EP0106840A1 - Flame resistant yarns and fabrics, and furnishings incorporating such fabrics - Google Patents
Flame resistant yarns and fabrics, and furnishings incorporating such fabricsInfo
- Publication number
- EP0106840A1 EP0106840A1 EP19820900974 EP82900974A EP0106840A1 EP 0106840 A1 EP0106840 A1 EP 0106840A1 EP 19820900974 EP19820900974 EP 19820900974 EP 82900974 A EP82900974 A EP 82900974A EP 0106840 A1 EP0106840 A1 EP 0106840A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- core
- covered
- yarn
- fabrics
- fabric
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 57
- 229920000642 polymer Polymers 0.000 claims abstract description 25
- 239000003365 glass fiber Substances 0.000 claims abstract description 18
- 239000000835 fiber Substances 0.000 claims abstract description 16
- 238000000576 coating method Methods 0.000 claims abstract description 15
- 239000011248 coating agent Substances 0.000 claims abstract description 14
- 238000009940 knitting Methods 0.000 claims abstract description 10
- 239000003063 flame retardant Substances 0.000 claims abstract description 9
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920002635 polyurethane Polymers 0.000 claims description 10
- 239000004814 polyurethane Substances 0.000 claims description 10
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 7
- 229920002554 vinyl polymer Polymers 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- 239000010985 leather Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims 1
- 239000004033 plastic Substances 0.000 claims 1
- 239000011152 fibreglass Substances 0.000 abstract description 2
- 239000011521 glass Substances 0.000 description 11
- 230000004888 barrier function Effects 0.000 description 6
- 235000019504 cigarettes Nutrition 0.000 description 6
- 239000002131 composite material Substances 0.000 description 6
- 238000002844 melting Methods 0.000 description 6
- 230000008018 melting Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 2
- 229920005830 Polyurethane Foam Polymers 0.000 description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000005038 ethylene vinyl acetate Substances 0.000 description 2
- 230000000622 irritating effect Effects 0.000 description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 2
- -1 polypropylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 239000011496 polyurethane foam Substances 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920000784 Nomex Polymers 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010616 electrical installation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000010047 integrated composite spinning Methods 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000004763 nomex Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/40—Yarns in which fibres are united by adhesives; Impregnated yarns or threads
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/16—Yarns or threads made from mineral substances
- D02G3/18—Yarns or threads made from mineral substances from glass or the like
- D02G3/182—Yarns or threads made from mineral substances from glass or the like the glass being present only in part of the structure
- D02G3/185—Yarns or threads made from mineral substances from glass or the like the glass being present only in part of the structure in the core
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/443—Heat-resistant, fireproof or flame-retardant yarns or threads
Definitions
- the invention relates to novel yarns having intrinsic flame-resistant properties, to weft-knitted fabrics made from such yarns, and to a novel use of such fabrics in furnishings to impart a good flame resistance thereto.
- a variety of flamer-resistant yarns is known, having inherent flame-resistant properties which vary from yarn to yarn. Some such yarns will burn if the temperature is sufficiently high, some owe their flame-resistance to surface treatment which can wear or wash away, and some are made from fibres which are themselves inherently incapable of supporting combustion.
- the most satisfactory flame-resistant yarns fall within the latter category
- Glass-fibre yarn which has this desirable property of inherent incombustibility, is however basically unsuitable for making up into furnishing fabrics because on the one hand it is brittle and cannot satisfactorily be knitted on a weft knitting machine, and on the other hand it does not handle well and tends to shed short broken filaments or fibrils which are a skin irritant.
- the above two disadvantages have confined the use of glass fibre fabrics to a field well removed from upholstery and-upholstery furnishing fabrics.
- the polyurethane is very inflammable, and is all the more dangerous because while burning it emits large quantities of highly toxic smoke. Many fires start with cigarette ends being dropped on the furniture, melting the outer fabric and igniting the foamed polyurethane. Thus it is not sufficient, as a fire retardant measure, even to cover the foamed polyurethane with a flame-resistant fabric. If that fabric is low-melting, then it will simply melt on the application of heat to expose the inflammable polyurethane foam below.
- This invention provides a novel yarn which can be knitted on a weft knitting machine to a novel fabric having the fire barrier and flame retardant properties needed in upholstered furniture.
- the invention also proposes .a novel way of incorporating such a fabric into upholstered furniture without affecting the appearance, feel or finish of the furniture.
- the novel yarn of the invention is a covered yarn comprising a multifilament glass fibre core covered with a staple fibre adhered to a polymer coating around the core.
- the technology is available for making a coated yarn according to the invention, using a Bobtex ICS (integrated composite spun) machine ("Bobtex" is a Trade Mark).
- the glass fibre core yarn is passed continuously through a solution of the polymer or through the molten polymer, to provide the core with its adhesive surface coating. Subsequent passage of the coated core yarn between opening rollers which rotate to open a sliver of staple yarn enables fibrils of the staple fibre to be adhered to the coating, and the yarn is then advantageously passed through a false twisting device, so as more firmly to anchor to the polymer of the composite yarn.
- the knitted fabric, and the yarn itself can be handled without the same irritant effect on the skin due to broken ends of glass fibres. This lack of irritation is probably due to the action of the polymer coating in retaining any broken ends of glass fibres within the yarn.
- the glass fibre core of the yarn of the invention is inherently flame-resistant and high melting, these same properties are passed to the covered yarn.
- the polymer coating and/or the staple fibre covering also have flame-resistant properties, to improve even further the flame-resistance of the covered yarn.
- suitable polymer coatings include. polypropylene/ethylene-vinyl acetate mixtures, and PVDC or SARAN (Trade Mark) of which the latter two are flame-resistant.
- suitable staple fibres include natural fibres (particularly wool, which is naturally flame-resistant), polyester fibres, SEF acrylic (SEF is a Trade Mark), carbon fibre and NOMEX (Trade Mark) of which the latter three are flame-resistant or self-extinguishing. Best Mode of Carrying Out The Invention
- a fibre and fabric according to the invention were prepared as follows using a commercially available continuous glass filament yarn, namely Owens Corning EC968 (1/0) Z20 679 fibre glass (Trade Mark), which is a 68 tex, Z direction twist, 20 filament yarn.
- the glass fibre yarn was tensioned and passed through a fine tube into an area of molten polymer at a speed of approximately 600 metres per minute.
- the polymer was a compound of 60% ethylene-vinyl acetate, being Imperial Chemical Industries' Evatane (Trade Mark) 28.20 (28% vinyl acetate content; 20 melt flow index) and 40% Polypropylene, Shell Chemicals' SY6100, at a temperature of 230°C.
- Molten polymer was presented to the point of contact with the filament glass by means of an extruder at a constant rate of 16 grams per minute. As the glass filaments pass through the molten polymer the polymer forms a cone around the running glass and is drawn down to form a very fine coating around the glass filament. Whilst the polymer was still in a molten state staple fibres were presented to the molten polymer coating by means of a fibre opening system so that the individual fibres partially penetrated or adhered to the polymer. The combination of glass/polymer/fibre was then passed through a false twist process which further acted to impress the individual fibres into the polymer coating to form a composite yarn. The yarn was allowed to cool and solidify prior to winding on a conventional textile package.
- a subsequent rewinding process was used to lubricate the yarn with a paraffin or silthane wax in the conventional manner before winding onto a conventional textile cone suitable for presentation to a knitting machine.
- the resultant yarn was then knitted without fracture on a conventional knitting machine, for example a conventional single Jersey weft knitting 12 gauge machine. at commercial speeds, to produce a single jersey fabric without filamentation of the glass.
- a conventional knitting machine for example a conventional single Jersey weft knitting 12 gauge machine. at commercial speeds, to produce a single jersey fabric without filamentation of the glass.
- the particular fabric described was manufactured as a reinforcing fabric for a vinyl coating for upholstery, so that should the vinyl be melted by, for example, a cigarette end the fibres and polymer will similarly melt but the glass knitted structure will remain intact to prevent the passage of the lighted cigarette end into the upholstery foam beneath, thereby creating a physical barrier that will not be destroyed below the melting point of the glass.
- Further fabrics of glass composite yarn have been manufactured using different, and inherently flame proof, polymers and fibres that themselves will not ignite or support combustion.
- the invention also provides a fabric knitted from the above coated yarn on a weft knitting machine.
- the fabric may be plain knit, and may be on any gauge of machine suitable for the tex of the yarn produced.
- the resulting fabric has the appearance of stockinette fabric, with good flexibility and stretch characteristics.
- One particularly important feature is the good abrasion resistance, which is many times greater than that of conventional woven glass fibre fabrics and which opens up a wide range of uses for the fabrics of the invention.
- the invention proposes a number of novel and useful applications for such a fabric.
- a first use is as a flame barrier layer in soft furnishings.
- a second is as a base fabric for vinyl and simulated leather upholstery materials.
- a third use is as a cladding to wrap around electrical installations or as a heat insulation bandage for pipework.
- a fourth use is as a reinforcement for tbermoset resin mouldings.
- the article to be upholstered such as a foamed polyurethane cushion is first encased in a fabric according to the invention.
- the polyurethane is stiched completely into a cover of the fabric of the invention.
- the outer cover may be either a flame-resistant fabric or one that burns; the provision of a sublayer of the fabric of the invention provides a flame barrier that effectively isolates the foamed polyurethane which is the most dangerous part of the furniture from the point of view of fire hazard.
- the plain knit fabric of the invention is simply substituted for the stockinette base fabric conventionally used.
- the result is a vinyl sheet with inherent fire-resistant properties.
- the vinyl covering itself might melt or burn away in a fire, the knitted base fabric of the invention will not burn and will maintain its integrity up to the melting point of the glass.
- the fabric of the invention When using the fabric of the invention as a reinforcement for sheets or mouldings, of theremoset resin, conventional moulding techniques should be followed.
- the fabric is much easier to handle than conventional glass fibre matting because on the one hand it does not have the same skin irritant effect and on the other hand its inherent stretch characteristics, resulting from the knitted structure, enable it to be formed into more complex shapes without creasing.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Knitting Of Fabric (AREA)
- Woven Fabrics (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/GB1982/000099 WO1983003434A1 (en) | 1982-03-31 | 1982-03-31 | Flame resistant yarns and fabrics, and furnishings incorporating such fabrics |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0106840A1 true EP0106840A1 (en) | 1984-05-02 |
Family
ID=10527425
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19820900974 Withdrawn EP0106840A1 (en) | 1982-03-31 | 1982-03-31 | Flame resistant yarns and fabrics, and furnishings incorporating such fabrics |
EP83301489A Withdrawn EP0090553A3 (en) | 1982-03-31 | 1983-03-17 | Flame resistant yarns and fabrics |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP83301489A Withdrawn EP0090553A3 (en) | 1982-03-31 | 1983-03-17 | Flame resistant yarns and fabrics |
Country Status (6)
Country | Link |
---|---|
EP (2) | EP0106840A1 (enrdf_load_html_response) |
JP (1) | JPS58186626A (enrdf_load_html_response) |
AU (2) | AU8277882A (enrdf_load_html_response) |
BR (1) | BR8301651A (enrdf_load_html_response) |
GR (1) | GR78803B (enrdf_load_html_response) |
WO (1) | WO1983003434A1 (enrdf_load_html_response) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2183540B (en) * | 1985-12-10 | 1990-01-31 | Christopher Francis Coles | Improvements in or related to fibres |
JPS63196731A (ja) * | 1987-02-04 | 1988-08-15 | 明星工業株式会社 | ヤ−ン及びシ−ト |
US5091243A (en) * | 1989-04-04 | 1992-02-25 | Springs Industries, Inc. | Fire barrier fabric |
WO2001007696A1 (en) * | 1999-07-22 | 2001-02-01 | Donato Galbiati | Yarn containing glass fibre and method of preparation thereof |
FR2834522B1 (fr) * | 2002-01-10 | 2005-05-13 | Schappe Sa | Fil resistant a la coupure, destine notamment a la realisation de vetements de protection |
CN104047085A (zh) * | 2014-07-03 | 2014-09-17 | 旌德南玻新材料有限公司 | 一种阻燃防静电玻璃纤维包芯纱 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1494876A1 (de) * | 1965-05-03 | 1969-05-22 | Kuehn Vierhaus & Cie Ag | Verfahren zur Herstellung von in Geweben oder in Parallelfadenlage verwendbaren Glasfaeden oder -zwirnen und Rovings |
GB1292055A (en) * | 1969-03-11 | 1972-10-11 | Courtaulds Ltd | Novelty textile yarns |
CA942487A (en) * | 1972-11-29 | 1974-02-26 | Emilian Bobkowicz | Aerodynamic spinning of composite yarn |
IT1002124B (it) * | 1973-11-29 | 1976-05-20 | Rimar Spa | Procedimento ed impianto per la sbozzimatura di tessuti |
FR2314958A1 (fr) * | 1975-06-17 | 1977-01-14 | Payen & Cie L | Nouvelle etoffe pour le renforcement des corps en matiere plastique armee |
DE2733454A1 (de) * | 1977-07-25 | 1979-02-08 | Barmag Barmer Maschf | Verfahren zur herstellung eines kernmantelgarns |
CA1108813A (en) * | 1977-11-03 | 1981-09-15 | Andrew J. Bobkowicz | Eva yarn compositions |
DE2848606A1 (de) * | 1978-07-17 | 1980-01-31 | Barmag Barmer Maschf | Verfahren zur herstellung eines kernmantelgarns und spinnvorrichtung zur durchfuehrung des verfahrens |
US4272950A (en) * | 1978-12-07 | 1981-06-16 | Commissariat A L'energie Atomique | Filiform textile material |
FR2494313A1 (fr) * | 1980-11-14 | 1982-05-21 | Brochier Fils Sa J | Tissu pour stores ou similaires et materiau pour son obtention |
-
1982
- 1982-03-31 EP EP19820900974 patent/EP0106840A1/en not_active Withdrawn
- 1982-03-31 WO PCT/GB1982/000099 patent/WO1983003434A1/en unknown
- 1982-03-31 AU AU82778/82A patent/AU8277882A/en not_active Abandoned
-
1983
- 1983-03-17 EP EP83301489A patent/EP0090553A3/en not_active Withdrawn
- 1983-03-25 AU AU12867/83A patent/AU1286783A/en not_active Abandoned
- 1983-03-28 GR GR70908A patent/GR78803B/el unknown
- 1983-03-30 BR BR8301651A patent/BR8301651A/pt unknown
- 1983-03-31 JP JP58056792A patent/JPS58186626A/ja active Pending
Non-Patent Citations (1)
Title |
---|
See references of WO8303434A1 * |
Also Published As
Publication number | Publication date |
---|---|
WO1983003434A1 (en) | 1983-10-13 |
EP0090553A2 (en) | 1983-10-05 |
EP0090553A3 (en) | 1984-02-22 |
JPS58186626A (ja) | 1983-10-31 |
AU8277882A (en) | 1983-10-24 |
BR8301651A (pt) | 1983-12-13 |
GR78803B (enrdf_load_html_response) | 1984-10-02 |
AU1286783A (en) | 1983-10-06 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE FR GB LI LU NL SE |
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STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 19840301 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: BARNES, ALAN |