EP0077005B1 - Produits fibreux à motifs sous forme de nappe, étendus à sec et à absorbtion améliorée - Google Patents
Produits fibreux à motifs sous forme de nappe, étendus à sec et à absorbtion améliorée Download PDFInfo
- Publication number
- EP0077005B1 EP0077005B1 EP82109199A EP82109199A EP0077005B1 EP 0077005 B1 EP0077005 B1 EP 0077005B1 EP 82109199 A EP82109199 A EP 82109199A EP 82109199 A EP82109199 A EP 82109199A EP 0077005 B1 EP0077005 B1 EP 0077005B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- web
- compacted
- imprinting
- product
- imprinted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000835 fiber Substances 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 13
- 238000007596 consolidation process Methods 0.000 claims description 8
- 239000007921 spray Substances 0.000 claims description 7
- 239000000853 adhesive Substances 0.000 claims description 5
- 230000001070 adhesive effect Effects 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 3
- 229920001131 Pulp (paper) Polymers 0.000 claims description 2
- 238000009736 wetting Methods 0.000 claims 2
- 238000010981 drying operation Methods 0.000 claims 1
- 239000000047 product Substances 0.000 description 30
- 238000004049 embossing Methods 0.000 description 12
- 230000008569 process Effects 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- 238000005056 compaction Methods 0.000 description 7
- 239000007767 bonding agent Substances 0.000 description 6
- 239000012530 fluid Substances 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 239000011800 void material Substances 0.000 description 5
- 230000006872 improvement Effects 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 239000012736 aqueous medium Substances 0.000 description 2
- 238000000280 densification Methods 0.000 description 2
- 230000000994 depressogenic effect Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000037361 pathway Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000011417 postcuring Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H5/00—Special paper or cardboard not otherwise provided for
- D21H5/26—Special paper or cardboard manufactured by dry method; Apparatus or processes for forming webs by dry method from mainly short-fibre or particle material, e.g. paper pulp
- D21H5/265—Treatment of the formed web
- D21H5/2657—Consolidation
- D21H5/2671—Compression of the web, optionally with the use of a binder
-
- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47L—DOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
- A47L13/00—Implements for cleaning floors, carpets, furniture, walls, or wall coverings
- A47L13/10—Scrubbing; Scouring; Cleaning; Polishing
- A47L13/16—Cloths; Pads; Sponges
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/02—Patterned paper
Definitions
- the present invention relates to a dry-laid fibrous web product of high bulk and enhanced absorbency rate comprising: (a) a web of randomly distributed wood pulp fibers; (b) an adhesive material substantially permeating said web, adjacent fibers being bonded to one another thereby, and (c) an imprinted pattern on at least one surface of said web, the pattern subdividing said surface into compacted regions and non-compacted regions in alternating relationship to one another, the area of the compacted regions being about 40% to about 80% of each imprinted surface and a method of making a dry-laid fibrous web product.
- the invention relates especially to tissue, towel and napkin products of high bulk and rapid absorbency obtained from bonded air laid cellulosic fibrous webs, in accordance with the method disclosed here.
- a non-nesting pattern is imprinted on the web to prevent loss of final product size, e.g., product roll diameter.
- Fibrous webs particularly low basis weight webs between 3,6 and 27,2 kg per 279 m 2 (8 and 60 lbs. per ream (3,000 sq. ft.)), for use ultimately as tissue, towel and napkin products, are fabricated conventionally by two alternate processes.
- the older wet laid process dispenses an aqueous slurry of pulped paper-making fibers, generally natural cellulose fibers, onto a moving foraminous support means, e.g., a fourdrinier wire, the aqueous medium being removed through the support means by vacuum means.
- the wet laid web is thermally dried and taken up on a parent roll. Because of the presence of water, the wet laid fibers bond naturally to one another by means of hydrogen bonding.
- Such conventionally prepared webs are sometimes creped to improve feel and enhance absorbency.
- the webs may be embossed to enhance softness and to provide a more aesthetic appearance.
- the second, now conventional, yet relatively recent, process defiberizes cellulose pulp, the dry individual fibers being pneumatically transported to the dispensing means, and then dry laid (or air laid) onto the moving foraminous support means. Vacuum means below the support means is employed to ensure that the dry fibers remain on the web, which web has little inherent strength inasmuch as hydrogen bonds are not formed substantially in the absence of an aqueous medium.
- the dry, initially laid web is then sprayed with a synthetic bonding agent, such as a latex emulsion, preferably on both surfaces of the web.
- the bonding agent is cured by passing the thus treated web through a dryer, e.g. a through air dryer, before being taken up on a parent roll. These webs may also be creped and embossed.
- wet laid webs provide better wiping absorbency than dry laid webs. That is, under dynamic conditions of use, wet laid webs absorb liquid at a faster rate and retain the liquid thus absorbed better than their dry laid. counterpart.
- the slower rate of wiping absorbency associated with dry laid webs is primarily due to the greater volume of interstitial voids, existing within the reticulated structure of these webs.
- the greater void volume is occasioned by the larger size, on average, of individual pores, as well as by the greater degree of reticulation extent in the overall web structure.
- These interstitial voids provide a greater interstitial liquid holding capacity under static conditions, but permit absorbed liquid to be squeezed back out more easily under dynamic wiping conditions. The net result is an appeared slower rate of wiping absorbency for dry laid webs.
- the advantages of greater void volume or bulk present in dry laid webs are several. Less fiber per ream is required to fabricate the web.
- the greater void size provides greater static liquid holding capacity, and typically contributes to a softer feeling web.
- dried laid webs have greater wet strength than conventional wet laid webs, and hence, do not break apart as readily during use. Thus, substantial improvement in wiping or dynamic absorbency characteristics would greatly improve product acceptance and usefulness.
- a raised pattern is formed on a portion of a first web surface (the raised portion), with corresponding depressions in the remaining portion of said web surface (the depressed portion).
- These discontinuities in the first surface of the web are occasioned by passing the web between two cylindrical rolls, one of which is resilient, the other being inextensible and having a plurality of bosses thereon.
- the bosses contact the second surface of the web forming the raised areas (and depressions) on the first surface in contact with the resilient roll.
- the raises comprise about 20 to 30% of the total first surface area, the depressions accounting for the remaining area.
- U.S. Patent 3616157 discloses an embossed non-woven fabric having a textured character and fabric-like qualities of softness and hand and suitable for wiping surfaces comprising a fibrous web containing at least one layer of overlapping, intersecting fibers, a pattern of intermittently spaced, embossed compacted fibrous areas lying in the planes of both surfaces of said web of overlapping, intersecting fibers and a pattern of unembossed, uncompacted fibrous portions lying between said planes and connecting said embossed, compacted fibrous areas.
- U.S. Patent 4135024 discloses a method of simultaneously strengthening and decorating a low integrity dry-formed nonwoven fibrous web, said method comprising the steps of: (a) forming spaced-apart densified regions in the web to strengthen the web by embossing a front surface of the web with spaced-apart raised surfaces of an embossing roll, the densified regions being able to transmit a treating fluid completely through the thickness of the web from a rear surface of the web to the front surface thereof, and simultaneous with the embossing; (b) applying a treating fluid that includes a coloring agent to the rear surface of the web from a treating fluid conveying surface that is free of raised, spaced-apart web embossing areas for causing the fluid to be transmitted completely through the thickness of the web from the rear surface to the front surface thereof in substantially only the densified regions to thereby impart a valley print decorative effect in the front surface, the treating fluid conveying surface being disposed opposite the raised surfaces on the embossing roll and constituting
- Imprinting compresses certain portions of a web surface in intaglio, the other surface not being raised thereby. Necessarily, imprinting densifies the compressed surface portions substantially more than embossing.
- Imprinting as opposed to embossing, has heretofore been used in wet laid processing in conjunction with subsequent creping as disclosed in, for example, U.S. Patents 4,191,609 and 4,125,659. In doing so the finally creped product exhibits greater softness, improved stretch and tensile strength, and enhanced bulk.
- Another object of the present invention is to provide a method for the manufacture of the web product of the present invention.
- an air laid bonded web is imprinted with a depressed design, preferably with a non-nesting pattern to avoid loss of final product roll diameter.
- the bonded web to be imprinted is wetted optionally with a spray of water and subjected to an areal pressure of at least about 1,10.10 5 Pa (16 Ibs./in 2 ) by platen means, said means having been heated to a temperature of between about 140 to about 180°C.
- platen means said means having been heated to a temperature of between about 140 to about 180°C.
- At least one surface of the treated web must have a compacted area of at least about 40% of the total imprinted surface area, preferably between 50% to 80% of the total imprinted surface area. Each side of the web may be so imprinted.
- the imprinting means is a pair of non-resilient cylindrical rolls adapted for imprinting the web continuously. While the levels of compaction are analogous, the applied pressure is at least 45,3 kg per lineal 2,54 cm (100 lbs. per lineal inch). Again, the imprinting means are heated to 140 to 180°C., and a water spray is optional.
- the diameter of individual product rolls or the composite thickness of packaged product sheets of the present invention are preferably reduced not more than 10% as compared to unimprinted products. Depending on the pressure applied by the imprinting means, said reduction may approach between 20 and 30%. However, the wiping absorbency of products of the present invention is increased by at least about 25%, preferably about 40% or more, as ascertained by relative values of mirror wipe time between imprinted and unimprinted products.
- a flow diagram of a process for making air laid webs, pulp sheets, laps or bales 10 are defiberized in defiberizer 11, here a hammermill, and transported pneumatically through line 12 to a distributor 14 by blower 13.
- defiberizer 11 here a hammermill
- Distributor arangements are well known in the art.
- the individual fibers are dispersed onto an endless fourdrinier wire 15, which circles continuously about guide rolls 16.
- Vacuum means 17 draws and retains the loose fibers 18 onto the wire 15 to form a loose web 19 which has little integrity.
- the loose web 19 is typically pressed by consolidation rolls 21, which compaction increases web strength to a limited extent, and permits transfer of the pressed web 22 to a carrier wire 23.
- Wire 23 has larger perforations than wire 15 and is made typically from a synthetic plastic material. The use of a separate wire 23, then, is less likely to cause plugging with bonding material 26 from spray dispensing means 27, and will improve clean up. As shown in Fig.
- the once bonded web 29, partially dried in dryer 28, is transferred from carrier wire 23 to a second carrier wire 31 where a second spray means 33 dispenses additional bonding material 32 onto the second surface of the web. While two bonding applications are shown, one application will suffice where the web is porous and has a low basis weight, e.g., less than about 9,1 kg per 279 m 2 (20 lbs. per 3000 sq. ft. ream). Additional information relating to a preferred process for bonding air laid webs is disclosed in commonly assigned U.S. Patent 4292271 entitled “Methods of Applying Bonding Materials Onto Fibrous Webs", filed December 28, 1979 by Pauls et al. After each bonding application, the web is at least partially cured in dryers 28, 35. If complete drying is not achieved in dryer 35, a curing oven 40 is provided.
- the bonded, cured web 39, and before take up on parent roll 41, is then imprinted at an imprinting station, here a pair of cylindrical rolls 42, although this location is not' critical.
- station 42 can be situated between consolidation rolls 21 and bonding station 27, or between dryer 28 and bonding station 33.
- the imprinting station may be located anywhere following the consolidation rolls 21. It should be noted that when the web is imprinted before the curing step, the compressive force applied by the imprinting means need not be as high as post curing imprinting because the pattern is less likely to "spring back".
- station 42 may be included as a step in the converting operation (not shown), either from parent rolls or individual product rolls.
- This failing of prior art products is attributed to the inherently large pore volume between fibers in air laid webs.
- wet laid webs begin to bond as soon as they are laid.
- the high moisture content of the wet laid web which decreases from about 99% per weight water beneath the head box to between about 65% to 85% just prior to consolidation, facilitates densification of the web.
- the water "lubricates” the web and "plasticizes" the fibers so that the individual fibers can come into close physical relationship with one another.
- Air laid webs do not have water to lubricate the fibers, resulting in less dense webs with greater bulk and larger interstitial void volumes. While bulk is highly advantageous, the consequences of excessively large void volume are not. Compaction by the vacuum means 17 and the consolidation rolls 21 is not intended to highly densify the webs. Although it would be possible to increase the pressure of the consolidation rolls to highly compact the webs, the beneficial bulk provided by the air laid process would be lost. Furthermore, densification of the web by the consolidation rolls 21 would compromise the ability to disperse bonding agent 26, 32 through the web.
- the invention disclosed herein can be used with air laid webs of between about 3,6 and 27,2 kg per 279 m 2 (8 and 60 Ibs. per ream (3000 sq. ft.)) basis weight which have been consolidated by rolls 21 with pressures of between 22,7 and 135,9 kg/lineal 2,54 cm (50 and 300 lbs./lineal inch.) and then bonded with a latex emulsion bonding agent, the bonding agent typically representing between about 10 to 30%, preferably between 15 and 25%, of the web basis weight.
- such webs have a bulk of between 1,78.10- 2 to about .
- MTT mirror wipe time
- test is being used herein to determine gross differences in absorbency rate so that the standard deviations of individual measurements are negligible by comparison.
- Caliper was measured with a Testing Machines, Inc. (Amityville, New York) Model 551M Micrometer having a 5,08 cm (2 inch) anvil.
- Fig. 3 and 4 are photomicrographs of a conventional uncompacted air laid web and a compacted air laid web, respectively, each enlarged 74 times.
- the densified web of Fig. 4 has much smaller interstitial voids between fibers as compared to the uncompacted web.
- capillary tension and wiping absorbency is increased in the web of Fig. 4 web as demonstrated by reduction in mirror wipe time.
- a significant loss in caliper occurs as a consequence of the compaction. This loss is more than about 80% in each instance.
- a web 50 representative of the invention was prepared using a pair of etched plates each having raised areas representing 69% of the plate.
- the web so treated had a grid pattern illustrated in Fig. 2.
- the compacted areas 51 were about 2,02 cm 2 (5/16 inch square) (dimension x) and the non-compacted surfaces 52, e.g., the essentially uncompacted zones which appear as intersecting ribs or bridge regions, were about 0,16 cm (1/16") wide (dimension y).
- the depth of the compacted areas is dependent upon the pressure applied by the plates.
- the uncompacted web (Table I) had a basis weight of 19,5 kg/279 m 2 (43 lbs./ream), and a caliper of 1,13 mm (44.6 mils).
- the imprinting of the web does not reduce the caliper of the non-compacted portions of the web, that is, dimension C i , remains about 1,12 mm (44 mils). However, some reduction occurs, typically less than about 10%, but possibly approaching 20 to 30%. A compression load of about seven tons was applied between the plates for about 20 seconds.
- the caliper C, of the imprinted web was measured as 0,79 mm (31 mils) with the Model 551 M Micrometer, as compared to 1,13 mm (44.6 mils) for the uncompacted web and as compared to less than 0,23 mm (9.04 mils) for the compacted webs.
- the loss in caliper is about 30% versus about at least 80% for the totally compacted webs.
- the caliper of the imprinted web is about 30% greater.
- Mirror wipe time for the imprinted web was measured at 17 seconds, which is an improvement of 46.9% over the conventional dry laid web.
- the actual pattern is not critical, it is essential that at least 40%, preferably more than 50%, of the area of one web surface be compacted. If both surfaces of web are compacted, each should be compacted to at least 40%, each preferably more than 50%.
- the plates or cylinders are heated to between 140 and 180°C., with water sprayed on the towel before pressing. The spray of water is not critical to the process, but it does aid in retention of the compaction.
- the grid pattern of Fig. 2 is not critical to the concept of improved web absorbency rate by high compaction imprinting, the grid pattern does affect the end product beneficially in that the grid pattern prevents nesting of the compacted zones within one another when the web is taken up on a product roll.
- the roll of the invention web has essentially the same diameter as conventional products, which is preferred.
- Fig. 6 illustrates an alternate embodiment of the web of the present invention. Although only one surface has received an imprinted pattern, both surfaces may be imprinted if desired.
- web 60 has compacted area 61 and a plurality of non-compacted areas.
- the web of Fig. 6 has contiguous compacted channel regions 61, which regions likewise represent at least 40% of the surface of the web so imprinted.
- densified zones here indicated by numeral 63, exist beneath the compacted area 61. These contiguous channel regions are desirable because they provided pathways for lateral wicking.
- Fig. 5 The data of Table I is reproduced graphically in Fig. 5.
- This graph a plot of compacted web density versus Mirror Wipe Time, shows that the improvement in MWT is rapid until a density of about 0.35 g/cm 3 is achieved, which value corresponds to a compression force of about 1,0.10 5 Pa (15 Ibs./in. 2 ). Thereafter, MWT increases slightly, an asymptote being reached at about 0.80 g/cm 3. It is believed that analogous relationships between MWT and web density are applicable to the product of this invention.
- the reduction in absorbency at the higher density values in Fig. 5 apparently occurs because the interstitial voids are too small to permit large amounts of water to be absorbed.
- the densities of the densified web region are between about 0.20 to about 0.50 g/cm 3 , which would correspond roughly to MWT's below 14 and 13 seconds, respectively, for the webs of this invention. It should be noted that the optical density of 0.35 g/cm 3 provides essentially equal absorbency as compared to conventional wet laid webs, that is, an MWT of about 11.5 seconds.
Landscapes
- Paper (AREA)
- Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)
- Machines For Manufacturing Corrugated Board In Mechanical Paper-Making Processes (AREA)
- Nonwoven Fabrics (AREA)
- Preliminary Treatment Of Fibers (AREA)
- Decoration Of Textiles (AREA)
- Absorbent Articles And Supports Therefor (AREA)
Claims (25)
caractérisé en ce que la nappe sèche desserrée est consolidée entre les étapes (a) et (b), et l'impression est effectuée à n'importe quelle étape du procédé suivant la consolidation de la nappe sèche desserrée sous une pression suffisante pour densifier les parties de la nappe sous-jacentes aux zones comprimées et atteindre une masse voluminique comprise environ entre 0,2 g/cm3 et 0,5 g/cm3.
l'étape d'impression étant effectuée après l'une ou l'autre opération de séchage.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT82109199T ATE22713T1 (de) | 1981-10-05 | 1982-10-05 | Trockengelegte gemusterte faserbahnprodukte mit erhoehter saugfaehigkeit. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US30901581A | 1981-10-05 | 1981-10-05 | |
US309015 | 1999-05-10 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0077005A1 EP0077005A1 (fr) | 1983-04-20 |
EP0077005B1 true EP0077005B1 (fr) | 1986-10-08 |
Family
ID=23196302
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP82109199A Expired EP0077005B1 (fr) | 1981-10-05 | 1982-10-05 | Produits fibreux à motifs sous forme de nappe, étendus à sec et à absorbtion améliorée |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0077005B1 (fr) |
JP (1) | JPS58144197A (fr) |
AT (1) | ATE22713T1 (fr) |
CA (1) | CA1193919A (fr) |
DE (1) | DE3273640D1 (fr) |
DK (1) | DK439282A (fr) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4476078A (en) * | 1982-05-04 | 1984-10-09 | James River-Dixie/Northern, Inc. | Process for manufacturing embossed nonwoven fibrous products |
CA2175240C (fr) * | 1993-10-28 | 1999-02-23 | Karl Kristian Kobs Kroyer (Deceased) | Latex modifie |
ATE158361T1 (de) * | 1993-10-28 | 1997-10-15 | Kobs Kroyer Ingelise | Mechanische teilneutralisation von wasserstoffbrücken zur herstellung eines weicheren, seidigeren, luftgelegten faserprodukts |
EP0745717A1 (fr) | 1995-06-01 | 1996-12-04 | Kaysersberg | Procédé d'ennoblissement d'une nappe formée par voie sèche et nappe ainsi ennoblie |
US5938893A (en) * | 1997-08-15 | 1999-08-17 | The Procter & Gamble Company | Fibrous structure and process for making same |
ATE330068T1 (de) * | 1998-12-17 | 2006-07-15 | Kimberly Clark Co | Zusammengepresste absorbierende faserstrukturen |
US6432272B1 (en) | 1998-12-17 | 2002-08-13 | Kimberly-Clark Worldwide, Inc. | Compressed absorbent fibrous structures |
FR2839918A1 (fr) * | 2002-05-27 | 2003-11-28 | Adco Mfg | Materiau complexe en plaque pour la realisation d'un emballage destine en particulier a des produits alimentaires, son procede de fabrication et l'emballage obtenu avec ce materiau |
US7924142B2 (en) * | 2008-06-30 | 2011-04-12 | Kimberly-Clark Worldwide, Inc. | Patterned self-warming wipe substrates |
JP2017190538A (ja) * | 2016-04-13 | 2017-10-19 | 山田 菊夫 | パルプ積繊シート製造装置及びパルプ積繊シート製造方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3017304A (en) * | 1956-05-24 | 1962-01-16 | Personal Products Corp | Absorbent fibrous structure and method of production |
US3867225A (en) * | 1969-01-23 | 1975-02-18 | Paper Converting Machine Co | Method for producing laminated embossed webs |
US3616157A (en) * | 1969-08-08 | 1971-10-26 | Johnson & Johnson | Embossed nonwoven wiping and cleaning materials |
GB1372502A (en) * | 1971-10-07 | 1974-10-30 | Johnson & Johnson | Non-woven fabric |
US3905863A (en) * | 1973-06-08 | 1975-09-16 | Procter & Gamble | Process for forming absorbent paper by imprinting a semi-twill fabric knuckle pattern thereon prior to final drying and paper thereof |
US3908659A (en) * | 1974-03-14 | 1975-09-30 | Procter & Gamble | Absorbent pad structure, diaper construction utilizing same and methods of manufacture thereof |
US4135024A (en) * | 1976-08-16 | 1979-01-16 | Scott Paper Company | Method of treating a low integrity dry-formed nonwoven web and product made therefrom |
US4191609A (en) * | 1979-03-09 | 1980-03-04 | The Procter & Gamble Company | Soft absorbent imprinted paper sheet and method of manufacture thereof |
-
1982
- 1982-10-04 DK DK439282A patent/DK439282A/da not_active Application Discontinuation
- 1982-10-04 CA CA000412745A patent/CA1193919A/fr not_active Expired
- 1982-10-05 JP JP57174098A patent/JPS58144197A/ja active Pending
- 1982-10-05 AT AT82109199T patent/ATE22713T1/de not_active IP Right Cessation
- 1982-10-05 DE DE8282109199T patent/DE3273640D1/de not_active Expired
- 1982-10-05 EP EP82109199A patent/EP0077005B1/fr not_active Expired
Also Published As
Publication number | Publication date |
---|---|
DE3273640D1 (en) | 1986-11-13 |
CA1193919A (fr) | 1985-09-24 |
JPS58144197A (ja) | 1983-08-27 |
EP0077005A1 (fr) | 1983-04-20 |
DK439282A (da) | 1983-04-06 |
ATE22713T1 (de) | 1986-10-15 |
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