EA201270005A1 - HYDROCARBON GAS PROCESSING - Google Patents

HYDROCARBON GAS PROCESSING

Info

Publication number
EA201270005A1
EA201270005A1 EA201270005A EA201270005A EA201270005A1 EA 201270005 A1 EA201270005 A1 EA 201270005A1 EA 201270005 A EA201270005 A EA 201270005A EA 201270005 A EA201270005 A EA 201270005A EA 201270005 A1 EA201270005 A1 EA 201270005A1
Authority
EA
Eurasian Patent Office
Prior art keywords
stream
absorption device
absorption
condensed
processing unit
Prior art date
Application number
EA201270005A
Other languages
Russian (ru)
Other versions
EA027815B1 (en
Inventor
Эндрю Ф. Джонк
У. Ларри Льюис
Джон Д. Уилкинсон
Джо Т. Линч
Хэнк М. Хадсон
Кайл Т. Кьюллар
Original Assignee
Ортлофф Инджинирс, Лтд.
Эс.Эм.И. ПРОДАКТС ЭлПи
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/689,616 external-priority patent/US9021831B2/en
Priority claimed from US12/717,394 external-priority patent/US9080811B2/en
Priority claimed from US12/750,862 external-priority patent/US8881549B2/en
Priority claimed from US12/772,472 external-priority patent/US9933207B2/en
Application filed by Ортлофф Инджинирс, Лтд., Эс.Эм.И. ПРОДАКТС ЭлПи filed Critical Ортлофф Инджинирс, Лтд.
Priority claimed from US12/781,259 external-priority patent/US9939195B2/en
Publication of EA201270005A1 publication Critical patent/EA201270005A1/en
Publication of EA027815B1 publication Critical patent/EA027815B1/en

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0209—Natural gas or substitute natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0219—Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0233—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0238—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 2 carbon atoms or more
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0295—Start-up or control of the process; Details of the apparatus used, e.g. sieve plates, packings
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J5/00—Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/02—Processes or apparatus using separation by rectification in a single pressure main column system
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/30—Processes or apparatus using separation by rectification using a side column in a single pressure column system
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/78—Refluxing the column with a liquid stream originating from an upstream or downstream fractionator column
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00—Processes or apparatus using separation by rectification
    • F25J2200/80—Processes or apparatus using separation by rectification using integrated mass and heat exchange, i.e. non-adiabatic rectification in a reflux exchanger or dephlegmator
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2205/00—Processes or apparatus using other separation and/or other processing means
    • F25J2205/02—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
    • F25J2205/04—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum in the feed line, i.e. upstream of the fractionation step
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00—Processes characterised by the type or other details of the feed stream
    • F25J2210/12—Refinery or petrochemical off-gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00—Processes or apparatus involving steps for expanding of process streams
    • F25J2240/02—Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/12—External refrigeration with liquid vaporising loop
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00—Refrigeration techniques used
    • F25J2270/60—Closed external refrigeration cycle with single component refrigerant [SCR], e.g. C1-, C2- or C3-hydrocarbons
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/40—Vertical layout or arrangement of cold equipments within in the cold box, e.g. columns, condensers, heat exchangers etc.

Abstract

Описываются способ и установка для извлечения этана, этилена, пропана, пропилена и более тяжелых компонентов углеводородов из потока газообразных углеводородов в компактной перерабатывающей установке. Газовый поток охлаждается, конденсируется и расширяется под более низким давлением и подается в качестве сырья в устройство абсорбции, расположенное внутри перерабатывающей установки. Поток отгонного конденсата образуется в устройстве абсорбции и направляется в устройство тепломассообмена вовнутрь перерабатывающей установки, освобождаясь от летучих компонентов и при этом охлаждая газовый поток. Потоки отгонного пара образуются в устройстве тепломассообмена и существенно охлаждаются до, по крайней мере, частичной конденсации, образуя остаточный поток пара и конденсированный поток. Количество и температуру указанных сырьевых потоков, направляемых в первое и второе устройства абсорбции, поддерживают в верхней части первого устройства абсорбции достаточными для извлечения из потока основной части указанных менее летучих компонентов.A method and installation for the extraction of ethane, ethylene, propane, propylene and heavier hydrocarbon components from a stream of gaseous hydrocarbons in a compact processing plant are described. The gas stream is cooled, condensed, and expanded at a lower pressure and fed as a raw material to an absorption device located inside the processing unit. The flow of distillate condensate is formed in the absorption device and is sent to the heat and mass transfer device inside the processing unit, freeing from volatile components while cooling the gas stream. Strips of steam are formed in the heat and mass transfer device and are substantially cooled to at least partial condensation, forming a residual steam stream and a condensed stream. The quantity and temperature of said feed streams sent to the first and second absorption devices is maintained at the top of the first absorption device to be sufficient to extract the main part of said less volatile components from the stream.

EA201270005A 2009-06-11 2010-05-17 Hydrocarbon gas processing EA027815B1 (en)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
US18636109P 2009-06-11 2009-06-11
US12/689,616 US9021831B2 (en) 2009-02-17 2010-01-19 Hydrocarbon gas processing
US12/717,394 US9080811B2 (en) 2009-02-17 2010-03-04 Hydrocarbon gas processing
US12/750,862 US8881549B2 (en) 2009-02-17 2010-03-31 Hydrocarbon gas processing
US12/772,472 US9933207B2 (en) 2009-02-17 2010-05-03 Hydrocarbon gas processing
PCT/US2010/035121 WO2010144217A1 (en) 2009-06-11 2010-05-17 Hydrocarbon gas processing
US12/781,259 US9939195B2 (en) 2009-02-17 2010-05-17 Hydrocarbon gas processing including a single equipment item processing assembly

Publications (2)

Publication Number Publication Date
EA201270005A1 true EA201270005A1 (en) 2012-06-29
EA027815B1 EA027815B1 (en) 2017-09-29

Family

ID=56291174

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201270005A EA027815B1 (en) 2009-06-11 2010-05-17 Hydrocarbon gas processing

Country Status (14)

Country Link
EP (1) EP2440869A1 (en)
JP (1) JP5753535B2 (en)
KR (1) KR101687851B1 (en)
CN (1) CN102483299B (en)
AR (1) AR077079A1 (en)
AU (1) AU2010259129A1 (en)
BR (1) BRPI1011526A2 (en)
CA (1) CA2764144C (en)
CO (1) CO6480935A2 (en)
EA (1) EA027815B1 (en)
MX (1) MX355018B (en)
MY (1) MY158312A (en)
PE (1) PE20121305A1 (en)
WO (1) WO2010144217A1 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BRPI1105770A2 (en) * 2010-03-31 2016-05-03 Ortloff Engineers Ltd hydrocarbon gas processing.
EP3044528A1 (en) * 2013-09-11 2016-07-20 Ortloff Engineers, Ltd Hydrocarbon gas processing

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS546500B1 (en) * 1976-02-15 1979-03-29
US4889545A (en) * 1988-11-21 1989-12-26 Elcor Corporation Hydrocarbon gas processing
US5568737A (en) * 1994-11-10 1996-10-29 Elcor Corporation Hydrocarbon gas processing
WO2002029341A2 (en) * 2000-10-02 2002-04-11 Elcor Corporation Hydrocarbon gas processing
UA76750C2 (en) * 2001-06-08 2006-09-15 Елккорп Method for liquefying natural gas (versions)
US6516631B1 (en) * 2001-08-10 2003-02-11 Mark A. Trebble Hydrocarbon gas processing
US6560989B1 (en) * 2002-06-07 2003-05-13 Air Products And Chemicals, Inc. Separation of hydrogen-hydrocarbon gas mixtures using closed-loop gas expander refrigeration
BRPI0407806A (en) * 2003-02-25 2006-02-14 Ortloff Engineers Ltd hydrocarbon gas processing
US7159417B2 (en) * 2004-03-18 2007-01-09 Abb Lummus Global, Inc. Hydrocarbon recovery process utilizing enhanced reflux streams
WO2005114076A1 (en) * 2004-04-26 2005-12-01 Ortloff Engineers, Ltd Natural gas liquefaction
US8919148B2 (en) * 2007-10-18 2014-12-30 Ortloff Engineers, Ltd. Hydrocarbon gas processing

Also Published As

Publication number Publication date
AU2010259129A1 (en) 2012-02-23
CN102483299A (en) 2012-05-30
AU2010259129A2 (en) 2012-05-03
KR101687851B1 (en) 2016-12-19
AU2010259129A9 (en) 2014-12-18
EA027815B1 (en) 2017-09-29
CA2764144C (en) 2017-10-24
CA2764144A1 (en) 2010-12-16
CO6480935A2 (en) 2012-07-16
KR20120027488A (en) 2012-03-21
AR077079A1 (en) 2011-07-27
CN102483299B (en) 2015-10-21
MX2011013068A (en) 2012-02-01
PE20121305A1 (en) 2012-10-08
JP5753535B2 (en) 2015-07-22
JP2012529623A (en) 2012-11-22
MX355018B (en) 2018-04-02
EP2440869A1 (en) 2012-04-18
MY158312A (en) 2016-09-30
BRPI1011526A2 (en) 2016-03-29
WO2010144217A1 (en) 2010-12-16

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