EA201691003A1 - Реактор на топливных элементах и способ прямой конверсии углеводородсодержащего газа в продукт высших углеводородов - Google Patents

Реактор на топливных элементах и способ прямой конверсии углеводородсодержащего газа в продукт высших углеводородов

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Publication number
EA201691003A1
EA201691003A1 EA201691003A EA201691003A EA201691003A1 EA 201691003 A1 EA201691003 A1 EA 201691003A1 EA 201691003 A EA201691003 A EA 201691003A EA 201691003 A EA201691003 A EA 201691003A EA 201691003 A1 EA201691003 A1 EA 201691003A1
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Eurasian Patent Office
Prior art keywords
reactor
product
higher hydrocarbons
walls
direct conversion
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EA201691003A
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English (en)
Inventor
Хассан Модарреси
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Хальдор Топсёэ А/С
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Application filed by Хальдор Топсёэ А/С filed Critical Хальдор Топсёэ А/С
Publication of EA201691003A1 publication Critical patent/EA201691003A1/ru

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    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/80—Processes with the aid of electrical means
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • H—ELECTRICITY
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    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H—ELECTRICITY
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    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04097—Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with recycling of the reactants
    • H—ELECTRICITY
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    • H—ELECTRICITY
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    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
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    • H01—ELECTRIC ELEMENTS
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    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
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    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0637—Direct internal reforming at the anode of the fuel cell
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    • H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
    • H01M8/0675—Removal of sulfur
    • H—ELECTRICITY
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
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    • C01B2203/0465—Composition of the impurity
    • C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
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    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
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    • C01B2203/0495—Composition of the impurity the impurity being water
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    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
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    • C01B2203/1241—Natural gas or methane
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    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1258—Pre-treatment of the feed
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    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/14—Details of the flowsheet
    • C01B2203/148—Details of the flowsheet involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
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    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Abstract

Ректор на топливных элементах, предпочтительно реактор на твердооксидных топливных элементах (ТОТЭ), для осуществления прямой конверсии углеводородсодержащего газа в продукт высших углеводородов, ограничен стенками, в котором реагирующие вещества втекают в анодные секции, и воздух подают в катодные секции, а кислород переносится с одной стороны стенок к другой стороне стенок для интенсификации или замедления химической реакции. Способ прямой конверсии углеводородсодержащего газа в продукт высших углеводородов осуществляют в анодной секции реактора, в которой полученный водород, ограничивающий конверсию до равновесия, вступает в реакцию в реакционной смеси с ионами кислорода, переносимыми из катодной секции для получения пара, таким образом удаляя из реакции ограничивающий равновесие водород.
EA201691003A 2013-11-20 2014-11-04 Реактор на топливных элементах и способ прямой конверсии углеводородсодержащего газа в продукт высших углеводородов EA201691003A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP13193626.2A EP2876097B1 (en) 2013-11-20 2013-11-20 Process for direct conversion of a hydrocarbon-containing gas to a higher hydrocarbons product and reactor for performing the process
PCT/EP2014/073674 WO2015074864A1 (en) 2013-11-20 2014-11-04 A fuel cell reactor and a process for direct conversion of a hydrocarbon-containing gas to a higher hydrocarbons product

Publications (1)

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EA201691003A1 true EA201691003A1 (ru) 2016-11-30

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EA201691003A EA201691003A1 (ru) 2013-11-20 2014-11-04 Реактор на топливных элементах и способ прямой конверсии углеводородсодержащего газа в продукт высших углеводородов
EA202092175A EA202092175A1 (ru) 2013-11-20 2014-11-04 Реактор на топливных элементах и способ прямой конверсии углеводородсодержащего газа в продукт высших углеводородов

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US (2) US10851029B2 (ru)
EP (1) EP2876097B1 (ru)
CN (1) CN105849034B (ru)
EA (2) EA201691003A1 (ru)
NO (1) NO2876097T3 (ru)
TW (1) TWI653214B (ru)
WO (1) WO2015074864A1 (ru)

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US9945801B1 (en) * 2016-10-14 2018-04-17 Air Products And Chemicals, Inc. Monitoring the activity of reforming catalyst
US10903511B2 (en) * 2016-11-29 2021-01-26 Lockheed Martin Energy, Llc Flow batteries having adjustable circulation rate capabilities and methods associated therewith
CN109385643B (zh) * 2017-08-10 2020-06-09 中国石油天然气股份有限公司 将甲烷转化为脂肪烃的方法、燃料电池及燃料电池的制备方法
US20220285712A1 (en) * 2021-03-04 2022-09-08 Saudi Arabian Oil Company Integrated production of hydrogen, electricity, and heat
CN114988364B (zh) * 2022-06-13 2023-05-12 重庆科技学院 一种基于天然气制氢与燃料电池技术的发电系统

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Also Published As

Publication number Publication date
NO2876097T3 (ru) 2018-07-28
EA202092175A1 (ru) 2021-01-13
TW201538457A (zh) 2015-10-16
TWI653214B (zh) 2019-03-11
US10851029B2 (en) 2020-12-01
US20160297727A1 (en) 2016-10-13
CN105849034B (zh) 2018-05-04
US20190375695A1 (en) 2019-12-12
US11078131B2 (en) 2021-08-03
EP2876097B1 (en) 2018-02-28
EP2876097A1 (en) 2015-05-27
CN105849034A (zh) 2016-08-10
WO2015074864A1 (en) 2015-05-28

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