EP0153496B1 - Verre de sécurité laminé - Google Patents

Verre de sécurité laminé Download PDF

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Publication number
EP0153496B1
EP0153496B1 EP19840116329 EP84116329A EP0153496B1 EP 0153496 B1 EP0153496 B1 EP 0153496B1 EP 19840116329 EP19840116329 EP 19840116329 EP 84116329 A EP84116329 A EP 84116329A EP 0153496 B1 EP0153496 B1 EP 0153496B1
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EP
European Patent Office
Prior art keywords
diol
safety glass
laminated safety
molecular weight
glass according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
EP19840116329
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German (de)
English (en)
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EP0153496A3 (en
EP0153496A2 (fr
Inventor
Hiroshi Washita
Kaoru C/O Asahi Glass Company Ltd. Oguro
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AGC Inc
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Asahi Glass Co Ltd
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Publication date
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Publication of EP0153496A2 publication Critical patent/EP0153496A2/fr
Publication of EP0153496A3 publication Critical patent/EP0153496A3/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6633—Compounds of group C08G18/42
    • C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/664—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10018—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising only one glass sheet
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10064—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising at least two glass sheets, only one of which being an outer layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/1077—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing polyurethane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/44—Polycarbonates
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31551—Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • Y10T428/31598—Next to silicon-containing [silicone, cement, etc.] layer
    • Y10T428/31601—Quartz or glass

Definitions

  • the present invention relates to laminated safety glass having a synthetic resin surface on one side, according to the preamble of claim 1.
  • laminated safety glass is known from US-A-3,764,457.
  • Laminated safety glass having an at least two-layered structure comprising an inorganic glass (hereinafter referred to simply as "glass") layer and a synthetic resin layer, and having a glass surface on one side and a synthetic resin surface on the other side, is referred to as resin-laminated glass.
  • resin-laminated glass has become attractive as a prospective window material for automobiles, instead of so- called two-ply glass comprising a laminate body of a pair of glass sheets and an intermediate film interposed between them.
  • a synthetic resin layer in the resin-laminated glass is usually made of a polyurethane type synthetic resin, mainly a polyurethane type thermoplastic synthetic resin.
  • thermoplastic resin for resin-laminated glass is required to have not only mechanical properties such as impact strength or penetration resistance, but also various other properties such as transparency, stability against hydrolysis, weather resistance or processability.
  • the present inventors have conducted extensive researches for a polyurethane type thermoplastic resin useful for the resin-laminated glass which satisfies all the above-mentioned requirements, and have finally found a certain specific polyurethane type thermoplastic resin having practically the most excellent properties.
  • the present invention is concerned with resin-laminated glass in which the major portion of a synthetic resin layer is made of this specific polyurethane type thermoplastic resin.
  • the present invention provides laminated safety glass having an at least two-layered structure comprising an inorganic glass layer and a synthetic resin layer which comprises a polyurethane type thermoplastic resin, and having an inorganic glass surface on one side and a synthetic resin surface on the other side, characterized in that the major portion of the synthetic resin layer is a polyurethane type thermoplastic resin obtained from a high molecular weight diol composed of a combination of from 40 to 70 % by weight of a poly(1,6-hexylene carbonate)diol having a molecular weight of from 800 to 4000 and from 30 to 60 % by weight of a polyester diol having a molecular weight of from 800 to 4000, a chain extender and a non-yellowing type diisocyanate compound containing no isocyanate group directly bonded to an aromatic ring, as essential starting materials.
  • a polyurethane type thermoplastic resin obtained from a high molecular weight diol composed of a combination of from 40 to 70 %
  • Figures 1 to 4 are schematic cross-sectional views illustrating various embodiments of the laminated safety glass of the present invention.
  • the major portion of the synthetic resin layer is meant for a part or whole of the synthetic resin layer upon which the required mechanical properties may mainly depend, and is not determined only by a thickness of the layer.
  • the synthetic resin layer is of a two-layered structure comprising a polyurethane type thermoplastic resin layer and an outermost layer of a polyurethane type thermosetting resin which is provided for improving the surface properties
  • the polyurethane type thermoplastic resin layer may not necessarily be required to be thicker than the polyurethane type thermosetting resin layer. The reason is that the mechanical properties of the polyurethane type thermoplastic resin are by far superior to those of the polyurethane type thermosetting resin having the same thickness.
  • the polyurethane type thermosetting resin is required to have at least a certain level of a thickness so as to exhibit surface properties such as self-restoration properties. Accordingly, at least about 1/3, preferably at least about 1/2, in thickness, of the synthetic resin layer may consist of the polyurethane type thermoplastic resin layer. It is more preferred that substantially the whole or at least 2/3, in thickness, of the synthetic resin layer consists of the polyurethane type thermoplastic resin layer. Further, from the viewpoint of the required mechanical properties, the polyurethane type thermoplastic resin layer should better have a thickness of at least 0.2 mm, preferably in a range of from 0.2 to 10 mm, more preferably in a range of from 0.4 to 2 mm.
  • the polyurethane type thermoplastic resin layer may consist of two or more layers. In such a case, the above-mentioned thickness represents the total thickness of such layers. Further, in the present invention, the-synthetic resin layer does not include a so- called intermediate film layer of polyvinyl butyral or a polyurethane type resin interposed between a pair of glass sheets.
  • substantially all of the above-mentioned polyurethane type thermoplastic resin is a polyurethane type thermoplastic resin obtained by using the specific high molecular weight diol.
  • a layer which plays a minor role in the required mechanical properties and is extremely thinner than the major polyurethane type thermoplastic resin layer may be made of another polyurethane type thermoplastic resin.
  • the polyurethane type thermoplastic resin layer in the synthetic resin layer consists essentially of a single layer, and such a layer is composed of a polyurethane type thermoplastic resin obtained'by using the above-mentioned specific high molecular weight diol.
  • the specific polyurethane type thermoplastic resin according to the present invention is composed of a combination of from 40 to 70% by weight of a poly(1,6-hexylene carbonate)diol and from 30 to 60% by weight of a polyester diol, preferably a combination of from 45 to 65% by weight of a poly(1,6-hexylene carbonate)diol and from 35 to 55% by weight of a polyester diol.
  • the poly(1,6-hexylene carbonate)diol has a molecular weight of from 800 to 4000, preferably from 1500 to 3000, and a softening point of about 40°C.
  • the poly(1,6-hexylene carbonate) diol may suitably be prepared by the reaction of 1,6-hexanediol with diallyl carbonate, but may also be prepared by other methods such as the reaction of 1,6-hexanediol with phosgene or a dialkyl carbonate.
  • the polyester diol has a molecular weight of from, 800 to 4000, preferably from 1500 to 3000.
  • the polyester diol is a diol having a residual group of a dihydric alcohol and a residual group of a dibasic carboxylic acid, or a diol having a residual group of a ring opened cyclic ester such as a ring opened polymer of a cyclic ester.
  • Each of the residual groups may be a mixture of two or more respective compounds, and the diol may have all the three types of the residual groups.
  • the dihydric alcohol it is possible to use a non-aliphatic diol such as 2,2-bis(4-hydroxycyclohexyl)propane or 2,2-bis(4-hydroxyethoxyphenyl)propane.
  • a non-aliphatic diol such as 2,2-bis(4-hydroxycyclohexyl)propane or 2,2-bis(4-hydroxyethoxyphenyl)propane.
  • preferred is an aliphatic diol, and particularly preferred is a saturated aliphatic diol having from 2 to 8 carbon atoms.
  • dihydric alcohol there may be mentioned ethylene glycol, propylene glycol, 1,3-propanediol, 1,4-butanediol, neopentyl glycol, 1,6-hexanediol and a polyalkylene glycol such as diethylene glycol or dipropylene glycol.
  • dibasic carboxylic acid it is possible to use a non-aliphatic dibasic carboxylic acid.
  • a saturated dibasic carboxylic acid having from 2 to 12 carbon atoms, such as maleic acid, succinic acid, adipic acid, azelaic acid or sebacic acid.
  • cyclic ester, e-caprolactone and the like is suitable.
  • the polyester diol may be produced by the direct reaction of a dihydric alcohol with a dibasic carboxylic acid, by the reaction of a dihydric alcohol with a dibasic carboxylic acid derivative such as acid chloride, or by the ester exchange reaction.
  • polyester diols are a poly(1,4-butylene adipate)diol, a poly(1,4-butylene azelate)diol, a poly(ethylene adipate)diol a poly(1,6-hexylene adipate)diol, a poly(e-caprolactone)diol, a poly(1,4-butylene adipate)-(s-caprolactone) copolymerized polyester diol, etc.
  • the chain extender there may preferably be employed a dihydric alcohol having a low molecular weight and a diamine. Its molecular weight is preferably at most 400, more preferably at most 250.
  • the dihydric alcohol there may be used such dihydric alcohols as mentioned above, and particularly preferred is a saturated aliphatic dihydric alcohol having from 2 to 8 carbon atoms.
  • a carboxylic acid group-containing dihydric alcohol such as a,a-dimethylol propionic acid or dimethylol acetic acid.
  • the carboxylic acid group-containing polyurethane type thermoplastic resin is inferior in the stability against hydrolysis.
  • the diamine there may be used hexamethylenediamine, tolylenediamine, diaminodiphenylmethane, isophoronediamine, MOCA and other diamines.
  • chain extenders may be used alone or in combination as a mixture of two or more different kinds.
  • the chain extender may also be used in combination with a small amount of a cross-linking agent (i.e. a low molecular weight tri- or higher hydric alcohol or an amine).
  • the cross-linking agent should not be used in such a large amount that the resulting polyurethane type resin loses its thermoplasticity.
  • the cross-linking agent there may be mentioned, for instance, trimethylolpropane, glycerin or triethanolamine.
  • the non-yellowing type diisocyanate compound is a diisocyanate compound containing no isocyanate group directly bonded to an aromatic ring.
  • it may be a diisocyanate compound having an aromatic ring, such as xylylene diisocyanate.
  • preferred is an aliphatic or cycloaliphatic diisocyanate compound having no aromatic ring.
  • non-yellowing type diisocyanate compounds include modified compounds such as a urea modified compound, a prepolymer type modified compound, a carbodiimide modified compound or a burette modified compound.
  • the non-yellowing type diisocyanate compounds may be used alone or in combination as a mixture of two or more different kinds.
  • Particularly preferred non-yellowing type diisocyanate compounds are 4,4'-methylenebis(cyclohexyl isocyanate) and isophorone diisocyanate.
  • the amount of the chain extender is suitably from 1.0 to 10.0 equivalents relative to 1 equivalent of the total of high molecular weight diols. If the amount of the chain extender is less than 1.0 equivalent, the polyurethane type thermoplastic resin thereby obtained tends to be too flexible, and no adequate mechanical properties required for resin-laminated glass will be obtainable. Rigidity can be increased by incorporating a small amount of a cross-linking agent, but even when such a cross-linking agent is used, the amount of the total of the cross-linking agent and the chain extender is preferably at least 1.0 equivalent relative to 1 equivalent of the high molecular weight diol.
  • a more preferred lower limit of the amount of the chain extender is 2.0 equivalents relative to 1 equivalent of the high molecular weight diol.
  • the amount of the chain extender exceeds the above-mentioned upper limit, the polyurethane type thermoplastic resin tends to be too rigid, and the impact resistance or other mechanical properties tend to be inferior.
  • a more preferred upper limit of the amount of the chain extender is 6.0 equivalents relative to 1 equivalent of the high molecular weight diol.
  • the amount of the non-yellowing type diisocyanate compound is preferably from 0.90 to 1.15 equivalents, more preferably 0.95 to 1.10 equivalents, relative to 1 equivalent of the total of the high molecular weight diol and the chain extender (a total inclusive of the cross-linking agent, in the case of using the cross-linking agent).
  • the polyurethane type thermoplastic resin according to the present invention may be prepared optionally by using other components in addition to the above-mentioned three major starting materials.
  • a catalyst as an essential component.
  • the catalyst there may be used, for instance, a tertiary amine catalyst, an organic metal compound catalyst such as an organic tin compound, or other various catalysts useful for the preparation of a polyurethane.
  • an organic tin compound such as dibutyltin dilaurate, is particularly preferred.
  • a method for preparing a polyurethane type thermoplastic resin is not critical, and there may be employed a prepolymer method, a quasi-prepolymer method or a one-shot method. The use of the prepolymer method is particularly preferred.
  • the resin-laminated glass may be prepared by a direct mold-pouring method wherein a mixture of the above-mentioned starting materials are directly molded between glass and a mold material as will be described hereinafter. However, it may preferably be prepared by a laminating method wherein a sheet or film of a polyurethane type thermoplastic resin is firstly prepared, and then the sheet or film is laminated with glass or further other materials.
  • the sheet or film of a polyurethane type thermoplastic resin may be prepared by molding a polyurethane type thermoplastic resin, which has already been formed, e.g. by means of an extrusion molding. Further, such a sheet or film may directly be prepared by molding a starting material mixture on a flat surface.
  • polyurethane type thermoplastic resin wherein a poly(1,6-hexylene carbonate)diol and a polyester diol are used as the high molecular weight diol.
  • U.K. Patant 1,179,222 discloses a polyurethane type thermoplastic resin wherein from 10 to 50 % by weight of a poly(1,6-hexylene carbonate)diol and from 50 to 90 % by weight of a polyester diol are used as the high molecular weight diol.
  • This reference does not disclose or suggest any application of the synthetic resin for laminated safety glass, such as the synthetic resin layer of the resin-laminated glass according to the present invention or an intermediate film layer in two-ply glass.
  • the polyurethane type thermoplastic resin useful for the resin-laminated glass it is essential to use a non-yellowing type diisocyanate compound, and it is required to be a relatively rigid elastomer.
  • the amount of the chain extender is at most about 0.5 equivalent relative to a total of high molecular weight diols. With use of such a small amount of the chain extender, the polyurethane type thermoplastic resin thereby obtained is not suitable for resin-laminated glass.
  • Patent 3,764,457 or 4,103,070 discloses the use of a polyurethane type thermoplastic resin wherein a polycarbonate diol other than a poly(1,6-hexylene carbonate)diol is used, for the resin-laminated glass.
  • a polycarbonate diol obtained by the reaction of a 1,2-epoxide with carbon dioxide or a cyclic carbonate, or by the reaction thereof with a 1,2-epoxide.
  • the latter discloses a polycarbonate diol containing a residual group of a cycloaliphatic diol.
  • the polycarbonate diol disclosed in the former appears to be substantially a polyethylene glycol carbonate diol alone.
  • Such a polyethylene glycol carbonate diol has a residual group of polyethylene glycol and thus is highly hydrophilic, and accordingly, there will be a problem that the polyurethane type thermoplastic resin obtained by using such a diol, is inferior e.g. in weather resistance.
  • the latter reference by the same applicant discloses that a polyurethane type thermoplastic resin obtained by the former invention, is likely to deteriorate by ultraviolet rays and thus is not suitable for the resin-laminated glass.
  • the polycarbonate diol described in the latter reference is a special polycarbonate diol, and is hardly available and difficult to produce. Accordingly, it is not yet practically useful.
  • the former reference discloses use of a polycarbonate diol in combination with a polyester diol.
  • the amount of the polyester diol is at most about 45% by weight, particularly from about 10 to about 30% by weight of the polycarbonate diol at maximum (see in column 9, lines 66 to 73). Namely, the amount of the polyester diol is at most about 31% by weight, particularly from about 9 to about 23% by weight of a mixture of the polycarbonate diol and the polyester diol.
  • the use of such a small amount of the polyester diol cannot solve problems inherent to the special polycarbonate diol per se of the invention.
  • the polyurethane type thermoplastic resin according to the present invention has extremely excellent mechanical properties useful for resin-laminated glass as well as other physical properties such as transparency, stability against hydrolysis or weather resistance. Further, when the present invention is compared with a polyurethane type thermoplastic resin using a polyester diol alone, the one using a polyester diol alone is inferior in the stability against hydrolysis to the present invention. Whereas, the one using a polycarbonate diol alone has a difficulty in handling in the preparation of a urethane type thermoplastic resin because of a high viscosity of the polycarbonate diol when melted. Besides, in consideration of the polycarbonate diol being expensive, the present invention is also economically advantageous in that the same properties are obtainable at a lower cost.
  • FIGS 1 to 4 are the schematic cross-sectional views showing four embodiments of the laminated safety glass of the present invention.
  • a glass layer 1 and a specific polyurethane type thermoplastic resin layer 2 (hereinafter referred to as "specific polyurethane layer"), respectively, are shown in common.
  • Figure 1 is a cross-sectional view showing resin-laminated glass consisting essentially of two layers of the glass layer 1 and the specific polyurethane layer 2.
  • An extremely thin adhesive layer may present at an interface between the glass layer 1 and the specific polyurethane layer 2.
  • the adshesive layer is not usually required since the polyurethane type thermoplastic resin by itself is bonded relatively firmly to glass.
  • the exposed surface of the specific polyurethane layer 2 may be as it is, without being subjected to treatment.
  • the solvent resistance and the like it is preferred to conduct surface treatment e.g. to treat this surface with a cross-linking agent.
  • a cross-linking agent e.g. to treat this surface with a cross-linking agent.
  • Figure 2 is a cross sectional view showing resin-laminated glass consisting essentially of a three-layered structure wherein a polyurethane type thermoplastic or thermosetting resin layer 3 having the self-restoration properties, is provided on the outer side of the specific polyurethane layer 2.
  • the polyurethane type thermosetting resin layer 3 serves mainly to provide the surface properties such as the self-restoration properties or solvent resistance, and the specific polyurethane layer 2 serves mainly to provide the desired mechanical properties.
  • Figure 3 is a cross sectional view showing resin-laminated glass consisting essentially of a three-layered structure having a polyurethane type thermoplastic resin iayer4which is different from the specific polyurethane layer 2.
  • a polyurethane type thermoplastic resin iayer4 which is different from the specific polyurethane layer 2.
  • Another polyurethane type thermoplastic resin layer 4 is provided on the outer side of the specific polyurethane layer 2 is that the above-mentioned surface treatment is thereby readily conducted, or that it is thereby possible to employ a polyurethane type thermoplastic resin superior in the surface properties (inferior in other properties) to the specific polyurethane layer 2.
  • the polyurethane type thermoplastic resin of the specific polyurethane layer 2 preferably should not be a carboxylic acid group-containing polyurethane type thermoplastic resin obtained by using a dihydric alcohol chain extender having the above-mentioned carboxylic acid group, from the viewpoint of e.g. stability against hydrolysis.
  • it should preferably be a polyurethane type thermoplastic resin having a reactive group, such as a carboxylic acid group-containing polyurethane type thermoplastic resin, in order to conduct surface treatment such as the grafting of a surface treating agent.
  • thermoplastic resin different from the specific polyurethane layer 2 there may preferably employed a polyurethane type thermoplastic resin other than the specific polyurethane type thermoplastic resin according to the present invention, or, within the scope of the specific polyurethane type thermoplastic resin according to the present invention, a polyurethane type thermoplastic resin (e.g. the one having a carboxilic acid group) different from that of the specific polyurethane layer 2.
  • a polyurethane type thermoplastic resin e.g. the one having a carboxilic acid group
  • Figure 4 is a cross-sectional view of resin laminated glass wherein as a glass layer having a multi-layered structure is used as the glass layer.
  • the glass layer having a multi-layered structure is made of a two-ply glass 6 having an intermediate film 5 such as polyvinyl butyral.
  • the synthetic resin layer 7 may be made of the specific polyurethane layer 2 alone as shown in Figures 1 to 3, or may be of a multi-layered structure containing the specific polyurethane layer 2.
  • Figure 4 shows resin-laminated glass wherein the polyurethane type thermosetting resin layer 3 as has already explained in the case of Figure 2, is provided on the outer side of the specific polyurethane layer 2.
  • the laminated safety glass of the present invention may be prepared by a known method.
  • a direct mold-pouring method there has been known a direct mold-pouring method, but a laminating method is preferably employed.
  • the direct mold-pouring method is the one which comprises pouring a polyurethane type resin material between a glass sheet and a releasing mold material, then curing the polyurethane type resin and removing the mold material.
  • the laminating method is the one which comprises press-bonding under heating one or more synthetic resin sheets or films and glass for fusion bonding. For instance, glass, a synthetic resin sheet and a mold material are assembled and press-bonded under heating, and then the mold material is removed to prepare resin-laminated glass.
  • This method has a feature such that a bonding strength between a glass layer and a synthetic resin layer is high, and a smooth surface is obtainable by pressing with the mold material. Further, a roll-pressing and the like may be conducted without use of a mold material.
  • the synthetic resin sheet or film there may be used a single layered sheet or film having the specific polyurethane type thermoplastic resin alone, or a multi-layered sheet or film having such a specific resin with other synthetic resin layers. Further, such a single or multi-layered sheet or film may be laminated simultaneously with other synthetic resin sheets or films.
  • the mold material a glass sheet, a metal sheet and other smooth sheets are suitable.
  • a surface treated with a releasing compound it is preferable to employ a heat press-bonding method using an autoclave, or to employ a two step method comprising a preliminary laminating and a main laminating.
  • the laminated safety glass of the present invention is preferably colorless transparent or colored transparent.
  • silicate glass to be used as a known window material is suitable, and it may be strengthened by air-cooling or with chemicals.
  • the glass may be two-ply glass comprising a laminate body of a pair of glass sheets and an intermediate film interposed between them.
  • the laminated safety glass of the present invention is suitable for use as a window material, particularly front glass, for automobiles.
  • a window material particularly front glass
  • it may be used as e.g. a window material for buildings.
  • a resin-laminated glass was manufactured by a heat pressing method. Namely, the resin sheet of 0.6 mm thick was interposed between glass sheets having a size of 30 cm x 30 cm, and then the laminate was press-bonded under heating in an appropriate autoclave.
  • one of the glass sheets was uniformly coated in advance, on its one surface to be in contact with the resin sheet, with polydimethyl siloxane and heat-treated at 350°C, while the other glass sheet was uniformly coated, on its one surface to be in contact with the resin sheet, with y-glycydoxypropyltrimethoxysilane.
  • the autoclave was firstly evacuated to remove air existing between the glass sheets and the resin sheet, followed by heating the laminate under vacuum at a temperature of 120°C, thereby carrying out the preliminary press-bonding. After opening, the autoclave was maintained for about 30 minutes at a temperature of 150°C and under a pressure of 12.74 bar (13 kg/cm2). After this, the laminate was taken out from the autoclave, and one of the glass sheets was removed from the laminate, thereby obtaining a resin-laminated glass.
  • urethane sheets having a thickness of 0.5 mm were produced from the respective compositions as shown in the following Examples, and resin-laminated glasses were manufactured.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Polyurethanes Or Polyureas (AREA)

Claims (11)

1. Verre de sécurité feuilleté présentant une structure à au moins deux couches, qui comprend une couche de verre minéral et une couche de résine synthétique comprenant une résine thermoplastique de type polyuréthanne, et qui présente une surface de verre minéral d'un côté et une surfaoe de résine synthétique de l'autre côté, caractérisé par le fait que la majeure partie de la couche de résine synthétique est une résine thermoplastique de type polyuréthanne, obtenue à partir d'un diol de masse moléculaire élevée, se composant d'une combinaison de 40 à 70% en poids d'un poly(1,6-hexylène carbonate)diol présentant une masse moléculaire de 800 à 4 000, et de 30 à 60% en poids d'un polyester diol ayant une masse moléculaire de 800 à 4 000, d'un agent d'allongement de chaîne et d'un composé diisocyanate du type ne jaunissant pas, ne contenant pas de groupe isocyanate directement lié à un cycle aromatique, en tant que matières de départ essentielles.
2. Verre de sécurité feuilleté selon la revendication 1, dans lequel l'agent d'allongement de chaîne est utilisé en une quantité allant de 1,0 à 10 équivalents par rapport à 1 équivalent du diol de masse moléculaire élevée.
3. Verre de sécurité feuilleté selon la revendication 2, dans lequel l'agent d'allongement de chaîne est utilisé en une quantité allant de 2,0 à 6,0 équivalents par rapport à 1 équivalent du diol de masse moléculaire élevée.
4. Verre de sécurité feuilleté selon la revendication 1, dans lequel le poly(1,6-hexylènecarbonate)diol présente une masse moléculaire de 1500 à 3000, et le polyester diol présente une masse moléculaire de 1500 à 3000.
5. Verre de sécurité feuilleté selon la revendication 1, dans lequel le polyester diol est un polyester diol aliphatique comprenant un groupe résiduel d'un diol aliphatique saturé ayant de 2 à 8 atomes de carbone, et un groupe résiduel d'un acide dicarboxylique saturé, ayant de 2 à 12 atomes de carbone.
6. Verre de sécurité feuilleté selon la revendication 1, dans lequel le polyester diol est le poly(s-caprolactone)diol.
7. Verre de sécurité feuilleté selon la revendication 1, dans lequel le diol de masse moléculaire élevée comprend de 45 à 65% en poids d'un poly(1,6-hexylène carbonate)diol, et de 35 à 55% en poids d'un polyester diol.
8. Verre de sécurité feuilleté selon la revendication 1, dans lequel l'agent d'allongement de chaîne est un dialcool ayant de 2 à 6 atomes de carbone.
9. Verre de sécurité feuilleté selon la revendication 1, dans lequel l'agent d'allongement de chaîne comprend au moins un composé choisi dans le groupe constitué par le butanediol-1,4 et l'éthylène glycol.
10. Verre de sécurité feuilleté selon la revendication 1, dans lequel le composé diisocyanate du type ne jaunissant pas comprend au moins un composé choisi dans le groupe constitué par les composés diisocyanates aliphatiques et les composés diisocyanates cycloaliphatiques.
11. Verre de sécurité feuilleté selon la revendication 10, dans lequel le composé diisocyanate de type ne jaunissant pas comprend au moins un composé choisi dans le groupe constitué par le 4,4'-méthylènebis(cyclohexyl isocyanate) et l'isophorone diisocyanate.
EP19840116329 1984-01-27 1984-12-27 Verre de sécurité laminé Expired EP0153496B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP59012003A JPS60157856A (ja) 1984-01-27 1984-01-27 積層安全ガラス
JP12003/84 1984-01-27

Publications (3)

Publication Number Publication Date
EP0153496A2 EP0153496A2 (fr) 1985-09-04
EP0153496A3 EP0153496A3 (en) 1987-03-25
EP0153496B1 true EP0153496B1 (fr) 1989-09-27

Family

ID=11793405

Family Applications (1)

Application Number Title Priority Date Filing Date
EP19840116329 Expired EP0153496B1 (fr) 1984-01-27 1984-12-27 Verre de sécurité laminé

Country Status (4)

Country Link
US (1) US4600653A (fr)
EP (1) EP0153496B1 (fr)
JP (1) JPS60157856A (fr)
DE (1) DE3479876D1 (fr)

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FR2576012B1 (fr) * 1985-01-15 1991-11-22 Saint Gobain Vitrage Procede et dispositif pour la fabrication d'un vitrage de securite
JPS61179733A (ja) * 1985-02-05 1986-08-12 旭硝子株式会社 積層体およびその製造方法
US4865919A (en) * 1987-01-02 1989-09-12 Ppg Industries, Inc. Method of fabricating a curved glass panel having a removable section and glass panel with a removable section
EP0287861B1 (fr) * 1987-04-03 1992-04-29 Asahi Glass Company Ltd. Couche ou film en résine synthétique transparente, son procédé de fabrication et d'utilisation
US4824926A (en) * 1987-12-16 1989-04-25 Ppg Industries, Inc. Bilayer windshield with an abrasion and solvent resistant polyurethane protective coating
US4923757A (en) * 1987-12-16 1990-05-08 Ppg Industries, Inc. Bilayer windshield with an abrasion and solvent resistant polyurethane protective coating
CA2079168A1 (fr) * 1991-10-18 1993-04-19 Ashok M. Sarpeshkar Polyurethanes thermoformables
GB9123643D0 (en) * 1991-11-07 1992-07-22 Triplex Aircraft And Special P Windows
DE4203307C1 (fr) * 1992-02-06 1992-12-03 Fa. Carl Freudenberg, 6940 Weinheim, De
ES2156881T3 (es) 1993-07-28 2001-08-01 Asahi Glass Co Ltd Procedimiento de preparacion de un cristal laminado.
ES2172622T3 (es) * 1995-12-28 2002-10-01 Asahi Glass Co Ltd Placa de resina de poliuretano reticulado y producto preparado que utiliza esta.
US5834124C1 (en) * 1996-12-27 2001-11-27 Pease Ind Inc Impact resistant laminated glass windows
DE19757569A1 (de) * 1997-12-23 1999-06-24 Bayer Ag Aliphatische, emissionsarme, sinterfähige thermoplastische Polyurethanformmassen
GB2339405A (en) * 1998-07-10 2000-01-26 Pilkington Plc Laminated glazing
US20040006249A1 (en) * 2002-07-08 2004-01-08 Showa Denko K.K., Nikon Corporation Fluorination treatment apparatus, process for producing fluorination treated substance, and fluorination treated substance
EP1918502A1 (fr) * 2006-10-27 2008-05-07 Nederlandse Organisatie voor toegepast-natuurwetenschappelijk Onderzoek TNO Procédé pour blinder une fenêtre
US20090092005A1 (en) * 2007-10-08 2009-04-09 Nicolas Goujon Controlling seismic source elements based on determining a three-dimensional geometry of the seismic source elements
JP5615134B2 (ja) * 2010-04-30 2014-10-29 日東電工株式会社 透明基板の製造方法
CN111876083B (zh) * 2020-07-14 2021-12-31 宁波惠之星新材料科技有限公司 一种应用于无基材热贴合3d保护膜的低软化点tpe胶层及其制备方法

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US3509233A (en) * 1968-04-02 1970-04-28 Bayer Ag Hydrolysis resistant elastomeric poly (carbonate urethanes)
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DE2644434C3 (de) * 1976-10-01 1981-08-27 Bayer Ag, 5090 Leverkusen Polyurethan-Polyharnstoffe

Also Published As

Publication number Publication date
DE3479876D1 (en) 1989-11-02
JPS6260989B2 (fr) 1987-12-18
EP0153496A3 (en) 1987-03-25
EP0153496A2 (fr) 1985-09-04
US4600653A (en) 1986-07-15
JPS60157856A (ja) 1985-08-19

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