Classifications

• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B24—GRINDING; POLISHING
  • B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
  • B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B24—GRINDING; POLISHING
  • B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
  • B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
  • B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
  • B24D3/20—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
  • B24D3/28—Resins or natural or synthetic macromolecular compounds
  • B24D3/285—Reaction products obtained from aldehydes or ketones

Definitions

• the present invention relates to the production of resin bonded abrasive products.
• Resin bonded abrasive products are conventionally produced by cold pressing a blend of particulate abrasive'material and synthetic resins with or without fillers to give a green(uncured)product of the required shape, size and density and subsequently heating the green product to cure the synthetic resin thereby to provide a firmbond between the abrasive particles.
• the pressures normally required for the cold pressing are in the range of 35 - 500 kg/sq. cm., the exact value depending on the properties required for the bonded product.
• Examples of resin bonded abrasive products manufactured by the above process are grinding and especially cut-off wheels i.e. abrasive wheels having a high diameter to thickness ratio (e.g. from 40:1 to 200:1).
• An application of large diameter cut-off wheels is the cutting off of hot steel billets produced by the continuous casting process.
• a method of producing resin bonded abrasive products using a warm pressing operation is also known.
• U.S. Patent No. 4,110,939 suggests that a blend of abrasive and resin may initially be pressed under a pressure of at least 3 kg/cm and at a temperature of 10-100°C prior to curing'of the resin, although, as far as we are aware, such low pressures have not been used commercially for producing resin bonded abrasive products.
• resin bonded abrasive products may be conveniently produced at pressures lower than those suggested for use in warm pressing operations, and substantially lower than those used in cold pressing operations, thereby avoiding the need for the expensive presses used for cold pressing.
• a method of producing a resin bonded abrasive product comprising preparing a blend of a particulate abrasive material and a predominantly powdered thermosetting resin bond, which bond will soften by heating to a temperature below that at which the rate of cross-linking is substantial, heating the blend to soften the resin, applying a pressure below 3 kg/cm 2 to the heated blend to effect compaction of the abrasive particles, and further heating the blend to cure the resin to produce the bonded abrasive product.
• the invention also provides bonded abrasive products made in accordance with the process defined in the preceding paragraph.
• the invention is particularly applicable to the production of grinding wheels and cut-off wheels.
• the bond comprises a liquid phase, which may itself be a thermosetting resin, and a major amount by weight of a powder which will include, or consist wholly of, a particulate thermosetting resin or resins.
• the powder may additionally include inorganic fillers, or organic modifiers such as epoxies, rubber, polyvinyl butyral, or the like, as is well known in the art, to give the desired properties for the finished product.
• the important feature of the invention is the utilisation of the basic properties of predominantly powdered resin bonds which soften on heating to a degree which enables compaction of the composite under a low pressure, i.e. less than 3 kg/cm 2 .
• a low pressure i.e. less than 3 kg/cm 2 .
• the exact pressure used in the method of the invention will be dependent on the flow characteristics of the particular predominantely powdered resin bond system used.
• the pressure will however be less than 3 kg/cm 2 , preferably less than 2.5 kg/cm and will most usually be less than 1.8 kg/cm 2 .
• the preferred pressure range is 0.1 to 1.8 kg/cm 2 with a pressure of about 0.3 kg/cm 2 being suitable for most cases.
• the low pressures required may be applied by means of weights or compressed springs or by low pressure hydraulic or pneumatic methods, or by any other convenient method.
• the predominantly powdered resin bond may be any such bond which softens on heating to a temperature lower than that at which the rate and degree of cross-linking will interfere with the compaction process.
• the bond may have a wide variety of flow'characteristics, and may soften at a greater or lesser temperature to suit the particular application, bearing in mind that the cured bond may have to withstand the forces encountered in high speed grinding or cutting operations.
• the bond used may be based on powdered phenolic novalac resins, together with liquid phenolic resins (e.g. resoles) or wetting agents which can combine with the resins.
• wetting agents are furfural or furfural in combination with cresols or xylenols, or plasticisers which are compatible with the resins at process temperatures.
• plasticisers which are compatible with the resins at process temperatures.
• calcium oxide is added to combine with the volatiles produced in the bord during the curing process.
• Powdered phenolic resins are available with a wide range of flow characteristics, which makes such resins particularly useful for the invention.
• Typical examples of such powdered phenolic resins have flow characteristics varying between l5 mm (low flow) and 100 mm (high flow) as determined by a common flow test used by phenolic resin manufacturers and grinding wheel Producers.
• the flow test ' uses a 0.5 g pellet of resin placed on a level glass plate in an oven, held at 120°C for 5 mins, and the plate is then tilted at an angle of 60°C. The length of the pellet in mm. after 10 minutes is measured and constitutes the flow value.
• Resins with flow values as specified above are readily available and can be utilised in the invention. In the case of bonds formulated with high flow resins it will be apparent that lower temperatures and pressures will be required to consolidate the bond in the process of the invention, than would be required for low flow resins.
• any particulate abrasive material of suitable grit size or combination of grit sizes may be used for the invention.
• abrasive are various types of fused alumina, silicon carbide, fused zirconia-alumina, and sintered abrasive either individually or in combination as commonly used for the production of grinding wheels.
• the blend of the particulate abrasive material and predominantly powdered resin bond may be produced in any convenient way.
• the abrasive material is firstly wetted with the liquid components of the bond, and then the powdered resin, optionally including fillers, is added and blended so that the powder adheres uniformly to the liquid coating on the abrasive.
• the formulation may be such that between the bond coated abrasive particles there exist resin particles wetted with a liquid which is a non-solvent for the resin at room temperature, but which combines with the resin during curing.
• the next step is to shape and compact the blend prior to curing of the resin.
• the blend may be introduced into a suitable mould, in which it is softened by heating and compacted to give a body of the required shape.
• the mould for producing a wheel may comprise a ring and a pin on a metal plate and, after the cavity is filled with the blend, a plunger is placed on the mould and the assembly heated to a temperature at which the bond softens and flows under the applied low pressure. Generally this temperature will be in the range of 30-100°C, the exact value depending on the flow characteristics and cross-linking rate of the bond.
• the composite produced is heated to a higher temperature to cure the resin and produce a resin bonded abrasive product.
• the pressure applied during compaction is maintained during the curing operation.
• the softening, compaction and curing are conveniently effected in a single oven with a programmed temperature control allowing the temperature of the oven to be raised firstly to the softening/ compaction temperature and, after a predetermined time, secondly to the curing temperature which is again maintained for a predetermined time prior to cooling of the body.
• the temperature of the oven may be slowly and continuously raised to the curing temperature, th p oven being at a temperature at which the resin is soft for a sufficient time to effect the desired compaction.
• the mould and also the plunger can be preheated to the required temperature prior to adding the blend and the low pressure can be applied after the relatively short period required for the blend to attain the mould temperature.
• the bottom plate of the mould can be a thin metal plate and, after distributing the blend into the mould, the barrel and pin can be removed leaving the blend in a thin layer on the plate.
• a number of similar plates carrying evenly spread layers of blend can be stacked on top of each other and covered with a plate on top of which are placed further plates of a weight sufficient to provide the low pressure required for consolidation.
• the whole assembly is then heated in an oven initially at the temperature required for consolidation to take place, and once this has been achieved the temperature is raised to completely cure the wheels.
• at least three spacers of a predetermined thickness may be placed between each pair of supporting plates in the stack, so that when the required degree of consolidation has taken place the top plate rests on the spacers.
• the blend can be distributed onto the mould base plate which is then placed in a microwave preheating oven for the period required to raise the temperature to the required degree. The plate is then removed from the microwave oven, a further plate placed on top of the blend the required low pressure is applied to achieve the required degree of consolidation and the wheel is finally cured between the plates or bats.
• the finally formed cured wheel may be produced directly in the mould, or alternatively the cured disc may be machined to size.
• the blend may be spread onto a plate, similar in size to the desired wheel size, covered with a similar sized plate, and after the low temperature and pressure have been applied to consolidate the bond, the excess mix which exudes from between the plates is removed by a scraper whilst it is still soft and plastic before subsequently completing the curing cycle.
• the bore of the wheel can be formed by placing a pin through a hole in the plate to give the desired hole size.
• Metal bushes to give the desired arbor size can also be incorporated into the wheel arbor to eliminate the necessity for finishing the bore.
• the process described can be applied equally to the production of both reinforced and non-reinforced resin bonded bodies, e.g. cut-off wheels.
• the reinforcement which will be one or more fabric layers, may be placed externally and/or internally of the wheel.
• the reinforcing layers commonly used are discs of phenolic resin impregnated woven or non-woven glass fabric.
• the method of the invention provides a convenient and easy way of producing a wide range of resin bonded abrasive bodies without the need for expensive presses. It is a further advantage of the invention that the method allows the use relatively inexpensive moulds with a high life expectancy. This is to be contrasted with the cold pressing process in which expensive heavy duty moulds are required in order to withstand the high pressures involved. Such moulds require frequent replacement due to a high wear rate resulting from application of abrasive.under high pressure to the mould surface.
• the invention is illustrated by the following Examples describing the production of cut off wheels by the method of the invention and also by a conventional cold pressing method.
• the mould for producing the cut off wheels comprised a circular bottom plate, an annular ring (or barrel) located in a shallow peripheral annular recess on the upper surface of the bottom plate, a centre pin centrally located on the upper surface of the bottom plate, and a centrally apertured plunger plate locatable over the centre pin and slidable within the barrel.
• the plunger plate serves to apply pressure to the contents of the mould to effect consolidation thereof.
• This Example illustrates the production of a cut off wheel having a diameter of 1220 mm, a thickness of 10 mm, and an arbor hole of 152.4 mm. by the method of the invention.
• the mould used had a bottom plate of diameter 1370 mm, a barrel having an inner diameter of 1235mm., and a centre pin of 150 mm diameter.
• the cut off wheel was prepared from the following ingredients:-
• the CS 14 and CL50 resins are produced by The Carborundum Co. Limited, Chemical Products Division.
• a bond coated granular mix was prepared by first wetting the abrasive grain in a mixer with the liquid phenolic resin. The powdered resin and fillers were then added and mixing continued until the blended powdered bond adhered to the abrasive grains to produce granular bond coated grains which could be readily separated but which adhered to each other under the influence of high pressure at room temperature.
• the cut off wheel was prepared as follows.
• a circular black tissue paper of 1235 mm diameter and with an aperture to locate over the centre pin was placed in the base of the mould followed by a 750 mm diameter phenolic resin impregnated glass fabric flange ply (external reinforcement for the finished wheel).
• One third of the abrasive mix required to give a finished wheel of 10 mm thickness was distributed in the mould and levelled to give an even layer.
• a full diameter ply of phenolic resin impregnated glass fabric (internal reinforcement for the finished wheel) was placed on top of the layer and flattened.
• a second layer of one third of the abrasive mix was distributed on top of the glass fabric and levelled.
• a further full diameter phenolic resin impregnated glass fabric was placed on the second mix layer followed by the final one third of the mix, which was then levelled to form an even layer.
• a flange ply similar to that used in the base of the mould was located on top of the upper mix layer and a circular black tissue paper laid over the flange ply, The plunger was then placed on the upper layer of tissue paper, and the barrel and centre pin removed.
• the assembly of unconsolidated wheel, plunger and bottom plate was transferred to a curing oven and a load was applied to the plunger so as to apply a pressure of 0.3 kg cm -2 to the wheel area.
• the load may for example be applied by weights.
• the oven was heated for a period of six hours at 70°C. During this heating the resin softened and the plunger moved downwardly to consolidate the bond. Consolidation was complete after six hours.
• Curing of the resin was effected by raising the temperature of the oven to 175°C over a period of 20 hours and holding this temperature for 9 hours. Subsequently the wheels were cooled to room temperature over a period of 24 hours.
• the arbor apertures of the cured wheels were then ground to the required diameter of 152.4 mm and the wheel periphery was ground concentric with the arbor to 1220 mm diameter.
• This Example describes the production of a cut off wheel of similar dimensions to that produced in Example 1 but using the conventional cold-pressing process.
• Example 1 The procedure of Example 1 was followed up to the point where the plunger is placed on the mould, which was then transferred to a press capable of taking a mould of 1370 mm diameter. A pressure of 70 kg cm -2 of wheel area (approximate total pressure 800 tonnes) was applied for 15 seconds to consolidate the wheel.
• Example 1 he wheel was cured in an oven in which the temperature was increased at a slow rate from room temperature to 70°C over a period of 8 hours and then to a temperature of 175°C over 20 hours. The oven was held at this temperature for 9 hours. As in Example 1 the wheel was cooled to room temperature over a period of 24 hours and then ground to the required dimensions.
• Wheels prepared by the methods of Examples 1 and 2 had similar densities of 2.33 grams/cc.
• the wheels were evaluated by cutting through 20 cm diameter Incalloy ingots with a cutting speed of 80 m/sec.
• the wheel produced in Example 1 gave a grinding ratio (i.e. ratio of area of metal cut to area of wheel worn) of 1.18 compared with a value of 1.00 for wheels produced by Example 2.
• the freedom of cut was similar for both wheels. Additionally the"squareness of cut” was similar for both wheels.
• the "squareness of cut” is an indication of the extent to which the wheels cut the ingots at right angles to ingot axes. Any deviation from a right angled cut indicates wheel breakdown with formation of a champhered periphery
• This Example describes the production of a wheel using the method of the invention and having a diameter of 1800 mm, a thickness of 18 mm. and an arbor hole of 450 mm diameter. As previously a mould was used which gave an undersized arbor hole and oversize wheel diameter so that the wheel could be finished by grinding.
• the wheel was prepared from the ingredients listed in Example 1 save that the 69.5 parts by weight of white fused aluminium oxide was replaced by the following mixture of abrasives.
• the wheel was to be externally reinforced with flange 'plies of 1220 mm diameter and internally reinforced with five plies of phenolic resin impregnated glass fabric (PRIGF). As full diameter PRIGF plies were not commercially available, semi-circular sections were cut from a roll of the fabric to fit into the mould with a 5 cm overlap.
• PRIGF phenolic resin impregnated glass fabric
• the position of the overlap on the five layers of PRIGF was staggered so that the overlays of each consecutive layer were positioned at an angle of 60 degrees in a clockwise direction.
• Example 1 The abrasive, resin and filler were mixed together as in Example 1.
• the mould was filled using the following sequence of operations.
• the mould containing the uncompressed wheel was placed on a stand, the plunger placed in position and the barrel and centre pin removed.
• the assembly was then transferred to a curing oven and a load applied to the plunger to give a weight of 0.3 kg/cm. -2 over the wheel area.
• the weighted wheel was then consolidated and cared under the conditions employed in Example 1.
• the arbor hole and the periphery were then ground to the required dimensions.
• Three wheels prepared by the above method were test speeded to destruction and burst at speeds of 170 to 174m/sec. This was well in excess of the minimum bursting speed of 140 m/sec. as specified for a maximum operating speed of 100 m/sec. by the German Grinding Wheel Committee is the accepted grinding wheel safety standard authority in Europe.
• a wheel as described was used to cut 80 mm diameter billets at a temperature of 800-900°C on a converted cold saw with a 250 KW motor. A cutting time of 1.7 seconds was obtained and a grinding ratio of 11.9 at an operating speed of.100 m/sec.

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• Engineering & Computer Science (AREA)
• Mechanical Engineering (AREA)
• Manufacturing & Machinery (AREA)
• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Polishing Bodies And Polishing Tools (AREA)
• Manufacture Of Macromolecular Shaped Articles (AREA)

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Citations (4)

• 1981
  • 1981-02-13 EP EP81300601A patent/EP0034898A3/de not_active Withdrawn
  • 1981-02-14 JP JP2080781A patent/JPS56134178A/ja active Pending

Patent Citations (4)

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