EP0151229A1 - Matrix for catalytic reactor - Google Patents
Matrix for catalytic reactor Download PDFInfo
- Publication number
- EP0151229A1 EP0151229A1 EP84112840A EP84112840A EP0151229A1 EP 0151229 A1 EP0151229 A1 EP 0151229A1 EP 84112840 A EP84112840 A EP 84112840A EP 84112840 A EP84112840 A EP 84112840A EP 0151229 A1 EP0151229 A1 EP 0151229A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- matrix
- matrix according
- strip
- layers
- strips
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011159 matrix material Substances 0.000 title claims abstract description 51
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 6
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 31
- 239000010959 steel Substances 0.000 claims abstract description 31
- 239000003054 catalyst Substances 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 5
- 238000000746 purification Methods 0.000 claims abstract description 5
- 238000002485 combustion reaction Methods 0.000 claims abstract description 3
- 230000001427 coherent effect Effects 0.000 claims abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 11
- 238000010276 construction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2839—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration
- F01N3/2842—Arrangements for mounting catalyst support in housing, e.g. with means for compensating thermal expansion or vibration specially adapted for monolithic supports, e.g. of honeycomb type
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- B01J35/56—
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
- F01N3/2807—Metal other than sintered metal
- F01N3/281—Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
- F01N3/2807—Metal other than sintered metal
- F01N3/281—Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
- F01N3/2814—Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates all sheets, plates or foils being corrugated
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/24—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
- F01N3/28—Construction of catalytic reactors
- F01N3/2803—Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
- F01N3/2807—Metal other than sintered metal
- F01N3/281—Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates
- F01N3/2821—Metallic honeycomb monoliths made of stacked or rolled sheets, foils or plates the support being provided with means to enhance the mixing process inside the converter, e.g. sheets, plates or foils with protrusions or projections to create turbulence
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/02—Metallic plates or honeycombs, e.g. superposed or rolled-up corrugated or otherwise deformed sheet metal
- F01N2330/04—Methods of manufacturing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2330/00—Structure of catalyst support or particle filter
- F01N2330/30—Honeycomb supports characterised by their structural details
- F01N2330/32—Honeycomb supports characterised by their structural details characterised by the shape, form or number of corrugations of plates, sheets or foils
- F01N2330/323—Corrugations of saw-tooth or triangular form
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N2450/00—Methods or apparatus for fitting, inserting or repairing different elements
- F01N2450/02—Fitting monolithic blocks into the housing
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/1241—Nonplanar uniform thickness or nonlinear uniform diameter [e.g., L-shape]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24628—Nonplanar uniform thickness material
- Y10T428/24669—Aligned or parallel nonplanarities
- Y10T428/24694—Parallel corrugations
- Y10T428/24711—Plural corrugated components
- Y10T428/24727—Plural corrugated components with planar component
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24744—Longitudinal or transverse tubular cavity or cell
Definitions
- the invention relates to a matrix for a catalytic reactor for exhaust gas purification, preferably in internal combustion engines and power plants, which are constructed from corrugated sheet steel strips coated with catalyst material, which lie adjacent to one another in several layers in a tubular housing o through which the exhaust gas flows axially and parallel to the boundary surfaces of the layers. the like are arranged.
- a matrix of this type is known (DE-PS 27 33 64o), in which steel strips constructed either from three layers, namely from two smooth strips and a corrugated strip enclosed between them, or from only one type of corrugated steel strip, are used as sheet steel strips , which are wound into a matrix and are designed such that tab-shaped punched-out punchings of one layer each press into corresponding openings in the adjacent layer, so that the wound-up layers of the steel sheet strips are secured in the axial direction. It is also known (DE-OS 29 02 779), in order to increase the turbulence of the flow through such a matrix, either to apply strips of corrugated sheets to smooth steel sheet strips or to connect individual smooth strips with a corrugated sheet.
- the invention is therefore based on the object of designing a matrix of the type mentioned at the outset in such a way that reactors with largely any desired external shapes can be created without great construction expenditure, which also offer the possibility of better radial compensation of the flow profile of the exhaust gas.
- the invention consists in the fact that the individual layers are parts of a single strip-shaped sheet steel strip which is folded in a meandering shape.
- This configuration allows the individual layers of the sheet steel strip to be joined onto one another in a relatively simple manner, and the manufacturing process already leaves them open at least on one side, so that, in contrast to a wound matrix, where gas equalization occurs even when the strip-shaped arrangement of corrugated strips is in itself In some respects permeable bands, gas compensation is only possible in the circumferential direction, and there is now a far simpler possibility for a radial passage of the exhaust gas, which leads to an equalization of the flow profile. As a result, the radially outer layers of the catalyst material can also participate in the reaction process.
- the matrix can be better used.
- a very simple embodiment of the matrix according to the invention results if the individual layers are folded onto one another in a zigzag shape. If the layers in the direction of folding are un have the same length, oval or round matrix inserts can be realized without a complicated construction from several parts being necessary. If the layers have the same length in the direction of folding, rectangular or Roman reactors can be constructed so that, depending on the space available, for example, in a motor vehicle, the shape of the matrix for the catalytic reactor for exhaust gas purification can be adapted to this space .
- the steel strips used to form the matrix are provided at the stops with prefabricated kink locations, for example in the manner of perforations, so that the manufacture of a matrix according to the invention, the individual layers of which, for example, zigzag-shaped are folded onto one another, can be achieved in a simple manner in that a single band, for example in the same way as continuous paper, folds behind a printer when it falls vertically into a shaft, is also passed into a shaft, at the folds easily bends and thereby folds onto each other to the desired matrix shape.
- the matrix formed in this way can then be inserted, for example, into a two-part housing and pressed together by this and also fastened to one another in the axial direction. But it can also be inserted axially through a funnel into a closed tubular housing.
- the sheet steel strip used for the production of the matrix can be constructed in a manner known per se from three layers, of which the two outer strips are each smooth strips with or without openings and the middle one is a corrugated strip, which is also formed with or without openings or interruptions can be. But it is easier if the sheet steel strip is a single corrugated strip, the corrugations of which, in a known manner, have a triangular cross section, each with straight walls on the outside, which are interrupted by gaps running transversely to the strip direction, but whose width in the strip direction is smaller than . is the width of the outer walls.
- Such a corrugated tape has the advantage that the individual layers that are folded onto one another do not slide into one another in this superimposed state, so that they can be folded up without the use of smooth strips.
- These corrugated strips can be provided with openings so that the radial compensation is not only possible in the direction of the layers folded onto one another, but can also take place transversely thereto.
- the free passage cross section of all openings is expediently chosen so that a proportion of at least 5% of the boundary surfaces adjacent to one another in the individual layers is achieved.
- the perforations must be coordinated in such a way that a good radial compensation is achieved without the loss of active surface having a negative effect.
- the perforations must also be distributed uniformly over the surface of the boundary surfaces, so that the aforementioned effect of a good radial compensation of the exhaust gas flow is achieved with an equalization of the flow profile.
- a strip of the type shown in FIG. 6 or in FIG. 7 can be used as the steel strip, which, as in FIG. 6, is composed of two smooth steel strips 1 with openings 2 and an intermediate corrugated strip 3 which 7 are soldered to one another, for example, or consist of a single corrugated strip - as shown in FIG. 7 - whose corrugations have a triangular cross section and which are arranged such that the outwardly facing surfaces 4 of each corrugation are wider in the direction of arrow 5, than the gap 6 located between these surfaces.
- Such a band cannot slide together when it is folded up with its individual layers.
- Tapes of this type can now be folded according to the invention in a meandering shape in the manner shown in FIG. 1 as a single continuous tape 7, so that a matrix according to FIG. 1 with a rectangular outer cross section is formed, which can be inserted into a rectangular housing 8. It is simpler to provide a zigzag meander as shown in FIG. 2, 3 or 4 for the folding, whereby in each case prefabricated folding points, for example in the manner of a perforation, can be provided at the folding points 9, which lead to the fact that the continuous ribbon 7 ', the zig-zag folded, successive sets itself automatically to the individual layers 7a, 7b, when it is, for example, lowered from above into a corresponding well and successive folds ierqtMail there like a Pa p.
- this can be done, for example, as indicated with reference to FIG. 5, in that a Sheet steel strip of the type shown in Fig. 6 is folded up in the manner shown in Fig. 2 and then. is jammed between the upper part 13 and the lower part 14 and is thereby also held in the axial direction, ie in the direction of the flow, which is indicated by the arrow 15.
- a matrix formed in this way in which, of course, the individual sheets 1 and 3 provided for production are coated with catalyst material in a known manner, has the advantage that it is very easy to produce. Due to the arrangement of the openings 2, gas equalization is also possible perpendicular to the boundary surfaces 17 of the individual layers 7A, 7B.
- the clear overall cross section of all openings 2 can be chosen so that this radial compensation is achieved to form a uniform flow profile. It has been shown that this is generally the case if the total cross section of the openings 2 makes up more than 5% of the area of the boundary surfaces 17.
- the openings can be provided in the corrugation direction or transversely thereto (2 '), which is more advantageous since they overlap better when layering.
- FIG. 8 shows the possibility of a practical embodiment of a matrix for a round tubular housing 11, which is produced from a sheet according to FIG. 7; in this case the tube 11 is in one piece.
- the folded matrix according to FIG. 3 can be pushed into the tubular housing 11 in the direction of the arrow 18 by a funnel indicated by a broken line.
- the clamping forces can be chosen so that an axial fit of the entire matrix is achieved; additional axial fastenings are of course also possible, in particular the matrix can be soldered or welded.
Abstract
Es wird eine Matrix für einen katalytischen Reaktor zur Abgasreinigung bei Brennkraftmaschinen beschrieben, die aus gewellten und mit Katalysatormaterial beschichtbaren Stahlblechbändern aufgebaut ist, welche in mehreren Lagen aneinanderliegend in einem vom Abgas durchströmten rohrförmigen Gehäuse angeordnet sind. Die einzelnen Lagen sind dabei Teile eines zusammenhängenden streifenförmigen Stahlblechbandes, das mäanderförmig insbesondere zick-zack-förmig aufeinandergefaltet ist. Diese Ausgestaltung ermöglicht eine einfache Herstellung und kann zu einer Anordnung führen, bei der ein Gasausgleich auch in radialer Richtung möglich ist, der zu einer Vergleichmäßigung des Strömungsprofiles und zu einer besseren Ausnutzung der Reaktion der Matrix führen kann.A matrix for a catalytic reactor for exhaust gas purification in internal combustion engines is described, which is constructed from corrugated steel strips which can be coated with catalyst material and which are arranged in several layers adjacent to one another in a tubular housing through which the exhaust gas flows. The individual layers are parts of a coherent strip-shaped sheet steel strip which is folded in a meandering manner, in particular in a zigzag shape. This configuration enables simple manufacture and can lead to an arrangement in which gas equalization is also possible in the radial direction, which can lead to a more uniform flow profile and better utilization of the reaction of the matrix.
Description
Die Erfindung betrifft eine Matrix für einen katalytischen Reaktor zur Abgasreinigung vorzugsweise bei Brennkraftmaschinen und Kraftwerken, die aus gewellten und mit Katalysatormaterial beschichteten Stahlblechbändern aufgebaut sind, welche in mehreren Lagen aneinanderliegend in einem vom Abgas axial und parallel zu den Begrenzungsflächen der Lagen durchströmten rohrförmigen Gehäuse o.dgl. angeordnet sind.The invention relates to a matrix for a catalytic reactor for exhaust gas purification, preferably in internal combustion engines and power plants, which are constructed from corrugated sheet steel strips coated with catalyst material, which lie adjacent to one another in several layers in a tubular housing o through which the exhaust gas flows axially and parallel to the boundary surfaces of the layers. the like are arranged.
Es ist eine Matrix dieser Art bekannt (DE-PS 27 33 64o), bei der als Stahlblechbänder entweder aus drei Schichten, nämlich aus zwei glatten Bändern und einem dazwischen eingeschlossenen Wellblechband aufgebaute Stahlbänder oder auch nur aus einer Art von gewellten Stahlblechbändern aufgebaute Bänder Verwendung finden, die zu einer Matrix aufgewickelt werden und so ausgebildet sind, daß jeweils lappenförmige Ausstanzungen einer Lage sich in entsprechende öffnungen der benachbarten Lage eindrücken, so daß die aufgewickelten Lagen der Stahlblechbänder in Axialrichtung gesichert sind. Bekannt ist es auch (DE-OS 29 02 779), zur Erhöhung der Turbulenz der Durchströmung einer solchen Matrix entweder auf glatten Stahlblechbändern Streifen von gewellten Blechen aufzubringen oder einzelne glatte Streifen mit einem gewellten Blech zu verbinden. Alle bekannten Ausführungen weisen aber zum einen den Nachteil auf, daß die Herstellung einer solchen Matrix verhältnismäßig aufwendig ist, insbesondere wenn die verwendeten Stahlblechbänder ihrerseits schon aus mehreren Bändern bestehen. Nachteilig ist vor allem aber, daß die bekannten Bauarten einer Matrix wegen des Wickelvorganges nur in etwa kreisrohrförmige Gehäuse einsetzbar sind, und daß die Gestaltung der äußeren Form solcher Reaktoren vom Aufbau der Matrix her beschränkt ist. Nachteilig ist ferner, daß ein radialer Ausgleich der die Matrix und den Reaktor durchströmenden Abgase nicht oder nur sehr unvollständig möglich ist, selbst wenn Stahlblechbänder der vorher erwähnten Art mit Durchbrechungen vorgesehen werden.A matrix of this type is known (DE-PS 27 33 64o), in which steel strips constructed either from three layers, namely from two smooth strips and a corrugated strip enclosed between them, or from only one type of corrugated steel strip, are used as sheet steel strips , which are wound into a matrix and are designed such that tab-shaped punched-out punchings of one layer each press into corresponding openings in the adjacent layer, so that the wound-up layers of the steel sheet strips are secured in the axial direction. It is also known (DE-OS 29 02 779), in order to increase the turbulence of the flow through such a matrix, either to apply strips of corrugated sheets to smooth steel sheet strips or to connect individual smooth strips with a corrugated sheet. All known designs, however, have the disadvantage, on the one hand, that the production of such a matrix is relatively complex, in particular if the steel sheet strips used in turn already consist of several strips. The main disadvantage, however, is that the known types of a matrix can only be used in approximately circular tubular housings because of the winding process, and that the design of the outer shape of such reactors is limited by the structure of the matrix. Another disadvantage is that a radial compensation of the matrix and Exhaust gases flowing through the reactor are not possible or only very incompletely, even if steel strips of the type mentioned above are provided with openings.
Der Erfindung liegt daher die Aufgabe zugrunde, eine Matrix der eingangs genannten Art so auszubilden, daß ohne großen Bauaufwand Reaktoren mit weitgehend beliebigen Außenformen geschaffen werden können, die auch die Möglichkeit zu einem besseren radialen Ausgleich des Strömungsprofiles des Abgases bieten.The invention is therefore based on the object of designing a matrix of the type mentioned at the outset in such a way that reactors with largely any desired external shapes can be created without great construction expenditure, which also offer the possibility of better radial compensation of the flow profile of the exhaust gas.
Die Erfindung besteht ausgehend von einer Matrix der eingangs genannten Art darin, daß die einzelnen Lagen Teile eines einzigen streifenförmigen Stahlblechbandes sind, das mäanderförmig gefaltet ist. Durch diese Ausgestaltung lassen sich die einzelnen Lagen des Stahlblechbandes in verhältnismäßig einfacher Weise aufeinanderfügen, und bleiben vom Herstellungsvorgang her schon zumindestens nach einer Seite hin offen, so daß im Gegensatz zu einer gewickelten Matrix wo ein Gasausgleich selbst bei in sich durch die streifenförmige Anordnung von Wellbändern in gewisser Hinsicht durchlässig gestalteten Bändern ein Gasausgleich nur in Umfangsrichtung möglich ist, nun eine weitgehende einfachere Möglichkeit für einen radialen Durchtritt des Abgases gegeben ist, der zu einer Vergleichmäßigung des Strömungsprofiles führt. Dadurch können auch die radial außen gelegenen Schichten des Katalysatormateriales mit an dem Reaktionsvorgang teilnehmen. Die Matrix kann besser ausgenützt werden.Starting from a matrix of the type mentioned at the outset, the invention consists in the fact that the individual layers are parts of a single strip-shaped sheet steel strip which is folded in a meandering shape. This configuration allows the individual layers of the sheet steel strip to be joined onto one another in a relatively simple manner, and the manufacturing process already leaves them open at least on one side, so that, in contrast to a wound matrix, where gas equalization occurs even when the strip-shaped arrangement of corrugated strips is in itself In some respects permeable bands, gas compensation is only possible in the circumferential direction, and there is now a far simpler possibility for a radial passage of the exhaust gas, which leads to an equalization of the flow profile. As a result, the radially outer layers of the catalyst material can also participate in the reaction process. The matrix can be better used.
Eine sehr einfache Ausführungsform der erfindungsgemäßen Matrix ergibt sich, wenn die einzelnen Lagen zick-zack-förmig aufeinandergefaltet sind. Wenn die Lagen in der Faltrichtung eine ungleiche Länge aufweisen, lassen sich dadurch ovale oder runde Matrixeinsätze verwirklichen, ohne daß ein komplizierter Aufbau aus mehreren Teilen erforderlich wird. Wenn die Lagen gleiche Länge in der Faltrichtung besitzen, können rechteckige oder auch rombische Reaktoren aufgebaut werden, so daß, je nach dem beispielsweise in einem Kraftfahrzeug zur Verfügung stehenden Platz, die Matrix für den katalytischen Reaktor zur Abgasreinigung in ihrer Form diesem Platz angepaßt werden kann.A very simple embodiment of the matrix according to the invention results if the individual layers are folded onto one another in a zigzag shape. If the layers in the direction of folding are un have the same length, oval or round matrix inserts can be realized without a complicated construction from several parts being necessary. If the layers have the same length in the direction of folding, rectangular or Roman reactors can be constructed so that, depending on the space available, for example, in a motor vehicle, the shape of the matrix for the catalytic reactor for exhaust gas purification can be adapted to this space .
Um den Herstellungsvorgang zu vereinfachen kann vorgesehen sein, daß die zur Bildung der Matrix\erwendeten Stahlblechbänder an den Haltstellen mit vorgefertigten Knickstellen beispielsweise in der Art von Perforationen versehen sind, so daß die Herstellung einer erfindungsgemäßen Matrix, deren einzelne Lagen beispielsweise zick-zack-förmig aufeinandergefaltet sind, sich in einfacher Weise dadurch erreichen läßt, daß ein einziges Band beispielsweise in der gleichen Art wie sich Endlospapier hinter einem Drucker in Falten legt, wenn es senkrecht in einen Schacht fällt, ebenfalls in einen Schacht geleitet wird, an den Knickstellen sich leicht abknickt und dadurch sich zu der gewünschten Matrixform aufeinanderfaltet. Die so gebildete Matrix kann anschließend beispielsweise in ein zweiteiliges Gehäuse eingesetzt und durch dieses zusammengepreßt und auch in axialer Richtung untereinander befestigt werden. Sie kann aber auch durch einen Trichter in ein geschlossenes rohrförmiges Gehäuse axial eingeschoben werden.In order to simplify the manufacturing process, it can be provided that the steel strips used to form the matrix are provided at the stops with prefabricated kink locations, for example in the manner of perforations, so that the manufacture of a matrix according to the invention, the individual layers of which, for example, zigzag-shaped are folded onto one another, can be achieved in a simple manner in that a single band, for example in the same way as continuous paper, folds behind a printer when it falls vertically into a shaft, is also passed into a shaft, at the folds easily bends and thereby folds onto each other to the desired matrix shape. The matrix formed in this way can then be inserted, for example, into a two-part housing and pressed together by this and also fastened to one another in the axial direction. But it can also be inserted axially through a funnel into a closed tubular housing.
Das für die Herstellung der Matrix verwendete Stahlblechband kann in an sich bekannter Weise aus drei Schichten aufgebaut sein, von denen die beiden äußeren jeweils glatte Bänder mit oder ohne Durchbrechungen sind und die mittlere ein gewelltes Band ist, das ebenfalls mit oder ohne Durchbrechungen oder Unterbrechungen ausgebildet sein kann. Einfacher aber ist es, wenn das Stahlblechband ein einzelnes Wellband ist, dessen Wellungen - in ebenfalls bekannter Weise - dreieckförmigen Querschnitt mit jeweils an den Außenseiten liegenden geraden Wänden aufweisen, die durch quer zur Bandrichtung verlaufende Spalte unterbrochen sind, deren Breite in Bandrichtung aber kleiner als . die Breite der außenliegenden Wände ist. Ein solches Wellband weist den Vorteil auf, daß sich die einzelnen aufeinandergefalteten Lagen in diesem aufeinanderliegenden Zustand nicht ineinanderschieben, so daß ohne den Einsatz glatter Bänder ein Aufeinanderfalten möglich ist. Diese Wellbänder können mit Durchbrechungen versehen werden, so daß der radiale Ausgleich nicht nur jeweils in Richtung der aufeinandergefalteten Schichten möglich ist, sondern auch quer dazu erfolgen kann. Dabei wird zweckmäßig der freie Durchlaßquerschnitt aller Durchbrechungen so gewählt, daß ein Anteil von mindestens 5 % der in den einzelnen Lagen aneinandergrenzenen Begrenzungsflächen erreicht wird. Die Durchbrechungen müssen so abgestimmt sein, daß ein guter radialer Ausgleich erzielt wird, ohne daß der Verlust an aktiver Oberfläche sich negativ bemerkbar macht. Die Durchbrechungen müssen auch gleichmäßig über die Fläche der Begrenzungsflächen verteilt sein, so daß dann der vorher erwähnte Effekt eines guten radialen Ausgleiches der Abgasströmung mit einer Vergleichmäßigung des Strömungsprofils erreicht wird.The sheet steel strip used for the production of the matrix can be constructed in a manner known per se from three layers, of which the two outer strips are each smooth strips with or without openings and the middle one is a corrugated strip, which is also formed with or without openings or interruptions can be. But it is easier if the sheet steel strip is a single corrugated strip, the corrugations of which, in a known manner, have a triangular cross section, each with straight walls on the outside, which are interrupted by gaps running transversely to the strip direction, but whose width in the strip direction is smaller than . is the width of the outer walls. Such a corrugated tape has the advantage that the individual layers that are folded onto one another do not slide into one another in this superimposed state, so that they can be folded up without the use of smooth strips. These corrugated strips can be provided with openings so that the radial compensation is not only possible in the direction of the layers folded onto one another, but can also take place transversely thereto. The free passage cross section of all openings is expediently chosen so that a proportion of at least 5% of the boundary surfaces adjacent to one another in the individual layers is achieved. The perforations must be coordinated in such a way that a good radial compensation is achieved without the loss of active surface having a negative effect. The perforations must also be distributed uniformly over the surface of the boundary surfaces, so that the aforementioned effect of a good radial compensation of the exhaust gas flow is achieved with an equalization of the flow profile.
Die Erfindung ist in der Zeichnung anhand von Ausführungsbeispielen skizziert und wird im folgenden erläutert. Es zeigen:
- Fig. 1 eine Möglichkeit einer erfindungsgemäßen Faltung eines für die Herstellung der Matrix verwendeten Stahlblechbandes in Mäanderform,
- Fig. 2 die schematische Darstellung ein in einem zick-zack-förmigen Mäander auf-einandergefalteten Stahlblechbandes zur Bildung eines ovalen Reaktoraußenkörpers,
- Fig. 3 die zick-zack-förmige Aufeinanderfaltung eines Stahlblechbandes zur Bildung eines runden Reaktorkörpers,
- Fig. 4 die zick-zack-förmige Aufeinanderfaltung eines Stahlblechbandes zur Bildung eines rechteckigen Reaktorkörpers,
- Fig. 5 eine perspektivische Skizze eines Reaktors, der durch das Aufeinanderfalten eines aus drei Lagen bestehenden, für die Bildung der Matrix verwendeten Stahlblechbandes hergestellt ist,
- Fig. 6 eine perspektivische Teilansicht des für die Herstellung der Matrix der Fig. 5 verwendeten Stahlblechbandes,
- Fig. 7 die perspektivische Teildarstellung eines mit dreieckförmigen Wellungen versehenen Stahlblechbandes, das in besonders einfacher Weise zur Bildung einer erfindungsgemäßen Matrix verwendet werden kann und
- Fig. 8 die schematische Darstellung einer für einen rohrförmigen Außenkörper geeigneten Matrix, die aus einem Wellband gemäß Fig. 7 hergestellt ist,
- 1 shows a possibility of folding according to the invention of a sheet steel strip used in the manufacture of the matrix in a meandering shape,
- 2 shows the schematic representation of a sheet steel strip folded on top of one another in a zigzag-shaped meander to form an oval outer body of the reactor,
- 3 the zigzag-shaped unfolding of a sheet steel strip to form a round reactor body,
- 4 shows the zigzag-shaped unfolding of a sheet steel strip to form a rectangular reactor body,
- 5 shows a perspective sketch of a reactor which is produced by unfolding a three-layer steel sheet strip used for forming the matrix,
- 6 is a partial perspective view of the sheet steel strip used for the production of the matrix of FIG. 5,
- Fig. 7 is a partial perspective view of a sheet steel strip provided with triangular corrugations, which can be used in a particularly simple manner to form a matrix according to the invention and
- 8 shows the schematic representation of a matrix suitable for a tubular outer body, which is produced from a corrugated strip according to FIG. 7,
In den Fig. 1 bis 4 sind Möglichkeiten gezeigt, wie erfindungsgemäß Stahlblechbänder zu einer Matrix für einen katalytischen Reaktor zur Abgasreinigung gefaltet werden können. Dabei kann als Stahlblechband beispielsweise ein Band der in der Fig. 6 oder in der Fig. 7 gezeigten Art verwendet werden, das entweder, wie in Fig. 6 aus zwei glatten Stahlblechbändern 1 mit öffnungen 2 und einem dazwischenliegenden Wellband 3 aufgebaut ist, die untereinander beispielsweise verlötet sind, oder aus einem einzigen Wellband - gemäß Fig. 7 - bestehen, dessen Wellungen einen dreieckförmigen Querschnitt besitzen und die so angeordnet sind, daß jeweils die nach außen gerichteten Flächen 4 jeder Wellung in der Richtung des Pfeiles 5 gesehen breiter sind, als die zwischen diesen Flächen gelegenen Spalte 6. Ein solches Band kann bei der Aufeinanderfaltung mit seinen einzelnen Lagen nichtineinanderrutschen. Natürlich ist es auch möglich, andere Formen von Bändern zu verwenden, wobei aber jeweils darauf geachtet werden muß, daß ein Ineinanderrutschen der einzelnen Bänder verhindert wird.1 to 4 show possibilities of how sheet steel strips according to the invention can be folded into a matrix for a catalytic reactor for exhaust gas purification. For example, a strip of the type shown in FIG. 6 or in FIG. 7 can be used as the steel strip, which, as in FIG. 6, is composed of two
Bänder dieser Art können nun erfindungsgemäß mäanderförmig in der in der Fig. 1 gezeigten Art als ein einziges durchlaufendes Band 7 gefaltet werden, so daß eine Matrix gemäß Fig. 1 mit einem rechte-ckigen Außenquerschnitt entsteht, die in ein rechteckiges Gehäuse 8 einsetzbar ist. Einfacher ist es, einen Zick-Zack-Mäander gemäß Fig. 2, 3 oder 4 für die Faltung vorzusehen, wobei jeweils an den Faltstellen 9 vorgefertigte Knickstellen, beispielsweise in der Art einer Perforation, vorgesehen sein können, die dazu führe, daß das durchlaufende Band 7', das zick-zack-förmig gefaltet ist, sich selbsttätig zu den einzelnen Lagen 7a, 7b aufeinanderlegt, wenn es beispielsweise von oben in einen entsprechenden Schacht herabgelassen wird und sich dort wie ein Papierqtreifen aufeinanderfaltet. Dabei ist es möglich, wie in den Fig. 2 und 3 angedeutet, die einzelnen Lagen 7a, 7b jeweils mit einer unterschiedlichen Faltlänge a bzw. b zu versehen, so daß ovale Außenabmessungen zum Einfügen in ein ovales rohrförmiges Gehäuse 10- wie in Fig. 2 - oder in ein rundes rohrförmiges Gehäuse 11 - wie in Fig. 3 - durch den Faltvorgang erreicht werden können. Natürlich ist es auch möglich, die einzelner Lagen mit gleicher Faltlänge b wie in Fig. 4 auszubilden, so daß die so gebildete Matrix ähnlich wie in Fig. 1 in ein rechteckförmides Außengehäuse 12 einsetzbar ist.Tapes of this type can now be folded according to the invention in a meandering shape in the manner shown in FIG. 1 as a single
In einer praktischen Ausführungsform kann dies beispielsweise, wie anhand von Fig. 5 angedeutet, dadurch geschehen, daß ein Stahlblechband der Art, wie es in Fig. 6 gezeigt ist, in der in Fig. 2 dargestellten Weise aufeinandergefaltet wird und dann. zwischen dem Oberteil 13 und dem Unterteil 14 verklemmt wird und dadurch auch in Axialrichtung, d.h. in Richtung der Durchströmung, gehalten wird, die mit dem Pfeil 15 angedeutet ist. Eine so gebildete Matrix, bei der natürlich die einzelnen zur Herstellung vorgesehenen Bleche 1 bzw. 3 in bekannter Weise mit Katalysatormaterial beschichtet werden, weist den Vorteil auf, daß sie sehr einfach herzustellen ist. Aufgrund der Anordnung der öffnungen 2 ist aber auch senkrecht zu den Begrenzungsflächen 17 der einzelnen Lagen 7A, 7B ein Gasausgleich möglich. Der lichte Gesamtquerschnitt aller öffnungen 2 kann so gewählt werden, daß dieser radiale Ausgleich zur Bildung eines gleichmäßigen Strömungsprofiles erreicht wird. Es hat sich gezeigt, daß dies im allgemeinen der Fall ist, wenn der gesamte Querschnitt der öffnungen 2 mehr als 5 % der Fläche der Begrenzungsflächen 17 ausmacht. Die öffnungen können in Wellrichtung oder quer dazu (2') vorgesehen werden, was vorteilhafter ist, da sie sich beim Schichten besser überlappen.In a practical embodiment, this can be done, for example, as indicated with reference to FIG. 5, in that a Sheet steel strip of the type shown in Fig. 6 is folded up in the manner shown in Fig. 2 and then. is jammed between the
In Fig. 8 ist die Möglichkeit einer praktischen Ausführungsform einer Matrix für ein rundes rohrförmiges Gehäuse 11 gezeigt, die aus einem Blech gemäß Fig. 7 hergestellt ist; das Rohr 11 ist in diesem Fall einteilig. Die gemäß Fig. 3 gefaltete Matrix kann in Richtung des Pfeiles 18 durch einen gestrichelt angedeuteten Trichter in das rohrförmige Gehäuse 11 eingeschoben werden. Die Klemmkräfte können so gewählt werden, daß ein axialer Sitz der gesamten Matrix erreicht wird; natürlich sind auch noch zusätzliche axiale Befestigungen möglich, insbesondere kann die Matrix gelötet oder geschweißt werden.FIG. 8 shows the possibility of a practical embodiment of a matrix for a round
Claims (10)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE3341868 | 1983-11-19 | ||
DE19833341868 DE3341868A1 (en) | 1983-11-19 | 1983-11-19 | MATRIX FOR A CATALYTIC REACTOR |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0151229A1 true EP0151229A1 (en) | 1985-08-14 |
EP0151229B1 EP0151229B1 (en) | 1988-06-15 |
Family
ID=6214741
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP84112840A Expired EP0151229B1 (en) | 1983-11-19 | 1984-10-25 | Matrix for catalytic reactor |
Country Status (3)
Country | Link |
---|---|
US (1) | US4647435A (en) |
EP (1) | EP0151229B1 (en) |
DE (2) | DE3341868A1 (en) |
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GB2094658A (en) * | 1981-03-13 | 1982-09-22 | Kernforschungsanlage Juelich | Pollutants filter for exhaust gases |
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EP0238831A1 (en) * | 1986-02-18 | 1987-09-30 | W.R. Grace & Co.-Conn. | Process for making a catalyst core |
EP0244798A1 (en) * | 1986-05-05 | 1987-11-11 | W.R. Grace & Co.-Conn. | Catalytic converter for a diesel engine |
EP0261445A2 (en) * | 1986-09-08 | 1988-03-30 | W.R. Grace & Co.-Conn. | Metal honeycomb catalyst support having a double taper |
EP0261445A3 (en) * | 1986-09-08 | 1988-05-25 | W.R. Grace & Co.-Conn. | Metal honeycomb catalyst support having a double taper |
EP0284891A1 (en) * | 1987-03-23 | 1988-10-05 | W.R. Grace & Co.-Conn. | Optimized stacking of metal foil in catalytic converters |
EP0315047A3 (en) * | 1987-11-03 | 1989-09-20 | Basf Aktiengesellschaft | Monolithic catalyst support |
EP0315047A2 (en) * | 1987-11-03 | 1989-05-10 | BASF Aktiengesellschaft | Monolithic catalyst support |
US4958428A (en) * | 1987-11-13 | 1990-09-25 | Suddeutsche Kuhlerfabrik Julius Fr. Behr Gmbh & Co. Kg | Process and an arrangement for producing a supporting body for a catalytic reactor |
EP0316596A3 (en) * | 1987-11-13 | 1989-07-12 | Emitec Gesellschaft für Emissionstechnologie mbH | Process and apparatus for producing a carrier body for a catalytic reactor |
EP0316596A2 (en) * | 1987-11-13 | 1989-05-24 | Emitec Gesellschaft für Emissionstechnologie mbH | Process and apparatus for producing a carrier body for a catalytic reactor |
EP0317075A1 (en) * | 1987-11-16 | 1989-05-24 | General Motors Corporation | Fabrication and assembly of metal catalytic converter catalyst substrate |
GB2242841A (en) * | 1990-04-13 | 1991-10-16 | Gilardini Spa | Catalytic converter |
GB2242841B (en) * | 1990-04-13 | 1994-03-23 | Gilardini Spa | A catalytic converter for vehicles,particularly motor vehicles |
DE4214340A1 (en) * | 1991-05-09 | 1992-11-12 | Showa Aircraft Ind | Honeycomb structure esp. for exhaust gas catalyst - accommodates differential thermal expansion stresses |
EP0590171A1 (en) * | 1992-09-26 | 1994-04-06 | Showa Aircraft Industry Co., Ltd. | Honeycomb structure for purifying exhaust gas and method of manufacturing same |
EP1977822A2 (en) * | 2007-03-29 | 2008-10-08 | Samsung SDI Co., Ltd. | Reaction vessel and reaction device |
EP1977822A3 (en) * | 2007-03-29 | 2008-12-24 | Samsung SDI Co., Ltd. | Reaction vessel and reaction device |
US7842260B2 (en) | 2007-03-29 | 2010-11-30 | Samsung Sdi Co. Ltd. | Reaction vessel and reaction device |
WO2018177777A1 (en) * | 2017-03-27 | 2018-10-04 | Continental Automotive Gmbh | Method for producing a honeycomb body |
US11131229B2 (en) | 2017-03-27 | 2021-09-28 | Vitesco Technologies GmbH | Method for producing a honeycomb body |
RU2767424C2 (en) * | 2017-03-27 | 2022-03-17 | Кпт Груп Гмбх | Method of making a honeycomb body |
Also Published As
Publication number | Publication date |
---|---|
US4647435A (en) | 1987-03-03 |
DE3341868A1 (en) | 1985-05-30 |
EP0151229B1 (en) | 1988-06-15 |
DE3472133D1 (en) | 1988-07-21 |
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