WO2001007696A1 - Yarn containing glass fibre and method of preparation thereof - Google Patents

Yarn containing glass fibre and method of preparation thereof Download PDF

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Publication number
WO2001007696A1
WO2001007696A1 PCT/IT1999/000231 IT9900231W WO0107696A1 WO 2001007696 A1 WO2001007696 A1 WO 2001007696A1 IT 9900231 W IT9900231 W IT 9900231W WO 0107696 A1 WO0107696 A1 WO 0107696A1
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WO
WIPO (PCT)
Prior art keywords
fibre
yarn
glass
filament
textile
Prior art date
Application number
PCT/IT1999/000231
Other languages
French (fr)
Inventor
Donato Galbiati
Original Assignee
Donato Galbiati
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Donato Galbiati filed Critical Donato Galbiati
Priority to PCT/IT1999/000231 priority Critical patent/WO2001007696A1/en
Priority to AU51926/99A priority patent/AU5192699A/en
Publication of WO2001007696A1 publication Critical patent/WO2001007696A1/en

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Classifications

    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/02Yarns or threads characterised by the material or by the materials from which they are made
    • D02G3/16Yarns or threads made from mineral substances
    • D02G3/18Yarns or threads made from mineral substances from glass or the like
    • D02G3/182Yarns or threads made from mineral substances from glass or the like the glass being present only in part of the structure
    • D02G3/185Yarns or threads made from mineral substances from glass or the like the glass being present only in part of the structure in the core
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02GCRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
    • D02G3/00Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
    • D02G3/22Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
    • D02G3/38Threads in which fibres, filaments, or yarns are wound with other yarns or filaments, e.g. wrap yarns, i.e. strands of filaments or staple fibres are wrapped by a helically wound binder yarn
    • D02G3/385Threads in which fibres, filaments, or yarns are wound with other yarns or filaments, e.g. wrap yarns, i.e. strands of filaments or staple fibres are wrapped by a helically wound binder yarn using hollow spindles, e.g. making coverspun yarns

Definitions

  • the present invention relates to a yarn containing glass fibre.
  • the present invention relates to a yarn of the above-mentioned type suitable for the manufacture of fabrics for clothing, knitwear, furnishings and accessories.
  • the present invention also relates to a method of preparing a yarn of the above-mentioned type.
  • glass fibre is highly non- inflammable, generally inert from a chemical point of view, and has good breaking strength and better impact strength than most natural and artificial textile fibres normally used in the textile field.
  • glass fibre yarns have the serious disadvantage of having a very poor ability to withstand knotting, that is to say that these yarns cannot be knotted by conventional weaving systems without substantial breakage occurring at the knots.
  • glass fibre also has a limited affinity for dyes, that is, it cannot be dyed substantially by any conventional method used for the dying of yarns of natural, artificial and synthetic fibres such as cotton, viscose, polyester, and acrylic yarns, etc.
  • yarns of these glass fibres are not very suitable for the production of fabrics for clothing and their use is in fact limited to the production of glass- reinforced plastics products generally used in building, or of fabrics for technical use.
  • the technical problem upon which the present invention is based is that of providing a yarn containing glass fibre which can be used for the production of fabrics for clothing, knitwear, furnishings and accessories by conventional weaving processes without having the disadvantages mentioned above with reference to the prior art .
  • a yarn comprising a glass- fibre core and a covering of the core constituted by least one filament of a textile fibre.
  • the at least one filament of textile fibre is preferably wound around the glass -fibre core in the yarn according to the invention.
  • the winding may, however, be performed by any conventional method known to an expert in the art such as, for example, doubling, twisting and coiling.
  • the glass fibre has a good ability to withstand knotting to the extent that the yarn can advantageously be subjected to conventional weaving operations without substantial occurrence of breakages at the knots.
  • the ability of the glass fibre to withstand knotting is increased as the thickness of the yarn increases since the space required to close the loop of the knot is larger, thus avoiding sharp bending of the glass fibre and consequent breakage thereof .
  • this number of twists or turns per metre may vary from 10 to 1500 and is preferably within the range of 200-400 turns/metre.
  • the glass fibre may be of any commercially-available count and glass composition.
  • An E-grade glass fibre having a count of from 34 to 136 tex is preferably used.
  • the glass-fibre core in the yarn according to the invention is preferably pre-twisted.
  • a glass fibre classified as EC9-34Z28 that is, an E-grade continuous-filament glass fibre having a filament diameter of 9 microns, a count of 34 tex and a twist equal to 28 turns of Z-twist is particularly preferred.
  • the at least one filament used for covering the glass fibre may be of any commercially-available, natural, artificial, synthetic or mixed textile fibre of any count.
  • filaments of natural textile fibres such as wool and cotton of artificial fibres such as viscose, of synthetic fibres such as nylon and polyester, and of mixed fibres such as, for example polyester/linen, viscose/wool, etc., may be used in the yarn according to the invention.
  • the textile fibres used for covering the glass-fibre core may be already dyed in the colours to be imparted to the yarn or may be used in the raw state, in which case the dying may be performed directly on the yarn on the reel or on the fabric produced from the yarn by dying the fabric in roll or garment form.
  • the yarn according to the invention is advantageously distinguished by being a fancy yarn in which the colour of the textile fibre of the covering, once dyed, is mirrored in the glass fibre, giving rise to a reflecting effect which produces a particular sheen.
  • the covering of the yarn is constituted by two filaments of a textile fibre twisted with a core of glass fibre with the same direction of twisting.
  • the covering of the yarn is constituted by two filaments coiled around a glass-fibre core, one of the filaments of textile fibre having an "S"-coil and the other having a "Z"-coil.
  • the order and type of twisting may be varied in dependence on the characteristics to be imparted to the yarn.
  • the main advantage of the yarn according to the invention is that the glass fibre is in fact introduced into some textile processes which cannot be performed with pure glass filaments, for example, printing, dying, raising of the thread, etc.
  • the yarn according to the invention can advantageously be processed in many textile processes such as weaving, knitting, dyeing, printing, coating, resin-finishing, etc., and can easily be dyed by conventional dyeing methods.
  • the yarn according to the invention can advantageously also be used for the production of fireproof fabrics since glass has good fire resistance.
  • the fireproof characteristics of textile fibres such as, for example, Trevira CS polyester can thus be improved by the addition of the glass filament in the yarn according to the invention.
  • the present invention also relates to a method of preparing the above-mentioned yarn, characterized in that at least one filament of a textile fibre is wound around a filament of glass fibre.
  • the number of twists or turns per metre imparted during the winding may vary from 10 to 1500 and is preferably within the range of 200-400.
  • the winding is performed by twisting two textile-fibre filaments with one glass-fibre filament with the same direction of twist.
  • the winding is performed by coiling of two textile fibre filaments around the glass fibre, one of the filaments having an "S"-coil and the other a "Z"-coil.
  • the twisting or coiling may be performed by any conventional apparatus known to an expert in the art for the production of conventional yarns.
  • the winding of two or more textile fibre filaments around or with the glass fibre may be performed simultaneously or in several steps .
  • the characteristics and advantages of the yarn and of the invention will become clear from the following detailed description of an embodiment of the method of the invention and of some examples illustrative of the preparation of yarns according to the invention, the description being given below by way of non-limiting example with reference to the appended drawing.
  • the drawing shows schematically hollow-spindle twisting apparatus suitable for implementing the method according to the invention.
  • hollow-spindle twisting apparatus comprises a supply system 2 on which a roll 3 of a glass-fibre filament 4 is mounted.
  • the glass- fibre filament 4 is unwound continuously from the roll 3 and is introduced by means of the supply system 2 and a pulley 5 into the hole in a first hollow spindle 6.
  • the filament 4, as well as the final yarn, are kept substantially taut by a wholly conventional yarn-drawing system 7.
  • a first filament 8 of a textile fibre is coiled around the filament 4 in conventional manner and with an "S" twist, thus producing a semi-finished product.
  • This semi-finished product is then introduced into a second hollow spindle 10 and, after it has passed through this spindle, a second filament 11 coming from a reel 12 is coiled around it with a "Z" -twist, thus producing a yarn 13 according to the invention.
  • the coiling of the filament 11 is performed in the opposite direction to that of the previous "S"-coil.
  • the yarn 13 After passing through the drawing rollers 7, the yarn 13 is then wound on a reel 14.
  • nylon filaments were coiled with an "S"- coil and the other was coiled with a "Z" -coil; in both cases a twist of.250 turns/metre was imparted.
  • the yarn thus produced had a final count of 22,400 Nm and a composition of 77% by weight of glass and 23% of nylon.
  • the yarn was subjected to conventional weaving operations, during which the glass fibre was shown to have a good ability to withstand knotting since no substantial breakages occurred at the knots.
  • a yarn was prepared with the apparatus of Example 1 by coiling of two raw wool filaments, both having a count of 32000 Nm, around a glass filament having a count of 34 tex - 29000 Nm.
  • One of the wool filaments was coiled with an "S"- coil and the other was coiled with a "Z"-coil; in both cases a twist of 250 turns/metre was imparted.
  • the yarn thus produced had a final count of 10,500 Nm and a composition of 40% by weight of glass and 60% of wool .
  • the yarn was subjected to conventional weaving operations, during which the glass fibre was shown to have an excellent ability to withstand knotting since no substantial breakages occurred at the knots.
  • Trevira CS polyester filaments was coiled with an "S"-coil and the other was coiled with a "Z"- coil; in both cases a twist of 250 turns/metre was imparted.
  • the dyed yarn thus produced had a final count of 13,200 Nm and a composition of 49% by weight of glass and 51% by weight of polyester.
  • the yarn was subjected to conventional weaving operations to produce a fireproof jacquard fabric, during which the glass fibre was shown to have an excellent ability to withstand knotting since no substantial breakages of this fibre occurred at the knots.

Abstract

A yarn comprising a glass-fibre core and a covering of the core constituted by at least one filament of a textile fibre is described. The yarn can preferably be produced by winding at least one filament of textile fibre around a filament of glass fibre by twisting or coiling.

Description

YARN CONTAINING GLASS FIBRE AND METHOD OF PREPARATION
THEREOF
DESCRIPTION
In general, the present invention relates to a yarn containing glass fibre.
In particular, the present invention relates to a yarn of the above-mentioned type suitable for the manufacture of fabrics for clothing, knitwear, furnishings and accessories.
The present invention also relates to a method of preparing a yarn of the above-mentioned type.
It is well known that, in the textile and fashion industry, ever greater and constant efforts are made to find new yarns and fabrics for the production of which fibres of new materials are often tested.
It is also known that glass fibre is highly non- inflammable, generally inert from a chemical point of view, and has good breaking strength and better impact strength than most natural and artificial textile fibres normally used in the textile field.
In spite of the good textile properties mentioned above, glass fibre yarns have the serious disadvantage of having a very poor ability to withstand knotting, that is to say that these yarns cannot be knotted by conventional weaving systems without substantial breakage occurring at the knots.
Moreover, glass fibre also has a limited affinity for dyes, that is, it cannot be dyed substantially by any conventional method used for the dying of yarns of natural, artificial and synthetic fibres such as cotton, viscose, polyester, and acrylic yarns, etc.
In the prior art, attempts have been made to improve the processability characteristics of glass intended for the production of fibres or for other applications by treating the glass with suitable binders such as, for example, cellulose acetate and/or sizing agents.
However, yarns of these glass fibres are not very suitable for the production of fabrics for clothing and their use is in fact limited to the production of glass- reinforced plastics products generally used in building, or of fabrics for technical use.
The technical problem upon which the present invention is based is that of providing a yarn containing glass fibre which can be used for the production of fabrics for clothing, knitwear, furnishings and accessories by conventional weaving processes without having the disadvantages mentioned above with reference to the prior art .
This problem is solved by a yarn comprising a glass- fibre core and a covering of the core constituted by least one filament of a textile fibre.
The at least one filament of textile fibre is preferably wound around the glass -fibre core in the yarn according to the invention.
The winding may, however, be performed by any conventional method known to an expert in the art such as, for example, doubling, twisting and coiling.
It has surprisingly been found that, in the yarn according to the invention, the glass fibre has a good ability to withstand knotting to the extent that the yarn can advantageously be subjected to conventional weaving operations without substantial occurrence of breakages at the knots.
In the yarn according to the invention, the ability of the glass fibre to withstand knotting is increased as the thickness of the yarn increases since the space required to close the loop of the knot is larger, thus avoiding sharp bending of the glass fibre and consequent breakage thereof .
However, this ability to withstand knotting is further increased in proportion to the number of turns of twisting per metre imparted during the winding of the textile fibre on the glass fibre.
In the yarn according to the invention, this number of twists or turns per metre may vary from 10 to 1500 and is preferably within the range of 200-400 turns/metre.
The yarn according to the invention may be produced with any count and the count is preferably within the range of 2000-40000 Nm (Nm = ratio of metres per kilogram = m/kg) .
The glass fibre may be of any commercially-available count and glass composition. An E-grade glass fibre having a count of from 34 to 136 tex is preferably used.
The glass-fibre core in the yarn according to the invention is preferably pre-twisted.
A glass fibre classified as EC9-34Z28, that is, an E-grade continuous-filament glass fibre having a filament diameter of 9 microns, a count of 34 tex and a twist equal to 28 turns of Z-twist is particularly preferred.
In the yarn according to the invention, the at least one filament used for covering the glass fibre may be of any commercially-available, natural, artificial, synthetic or mixed textile fibre of any count.
For example, filaments of natural textile fibres such as wool and cotton, of artificial fibres such as viscose, of synthetic fibres such as nylon and polyester, and of mixed fibres such as, for example polyester/linen, viscose/wool, etc., may be used in the yarn according to the invention.
The textile fibres used for covering the glass-fibre core may be already dyed in the colours to be imparted to the yarn or may be used in the raw state, in which case the dying may be performed directly on the yarn on the reel or on the fabric produced from the yarn by dying the fabric in roll or garment form.
In both cases, the yarn according to the invention is advantageously distinguished by being a fancy yarn in which the colour of the textile fibre of the covering, once dyed, is mirrored in the glass fibre, giving rise to a reflecting effect which produces a particular sheen.
According to a preferred embodiment of the invention, the covering of the yarn is constituted by two filaments of a textile fibre twisted with a core of glass fibre with the same direction of twisting.
According to a particularly preferred embodiment of the invention, the covering of the yarn is constituted by two filaments coiled around a glass-fibre core, one of the filaments of textile fibre having an "S"-coil and the other having a "Z"-coil.
Naturally, the order and type of twisting may be varied in dependence on the characteristics to be imparted to the yarn.
The main advantage of the yarn according to the invention is that the glass fibre is in fact introduced into some textile processes which cannot be performed with pure glass filaments, for example, printing, dying, raising of the thread, etc.
The yarn according to the invention can advantageously be processed in many textile processes such as weaving, knitting, dyeing, printing, coating, resin-finishing, etc., and can easily be dyed by conventional dyeing methods.
Moreover, it is of good quality from an aesthetic point of view and is particularly suitable for the production of clothing textiles in accordance with new fashion trends .
The yarn according to the invention can advantageously also be used for the production of fireproof fabrics since glass has good fire resistance.
The fireproof characteristics of textile fibres such as, for example, Trevira CS polyester can thus be improved by the addition of the glass filament in the yarn according to the invention.
The present invention also relates to a method of preparing the above-mentioned yarn, characterized in that at least one filament of a textile fibre is wound around a filament of glass fibre.
In the method according to the invention, the number of twists or turns per metre imparted during the winding may vary from 10 to 1500 and is preferably within the range of 200-400.
According to a preferred embodiment of the invention, the winding is performed by twisting two textile-fibre filaments with one glass-fibre filament with the same direction of twist.
According to a particularly preferred embodiment, the winding is performed by coiling of two textile fibre filaments around the glass fibre, one of the filaments having an "S"-coil and the other a "Z"-coil.
The twisting or coiling may be performed by any conventional apparatus known to an expert in the art for the production of conventional yarns.
In particular, according to the apparatus used, the winding of two or more textile fibre filaments around or with the glass fibre may be performed simultaneously or in several steps . The characteristics and advantages of the yarn and of the invention will become clear from the following detailed description of an embodiment of the method of the invention and of some examples illustrative of the preparation of yarns according to the invention, the description being given below by way of non-limiting example with reference to the appended drawing.
The drawing shows schematically hollow-spindle twisting apparatus suitable for implementing the method according to the invention.
With reference to the drawing, hollow-spindle twisting apparatus, generally indicated 1, comprises a supply system 2 on which a roll 3 of a glass-fibre filament 4 is mounted.
The glass- fibre filament 4 is unwound continuously from the roll 3 and is introduced by means of the supply system 2 and a pulley 5 into the hole in a first hollow spindle 6.
The filament 4, as well as the final yarn, are kept substantially taut by a wholly conventional yarn-drawing system 7.
Once the filament 4 has emerged from the hollow spindle 6, a first filament 8 of a textile fibre, unwound continuously from a reel 9, is coiled around the filament 4 in conventional manner and with an "S" twist, thus producing a semi-finished product.
This semi-finished product is then introduced into a second hollow spindle 10 and, after it has passed through this spindle, a second filament 11 coming from a reel 12 is coiled around it with a "Z" -twist, thus producing a yarn 13 according to the invention.
As is clear from the drawing, the coiling of the filament 11 is performed in the opposite direction to that of the previous "S"-coil.
After passing through the drawing rollers 7, the yarn 13 is then wound on a reel 14.
In order to satisfy further and contingent requirements, an expert in the art may apply to the above-mentioned method many further modifications and variations all of which, however, are included within the scope of protection defined by the appended claims.
EXAMPLE 1
A yarn was prepared with apparatus of the type described above by coiling two raw (that is, not dyed) nylon filaments both having a count of 44 dtex = 230000 Nm around a glass filament having a count of 34 tex = 29000 Nm.
One of the nylon filaments was coiled with an "S"- coil and the other was coiled with a "Z" -coil; in both cases a twist of.250 turns/metre was imparted.
The yarn thus produced had a final count of 22,400 Nm and a composition of 77% by weight of glass and 23% of nylon.
The yarn was subjected to conventional weaving operations, during which the glass fibre was shown to have a good ability to withstand knotting since no substantial breakages occurred at the knots.
Finally, the fabric produced with the above- mentioned yarn could easily be dyed in conventional manner.
EXAMPLE 2
A yarn was prepared with the apparatus of Example 1 by coiling of two raw wool filaments, both having a count of 32000 Nm, around a glass filament having a count of 34 tex - 29000 Nm.
One of the wool filaments was coiled with an "S"- coil and the other was coiled with a "Z"-coil; in both cases a twist of 250 turns/metre was imparted.
The yarn thus produced had a final count of 10,500 Nm and a composition of 40% by weight of glass and 60% of wool .
The yarn was subjected to conventional weaving operations, during which the glass fibre was shown to have an excellent ability to withstand knotting since no substantial breakages occurred at the knots.
Finally, the fabric produced with the yarn could easily be dyed in conventional manner.
EXAMPLE 3
A fireproof yarn was prepared with the apparatus of Example 1 by coiling of two dyed Trevira CS polyester filaments, both having a count of 167 dtex = 60000 Nm, around a glass filament having a count of 34 tex = 29000 Nm.
One of the Trevira CS polyester filaments was coiled with an "S"-coil and the other was coiled with a "Z"- coil; in both cases a twist of 250 turns/metre was imparted.
The dyed yarn thus produced had a final count of 13,200 Nm and a composition of 49% by weight of glass and 51% by weight of polyester.
The yarn was subjected to conventional weaving operations to produce a fireproof jacquard fabric, during which the glass fibre was shown to have an excellent ability to withstand knotting since no substantial breakages of this fibre occurred at the knots.

Claims

1. A yarn comprising a glass-fibre core and a covering of the core constituted by at least one filament of a textile fibre.
2. A yarn according to Claim 1, in which the at least one filament of textile fibre is wound around the glass-fibre core.
3. A yarn according to Claim 2 , in which the covering is constituted by two filaments of the textile fibre twisted with the glass-fibre core with the same direction of twisting.
4. A yarn according to Claim 2, in which the covering is constituted by two filaments of the textile fibre coiled around the glass-fibre core, one of the two filaments being coiled with an "S"-coil and the other with a "Z"-coil.
5. A yarn according to any one of the preceding claims, in which the number of twists or turns of twisting per metre of yarn varies from 10 to 1500.
6. A yarn according to Claim 5, in which the number of twisting turns per metre is within the range of 200- 400.
7. A yarn according to any one of the preceding claims, in which the glass fibre is an E-grade glass fibre and has a count of between 34 and 136 tex.
8. A yarn according to any one of the preceding claims, characterized in that it has a final count of from 2000 Nm to 40000 Nm.
9. A method of preparing a yarn according to any one of the preceding claims, characterized in that at least one filament of a textile fibre is wound around a glass - fibre filament.
10. A method according to Claim 9, in which the winding is performed by twisting two filaments of the textile fibre with the glass-fibre filament with the same direction of twisting.
11. A method according to Claim 9, in which the winding is performed by coiling of two filaments of textile fibre around the glass-fibre filament, one of the filaments of textile fibre being coiled with an "S"-coil and the other with a "Z"-coil.
12. A method according to any one of Claims 9 to 11, in which the number of twisting turns per metre of yarn is between 10 and 1500.
13. A method according to Claim 12, in which the number of twisting turns is 200-400.
PCT/IT1999/000231 1999-07-22 1999-07-22 Yarn containing glass fibre and method of preparation thereof WO2001007696A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
PCT/IT1999/000231 WO2001007696A1 (en) 1999-07-22 1999-07-22 Yarn containing glass fibre and method of preparation thereof
AU51926/99A AU5192699A (en) 1999-07-22 1999-07-22 Yarn containing glass fibre and method of preparation thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/IT1999/000231 WO2001007696A1 (en) 1999-07-22 1999-07-22 Yarn containing glass fibre and method of preparation thereof

Publications (1)

Publication Number Publication Date
WO2001007696A1 true WO2001007696A1 (en) 2001-02-01

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Country Status (2)

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AU (1) AU5192699A (en)
WO (1) WO2001007696A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107460585A (en) * 2017-09-01 2017-12-12 西安工程大学 Based on hollow ingot spinning without weak section flame and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH601526A5 (en) * 1976-06-15 1978-07-14 Iws Nominee Co Ltd Composite yarn for flame-resistant textile fabric
EP0090553A2 (en) * 1982-03-31 1983-10-05 Remora Textiles Limited Flame resistant yarns and fabrics
US5177948A (en) * 1989-06-13 1993-01-12 Kolmes Nathaniel H Yarn and glove

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH601526A5 (en) * 1976-06-15 1978-07-14 Iws Nominee Co Ltd Composite yarn for flame-resistant textile fabric
EP0090553A2 (en) * 1982-03-31 1983-10-05 Remora Textiles Limited Flame resistant yarns and fabrics
US5177948A (en) * 1989-06-13 1993-01-12 Kolmes Nathaniel H Yarn and glove
US5177948B1 (en) * 1989-06-13 1995-04-18 Nathaniel H Kolmes Yarn and glove

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107460585A (en) * 2017-09-01 2017-12-12 西安工程大学 Based on hollow ingot spinning without weak section flame and preparation method thereof
CN107460585B (en) * 2017-09-01 2019-10-25 西安工程大学 Based on hollow ingot spinning without weak section flame and preparation method thereof

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