EA201391220A1 - METHOD FOR HYDROHALOGENATIZATION OF ALKINE AND FOR THE PRODUCTION OF VINYL CHLORIDE BY MEANS OF HYDROCHLORINE ACETYLENE - Google Patents

METHOD FOR HYDROHALOGENATIZATION OF ALKINE AND FOR THE PRODUCTION OF VINYL CHLORIDE BY MEANS OF HYDROCHLORINE ACETYLENE

Info

Publication number
EA201391220A1
EA201391220A1 EA201391220A EA201391220A EA201391220A1 EA 201391220 A1 EA201391220 A1 EA 201391220A1 EA 201391220 A EA201391220 A EA 201391220A EA 201391220 A EA201391220 A EA 201391220A EA 201391220 A1 EA201391220 A1 EA 201391220A1
Authority
EA
Eurasian Patent Office
Prior art keywords
production
vinyl chloride
acetylene
hydrohalogenatization
hydrochlorine
Prior art date
Application number
EA201391220A
Other languages
Russian (ru)
Other versions
EA025978B1 (en
Inventor
Мишель Стребелль
Кристиан Франк
Original Assignee
Солвей Са
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Солвей Са filed Critical Солвей Са
Publication of EA201391220A1 publication Critical patent/EA201391220A1/en
Publication of EA025978B1 publication Critical patent/EA025978B1/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/07—Preparation of halogenated hydrocarbons by addition of hydrogen halides
    • C07C17/08—Preparation of halogenated hydrocarbons by addition of hydrogen halides to unsaturated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B01J31/0281—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member
    • B01J31/0282—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member of an aliphatic ring, e.g. morpholinium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B01J31/0281—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member
    • B01J31/0284—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member of an aromatic ring, e.g. pyridinium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0287—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing atoms other than nitrogen as cationic centre
    • B01J31/0288—Phosphorus
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0298—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature the ionic liquids being characterised by the counter-anions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/28—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of the platinum group metals, iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Способ для гидрогалогенизации алкина и для производства винилхлорида с помощью гидрохлорирования ацетилена в присутствии каталитической системы, содержащей по меньшей мере одну ионную жидкость, содержащую по меньшей мере один не протонированный катион, который проводится в устройстве, сделанном из или покрытом материалами, которые устойчивы к галогеновым кислотам, в частности к HCl, в диссоциированной форме.Method for the halogenation of alkyne and for the production of vinyl chloride using acetylene hydrochlorination in the presence of a catalytic system containing at least one ionic liquid containing at least one non-protonated cation which is carried out in a device made of or coated with materials that are resistant to halogen acids , in particular to HCl, in the dissociated form.

EA201391220A 2011-02-24 2012-02-21 Process for the hydrohalogenation of an alkyne and for the manufacture of vinyl chloride by hydrochlorination of acetylene EA025978B1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP11155813 2011-02-24
PCT/EP2012/052911 WO2012113778A1 (en) 2011-02-24 2012-02-21 Process for the hydrohalogenation of an alkyne and for the manufacture of vinyl chloride by hydrochlorination of acetylene

Publications (2)

Publication Number Publication Date
EA201391220A1 true EA201391220A1 (en) 2013-12-30
EA025978B1 EA025978B1 (en) 2017-02-28

Family

ID=44140742

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201391220A EA025978B1 (en) 2011-02-24 2012-02-21 Process for the hydrohalogenation of an alkyne and for the manufacture of vinyl chloride by hydrochlorination of acetylene

Country Status (3)

Country Link
CN (2) CN107417487A (en)
EA (1) EA025978B1 (en)
WO (1) WO2012113778A1 (en)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2617698A1 (en) * 2012-06-27 2013-07-24 Solvay Sa Process for the hydrohalogenation of an unsaturated hydrocarbon and for the manufacture of vinyl chloride by hydrochlorination of acetylene
CN103623838B (en) * 2012-08-24 2015-12-02 天津大学 The Ru-Pt-Cu catalyst of acetylene hydrochlorination synthesizing chloroethylene
EA029427B1 (en) * 2012-12-19 2018-03-30 Солвей Са Process for the hydrohalogenation of an unsaturated hydrocarbon
US8877988B2 (en) * 2012-12-21 2014-11-04 Honeywell International Inc. Synthesis of 1-BROM0-3,3,3-trifluoropropene
CN106397108B (en) * 2015-07-31 2018-07-10 天津大学 The catalyst for preparing vinyl chloride prepares the purposes of vinyl chloride in catalysis dichloroethanes and acetylene one-step method
CN107837824A (en) * 2016-09-18 2018-03-27 天津大学 Purposes of the catalyst of load quaternary alkylphosphonium salt and metal chloride in acetylene hydrochlorination
CN108339569B (en) * 2017-01-23 2020-07-28 天津大学 Supported quaternary phosphonium salt non-metallic catalyst, preparation method and application
CN107715915B (en) * 2017-09-29 2020-07-28 浙江工业大学 Sulfide ionic liquid complexed palladium catalyst and preparation method and application thereof
CN107715919B (en) * 2017-09-29 2020-10-09 浙江工业大学 Load type [ PdSClx]x-Catalyst, preparation thereof and application of catalyst in vinyl chloride synthesis
CN109158126B (en) * 2018-07-12 2021-10-29 天津大学 Metal halide acid radical ionic liquid for catalyzing hydrochlorination of acetylene and application method thereof
CN109499617A (en) * 2018-12-05 2019-03-22 安徽华塑股份有限公司 A kind of no mercury catalyst and its production method
GB201908844D0 (en) * 2019-06-20 2019-08-07 Johnson Matthey Plc Gold containing catalyst, method of preparation and use
CN110550997B (en) * 2019-07-22 2022-04-26 内蒙古亿利化学工业有限公司 Process for producing vinyl chloride by catalysis of mercury-free catalyst
CN113145175B (en) * 2021-04-29 2023-09-05 沈阳化工大学 Preparation method and application of catalyst with pyridine copper chloride as active component
CN113546679B (en) * 2021-06-15 2023-04-28 石河子大学 Ionic liquid-ruthenium-based catalyst for catalyzing hydrochlorination of acetylene as well as preparation method and application thereof
CN113549116B (en) * 2021-08-18 2022-11-08 河北美邦工程科技股份有限公司 Preparation method and application of metal chelating imidazole catalyst
CN113600237B (en) * 2021-08-27 2023-04-18 河北美邦工程科技股份有限公司 Polyion liquid catalyst for catalyzing hydrochlorination of acetylene
CN115626863B (en) * 2022-10-18 2023-06-23 南京工业大学 Method for preparing chloroethylene by hydrochlorination of acetylene in fixed bed by using low-content ruthenium-based catalyst

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Publication number Priority date Publication date Assignee Title
DE709000C (en) 1936-03-01 1941-08-02 Chem Fab Von Heyden Akt Ges Process for the preparation of vinyl halides
JPS52136104A (en) 1976-05-08 1977-11-14 Denki Kagaku Kogyo Kk Preparation of vinyl chloride
DE3824634A1 (en) 1988-04-30 1989-11-09 Huels Chemische Werke Ag METHOD FOR PRODUCING VINYL CHLORIDE BY REACTIVATING ACETYLENE WITH HYDROCHLORINE
BE1004983A3 (en) 1991-06-20 1993-03-09 Solvay CATALYST SYSTEM AND METHOD hydrochlorination CHLORIDE PRODUCTION START IN VINYL CHLORIDE ACETYLENE AND HYDROGEN IN THE PRESENCE OF THIS SYSTEM CATALYST.
BE1004984A3 (en) 1991-06-20 1993-03-09 Solvay CATALYST SYSTEM AND METHOD hydrochlorination CHLORIDE PRODUCTION START IN VINYL CHLORIDE ACETYLENE AND HYDROGEN IN THE PRESENCE OF THIS SYSTEM CATALYST.
DE102004044592A1 (en) * 2004-09-13 2006-03-30 Basf Ag Process for the separation of hydrogen chloride and phosgene
EP1762556A1 (en) * 2005-05-20 2007-03-14 SOLVAY (Société Anonyme) Process for producing dichloropropanol from glycerol
FR2910350B1 (en) 2006-12-22 2009-01-30 Solvay CATALYTIC HYDROCHLORIZATION SYSTEM AND PROCESS FOR PRODUCING VINYL CHLORIDE FROM ACETYLENE AND HYDROGEN CHLORIDE IN THE PRESENCE OF THIS CATALYTIC SYSTEM
JP2011502032A (en) 2007-10-02 2011-01-20 ソルヴェイ（ソシエテ アノニム） Use of silicon-containing compositions to improve the corrosion resistance of containers
CN101716528B (en) * 2009-10-30 2012-10-31 于志勇 Catalyst system of chloroethylene prepared by hydrochlorinating acetylene and preparation method and application thereof
CN101879464B (en) * 2010-05-28 2012-06-27 于志勇 Catalyst system for preparing vinyl chloride by hydrochlorinating acetylene and preparation and application thereof

Also Published As

Publication number Publication date
CN107417487A (en) 2017-12-01
CN103391911A (en) 2013-11-13
EA025978B1 (en) 2017-02-28
WO2012113778A1 (en) 2012-08-30

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Designated state(s): AM AZ BY KG MD TJ TM

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): RU

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): KZ