EP0047914A1 - Apparatus for extracting heat from a hygroscopic pulverulent material with a temperature lower than 100 degrees centigrade - Google Patents
Apparatus for extracting heat from a hygroscopic pulverulent material with a temperature lower than 100 degrees centigrade Download PDFInfo
- Publication number
- EP0047914A1 EP0047914A1 EP81106805A EP81106805A EP0047914A1 EP 0047914 A1 EP0047914 A1 EP 0047914A1 EP 81106805 A EP81106805 A EP 81106805A EP 81106805 A EP81106805 A EP 81106805A EP 0047914 A1 EP0047914 A1 EP 0047914A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- water
- grains
- sand
- heat
- pulverulent material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28C—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA COME INTO DIRECT CONTACT WITHOUT CHEMICAL INTERACTION
- F28C3/00—Other direct-contact heat-exchange apparatus
- F28C3/10—Other direct-contact heat-exchange apparatus one heat-exchange medium at least being a fluent solid, e.g. a particulate material
- F28C3/12—Other direct-contact heat-exchange apparatus one heat-exchange medium at least being a fluent solid, e.g. a particulate material the heat-exchange medium being a particulate material and a gas, vapour, or liquid
- F28C3/16—Other direct-contact heat-exchange apparatus one heat-exchange medium at least being a fluent solid, e.g. a particulate material the heat-exchange medium being a particulate material and a gas, vapour, or liquid the particulate material forming a bed, e.g. fluidised, on vibratory sieves
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C5/00—Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose
- B22C5/08—Machines or devices specially designed for dressing or handling the mould material so far as specially adapted for that purpose by sprinkling, cooling, or drying
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28C—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA COME INTO DIRECT CONTACT WITHOUT CHEMICAL INTERACTION
- F28C3/00—Other direct-contact heat-exchange apparatus
- F28C3/10—Other direct-contact heat-exchange apparatus one heat-exchange medium at least being a fluent solid, e.g. a particulate material
- F28C3/12—Other direct-contact heat-exchange apparatus one heat-exchange medium at least being a fluent solid, e.g. a particulate material the heat-exchange medium being a particulate material and a gas, vapour, or liquid
- F28C3/14—Other direct-contact heat-exchange apparatus one heat-exchange medium at least being a fluent solid, e.g. a particulate material the heat-exchange medium being a particulate material and a gas, vapour, or liquid the particulate material moving by gravity, e.g. down a tube
Definitions
- the invention relates to a device for extracting heat from a hydrophilic pulverulent material below 100 ° C.
- This material can for example be foundry sand which has just been used and has been cooled to 100 ° C. by spraying with water, or sand which has been dried with a flame and maintains a temperature of 100 ° C. To continue handling this material it is desirable to start by cooling it from 100 ° C to 40 ° C.
- the heat transfer coefficients are quite low, of the order of a few tens of kcal / hm 2. ° C while the transfer coefficients by direct evaporation and condensation of water are of the order 1000 kcal / hm 2. ° C.
- the sand to be cooled is sand which has been dried in a rotary kiln, it is desirable to cool it while obtaining a sand at 40 C perfectly dry for its use in a foundry mold or for its shipment . In addition, it is often useful to recover the heat from the sand.
- the object of the present invention is to provide a device for extracting heat from a hydrophilic pulverulent material below 100 ° C. enabling a cool and dry material to be obtained in a simple manner and for recovering the heat. extracted.
- the invention therefore relates to a device for extracting heat from a hydrophilic pulverulent material below 100 ° C, characterized in that it comprises means for turbulent movement of the material, means for spraying water on the surface of this moving material in an amount just necessary for the desired extraction of heat by subsequent evaporation of the water removed from the grains, and means for circulating a gas upon contact with the moving material so that the deposited water evaporates before contact with neighboring grains has been able to create a possibility of aggregation of these grains, said gas ensuring the evacuation of the water vapor thus produced.
- the means for setting in motion the pulverulent material comprise a shaker conveyor, said conveyor carrying a succession of ramps, the shaking of this conveyor being chosen to successively climb all these ramps by the grains leaving them fall down each time they have reached the top of a ramp, the means for spraying the water being arranged in the vicinity of the zones where the grains fall from the top of a ramp.
- the water is sprayed so that the droplets formed have diameters substantially between 60% and 30% of the average diameter of the grains of the material.
- the single figure is a schematic view of a preferred embodiment of the invention.
- the quantity of water just necessary for cooling is uniformly sprayed on the surface of the sand, this quantity corresponding to approximately 550 calories / kg of evaporated water.
- Evaporation of the water is ensured by a low gas circulation, possibly under reduced pressure, which decreases the partial pressure of water vapor at the level of each grain and thus allows evaporation before the grains have been able to agglomerate.
- the gas also allows evacuation by entrainment of the water vapor produced.
- a uniform spraying of water on the surface of the sand is necessary and, preferably, 3% of cold water is injected by weight relative to the sand.
- the device shown in the figure includes a hopper 2 for the supply of pulverulent material, for example hot foundry sand.
- Sand falls on shaker conveyor comprising a table 4 set in motion by a mechanism 6 of known type. On this table are arranged three ascending ramps 8, 10 and 12 that the sand successively climbs under the action of the tremors applied by the mechanism 6.
- a water sprayer In the vicinity of each of the ramp tops is arranged a water sprayer, respectively (16), 18) and (20), which directs the water onto the sand in the areas where the layers of sand mix in the vicinity from the top of the ramp, and where the sand falls.
- shaker conveyor can be horizontal, inclined or helical.
- the gas which, as indicated above, ensures evaporation is preferably air; it is sent, via a pipe 21, preferably in the opposite direction to that of the sand, and meets each grain which falls from the ramps, thus ensuring the evaporation of the water and the transport of the water vapor produced.
- the air taken up in the vicinity of the hopper 2 is then hot and humid; it is sent to a condenser 22 which recovers the heat.
Abstract
Description
L'invention concerne un dispositif pour l'extraction de la chaleur d'un matériau pulvérulent hydrophile au-dessous de 100°C.The invention relates to a device for extracting heat from a hydrophilic pulverulent material below 100 ° C.
Ce matériau peut être par exemple du sable de fonderie qui vient d'être utilisé et a été refroidi à 100°C par vaporisation d'eau, ou du sable qui a été séché à la flamme et conserve une température de 100°C. Pour continuer à manipuler ce matériau il est souhaitable de commencer par le refroidir de 100°C à 40°C.This material can for example be foundry sand which has just been used and has been cooled to 100 ° C. by spraying with water, or sand which has been dried with a flame and maintains a temperature of 100 ° C. To continue handling this material it is desirable to start by cooling it from 100 ° C to 40 ° C.
Il est connu que l'on peut refroidir du sable très chaud jusqu'au voisinage de 100°C par pulvérisation d'eau. Quant au refroidissement au-dessous de 100°C il est classiquement effectué sans pulvérisation d'eau pour obtenir un sable très sec.It is known that very hot sand can be cooled to around 100 ° C by spraying water. As for cooling below 100 ° C, it is conventionally carried out without spraying water to obtain very dry sand.
Par exemple, pour refroidir du sable de fonderie de 100°C à 40°C et récupérer la chaleur, on peut employer plusieurs procédés connus utilisant comme fluide caloporteur :
- - soit l'air atmosphérique en contact direct avec le sable,
- - soit l'eau en contact indirect à travers la paroi d'un échangeur de chaleur.
- - either atmospheric air in direct contact with the sand,
- - or water in indirect contact through the wall of a heat exchanger.
Dans ces deux cas, les coefficients de transfert de chaleur sont assez bas, de l'ordre de quelques dizaines de kcal/h.m 2.°C alors que les coefficients de transfert par évaporation et condensation directes de l'eau sont de l'ordre de 1000 kcal/h.m 2 .°C.In these two cases, the heat transfer coefficients are quite low, of the order of a few tens of kcal / hm 2. ° C while the transfer coefficients by direct evaporation and condensation of water are of the order 1000 kcal / hm 2. ° C.
On a donc intérêt à utiliser l'eau comme fluide caloporteur ; mais, comme dans certains cas le sable à refroidir est du sable qui a été séché dans un four tournant, il est souhaitable de le refroidir tout en obtenant un sable à 40 C parfaitement sec pour son utilisation dans un moule de fonderie ou pour son expédition. De plus, il est souvent utile de récupérer la chaleur du sable.It is therefore advantageous to use water as a heat transfer fluid; but, as in some cases the sand to be cooled is sand which has been dried in a rotary kiln, it is desirable to cool it while obtaining a sand at 40 C perfectly dry for its use in a foundry mold or for its shipment . In addition, it is often useful to recover the heat from the sand.
La présente invention a pour but la réalisation d'un dispositif pour l'extraction de la chaleur d'un matériau pulvérulent hydrophile au-dessous de 100°C permettant d'obtenir de manière simple un matériau refroidi et sec, et de récupérer la chaleur extraite.The object of the present invention is to provide a device for extracting heat from a hydrophilic pulverulent material below 100 ° C. enabling a cool and dry material to be obtained in a simple manner and for recovering the heat. extracted.
L'invention a donc pour objet un dispositif pour l'extraction de la chaleur d'un matériau pulvérulent hydrophile au dessous de 100°C, caractérisé par le fait qu'il comprend des moyens de mise en mouvement turbulent du matériau, des moyens pour pulvériser de l'eau sur la surface de ce matériau en mouvement en quantité juste nécessaire à l'extraction souhaitée de chaleur par évaporation ultérieure de l'eau dépcsée sur les grains, et des moyens pour faire circuler un gaz au ccntact du matériau en mouvement de manière que l'eau déposée s'évapore avant que l'entrée en contact des grains voisins n'ait pu créer une possibilité d'aggrégation de ces grains, ledit gaz assurant l'évacuation de la vapeur d'eau ainsi produite.The invention therefore relates to a device for extracting heat from a hydrophilic pulverulent material below 100 ° C, characterized in that it comprises means for turbulent movement of the material, means for spraying water on the surface of this moving material in an amount just necessary for the desired extraction of heat by subsequent evaporation of the water removed from the grains, and means for circulating a gas upon contact with the moving material so that the deposited water evaporates before contact with neighboring grains has been able to create a possibility of aggregation of these grains, said gas ensuring the evacuation of the water vapor thus produced.
Dans un mode préféré de réalisation, les moyens de mise en mouvement du matériau pulvérulent comprennent un transporteur à secousses, ledit transporteur portant une succession de rampes, les secousses de ce transporteur étant choisies pour faire gravir successivement toutes ces rampes par les grains en les laissant retomber chaque fois qu'ils sont arrivés au sommet d'une rampe, les moyens pour pulvériser l'eau étant disposés au voisinage des zones où les grains retombent du sommet d'une rampe.In a preferred embodiment, the means for setting in motion the pulverulent material comprise a shaker conveyor, said conveyor carrying a succession of ramps, the shaking of this conveyor being chosen to successively climb all these ramps by the grains leaving them fall down each time they have reached the top of a ramp, the means for spraying the water being arranged in the vicinity of the zones where the grains fall from the top of a ramp.
Ce dispositif met en oeuvre le procédé suivant :
- - on met le matériau à refroidir en mouvement turbulent - on pulvérise de l'eau sur la surface de ce matériau en mouvement en quantité juste nécessaire à l'extraction souhaitée de chaleur par évaporation ultérieure de l'eau déposée sur les grains,
- - et on fait circuler un gaz au contact du matériau en mouvement de manière à faire évaporer l'eau déposée.
- - the material to be cooled is put into turbulent movement - water is sprayed on the surface of this moving material in an amount just necessary for the desired heat extraction by subsequent evaporation of the water deposited on the grains,
- - And a gas is circulated in contact with the moving material so as to evaporate the water deposited.
Ce procédé répond de plus, de préférence, aux caractéristiques suivantes :
- - on pulvérise l'eau de manière que 90% au moins des gouttelettes formées aient un diamètre inférieure à 70% de celui de 90% au moins des grains du matériau pulvérulent.
- the water is sprayed so that at least 90% of the droplets formed have a diameter less than 70% of that of at least 90% of the grains of the pulverulent material.
Dans le cas d'un matériau pulvérulent de diamètre de grains sensiblement uniforme, on pulvérise l'eau de manière que les gouttelettes formées aient des diamètres compris sensiblement entre 60% et 30% du diamètre moyen des grains du matériau.In the case of a pulverulent material with a substantially uniform grain diameter, the water is sprayed so that the droplets formed have diameters substantially between 60% and 30% of the average diameter of the grains of the material.
A l'aide des figures schématiques ci-jointes, on va décrire ci-après, à titre non limitatif, un exemple de réalisation du dispositif de l'invention.With the aid of the attached diagrammatic figures, an exemplary embodiment of the available will be described below, without limitation. sitive of the invention.
La figure unique est une vue schématique d'un mode préféré de réalisation de l'invention.The single figure is a schematic view of a preferred embodiment of the invention.
Avant de décrire le dispositif, quelques explications seront données sur le procédé qu'il met en oeuvre.Before describing the device, some explanations will be given on the process it implements.
On pulvérise uniformément à la surface du sable, la quantité d'eau juste nécessaire au refroidissement, cette quantité correspondant à environ 550 calories/kg d'eau évaporée.The quantity of water just necessary for cooling is uniformly sprayed on the surface of the sand, this quantity corresponding to approximately 550 calories / kg of evaporated water.
L'évaporation de l'eau est assurée par une faible circulation de gaz, éventuellement sous pression réduite, qui diminue la pression partielle de vapeur d'eau au niveau de chaque grain et permet ainsi l'évaporation avant que les grains n'aient pu s'agglomérer. Le gaz permet en outre l'évacuation par entraînement de la vapeur d'eau produite..Evaporation of the water is ensured by a low gas circulation, possibly under reduced pressure, which decreases the partial pressure of water vapor at the level of each grain and thus allows evaporation before the grains have been able to agglomerate. The gas also allows evacuation by entrainment of the water vapor produced.
Une pulvérisation uniforme de l'eau à la surface du sable est nécessaire et, de préférence on injecte 3% d'eau froide en poids par rapport au sable.A uniform spraying of water on the surface of the sand is necessary and, preferably, 3% of cold water is injected by weight relative to the sand.
Les pulvérisateurs du commerce produisent des gouttes relativement grosses par rapport à la granulométrie du sable, gouttes de 200 pour un sable ayant une granulométrie moyenne de 130 (sable compris entre 40 et 200 ) si bien que les 3% d'eau ont tendance à former de petites boulettes de sable humide qu'il faut disperser par des moyens mécaniques (tambour tournant, agitateur, etc....).Commercial sprayers produce relatively large drops compared to the particle size of the sand, drops of 200 for a sand having an average particle size of 130 (sand between 40 and 200) so that 3% of water tends to form small balls of wet sand which must be dispersed by mechanical means (rotating drum, agitator, etc.).
Il est préférable d'humecter le plus régulièrement possible le sable avec seulement 3% d'eau. Pour cela, il est possible d'utiliser des pulvérisateurs du type "ultra-sons" produisant un "brouillard" de très fines particules, par exemple de 20 . Par rapport aux gouttelettes de diamètre 200 , on a 1000 fois plus de gouttes de 20 , ainsi le sable est humecté beaucoup plus régulièrement, donc son refroidissement par évaporation sera plus rapide et plus uniforme.It is best to moisten the sand as regularly as possible with only 3% water. For this, it is possible to use sprayers of the "ultrasonic" type producing a "mist" of very fine particles, for example 20. Compared to droplets of diameter 200, there are 1000 times more drops of 20, so the sand is moistened much more regularly, so its cooling by evaporation will be faster and more uniform.
Le dispositif représenté dans la figure comporte une trémie 2 pour l'alimentation en matière pulvérulente, par exemple du sable chaud de fonderie. Le sable tombe sur un transporteur à secousses comportant une table 4 mise en mouvement par un mécanisme 6 de type connu. Sur cette table sont disposées trois rampes ascendantes 8, 10 et 12 que le sable gravit successivement sous l'action des secousses appliquées par le mécanisme 6.The device shown in the figure includes a hopper 2 for the supply of pulverulent material, for example hot foundry sand. Sand falls on shaker conveyor comprising a table 4 set in motion by a mechanism 6 of known type. On this table are arranged three ascending
Au sommet de chacune des rampes le sable retombe sur le début de la rampe suivante, pour être finalement amené à un récepteur de sortie 14.At the top of each of the ramps the sand falls back onto the start of the next ramp, to be finally brought to an
' Au voisinage de chacun des sommets de rampe est disposé un pulvérisateur d'eau, respectivement (16), 18) et (20), qui dirige l'eau sur le sable dans les zones où les couches de sable, se mélangent au voisinage du sommet de la rampe, et où le sable retombe.'' In the vicinity of each of the ramp tops is arranged a water sprayer, respectively (16), 18) and (20), which directs the water onto the sand in the areas where the layers of sand mix in the vicinity from the top of the ramp, and where the sand falls.
Bien entendu le transporteur à secousses peut être horizontal, incliné ou hélicoïdal.Of course the shaker conveyor can be horizontal, inclined or helical.
Le gaz qui, comme indiqué ci-dessus, assure l'évaporation est de préférence de l'air ; il est envoyé, par une canalisation 21, de préférence en sens inverse de celui du sable, et rencontre chaque grain qui tombe des rampes, assurant ainsi l'évaporation de l'eau et le transport de la vapeur d'eau produite.The gas which, as indicated above, ensures evaporation is preferably air; it is sent, via a
L'air, repris au voisinage de la trémie 2 est alors chaud et humide ; il est envoyé dans un condenseur 22 qui permet de récupérer la chaleur.The air taken up in the vicinity of the hopper 2 is then hot and humid; it is sent to a
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT81106805T ATE11017T1 (en) | 1980-09-04 | 1981-09-01 | DEVICE FOR EXTRACTING HEAT FROM A HYGROSCOPIC GRANULATED MATERIAL WITH A TEMPERATURE BELOW 100 DEGREES CELSIUS. |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8019093 | 1980-09-04 | ||
FR8019093A FR2489489A1 (en) | 1980-09-04 | 1980-09-04 | METHOD OF EXTRACTING THE HEAT OF A HYDROPHILIC PULVERULENT MATERIAL BELOW 100 OC |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0047914A1 true EP0047914A1 (en) | 1982-03-24 |
EP0047914B1 EP0047914B1 (en) | 1985-01-02 |
Family
ID=9245649
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP81106805A Expired EP0047914B1 (en) | 1980-09-04 | 1981-09-01 | Apparatus for extracting heat from a hygroscopic pulverulent material with a temperature lower than 100 degrees centigrade |
Country Status (9)
Country | Link |
---|---|
US (1) | US4377937A (en) |
EP (1) | EP0047914B1 (en) |
AT (1) | ATE11017T1 (en) |
BR (1) | BR8105611A (en) |
CA (1) | CA1162842A (en) |
DE (1) | DE3168042D1 (en) |
ES (1) | ES8206823A1 (en) |
FR (1) | FR2489489A1 (en) |
MA (1) | MA19259A1 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2674320B1 (en) * | 1991-03-21 | 1999-01-29 | Lair Liquide | FREEZING PROCESS AND DEVICE |
NZ250270A (en) * | 1992-12-29 | 1995-07-26 | Boc Group Inc | Freezing food using liquid refrigerant: turbulent flow of refrigerant induced in trough type conveyor |
FR2701552B1 (en) * | 1993-02-10 | 1995-03-24 | Air Liquide | Vibrating aisle freezer. |
DE202010010804U1 (en) * | 2010-07-29 | 2011-11-02 | Lintec Gmbh & Co. Kg | Mobile device for concrete production with cooling of bulk material |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE942271C (en) * | 1952-10-17 | 1956-05-03 | Metallgesellschaft Ag | Process for the continuous cooling of extracted material |
US2863190A (en) * | 1954-10-20 | 1958-12-09 | Fischer Ag Georg | Method and means for cooling granular masses containing evaporable liquid |
US3161485A (en) * | 1957-12-20 | 1964-12-15 | Fischer Ag Georg | Sand cooling plant |
US3172177A (en) * | 1964-02-05 | 1965-03-09 | Herbert C Brauchla | Continuous method of preparing foundry sand |
US3205543A (en) * | 1963-05-27 | 1965-09-14 | Rex Chainbelt Inc | Process and apparatus for cooling foundry sand on a vibratory conveyor |
DE2540124A1 (en) * | 1974-10-10 | 1976-04-22 | Gen Kinematics Corp | FLUID BED COOLING AND MIXING DEVICE |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1844782A (en) * | 1926-10-30 | 1932-02-09 | Krupp Fried Grusonwerk Ag | Apparatus for cooling loose material |
US3089653A (en) * | 1961-09-20 | 1963-05-14 | Dundee Cement Co | Hot clinker conveying and cooling apparatus |
DE1483123A1 (en) * | 1965-01-26 | 1969-01-23 | Peters Ag Claudius | Rust cooler for cement clinker and the like. |
-
1980
- 1980-09-04 FR FR8019093A patent/FR2489489A1/en active Granted
-
1981
- 1981-09-01 EP EP81106805A patent/EP0047914B1/en not_active Expired
- 1981-09-01 AT AT81106805T patent/ATE11017T1/en not_active IP Right Cessation
- 1981-09-01 MA MA19459A patent/MA19259A1/en unknown
- 1981-09-01 DE DE8181106805T patent/DE3168042D1/en not_active Expired
- 1981-09-02 BR BR8105611A patent/BR8105611A/en unknown
- 1981-09-03 ES ES505181A patent/ES8206823A1/en not_active Expired
- 1981-09-03 US US06/299,251 patent/US4377937A/en not_active Expired - Fee Related
- 1981-09-03 CA CA000385117A patent/CA1162842A/en not_active Expired
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE942271C (en) * | 1952-10-17 | 1956-05-03 | Metallgesellschaft Ag | Process for the continuous cooling of extracted material |
US2863190A (en) * | 1954-10-20 | 1958-12-09 | Fischer Ag Georg | Method and means for cooling granular masses containing evaporable liquid |
US3161485A (en) * | 1957-12-20 | 1964-12-15 | Fischer Ag Georg | Sand cooling plant |
US3205543A (en) * | 1963-05-27 | 1965-09-14 | Rex Chainbelt Inc | Process and apparatus for cooling foundry sand on a vibratory conveyor |
US3172177A (en) * | 1964-02-05 | 1965-03-09 | Herbert C Brauchla | Continuous method of preparing foundry sand |
DE2540124A1 (en) * | 1974-10-10 | 1976-04-22 | Gen Kinematics Corp | FLUID BED COOLING AND MIXING DEVICE |
Also Published As
Publication number | Publication date |
---|---|
DE3168042D1 (en) | 1985-02-14 |
ATE11017T1 (en) | 1985-01-15 |
FR2489489B1 (en) | 1984-04-27 |
FR2489489A1 (en) | 1982-03-05 |
ES505181A0 (en) | 1982-08-16 |
MA19259A1 (en) | 1982-04-01 |
EP0047914B1 (en) | 1985-01-02 |
CA1162842A (en) | 1984-02-28 |
US4377937A (en) | 1983-03-29 |
BR8105611A (en) | 1982-05-18 |
ES8206823A1 (en) | 1982-08-16 |
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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AK | Designated contracting states |
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17P | Request for examination filed |
Effective date: 19820916 |
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