EP0153946A1 - Method for perfuming balls and pieces of plastic material enabling the diffusion of perfume - Google Patents

Method for perfuming balls and pieces of plastic material enabling the diffusion of perfume

Info

Publication number
EP0153946A1
EP0153946A1 EP84903285A EP84903285A EP0153946A1 EP 0153946 A1 EP0153946 A1 EP 0153946A1 EP 84903285 A EP84903285 A EP 84903285A EP 84903285 A EP84903285 A EP 84903285A EP 0153946 A1 EP0153946 A1 EP 0153946A1
Authority
EP
European Patent Office
Prior art keywords
perfume
plastic
balls
diffusion
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP84903285A
Other languages
German (de)
French (fr)
Inventor
André Slagmulder
Evelyne Barra
Jean Pierre Rivoallan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR8314299A external-priority patent/FR2551448A1/en
Priority claimed from FR8400839A external-priority patent/FR2558474A2/en
Application filed by Individual filed Critical Individual
Publication of EP0153946A1 publication Critical patent/EP0153946A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L15/00—Washing or rinsing machines for crockery or tableware
    • A47L15/42—Details
    • A47L15/44—Devices for adding cleaning agents; Devices for dispensing cleaning agents, rinsing aids or deodorants
    • A47L15/4481—Deodorants, perfumes or odor removals
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00—Disinfection, sterilisation or deodorisation of air
    • A61L9/015—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone
    • A61L9/04—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating
    • A61L9/042—Disinfection, sterilisation or deodorisation of air using gaseous or vaporous substances, e.g. ozone using substances evaporated in the air without heating with the help of a macromolecular compound as a carrier or diluent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06F—LAUNDERING, DRYING, IRONING, PRESSING OR FOLDING TEXTILE ARTICLES
    • D06F39/00—Details of washing machines not specific to a single type of machines covered by groups D06F9/00 - D06F27/00 
    • D06F39/02—Devices for adding soap or other washing agents
    • D06F39/024—Devices for adding soap or other washing agents mounted on the agitator or the rotating drum; Free body dispensers

Definitions

  • the present invention relates to a method of diffusing perfume by means of plastic balls or of parts produced by injection from these balls as well as the impregnation of said balls or parts.
  • the diffusion of perfume in the atmosphere calls upon many known techniques. We will cite as examples odoriferous wicks, aerosols, diffusers, etc. All of these devices are of specific use and often difficult.
  • the object of the invention is to present a simple and elegant way of perfuming any environment using an easy-to-use product that leaves no greasy traces, unlike most of the examples cited above. above.
  • the invention relates first of all to the impregnation of plastic balls with various perfumes.
  • These balls can be used in the most diverse places such as cupboards, living rooms, cars, letters, suitcases, etc.
  • the plastic material is in the form of small balls intended to be extruded in a plodder.
  • An example of a plastic material which is perfectly suitable for this use is made of Vinyl Vinyl Acetate at various concentrations, the best being 28%.
  • Other plastic materials can be envisaged, for example: Ethylacrylate of Ethyl.
  • the impregnation is done by simple cold addition of the desired amount of perfume, then the mass is kneaded until swelling of the granules (about 30%) and a clear and dry appearance of these in a varying time depending on the scent from two to twenty four hours.
  • the percentage of perfume can vary from 15 to 30% or more. If the incorporation of the perfume presents difficulties, a vehicle may be necessary, most of the usual solvents in perfumery are not suitable for this use (diethyl phthalate, dipropylene glycol, etc ...) because they leave a greasy film on the surface of the balls which does not disappear over time, hence impossible to use. Two solvents escape the rule: benzoate and benzyl solicylate.
  • Fixer 20 100 Lavender composition: Lavender 50-52 35.2
  • the invention also relates to impregnation by the same method as mentioned above and all plastic parts based on Vinyl Ethylacetate or Ethylacetate produced both by injection and by extrusion.
  • This process brings the important advantage of avoiding hot perfuming of the plastic, this operation having the disadvantage of destroying part of the perfume due to the high temperature (180 °) at the time of injection.
  • the operation allows the perfuming of parts such as diffusing washers for the telephone, for car air filters, air conditioning and any forced air device as well as the perfuming of balls or plastic parts for costume jewelry.
  • the beads are contained in a perforated container or in a fabric resistant to washing agents and to the temperature necessary for washing dishes. Numerous tests have shown that the odors were perfectly covered and pleasant during the washing cycle. The beads tend to agglomerate with use, but this does not affect their marked and odorous property in any way.
  • One bag of beads inserted in the dishwashing container is sufficient for ten to twenty washes. In addition, the fragrance does not adhere to the dishes. This process can be extended to washing machines as well as automatic clothes dryers.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Fats And Perfumes (AREA)

Abstract

Procédé de parfumage à froid de billes et de pièces en matière plastique permettant la diffusion du parfum, la couverture ou absorption d'odeurs désagréables. L'invention concerne une manière simple et pratique permettant la diffusion à sec, puissante et progressive de parfums à partir d'un support en matière plastique. Les billes ou pièces de plastique sont imprégnées de parfum par simple ajout et brassage du parfum, événtuellement dilué dans un véhicule ad hoc. L'usage des billes ou pièces de plastique permet la diffusion du parfum dans l'atmosphere.Process of cold perfuming of balls and plastic parts allowing the diffusion of the perfume, the covering or absorption of unpleasant odors. The invention relates to a simple and practical way for the dry, powerful and progressive diffusion of perfumes from a plastic carrier. The balls or plastic pieces are impregnated with perfume by simple addition and mixing of the perfume, optionally diluted in a suitable vehicle. The use of balls or plastic parts allows the diffusion of the perfume in the atmosphere.

Description

TITRE DE L'INVENTION Procédé de parfumage de billes et de pièces en matière plastique permettant le diffusion du parfum TITLE OF THE INVENTION Method of perfuming beads and plastic parts allowing the diffusion of perfume
La présente invention concerne un procédé de diffusion de parfum au moyen de billes en matière plastique ou de pièces réalisées par injection à partir de ces billes ainsi que l'imprégnation des dites billes ou pièces.The present invention relates to a method of diffusing perfume by means of plastic balls or of parts produced by injection from these balls as well as the impregnation of said balls or parts.
La diffusion de parfum dans l'atmosphère fait appel à de nombreuses techniques connues. Nous citerons pour exemples les mèches odoriférantes, les aérosols, les diffuseurs, etc ... Tous ces dispositifs sont d'un emploi spécifique et souvent malaisé. Le but de l'invention est de présenter une façon simple et él|ante de parfumer n'importe ..quelle ambiance à l'aide d'un produit de manipulaiton facile ne laissant aucune trace grasse contrairement à la plupart des exemples cités ci-dessus.The diffusion of perfume in the atmosphere calls upon many known techniques. We will cite as examples odoriferous wicks, aerosols, diffusers, etc. All of these devices are of specific use and often difficult. The object of the invention is to present a simple and elegant way of perfuming any environment using an easy-to-use product that leaves no greasy traces, unlike most of the examples cited above. above.
L'invention concerne tout d'abord l'imprégnation de billes en matière plastique par divers parfums. Ces billes peuvent être employées dans les endroits les plus divers tels qu'armoires, pièces d'habitation, automobiles, lettres, valises, etc ........ La matière plastique se présente sous forme de petites billes destinées à être extrudées dans une boudineuse. Un exemple de matière plastique convenant parfaitement à cet usage est constitué d'Ethyl Acétate de Vinyl à diverses concentrations, la meilleure étant à 28 %. D'autres matières plastique peuvent être envisagées, par exemple : L'Ethylacrylate d'Ethyl.The invention relates first of all to the impregnation of plastic balls with various perfumes. These balls can be used in the most diverse places such as cupboards, living rooms, cars, letters, suitcases, etc. The plastic material is in the form of small balls intended to be extruded in a plodder. An example of a plastic material which is perfectly suitable for this use is made of Vinyl Vinyl Acetate at various concentrations, the best being 28%. Other plastic materials can be envisaged, for example: Ethylacrylate of Ethyl.
L'imprégnation se fait par simple addition à froid de la quantité voulue de parfum, ensuite la masse est malaxée jusqu'à obtention d'un gonflement des granules ( environ 30 %) et un aspect net et sec de ceux ci en un temps variant selon les parfums de deux à vingt quatre heures. Le pourcentage de parfum peur varier de 15 à 30 % voire plus. Si l'incorporation du parfum présente des difficultés, un véhicule peut être nécessaire, la plupart des solvants usuels en parfumerie ne conviennent pas à cet usage ( phtalate de diethyle, dipropylène glycol, etc .....) car ils laissent un film gras à la surface des billes qui ne disparait pas avec le temps, d'où impossible d'emploi. Deux solvants échappent à la règle : le benzoate et solicylate de benzyle. Les meilleurs véhicules sont les terpènes d'agrumes ( orange, citron, bergamote ) les terpènes de citronnelle, de litséa d'aucalyptus globulus et citriodora de menthe, de romarin, etc .......The impregnation is done by simple cold addition of the desired amount of perfume, then the mass is kneaded until swelling of the granules (about 30%) and a clear and dry appearance of these in a varying time depending on the scent from two to twenty four hours. The percentage of perfume can vary from 15 to 30% or more. If the incorporation of the perfume presents difficulties, a vehicle may be necessary, most of the usual solvents in perfumery are not suitable for this use (diethyl phthalate, dipropylene glycol, etc ...) because they leave a greasy film on the surface of the balls which does not disappear over time, hence impossible to use. Two solvents escape the rule: benzoate and benzyl solicylate. The best vehicles are the citrus terpenes (orange, lemon, bergamot), the lemongrass terpenes, ofalyptus globulus and citriodora mint, rosemary, etc .......
Le résultat final est un granule mat et sec après gonflement, contenant de 15 à 30 % de parfum, voire plus. Exemple de trois compositions possibles :The final result is a matte, dry granule after swelling, containing 15 to 30% or more fragrance. Example of three possible compositions:
- Composition verveine Citral 2- Citral verbena composition 2
Libséa cubeba 5Libséa cubeba 5
Terpènes menthe 2Mint terpenes 2
Composition citronnée 71Lemon composition 71
Fixateur 20 100 Composition lavandée : Lavande 50-52 35,2Fixer 20 100 Lavender composition: Lavender 50-52 35.2
Lavande fine 12,2Fine lavender 12.2
Absolue lavande fine 35Fine lavender absolute 35
Coumarine 3Coumarin 3
Fixateur lavande 20Lavender fixer 20
Benzoate de benzyle 107Benzyl benzoate 107
Renforçateur lavande 10Lavender enhancer 10
Musce ambrette 20Musce ambrette 20
Composition base 107,6Basic composition 107.6
Composition luxe épicée : Base jasmin 5Spicy luxury composition: Jasmine base 5
Base opopanax 5Opopanax 5 base
Base épicée 10Spicy base 10
Base oeillet 2Eyelet base 2
Arova CX 88Arova CX 88
Composition fleurie 70Flower arrangement 70
100100
L'invention concerne aussi l'imprégnation par la même méthode que citée précédemment et toutes pièces en matière plastique à base d'Ethylacetate de Vinyl ou Ethylacetate réalisées aussi bien par injection que par extrusion. Ce procédé apporte l'important avantage d'éviter le parfumage à chaud du plastique, cette opération ayant l'inconvénient de détruire une partie du parfum en raison de la température élevée ( 180°) au moment de l'injection.The invention also relates to impregnation by the same method as mentioned above and all plastic parts based on Vinyl Ethylacetate or Ethylacetate produced both by injection and by extrusion. This process brings the important advantage of avoiding hot perfuming of the plastic, this operation having the disadvantage of destroying part of the perfume due to the high temperature (180 °) at the time of injection.
L'opération permet le parfumage de pièces telles que rondelles diffuseurs pour le téléphone, pour les filtres à air de voitures, d'air conditionné et tout appareil à air puisé ainsi que le parfumage de bille ou pièces en matière plastique pour la bijouterie fantaisie.The operation allows the perfuming of parts such as diffusing washers for the telephone, for car air filters, air conditioning and any forced air device as well as the perfuming of balls or plastic parts for costume jewelry.
L'Opération permet enfin le parfumage de bille ou de pièces en matières plastique permettant l'absorption des mauvaises odeurs ( fumée de cigares, etc) Une application intéressante consiste à employer ces billes ou pièces dans les machines à laver la vaisselle. En effet, c'est un fait bien connu des parfumeurs qu'il est quasi impossible de parfumer les produits pour les lave vaisselle auto- matiques, car aucun parfum ne tient sur ces bases à l'exception de certaines menthes. Du fait que les odeurs dégagées durant tout le cycle ne sont guère agréable, une solution élégante consiste à introduire une petite quantité ( 25 à 50 Gr ) de billes parfumées, ou une pièces de plastique de poids équivalent, imprégnées de 20 à 30 % avec une composition parfumante ( citron, citronnelle, mandarine, etc ...). Les billes sont contenues dans un récipient perforé ou dans un tissu résistant aux agents de lavage et à la température nécessaire à la vaisselle. De nombreux essais ont démontré que les odeurs étaient parfaitement couvertes et agreables pendant le cycle de lavage. Les billes ont tendance à s'agglomérer à l'usage, mais cela n'affecte en rien leur propriété marquante et odorante. Un sachet de billes introduit dans le bac à vaisselle suffit pour dix à vingt lavages. De plus, le parfum n'adhère pas à la vaisselle. Ce procédé peut être étendu aux machines à laver le linge ainsi qu'aux séchoirs à linge automatiques. The Operation finally allows the scent of balls or plastic parts allowing the absorption of bad smells (cigar smoke, etc.) An interesting application consists in using these balls or parts in dish washing machines. Indeed, it is a fact well known to perfumers that it is almost impossible to perfume products for automatic dishwashers, because no perfume stands on these bases with the exception of certain mints. Since the odors released during the whole cycle are not very pleasant, an elegant solution consists in introducing a small quantity (25 to 50 Gr) of scented balls, or a piece of plastic of equivalent weight, impregnated with 20 to 30% with a perfuming composition (lemon, lemongrass, mandarin, etc ...). The beads are contained in a perforated container or in a fabric resistant to washing agents and to the temperature necessary for washing dishes. Numerous tests have shown that the odors were perfectly covered and pleasant during the washing cycle. The beads tend to agglomerate with use, but this does not affect their marked and odorous property in any way. One bag of beads inserted in the dishwashing container is sufficient for ten to twenty washes. In addition, the fragrance does not adhere to the dishes. This process can be extended to washing machines as well as automatic clothes dryers.

Claims

REVENDICATIONS
1) Procédé d'imprégnation à froid après malaxage à température ambiante de billes en matières plastique ou de pièces réalisées par injection ou extrusion à partir de ces billes par des parfums en vue de leur diffusion progressive caractérisée en ce que l'on met en présence les billes de matière plastique EVA ( Ethylacetate de Vynil ) ou les pièces réalisées à partir de ces billes et un parfum. Après malaxage, le plastique gonfle d'un tiers, absorbe le parfum totalement tout en gardant un aspect complètement sec. L'Ethylacrylate d'Ethyle présente des propriétés similaires, le pourcentage de parfum peut varier de 1 à 30 %. le temps d'imprégnation varie de deux à quarantethuitehesses selon les parfums. L'opération permet d'éviter la destruction thermique du parfum, la température du plastique au moment de l'injection atteignant environ 180°1) Cold impregnation process after kneading at room temperature of plastic balls or of parts produced by injection or extrusion from these balls with perfumes with a view to their gradual diffusion, characterized in that one puts in the presence EVA plastic beads (Vynil Ethylacetate) or parts made from these beads and a perfume. After mixing, the plastic swells by a third, completely absorbing the perfume while keeping a completely dry appearance. Ethylacrylate has similar properties, the percentage of perfume can vary from 1 to 30%. the impregnation time varies from two to forty fortuithesses depending on the perfumes. The operation avoids thermal destruction of the perfume, the temperature of the plastic at the time of injection reaching approximately 180 °
2) Procédé d'imprégnation d'Ethylacetate de Vinyl ou Ethylacrylate selon la revendication nº 1 caractérisé en ce que dans le cas de parfums difficilement absorbables, tel que les terpènes d'agrumes, le pourcentage des terpènes peut atteindre 50 % du parfum mis en oeuvre.2) Method for impregnating Vinyl Ethylacetate or Ethylacrylate according to claim 1, characterized in that in the case of scents which are difficult to absorb, such as citrus terpenes, the percentage of terpenes can reach 50% of the perfume put in artwork.
3) Procédé d'imprégnation d' Ethylacetate de Vinyl ou Ethylacrylate selon la revendication n° 2 caractérisé en ce que tous les solvants usuels laissent un film gras, à l'exception du Benzoate de Benzyle et du Salicylate.3) Process for impregnating Vinyl Ethylacetate or Ethylacrylate according to Claim 2, characterized in that all the usual solvents leave a fatty film, with the exception of Benzyl Benzoate and Salicylate.
4) Billes de matière plastique selon la revendication n° 2 actuelle parfumées avec une composition : Lavandée avec une composition : Verveine avec une composition : Parfumeur4) Plastic balls according to claim 2 currently perfumed with a composition: Lavender with a composition: Verbena with a composition: Perfumer
5) Rondelles de plastique parfumée réalisées selon le procédé de la revendication n° 1 caractérisé en ce que l'on imprègne à froid une rondelle de plastique en Ethylacetate de Vinyl et permettant la diffusion du parfum lorsque cette rondelle est placée dans le combiné du téléphone, sur le micro.5) Perfumed plastic washers produced according to the method of claim No. 1 characterized in that one cold impregnates a plastic washer of Vinyl Ethylacetate and allowing the diffusion of the perfume when this washer is placed in the telephone handset , on the microphone.
6) Rondelles en matière plastique réalisées selon les procédés de la revendication 1 caractérisé en ce qu'elles peuvent être fixées sur ou dans des filtres à air de voiture, dans les circuits d'appareils à air conditionné, dans les aspirateurs, les sèches-mains, et d'une manière générale dans tout appareil à air puisé.6) Plastic washers made according to the methods of claim 1 characterized in that they can be fixed on or in car air filters, in circuits of air conditioning apparatus, in vacuum cleaners, dryers- hands, and generally in any air blower.
7) Pièces en matière plastique réalisées selon le procédé de la revendication 1, destinée à la fabrication de bijoux parfumés.7) Plastic parts produced according to the method of claim 1, intended for the manufacture of perfumed jewelry.
8) Billes ou pièces en matière réalisées selon la revendication 1 caractérisée en ce que ces billes ou pièces ont la propriété d'absorber les odeurs8) balls or parts made of material according to claim 1 characterized in that these balls or parts have the property of absorbing odors
( fumée de cigarettes, cigares, odeurs désagréables des lave vaisselles ) Du fait de leur imprégnation à froid, les billes peuvent recevoir des produits spécifiques absorbeurs d'odeur tel le Ricinoléate de Zinc afin d'améliorer éventuellement le procédé. Deux autres produits peuvent être employés : le Triethélène Glycol et le Glyoscol. (cigarette smoke, cigars, unpleasant odors of dishwashers) Due to their cold impregnation, the beads can receive specific odor absorbing products such as Zinc Ricinoleate in order to possibly improve the process. Two other products can be used: Triethélène Glycol and Glyoscol.
EP84903285A 1983-09-07 1984-09-07 Method for perfuming balls and pieces of plastic material enabling the diffusion of perfume Withdrawn EP0153946A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR8314299A FR2551448A1 (en) 1983-09-07 1983-09-07 Process for perfuming plastic beads permitting the diffusion of the perfume
FR8314299 1983-09-07
FR8400839A FR2558474A2 (en) 1984-01-19 1984-01-19 Cold perfuming by impregnation of any articles made of plastic based on vinyl ethyl acetate or ethyl acrylate which are produced either by injection moulding or by extrusion
FR8400839 1984-01-19

Publications (1)

Publication Number Publication Date
EP0153946A1 true EP0153946A1 (en) 1985-09-11

Family

ID=26223574

Family Applications (1)

Application Number Title Priority Date Filing Date
EP84903285A Withdrawn EP0153946A1 (en) 1983-09-07 1984-09-07 Method for perfuming balls and pieces of plastic material enabling the diffusion of perfume

Country Status (2)

Country Link
EP (1) EP0153946A1 (en)
WO (1) WO1985000981A1 (en)

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US10501924B2 (en) 2014-11-05 2019-12-10 Fresh Products, Inc. Urinal screens
USD960329S1 (en) 2014-11-05 2022-08-09 The Fresh Products, Inc. Urinal screen
US11585078B2 (en) 2017-12-20 2023-02-21 Fresh Products, Inc. Urinal screens

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FR2744019B1 (en) * 1996-01-29 2000-03-17 Martz Jacques PROCESS FOR THE CONTROLLED ABSORPTION OF ESSENTIAL OILS
FR2765484B1 (en) * 1997-07-04 2000-12-15 Daniel Madec PROCESS FOR OBTAINING A SCENTED OBJECT IN THE MASS AND OBJECT THUS OBTAINED
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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10501924B2 (en) 2014-11-05 2019-12-10 Fresh Products, Inc. Urinal screens
US11198997B2 (en) 2014-11-05 2021-12-14 Fresh Products, Inc. Urinal screens
US11396745B2 (en) 2014-11-05 2022-07-26 Fresh Products, Inc. Urinal screens
USD960329S1 (en) 2014-11-05 2022-08-09 The Fresh Products, Inc. Urinal screen
US11781305B2 (en) 2014-11-05 2023-10-10 Fresh Products, Inc. Urinal screens
US11585078B2 (en) 2017-12-20 2023-02-21 Fresh Products, Inc. Urinal screens

Also Published As

Publication number Publication date
WO1985000981A1 (en) 1985-03-14

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