EA201391784A1 - Способ каталитической конверсии синтез-газа в углеводороды - Google Patents

Способ каталитической конверсии синтез-газа в углеводороды

Info

Publication number
EA201391784A1
EA201391784A1 EA201391784A EA201391784A EA201391784A1 EA 201391784 A1 EA201391784 A1 EA 201391784A1 EA 201391784 A EA201391784 A EA 201391784A EA 201391784 A EA201391784 A EA 201391784A EA 201391784 A1 EA201391784 A1 EA 201391784A1
Authority
EA
Eurasian Patent Office
Prior art keywords
sic
catalytic conversion
composite
hydrocarbon
synthesis gas
Prior art date
Application number
EA201391784A
Other languages
English (en)
Other versions
EA025257B1 (ru
Inventor
Франсис Люк
Шарлотт Фам
Патрик Нгуйен
Кюонг Фам-Хюю
Бенуа Де Тимовски
Original Assignee
СИКАТ ЭлЭлСи
Тоталь С.А.
Сантр Насьональ Де Ля Решерш Сьянтифик
Юниверсите Де Страсбур
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR1101704A external-priority patent/FR2978681A1/fr
Application filed by СИКАТ ЭлЭлСи, Тоталь С.А., Сантр Насьональ Де Ля Решерш Сьянтифик, Юниверсите Де Страсбур filed Critical СИКАТ ЭлЭлСи
Publication of EA201391784A1 publication Critical patent/EA201391784A1/ru
Publication of EA025257B1 publication Critical patent/EA025257B1/ru

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8906—Iron and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/22—Carbides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/20—Carbon compounds
    • B01J27/22—Carbides
    • B01J27/224—Silicon carbide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/612—Surface area less than 10 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/651—50-500 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1022—Fischer-Tropsch products
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70—Catalyst aspects
    • C10G2300/703—Activation

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Nanotechnology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Способ каталитической конверсии, по меньшей мере парциальной, смеси газов, содержащей моно монооксид углерода и водород, в смесь углеводородов, включающий этап контактирования указанной газовой смеси с твердым катализатором, причем указанный твердый катализатор содержит пористую подложку, содержащую композиционный материал, включающий SiC и карбид титана (композит, обозначенный SiC/TiC) и/или оксид титан (композит, обозначенный SiC/TiO), и активную фазу. Подложка может быть получена в форме зерен, шариков или экструдатов, или в форме цилиндров или пластинок ячеистого пеноматериала. Мольное содержание в ней титана в расчете на сумму мольных содержаний Si+Ti предпочтительно составляет от 0,5 до 15%.
EA201391784A 2011-06-01 2012-05-31 Способ каталитической конверсии синтез-газа в углеводороды EA025257B1 (ru)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1101704A FR2978681A1 (fr) 2011-06-01 2011-06-01 Procede catalytique pour la conversion d'un gaz de synthese en hydrocarbures
FR1157096A FR2978682B1 (fr) 2011-06-01 2011-08-02 Procede catalytique pour la conversion d'un gaz de synthese en hydrocarbures
PCT/FR2012/051224 WO2012164231A1 (fr) 2011-06-01 2012-05-31 Procédé catalytique pour la conversion d'un gaz de synthèse en hydrocarbures

Publications (2)

Publication Number Publication Date
EA201391784A1 true EA201391784A1 (ru) 2014-04-30
EA025257B1 EA025257B1 (ru) 2016-12-30

Family

ID=46354407

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201391784A EA025257B1 (ru) 2011-06-01 2012-05-31 Способ каталитической конверсии синтез-газа в углеводороды

Country Status (10)

Country Link
US (1) US9493381B2 (ru)
EP (1) EP2714848B1 (ru)
CN (1) CN103748193B (ru)
AP (1) AP3640A (ru)
AU (1) AU2012264468B2 (ru)
BR (1) BR112013030497A2 (ru)
EA (1) EA025257B1 (ru)
FR (1) FR2978682B1 (ru)
WO (1) WO2012164231A1 (ru)
ZA (1) ZA201308854B (ru)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014140973A1 (en) * 2013-03-14 2014-09-18 Sasol Technology (Pty) Limited A hydrocarbon synthesis process using a cobalt-based catalyst supported on a silicon carbide comprising support
WO2014207096A1 (en) 2013-06-27 2014-12-31 Sicat Method for manufacturing shaped beta-sic mesoporous products and products obtained by this method
CN106268892B (zh) * 2015-06-12 2018-08-24 中国科学院大连化学物理研究所 用于co加氢制c2含氧化合物的催化剂及其制备和应用
WO2017009428A1 (en) * 2015-07-14 2017-01-19 Bp P.L.C. Extruded titania-based material comprising zirconium oxide
US10683247B1 (en) * 2018-12-21 2020-06-16 Honeywell International Inc. Catalysts and integrated processes for producing trifluoroiodomethane

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5484757A (en) 1994-06-02 1996-01-16 Norton Chemical Process Products Corp. Titania-based catalyst carriers
US5648312A (en) * 1994-12-29 1997-07-15 Intevep, S.A. Hydrogenation catalyst with improved attrition resistance and heat dissipation
ATE341396T1 (de) 2000-07-24 2006-10-15 Sasol Tech Pty Ltd Verfahren zur herstellung von kohlenwasserstoffen aus einem synthesegas
GB0030170D0 (en) 2000-12-11 2001-01-24 Norske Stats Oljeselskap Fischer-tropsch catalyst
DE602004005107T2 (de) * 2003-07-02 2007-06-28 Haldor Topsoe A/S Verfahren und Filter zur katalytischen Behandlung von Dieselabgasen
US7163963B2 (en) 2003-09-08 2007-01-16 Conocophillips Company Chemically and thermally stabilized alumina for Fischer-Tropsch catalysts
US7348293B2 (en) 2003-12-05 2008-03-25 Chevron U.S.A. Inc. Homogeneous modified-alumina Fischer-Tropsch catalyst supports
US20060133977A1 (en) * 2004-12-22 2006-06-22 Male Jonathan L Catalyst system and method for the reduction of NOx
GB0704003D0 (en) * 2007-03-01 2007-04-11 Oxford Catalysts Promoted carbide-based fischer-tropsch catalyst, method for its preparation and uses thereof
EP1985361A1 (en) * 2007-04-24 2008-10-29 Järäs, Sven Method for depositing metal particles on a support
GB0819849D0 (en) * 2008-10-30 2008-12-03 Johnson Matthey Plc Cobalt catalyst precursor
WO2011028466A2 (en) * 2009-08-24 2011-03-10 University Of South Florida Eggshell catalyst and method of its preparation
EP2314557A1 (en) * 2009-10-23 2011-04-27 Netherlands Organisation for Scientific Research (Advanced Chemical Technologies for Sustainability) Production of lower olefins from synthesis gas
GB201014950D0 (en) * 2010-09-08 2010-10-20 Johnson Matthey Plc Catalyst manufacturing method

Also Published As

Publication number Publication date
US20140194542A1 (en) 2014-07-10
CN103748193B (zh) 2017-06-06
EA025257B1 (ru) 2016-12-30
FR2978682A1 (fr) 2013-02-08
CN103748193A (zh) 2014-04-23
AP2013007309A0 (en) 2013-12-31
BR112013030497A2 (pt) 2016-09-27
ZA201308854B (en) 2016-02-24
AU2012264468B2 (en) 2016-09-22
FR2978682B1 (fr) 2016-01-01
US9493381B2 (en) 2016-11-15
WO2012164231A1 (fr) 2012-12-06
AP3640A (en) 2016-03-14
EP2714848A1 (fr) 2014-04-09
EP2714848B1 (fr) 2019-05-22

Similar Documents

Publication Publication Date Title
EA201391784A1 (ru) Способ каталитической конверсии синтез-газа в углеводороды
EA201000055A1 (ru) Каталитическое гидрирование диоксида углерода до смеси синтез-газа
Nishikawa et al. Promoting effect of Pt addition to Ni/CeO2/Al2O3 catalyst for steam gasification of biomass
Zeng et al. Promotion effect of single or mixed rare earths on cobalt-based catalysts for Fischer–Tropsch synthesis
MX2012005845A (es) Proceso para la preparacion de un catalizador de zeolita de titanio.
MX2012010334A (es) Catalizador para la conversión de monóxido de carbono.
WO2006063230A8 (en) Catalyst and method for converting low molecular weight paraffinic hydrocarbons into alkenes
WO2015055349A1 (en) Integrated process/plant for storage of co2 by conversion to synthetic natural gas
WO2014188278A3 (en) Clay mineral supported catalysts
MX2009003133A (es) Metodos para la conversion de metano a hidrocarburos utiles, catalizadores para el uso en los mismos y regeneracion de los catalizadores.
BRPI0915369B8 (pt) processo para enriquecimento do gás síntese em hidrogênio e uso de um catalisador contendo os óxidos de zinco e alumínio
EA200702557A1 (ru) Приготовление катализатора
TW200635665A (en) Charging of a reactor
RU2013134233A (ru) Способ получения органических соединений с помощью ферментации биомассы и катализа на цеолите
EA200701037A1 (ru) Способ каталитического дегидрирования пропана в пропилен
TN2014000178A1 (en) PROCESS FOR THE CATALYTIC REMOVAL OF CARBON DIOXIDE, NOx FROM EXHAUST GASES
MY171117A (en) A catalyst for treating exhaust gas of natural gas vehicles
EA201000253A1 (ru) Частичное окисление углеводородов
WO2009083082A3 (de) Poröse monolithische materialien
WO2012118656A3 (en) Method of coating a catalyst on a substrate
RU2011102384A (ru) Дегидрогенизация углеводорода двуокисью циркония
DK2125201T3 (da) Fremgangsmåde til selektiv methanisering af carbonmonoxid
JP2009034659A (ja) 炭化水素類合成用触媒とその製造方法およびそれを用いた炭化水素類の製造方法
MY148931A (en) Process for producing hydrocarbon by reduction of carbon monoxide
EA200702380A1 (ru) Способ превращения синтез-газа в оксигенаты

Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG TJ

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): TM RU