EA202191930A1 - Способ производства метанола из синтез-газа, произведенного каталитическим частичным окислением, интегрированным с крекингом - Google Patents

Способ производства метанола из синтез-газа, произведенного каталитическим частичным окислением, интегрированным с крекингом

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EA202191930A1
EA202191930A1 EA202191930A EA202191930A EA202191930A1 EA 202191930 A1 EA202191930 A1 EA 202191930A1 EA 202191930 A EA202191930 A EA 202191930A EA 202191930 A EA202191930 A EA 202191930A EA 202191930 A1 EA202191930 A1 EA 202191930A1
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hydrogen
cpo
hydrocarbons
stream
rich
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EA202191930A
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English (en)
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Сивадинарайана Чинта
Равичандер Нарайанасвами
Атул Пант
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Эни С.П.А.
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Publication of EA202191930A1 publication Critical patent/EA202191930A1/ru

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    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
    • B01D53/047—Pressure swing adsorption
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    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/229—Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
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    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
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    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/382—Multi-step processes
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    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
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    • C07C29/74—Separation; Purification; Use of additives, e.g. for stabilisation
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    • C07C29/76—Separation; Purification; Use of additives, e.g. for stabilisation by physical treatment
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    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
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    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/14—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts
    • C10G11/18—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid catalysts according to the "fluidised-bed" technique
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
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    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/061—Methanol production
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    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0833—Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases
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    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/22—Higher olefins
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Предложен способ производства синтез-газа и олефинов, включающий подачу смеси реагентов каталитического частичного окисления (КЧО) (кислород, первые углеводороды, водяной пар) в реактор КЧО (катализатор КЧО), где смесь реагентов КЧО взаимодействует посредством реакции КЧО в реакторе КЧО с получением выходящего потока реактора КЧО (H2, CO, CO2, вода, непрореагировавшие первые углеводороды); подачу сырья крекинг-установки (вторые углеводороды) в крекинг-установку с получением продукта крекинг-установки (олефинов), богатого водородом потока (водород, CH4) и потока извлечения углеводородов (C4+ углеводороды), где первый и второй углеводороды являются одинаковыми или разными; извлечение обогащенного водородом потока (водород) и обогащенного углеводородами потока (CH4) из богатого водородом потока; и введение в контакт выходящего потока реактора КЧО с обогащенным водородом потоком с получением обогащенного водородом синтез-газа, и где отношение M ((H2-CO2)/(CO+CO2)) обогащенного водородом синтез-газа больше, чем отношение M выходящего потока реактора КЧО.
EA202191930A 2019-01-17 2019-12-31 Способ производства метанола из синтез-газа, произведенного каталитическим частичным окислением, интегрированным с крекингом EA202191930A1 (ru)

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US201962793606P 2019-01-17 2019-01-17
PCT/US2019/069067 WO2020150005A1 (en) 2019-01-17 2019-12-31 Methanol production process from syngas produced by catalytic partial oxidation integrated with cracking

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US (1) US20220081380A1 (ru)
EP (1) EP3911596A4 (ru)
CN (1) CN113574009A (ru)
AU (1) AU2019423356A1 (ru)
CA (1) CA3126756A1 (ru)
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US11643608B2 (en) * 2018-11-07 2023-05-09 Exxonmobil Chemical Patents Inc. Process for C5+ hydrocarbon conversion
US20230167561A1 (en) * 2021-11-23 2023-06-01 Halliburton Energy Services, Inc. Continuous Capture of Carbon Dioxide From Exhaust Gas and Conversion Thereof to Useful Chemistries
WO2024112376A1 (en) * 2022-11-23 2024-05-30 University Of Southern California A reactive separation process for carbon dioxide capture from flue gas

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NO171409C (no) * 1982-09-30 1993-03-10 Engelhard Corp Fremgangsmaate ved fremstilling av en hydrogenrik gass vedautotermisk reformering av et hydrokarbonholdig utgangsmateriale
US6903139B2 (en) * 2002-11-19 2005-06-07 Conocophillips Company Production of synthesis gas from a feed stream comprising hydrogen
US8216323B2 (en) * 2005-06-30 2012-07-10 General Electric Company System and method for hydrogen production
DE102006054472B4 (de) * 2006-11-18 2010-11-04 Lurgi Gmbh Verfahren zur Gewinnung von Kohlendioxid
EP2499222A2 (en) * 2009-11-10 2012-09-19 Shell Internationale Research Maatschappij B.V. Process for producing olefins
WO2013062415A1 (en) * 2011-10-26 2013-05-02 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Method for producing synthesis gas for methanol production
RU2648327C2 (ru) * 2013-01-16 2018-03-23 Басф Се Способ получения ацетилена и синтез-газа
WO2017087125A1 (en) * 2015-11-16 2017-05-26 Sabic Global Technologies, B.V. A carbon efficient process for converting methane to olefins and methanol by oxidative coupling of methane
EP3405448A4 (en) * 2015-12-14 2019-07-17 SABIC Global Technologies B.V. METHANE CONVERSION TO ETHYLENE COMPRISING INTEGRATION IN IN SITU ETHANE CRACKING AND DIRECT CONVERSION OF THE CO2 BYPRODUCT TO METHANOL
WO2018202829A1 (en) * 2017-05-05 2018-11-08 Borealis Ag Integrated process for producing c2+ hydrocarbons and a process system for such a process

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WO2020150005A1 (en) 2020-07-23
US20220081380A1 (en) 2022-03-17
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EP3911596A4 (en) 2022-10-19
CA3126756A1 (en) 2020-07-23
CN113574009A (zh) 2021-10-29

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