EA201401325A1 - Способ высокотемпературной селективной абсорбции сероводорода - Google Patents

Способ высокотемпературной селективной абсорбции сероводорода

Info

Publication number
EA201401325A1
EA201401325A1 EA201401325A EA201401325A EA201401325A1 EA 201401325 A1 EA201401325 A1 EA 201401325A1 EA 201401325 A EA201401325 A EA 201401325A EA 201401325 A EA201401325 A EA 201401325A EA 201401325 A1 EA201401325 A1 EA 201401325A1
Authority
EA
Eurasian Patent Office
Prior art keywords
temperature selective
selective absorption
gas stream
hydrogen
hydrogen sulfide
Prior art date
Application number
EA201401325A
Other languages
English (en)
Other versions
EA026972B1 (ru
Inventor
Джеймс Эдвард Критчфилд
Цзинцзюнь Чжоу
Original Assignee
Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Хантсмен Петрокемикал Ллк
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Шелл Интернэшнл Рисерч Маатсхаппий Б.В., Хантсмен Петрокемикал Ллк filed Critical Шелл Интернэшнл Рисерч Маатсхаппий Б.В.
Publication of EA201401325A1 publication Critical patent/EA201401325A1/ru
Publication of EA026972B1 publication Critical patent/EA026972B1/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1493—Selection of liquid materials for use as absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1425—Regeneration of liquid absorbents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/1456—Removing acid components
    • B01D53/1468—Removing hydrogen sulfide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/52—Hydrogen sulfide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/0408—Pretreatment of the hydrogen sulfide containing gases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/02—Preparation of sulfur; Purification
    • C01B17/04—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides
    • C01B17/0404—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process
    • C01B17/0456—Preparation of sulfur; Purification from gaseous sulfur compounds including gaseous sulfides by processes comprising a dry catalytic conversion of hydrogen sulfide-containing gases, e.g. the Claus process the hydrogen sulfide-containing gas being a Claus process tail gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B17/00—Sulfur; Compounds thereof
    • C01B17/16—Hydrogen sulfides
    • C01B17/167—Separation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C217/00—Compounds containing amino and etherified hydroxy groups bound to the same carbon skeleton
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/202—Alcohols or their derivatives
    • B01D2252/2023—Glycols, diols or their derivatives
    • B01D2252/2026—Polyethylene glycol, ethers or esters thereof, e.g. Selexol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2252/00—Absorbents, i.e. solvents and liquid materials for gas absorption
    • B01D2252/20—Organic absorbents
    • B01D2252/204—Amines
    • B01D2252/20405—Monoamines

Abstract

Способ высокотемпературной селективной абсорбции, осуществляемой для очистки газового потока, имеющего определенные концентрации сероводорода и диоксида углерода, и получения очищенного газового потока с пониженной концентрацией сероводорода. Способ высокотемпературной селективной абсорбции использует исключительно новую композицию абсорбента, которая позволяет производить обработку газового потока в затрудненных условиях абсорбции и обеспечивает другие преимущества процесса абсорбции, проводимого в соответствии с изобретением.
EA201401325A 2012-05-31 2013-05-29 Способ высокотемпературной селективной абсорбции сероводорода EA026972B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261653927P 2012-05-31 2012-05-31
PCT/US2013/043110 WO2013181249A1 (en) 2012-05-31 2013-05-29 A process for the high temperature selective absorption of hydrogen sulfide

Publications (2)

Publication Number Publication Date
EA201401325A1 true EA201401325A1 (ru) 2015-04-30
EA026972B1 EA026972B1 (ru) 2017-06-30

Family

ID=48577948

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201401325A EA026972B1 (ru) 2012-05-31 2013-05-29 Способ высокотемпературной селективной абсорбции сероводорода

Country Status (12)

Country Link
US (1) US20150151241A1 (ru)
EP (1) EP2854992A1 (ru)
JP (1) JP2015525121A (ru)
KR (1) KR20150044857A (ru)
CN (1) CN104718014A (ru)
AU (1) AU2013267521B2 (ru)
BR (1) BR112014029667A2 (ru)
CA (1) CA2874734A1 (ru)
EA (1) EA026972B1 (ru)
IN (1) IN2014DN10048A (ru)
MX (1) MX2014014373A (ru)
WO (1) WO2013181249A1 (ru)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2748547C2 (ru) * 2016-11-01 2021-05-26 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ получения очищенного газового потока

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3347621A (en) 1964-11-02 1967-10-17 Shell Oil Co Method of separating acidic gases from gaseous mixtures
US4080423A (en) * 1974-04-17 1978-03-21 Massachusetts Institute Of Technology Gas absorption
US3965244A (en) 1974-11-27 1976-06-22 Shell Oil Company Selective removal of sulfur compounds from acid gas mixtures containing significant quantities of carbonyl sulfide
US3989811A (en) 1975-01-30 1976-11-02 Shell Oil Company Process for recovering sulfur from fuel gases containing hydrogen sulfide, carbon dioxide, and carbonyl sulfide
US4152353A (en) 1977-08-29 1979-05-01 The Dow Chemical Company Method of producing amines from alcohols, aldehydes, ketones and mixtures thereof
US4240922A (en) * 1977-09-22 1980-12-23 Exxon Research & Engineering Co. Process and amine-solvent absorbent for removing acidic gases from gaseous mixtures
US4471138A (en) * 1982-01-18 1984-09-11 Exxon Research And Engineering Co. Severely sterically hindered secondary aminoether alcohols
US4405583A (en) * 1982-01-18 1983-09-20 Exxon Research And Engineering Co. Process for selective removal of H2 S from mixtures containing H22 using di-severely sterically hindered secondary aminoethers
US4894178A (en) 1987-10-13 1990-01-16 Exxon Research And Engineering Company Absorbent composition containing severely-hindered amine mixture for the absorption of H2 S
US4961873A (en) 1987-10-13 1990-10-09 Exxon Research And Engineering Company Absorbent composition containing a severely-hindered amine mixture with amine salts and/or aminoacid additives for the absorption of H2 S
DE19742911A1 (de) 1997-09-29 1999-04-01 Basf Ag Verfahren zur Herstellung von Aminen
US7196033B2 (en) 2001-12-14 2007-03-27 Huntsman Petrochemical Corporation Advances in amination catalysis
CA2618499C (en) * 2005-08-09 2013-08-20 Exxonmobil Research And Engineering Company Alkylamino alkyloxy (alcohol) monoalkyl ether for acid gas scrubbing process
EP1911506B1 (de) * 2006-10-06 2009-08-19 Umicore AG & Co. KG Stickoxidspeicherkatalysator mit abgesenkter Entschwefelungstemperatur
US9352271B2 (en) * 2010-12-01 2016-05-31 Huntsman Petrochemical Llc Sterically hindered amines and associated methods

Also Published As

Publication number Publication date
AU2013267521A1 (en) 2014-12-11
CA2874734A1 (en) 2013-12-05
EA026972B1 (ru) 2017-06-30
KR20150044857A (ko) 2015-04-27
EP2854992A1 (en) 2015-04-08
BR112014029667A2 (pt) 2017-08-22
WO2013181249A1 (en) 2013-12-05
AU2013267521B2 (en) 2015-11-26
US20150151241A1 (en) 2015-06-04
CN104718014A (zh) 2015-06-17
IN2014DN10048A (ru) 2015-08-14
MX2014014373A (es) 2015-06-23
JP2015525121A (ja) 2015-09-03

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Legal Events

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MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KG TJ

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): KZ TM RU