17) für die Brennstoffzufuhr aufweist, wobei die Leitung in den Raum zwischen der Zwischenelektrode (6) und der Anode (2) mündet, und zwar vorzugsweise unmittelbar vor dem Eingangsbereich der Anodenkammer (11).
dadurch gekennzeichnet, daß das Endstück des Auslasses der genannten Zuleitung (17) derart ausgerichtet ist, daß seine Achse die Längsachse der Anode hinter dem Vorderende der Anode schneidet.
dadurch gekennzeichnet, daß er zwischen der Zwischenelektrode und der Anode einen Ring (16) aus elektrisch isolierendem, feuerfestem Material enthält, wobei der Innendurchmesser des Ringes zumindest so groß ist wie der Innendurchmesser der Anodenkammer (11), und vorzugsweise etwa gleich - groß wie der Innendurchmesser der Anodenkammer plus 10 mm ist.
dadurch gekennzeichnet, daß die Vorrichtungen zur Einführung eines Gases in wenigstens eine der genannten Kammern so angeordnet sind, daß sie das Gas in der genannten Kammer in eine vorzugsweise spiralförmige Bewegung versetzen.
dadurch gekennzeichnet, daß die Anode (2) mit einem peripheren, spiralförmigen Kühlkreis ausgestattet ist, wobei der Kühlkreis aus spiralförmigen Rippen (12) besteht die durch ein Rohr (13) abgedeckt sind.
dadurch gekennzeichnet, daß der Abstand zwischen der Glühkathode (3) und der Zwischenelektrode (6) zwischen 0 und 5 mm einstellbar ist.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE6/47929A BE898951A (fr) | 1984-02-17 | 1984-02-17 | Torche a plasma a arc electrique. |
BE6047929 | 1984-02-17 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0155254A2 EP0155254A2 (de) | 1985-09-18 |
EP0155254A3 EP0155254A3 (en) | 1986-03-19 |
EP0155254B1 true EP0155254B1 (de) | 1989-07-12 |
Family
ID=3874937
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP85870025A Expired EP0155254B1 (de) | 1984-02-17 | 1985-02-13 | Lichtbogenplasmabrenner |
Country Status (9)
Country | Link |
---|---|
US (1) | US4596918A (de) |
EP (1) | EP0155254B1 (de) |
JP (1) | JPS60189199A (de) |
AU (1) | AU579851B2 (de) |
BE (1) | BE898951A (de) |
BR (1) | BR8500708A (de) |
CA (1) | CA1230387A (de) |
DE (1) | DE3571544D1 (de) |
ZA (1) | ZA851134B (de) |
Families Citing this family (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61259777A (ja) * | 1985-05-13 | 1986-11-18 | Onoda Cement Co Ltd | 単ト−チ型プラズマ溶射方法及び装置 |
JPH0622719B2 (ja) * | 1985-05-13 | 1994-03-30 | 小野田セメント株式会社 | 複ト−チ型プラズマ溶射方法及びその装置 |
US4926632A (en) * | 1988-02-01 | 1990-05-22 | Olin Corporation | Performance arcjet thruster |
US4995231A (en) * | 1988-02-01 | 1991-02-26 | Olin Corporation | Performance arcjet thruster |
US4853515A (en) * | 1988-09-30 | 1989-08-01 | The Perkin-Elmer Corporation | Plasma gun extension for coating slots |
EP0428671A1 (de) * | 1989-06-08 | 1991-05-29 | Jean Albert François SÜNNEN | Verfahren und vorrichtung zur erhaltung hoher temperaturen |
FR2654294B1 (fr) * | 1989-11-08 | 1992-02-14 | Aerospatiale | Torche a plasma a amorcage par court-circuit. |
US5262616A (en) * | 1989-11-08 | 1993-11-16 | Societe Nationale Industrielle Et Aerospatiale | Plasma torch for noncooled injection of plasmagene gas |
FR2654293B1 (fr) * | 1989-11-08 | 1996-05-24 | Aerospatiale | Torche a plasma a injection non refroidie de gaz plasmagene. |
US6163008A (en) * | 1999-12-09 | 2000-12-19 | Thermal Dynamics Corporation | Plasma arc torch |
US6946617B2 (en) * | 2003-04-11 | 2005-09-20 | Hypertherm, Inc. | Method and apparatus for alignment of components of a plasma arc torch |
US20080116179A1 (en) * | 2003-04-11 | 2008-05-22 | Hypertherm, Inc. | Method and apparatus for alignment of components of a plasma arc torch |
KR100807806B1 (ko) * | 2006-04-04 | 2008-02-27 | 제주대학교 산학협력단 | 직류 아크 플라즈마트론 장치 및 사용 방법 |
CN101309546B (zh) * | 2008-07-02 | 2012-12-12 | 北京光耀能源技术股份有限公司 | 交流等离子发射枪 |
KR101025035B1 (ko) * | 2009-06-23 | 2011-03-25 | 주성호 | 프라즈마를 이용한 버어너 |
EP2716140B1 (de) * | 2011-05-24 | 2017-07-12 | Victor Equipment Company | Plasmalichtbogenbrenner mit sekundärer anlassschaltung und elektrode |
CN102438387B (zh) * | 2011-09-28 | 2014-12-24 | 南京创能电力科技开发有限公司 | 气旋式低温等离子发生器 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB845410A (en) * | 1955-07-26 | 1960-08-24 | Union Carbide Corp | Improved arc working process and apparatus |
DE1571153A1 (de) * | 1962-08-25 | 1970-08-13 | Siemens Ag | Plasmaspritzpistole |
GB1360659A (en) * | 1971-12-09 | 1974-07-17 | British Titan Ltd | Heating device |
US3832513A (en) * | 1973-04-09 | 1974-08-27 | G Klasson | Starting and stabilizing apparatus for a gas-tungsten arc welding system |
IT1055884B (it) * | 1976-02-17 | 1982-01-11 | Montedison Spa | Procedimento ad arco plasma di prodotti ceramici metallici e simili |
-
1984
- 1984-02-17 BE BE6/47929A patent/BE898951A/fr unknown
-
1985
- 1985-02-13 DE DE8585870025T patent/DE3571544D1/de not_active Expired
- 1985-02-13 EP EP85870025A patent/EP0155254B1/de not_active Expired
- 1985-02-14 BR BR8500708A patent/BR8500708A/pt unknown
- 1985-02-14 US US06/701,863 patent/US4596918A/en not_active Expired - Fee Related
- 1985-02-14 ZA ZA851134A patent/ZA851134B/xx unknown
- 1985-02-15 CA CA000474456A patent/CA1230387A/en not_active Expired
- 1985-02-18 AU AU38930/85A patent/AU579851B2/en not_active Ceased
- 1985-02-18 JP JP60030140A patent/JPS60189199A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
ZA851134B (en) | 1985-09-25 |
AU579851B2 (en) | 1988-12-15 |
AU3893085A (en) | 1985-08-22 |
BR8500708A (pt) | 1985-10-08 |
BE898951A (fr) | 1984-08-17 |
DE3571544D1 (en) | 1989-08-17 |
EP0155254A3 (en) | 1986-03-19 |
CA1230387A (en) | 1987-12-15 |
JPS60189199A (ja) | 1985-09-26 |
EP0155254A2 (de) | 1985-09-18 |
US4596918A (en) | 1986-06-24 |
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