EP0078401A1 - Marqueur antivol amorphe - Google Patents
Marqueur antivol amorphe Download PDFInfo
- Publication number
- EP0078401A1 EP0078401A1 EP82108920A EP82108920A EP0078401A1 EP 0078401 A1 EP0078401 A1 EP 0078401A1 EP 82108920 A EP82108920 A EP 82108920A EP 82108920 A EP82108920 A EP 82108920A EP 0078401 A1 EP0078401 A1 EP 0078401A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- atom
- ranges
- marker
- interrogation zone
- magnetic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- G—PHYSICS
- G08—SIGNALLING
- G08B—SIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
- G08B13/00—Burglar, theft or intruder alarms
- G08B13/22—Electrical actuation
- G08B13/24—Electrical actuation by interference with electromagnetic field distribution
- G08B13/2402—Electronic Article Surveillance [EAS], i.e. systems using tags for detecting removal of a tagged item from a secure area, e.g. tags for detecting shoplifting
- G08B13/2405—Electronic Article Surveillance [EAS], i.e. systems using tags for detecting removal of a tagged item from a secure area, e.g. tags for detecting shoplifting characterised by the tag technology used
- G08B13/2408—Electronic Article Surveillance [EAS], i.e. systems using tags for detecting removal of a tagged item from a secure area, e.g. tags for detecting shoplifting characterised by the tag technology used using ferromagnetic tags
- G08B13/2411—Tag deactivation
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C45/00—Amorphous alloys
- C22C45/02—Amorphous alloys with iron as the major constituent
-
- G—PHYSICS
- G08—SIGNALLING
- G08B—SIGNALLING OR CALLING SYSTEMS; ORDER TELEGRAPHS; ALARM SYSTEMS
- G08B13/00—Burglar, theft or intruder alarms
- G08B13/22—Electrical actuation
- G08B13/24—Electrical actuation by interference with electromagnetic field distribution
- G08B13/2402—Electronic Article Surveillance [EAS], i.e. systems using tags for detecting removal of a tagged item from a secure area, e.g. tags for detecting shoplifting
- G08B13/2428—Tag details
- G08B13/2437—Tag layered structure, processes for making layered tags
- G08B13/2442—Tag materials and material properties thereof, e.g. magnetic material details
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/147—Alloys characterised by their composition
- H01F1/153—Amorphous metallic alloys, e.g. glassy metals
- H01F1/15308—Amorphous metallic alloys, e.g. glassy metals based on Fe/Ni
Definitions
- This invention relates to antipilferage systems and markers for use therein. More particularly, the invention provides ductile, amorphous metal markers that enchance the sensitivity and reliability of the antipilferage system.
- the markers contain lower proportions of costly and stategic metals.
- Systems employed to prevent theft of articles generally comprise a marker element secured to an object to be detected and instruments adapted to sense a signal produced by the marker upon passage thereof through an interrogation zone.
- the invention provides an amorphous ferromagnetic metal marker capable of producing identifying signal characteristics in the presence of an applied magnetic field.
- the marker comprises an elongated, ductile strip of amorphous ferromagnetic material having a composition consisting essentially of the formula FeacrbccPdMOeCUfBgSih where "a” ranges from about 63-81 atom %, "b” ranges from about 0-10 atom %, “c” ranges from about 11-16 atom %, “d” ranges from about 4-10 atom %, “e” ranges from about 0-2 atom %, “f” ranges from about 0-1 atom %, “g” ranges from about 0-4 atom % and “i” ranges from about 0-2 atom %, with the proviso that the sum (c+d+g+h) ranges from 19-24 atom % and the fraction [c/(c+d+g+h)] is less than about 0.
- the marker is capable of producing magnetic fields at frequencies which are harmonics of the frequency of an incident field. Such frequencies have selected tones that provide the marker with signal identity.
- a detecting means is arranged to detect magnetic field variations at selected tones of the harmonics produced in the vicinity of the interrogation zone by the presence of the marker therewithin.
- the marker retains its signal identity after being flexed or bent. As a result, the theft detection system is more reliable in operation than system wherein signal degradation is effected by bending or flexing of the marker. Further, the marker contains no costly and strategic metals such as nickel or cobalt.
- FIG. 1 and 2 of the drawings there is shown a magnetic theft detection system 10 responsive to the presence of an article within an interrogation zone.
- the system 10 has means for defining an interrogation zone 12.
- a field generating means 14 is provided for generating a magnetic field within the interrogation zone 12.
- a marker 16 is secured to an article 19 appointed for passage through the interrogation zone 12.
- the marker comprises an elongated, ductile strip 18 of amorphous, ferromagnetic metal having a composition consisting essentially of the formula Fe a Cr b C c P d M Oe CU f BgSi h where "a” ranges from about 63-81 atom %, "b” ranges from about 0-10 atom %, “c” ranges from about 11-16 atom %, “d” ranges from about 4-10 atom %, “e” ranges from about 0-2 atom %, “f” ranges from about 0-1 atom %, “g” ranges from about 0-4 atom % and “i” ranges from about 0-2 atom %, with the proviso that the sum (c+d+g+h) ranges from 19-24 atom % and the fraction [c/(c+d+g+h)] is less than about 0.84.
- the marker is capable of producing magnetic fields at frequencies which are harmonics of the frequency of an incident field. Such frequencies have selected tones that provide the marker with signal identity.
- a detecting means 20 is arranged to detect magnetic field variations at selected tones of the harmonics produced in the vicinity of the interrogation zone 12 by the presence of marker 16 therewithin.
- the system 10 includes a pair of coil units 22, 24 disposed on opposing sides of a path leading to the exit 26 of a store.
- Detection circuitry including an alarm 28, is housed within a cabinet 30 located near the exit 26.
- Articles of merchandise 19 such as wearing apparel, appliances, books and the like are displayed within the store.
- Each of the articles 19 has secured thereto a marker 16 constructed in accordance with the present invention.
- the marker 16 includes an elongated, ductile amorphous ferromagnetic strip 18 that is normally in an activated mode. When marker 16 is in the activated mode, placement of an article 19 between coil units 22 and 24 of interrogation zone 12 will cause an alarm to be emitted from cabinet 30. In this manner, the system 10 prevents unauthorized removal of articles of merchandise 19 from the store.
- a deactivator system 38 Disposed on a checkout counter near cash register 36 is a deactivator system 38. The latter is electrically connected to cash register 36 by wire 40. Articles 19 that have been properly paid for are placed within an aperture 42 of deactivation system 38, whereupon a magnetic field similar to that produced by coil units 22 and 24 of interrogation zone 12 is applied to marker 16.
- the deactivation system 38 has detection circuitry adapted to activate a gaussing circuit in response to harmonic signals generated by marker 16. The gaussing circuit applies to marker 16 a high magnetic field that places the marker 16 in a deactivated mode. The article 19 carrying the deactivated marker 16 may then be carried through interrogation zone 12 without triggering the alarm 28 in cabinet 30.
- the theft detection system circuitry with which the marker 16 is associated can be any system capable of (1) generating within an interrogation zone an incident magnetic field, and (2) detecting magnetic field variations at selected harmonic frequencies produced in the vicinity of the interrogation zone by the presence of the marker therewithin.
- Such systems typically include means for transmitting a varying electrical current from an oscillator and amplifier through conductive coils that form a frame antenna capable of developing a varying magnetic field.
- An example of such antenna arrangement is disclosed in French Patent 763,681, published May 4, 1934, which description is incorporated herein by reference thereto.
- an amorphous ferromagnetic metal marker is provided.
- the marker is in the form of an elongated, ductile strip having a composition consisting essentially of the formula FeacrbccPdMOeCUfBgSih where "a” ranges from about 63-81 atom %, "b” ranges from about 0-10 atom %,”c” ranges from about 11-16 atom %, “d” ranges from about 4-10 atom %, "e” ranges from about 0-2 atom %, “f” ranges from about 0-1 atom %, “g” ranges from about 0-4 atom % and “i” ranges from about 0-2 atom %, with the proviso that the sum (c+d+g+h) ranges from 19-24 atom % and the fraction [c/(c+d+g+h)] is less than about 0.84.
- the marker is capable of producing magnetic fields at frequencies which are harmonics of the frequency of an incident field.
- amorphous ferromagnetic marker compositions within the scope of the invention are set forth in Table I below:
- the amorphous ferromagnetic metal marker of the invention is prepared by cooling a melt of the desired composition at a rate of at least about 10 5 °C/ sec, employing metal alloy quenching techniques well-known to the glassy metal alloy art; see, e.g., U.S. Patent 3,856,513 to Chen et al.
- the purity of all compositions is that found in normal commercial practice.
- a variety of techniques are available for fabricating continuous ribbon, wire, sheet, etc. Typically, a particular composition is selected, powders or granules of the requisite elements in the desired portions are melted and homogenized, and the molten alloy is rapidly quenched on a chill surface, such as a rapidly rotating metal cylinder, a rapidly moving metal belt or the like.
- the metastable material may be glassy, in which case there is no long-range order.
- X-ray diffraction patterns of glassy metal alloys show only a diffuse halo, similar to that observed for inorganic oxide glasses.
- Such glassy alloys must be at least 50% glassy to be sufficiently ductile to permit subsequent handling, such as stamping complex marker shapes from ribbons of the alloys without degradation of the marker's signal identity.
- the glassy metal marker must be at least 80% glassy to attain superior ductility.
- the metastable phase may also be a solid solution of the constituent elements.
- such metastable, solid solution phases are not ordinarily produced under conventional processing techniques employed in the art of fabricating crystalline alloys.
- X-ray diffraction patterns of the solid solution alloys show the sharp diffraction peaks characteristic of crystalline alloys, with some broadening of the peaks due to desired fine-grained size of crystallites.
- Such metastable materials are also ductile when produced under the conditions described above.
- the marker of the invention is advantageously produced in foil (or ribbon) form, and may be used in theft detection applications as cast, whether the material is glassy or a solid solution.
- foils of glassy metal alloys may be heat treated to obtain a crystallilne phase, preferably fine-grained, in order to promote longer die life when stamping of complex marker shapes is contemplated.
- Markers having partially crystalline, partially glassy phases are particularly suited to be desensitized by a deactivation system 38 of the type shown in Fig. 2.
- Totally amorphous ferromagnetic marker strips can be provided with one or more small magnetizable elements 44. Such elements 44 are made of crystalline regions of ferromagnetic material having a higher coercivity than that possessed by the strip 18.
- totally amorphous marker strip can be spot welded, heat treated with coherent or incoherent radiation, charged particle beams, directed flames, heated wires or the like to provide the strip with magnetizable elements 44 that are integral therewith.
- elements 44 can be integrated with strip 18 during casting thereof by selectively altering the cooling rate of the strip 18. Cooling rate alteration can be effected by quenching the alloy on a chill surface that is slotted or contains heated portions adapted to allow partial crystallazation during quenching. Alternatively, alloys can be selected that partially crystallize during casting. The ribbon thickness can be varied during casting to produce crystalline regions over a portion of strip 18.
- the elements 44 Upon permanent magnetization of the elements 44, their permeability is substantially decreased.
- the magnetic fields associated with such magnetization bias the strip 18 and thereby alter its response to the magnetic field extant in the interrogation zone 12.
- the strip 18 In the activated mode, the strip 18 is unbiased with the result that the high permeability state of strip 18 has a pronounced effect upon the magnetic field applied thereto by field generating means 14.
- the marker 16 is deactivated by magnetizing elements 44 to decrease the effective permeability of the strip 18.
- the reduction in permeability significantly decreases the effect of the marker 16 on the magnetic field, whereby the marker 16 loses its signal identity (e.g., marker 16 is less able to distort or reshape the field). Under these conditions, the protected articles 19 can pass through interrogation zone 12 without triggering alarm 28.
- the amorphous ferromagnetic marker of the present invention is exceedingly ductile.
- ductile is meant that the strip 18 can be bent to a bend diameter less than 35 mils.
- the marker retains its signal identity despite being flexed or bent during (1) manufacture (e.g., cutting, stamping or otherwise forming the strip 18 into the desired length and configuration) and, optionally, applying hard magnetic chips thereto to produce an on/off marker, (2) application of the marker 16 to the protected articles 19, (3) handling of the articles 19 by employees and customers and (4) attempts at signal destruction designed to circumvent the system 10.
- Generation of harmonics by marker 16 is caused by nonlinear magnetization response of the marker 16 to an incident magnetic field.
- High permeability - low coercive force material such as Permalloy, Supermalloy and the like produce such nonlinear response in an amplitude region of the incident field wherein the magnetic field strength is sufficiently great to saturate the material.
- Amorphous ferromagnetic materials have nonlinear magnetization response over a significantly greater amplitude region ranging from relatively low magnetic fields to higher magnetic field values approaching saturation. The additional amplitude region of nonlinear magnetization response possessed by amorphous ferromagnetic materials increases the magnitude of harmonics generated by, and hence the signal strength of, marker 16. This feature permits use of lower magnetic fields, eliminates false alarms and improves detection reliability of the system 10.
- elongated strips composed of ferromagnetic amorphous and crystalline materials were prepared. The strips were evaluated to determine their signal strength before and after flexure using a harmonic signal amplitute test apparatus 100.
- a schematic electrical diagram of the test apparatus 100 is shown in Fig. 5.
- the apparatus 100 had an oscillator generator 101 for generating a sinusoidal signal at a frequency of 2.5 KHz.
- Oscillator generator 101 drove a power amplifier 102 connected in series with an applied field coil 104 through a sampling resistor 106.
- the current output of amplifier 102 was adjusted to produce a magnetic field of 1.0 Oersted within applied field coil 104.
- a dc 0.41 Oersted field was used to bias the sample and the coil 104 were oriented perpendicular to the earth's magnetic field.
- Applied field coil 104 was constructed of 121 twins of closely wrapped, #14 AWG. insulated copper wire. Coil 104 had an inside diameter of 5.1 cm and was 45.7 cm long.
- Pick up coil 112 was constructed of 540 turns of closely wrapped #26 AWG. insulated copper wire. The coil 112 had an inside diameter of 1.9 cm and was 7.6 cm long.
- a sample marker 110 was placed in pick-up coil 112, which is coaxially disposed inside the applied field coil 104.
- the voltage generated by the pick-up coil 112 was fed into tunable wave analyzer 114 comprised of a frequency selectable band pass filter and a-c voltmeter.
- the band pass filter was tuned to 15 KHz, an integer multiple of the drive frequency generated by the oscillator generator 101.
- the amplitude of harmonic response by the sample marker 110 was measured with the wave analyzer 114 and indicated by an analogue display.
- a dual channel oscilloscope 116 was also used to graphically display the applied and reradiated signal.
- the harmonic generation test apparatus 100 was used to test marker samples composed of material identified in Table IV. Each of the samples, numbered 1-15 in Table IV was 10.2 cm long. The samples were placed inside pickup coil 112 and applied field coil 104 and the amplitude of harmonic response for each sample 110 was observed.
- the samples composed of the amorphous ferromagnetic materials of this invention showed equal or improved harmonic amplitude per unit volume of sample compared to the control samples.
- sample No. 2 of Table IV of composition Fe 73.25, Cr 6, Mo 0.25, C 15, P 5, B 0.5 showed a harmonic signal of 43.0 megavolts per cubic meter (MV/m 3 ) of sample compound to 12.6 to 21.8 MV/m 3 for the control samples.
- the alloys of this invention contained no content of strategic and costly metals such as nickel or cobalt other than in concentrations which normally would be present as impurities.
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- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Electromagnetism (AREA)
- Chemical & Material Sciences (AREA)
- General Physics & Mathematics (AREA)
- Computer Security & Cryptography (AREA)
- Automation & Control Theory (AREA)
- Mechanical Engineering (AREA)
- Dispersion Chemistry (AREA)
- Power Engineering (AREA)
- Organic Chemistry (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Burglar Alarm Systems (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US31762581A | 1981-11-02 | 1981-11-02 | |
US317625 | 1981-11-02 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0078401A1 true EP0078401A1 (fr) | 1983-05-11 |
EP0078401B1 EP0078401B1 (fr) | 1985-08-07 |
Family
ID=23234528
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP82108920A Expired EP0078401B1 (fr) | 1981-11-02 | 1982-10-11 | Marqueur antivol amorphe |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0078401B1 (fr) |
JP (1) | JPS5886694A (fr) |
CA (1) | CA1196986A (fr) |
DE (1) | DE3265257D1 (fr) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0226812A2 (fr) * | 1985-12-21 | 1987-07-01 | Vacuumschmelze GmbH | Etiquette désactivalbe de sécurité pour système de sécurité anti-vol |
WO1988001427A1 (fr) * | 1986-08-14 | 1988-02-25 | Tyren Carl | Procede de detection d'objets a distance |
EP0295028A1 (fr) * | 1987-06-08 | 1988-12-14 | Esselte Meto International GmbH | Dispositifs magnétiques |
EP0446910A1 (fr) * | 1990-03-13 | 1991-09-18 | Knogo Corporation | Dispositif antivol à marqueur à bande magnétique et procédé de fabrication de celui-ci |
EP0451812A2 (fr) * | 1990-04-10 | 1991-10-16 | Knogo Corporation | Marqueur magnétique dans un système de surveillance d'articles et procédé pour produire dudit marqueur |
US5304983A (en) * | 1991-12-04 | 1994-04-19 | Knogo Corporation | Multiple pulse responder and detection system and method of making and using same |
WO1994009172A1 (fr) * | 1992-10-16 | 1994-04-28 | Allied-Signal Inc. | Indicateurs d'harmoniques ameliores fabriques a partir d'alliages magnetiques doux a base de fe-ni possedant une structure nanocristalline |
US5786764A (en) * | 1995-06-07 | 1998-07-28 | Engellenner; Thomas J. | Voice activated electronic locating systems |
CN109778082A (zh) * | 2019-01-24 | 2019-05-21 | 南京航空航天大学 | 一种高低温退火韧性的铁基非晶合金及其制备方法和用途 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60204100A (ja) * | 1984-03-28 | 1985-10-15 | 日本電気株式会社 | 磁気標識体 |
DE3717043A1 (de) * | 1987-05-21 | 1988-12-15 | Vacuumschmelze Gmbh | Amorphe legierung fuer streifenfoermige sensorelemente |
JP5653051B2 (ja) | 2010-03-03 | 2015-01-14 | ローランド株式会社 | 電子鍵盤楽器のペダル装置 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3665449A (en) * | 1969-07-11 | 1972-05-23 | Minnesota Mining & Mfg | Method and apparatus for detecting at a distance the status and identity of objects |
US3820104A (en) * | 1972-12-15 | 1974-06-25 | Stop Loss Inc | Method and system for detecting an object within a magnetic field interrogation zone |
US3938125A (en) * | 1974-02-20 | 1976-02-10 | Minnesota Mining And Manufacturing Company | Antipilferage system and marker therefor |
EP0017801A1 (fr) * | 1979-04-23 | 1980-10-29 | Allied Corporation | Marqueur amorphe antivol et système de détection le comportant |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR763681A (fr) * | 1933-11-10 | 1934-05-04 | Procédé de repérage des objets par modification d'un champ magnétique | |
US3856513A (en) * | 1972-12-26 | 1974-12-24 | Allied Chem | Novel amorphous metals and amorphous metal articles |
-
1982
- 1982-10-11 DE DE8282108920T patent/DE3265257D1/de not_active Expired
- 1982-10-11 EP EP82108920A patent/EP0078401B1/fr not_active Expired
- 1982-10-25 CA CA000414116A patent/CA1196986A/fr not_active Expired
- 1982-11-02 JP JP19327682A patent/JPS5886694A/ja active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3665449A (en) * | 1969-07-11 | 1972-05-23 | Minnesota Mining & Mfg | Method and apparatus for detecting at a distance the status and identity of objects |
US3820104A (en) * | 1972-12-15 | 1974-06-25 | Stop Loss Inc | Method and system for detecting an object within a magnetic field interrogation zone |
US3938125A (en) * | 1974-02-20 | 1976-02-10 | Minnesota Mining And Manufacturing Company | Antipilferage system and marker therefor |
EP0017801A1 (fr) * | 1979-04-23 | 1980-10-29 | Allied Corporation | Marqueur amorphe antivol et système de détection le comportant |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0226812A3 (en) * | 1985-12-21 | 1989-03-22 | Vacuumschmelze Gmbh | Security label for theft security system capable of deactivation |
EP0226812A2 (fr) * | 1985-12-21 | 1987-07-01 | Vacuumschmelze GmbH | Etiquette désactivalbe de sécurité pour système de sécurité anti-vol |
WO1988001427A1 (fr) * | 1986-08-14 | 1988-02-25 | Tyren Carl | Procede de detection d'objets a distance |
US5001458A (en) * | 1986-08-14 | 1991-03-19 | Tyren Carl | Method of remote sensing of objects |
EP0295028A1 (fr) * | 1987-06-08 | 1988-12-14 | Esselte Meto International GmbH | Dispositifs magnétiques |
EP0446910A1 (fr) * | 1990-03-13 | 1991-09-18 | Knogo Corporation | Dispositif antivol à marqueur à bande magnétique et procédé de fabrication de celui-ci |
US5146204A (en) * | 1990-03-13 | 1992-09-08 | Knogo Corporation | Theft detection apparatus and flattened wire target and method of making same |
EP0701235A3 (fr) * | 1990-04-10 | 1996-11-13 | Knogo Corp | Procédé et dispositif pour produire et utiliser des marqueurs magnétiques dans un système de surveillance d'articles |
EP0451812A2 (fr) * | 1990-04-10 | 1991-10-16 | Knogo Corporation | Marqueur magnétique dans un système de surveillance d'articles et procédé pour produire dudit marqueur |
EP0451812A3 (en) * | 1990-04-10 | 1991-12-18 | Knogo Corporation | Electromagnetic sensor element and methods and apparatus for making and using same |
US5304983A (en) * | 1991-12-04 | 1994-04-19 | Knogo Corporation | Multiple pulse responder and detection system and method of making and using same |
WO1994009172A1 (fr) * | 1992-10-16 | 1994-04-28 | Allied-Signal Inc. | Indicateurs d'harmoniques ameliores fabriques a partir d'alliages magnetiques doux a base de fe-ni possedant une structure nanocristalline |
US5786764A (en) * | 1995-06-07 | 1998-07-28 | Engellenner; Thomas J. | Voice activated electronic locating systems |
US5798693A (en) * | 1995-06-07 | 1998-08-25 | Engellenner; Thomas J. | Electronic locating systems |
US6057756A (en) * | 1995-06-07 | 2000-05-02 | Engellenner; Thomas J. | Electronic locating systems |
US6388569B1 (en) * | 1995-06-07 | 2002-05-14 | Thomas J. Engellenner | Electronic locating methods |
US6891469B2 (en) * | 1995-06-07 | 2005-05-10 | Thomas J. Engellenner | Electronic locating systems |
US7321296B2 (en) | 1995-06-07 | 2008-01-22 | Thomas J. Engellenner | Electronic locating systems |
US7902971B2 (en) | 1995-06-07 | 2011-03-08 | Xalotroff Fund V, Limtied Liability Company | Electronic locating systems |
CN109778082A (zh) * | 2019-01-24 | 2019-05-21 | 南京航空航天大学 | 一种高低温退火韧性的铁基非晶合金及其制备方法和用途 |
Also Published As
Publication number | Publication date |
---|---|
JPS5886694A (ja) | 1983-05-24 |
EP0078401B1 (fr) | 1985-08-07 |
CA1196986A (fr) | 1985-11-19 |
DE3265257D1 (en) | 1985-09-12 |
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