EA200601209A1 - Способ конверсии оксигенатов в олефины в вертикальном реакторе - Google Patents

Способ конверсии оксигенатов в олефины в вертикальном реакторе

Info

Publication number
EA200601209A1
EA200601209A1 EA200601209A EA200601209A EA200601209A1 EA 200601209 A1 EA200601209 A1 EA 200601209A1 EA 200601209 A EA200601209 A EA 200601209A EA 200601209 A EA200601209 A EA 200601209A EA 200601209 A1 EA200601209 A1 EA 200601209A1
Authority
EA
Eurasian Patent Office
Prior art keywords
oxygenates
olefins
conversion
vertical reactor
solid catalyst
Prior art date
Application number
EA200601209A
Other languages
English (en)
Other versions
EA009365B1 (ru
Inventor
Джеффри С. Смит
Original Assignee
Эксонмобил Кемикэл Пейтентс Инк.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Эксонмобил Кемикэл Пейтентс Инк. filed Critical Эксонмобил Кемикэл Пейтентс Инк.
Publication of EA200601209A1 publication Critical patent/EA200601209A1/ru
Publication of EA009365B1 publication Critical patent/EA009365B1/ru

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J4/00Feed or outlet devices; Feed or outlet control devices
    • B01J4/001Feed or outlet devices as such, e.g. feeding tubes
    • B01J4/002Nozzle-type elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01FMIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F25/00Flow mixers; Mixers for falling materials, e.g. solid particles
    • B01F25/20Jet mixers, i.e. mixers using high-speed fluid streams
    • B01F25/23Mixing by intersecting jets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/26Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1818Feeding of the fluidising gas
    • B01J8/1827Feeding of the fluidising gas the fluidising gas being a reactant
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42Catalytic treatment
    • C10G3/44Catalytic treatment characterised by the catalyst used
    • C10G3/48Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42Catalytic treatment
    • C10G3/44Catalytic treatment characterised by the catalyst used
    • C10G3/48Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
    • C10G3/49Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/62Catalyst regeneration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049Controlling or regulating processes
    • B01J2219/00245Avoiding undesirable reactions or side-effects
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20C2-C4 olefins
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/40Ethylene production
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00Chemistry of hydrocarbon compounds
    • Y10S585/919Apparatus considerations
    • Y10S585/921Apparatus considerations using recited apparatus structure
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00Chemistry of hydrocarbon compounds
    • Y10S585/919Apparatus considerations
    • Y10S585/921Apparatus considerations using recited apparatus structure
    • Y10S585/924Reactor shape or disposition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

В заявке описан способ повышения эффективности взаимодействия между твердыми частицами катализатора и исходным сырьем с одновременным снижением вероятности возникновения нежелательных побочных реакций. Исходное сырье в виде множества отдельных струй взаимодействует с твердыми частицами катализатора в реакторе, который имеет зону реакции с неоднородной структурой потока и зону реакции с однородной структурой потока.
EA200601209A 2003-12-23 2004-11-12 Способ конверсии оксигенатов в олефины в вертикальном реакторе EA009365B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/745,771 US7619127B2 (en) 2003-12-23 2003-12-23 Method of operating a riser reactor
PCT/US2004/037710 WO2005066312A1 (en) 2003-12-23 2004-11-12 Method of operating a riser reactor

Publications (2)

Publication Number Publication Date
EA200601209A1 true EA200601209A1 (ru) 2007-02-27
EA009365B1 EA009365B1 (ru) 2007-12-28

Family

ID=34679184

Family Applications (1)

Application Number Title Priority Date Filing Date
EA200601209A EA009365B1 (ru) 2003-12-23 2004-11-12 Способ конверсии оксигенатов в олефины в вертикальном реакторе

Country Status (8)

Country Link
US (1) US7619127B2 (ru)
EP (1) EP1702026B1 (ru)
CN (1) CN1898361B (ru)
AT (1) ATE419319T1 (ru)
DE (1) DE602004018830D1 (ru)
EA (1) EA009365B1 (ru)
ES (1) ES2319905T3 (ru)
WO (1) WO2005066312A1 (ru)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8415519B2 (en) * 2008-12-17 2013-04-09 Exxonmobil Chemical Patents Inc. Methods for determining efficacy of metal oxide co-catalysts for oxygenates-to-olefins reactions
SG171873A1 (en) * 2008-12-22 2011-07-28 Shell Int Research Process and reactor system for the preparation of an olefinic product
EP3040401A1 (en) * 2014-12-30 2016-07-06 Shell Internationale Research Maatschappij B.V. An oxygenate to olefins conversion reactor system and process for use thereof
EP3623452A1 (en) * 2018-09-14 2020-03-18 Lyondell Chemical Technology, L.P. Phosphorus removal and alkylate production
WO2021024066A1 (en) * 2019-08-05 2021-02-11 Sabic Global Technologies B.V. High-density fluidized bed systems
US12012556B2 (en) 2019-08-05 2024-06-18 Sabic Global Technologies B.V. Dense phase riser to maximize light olefins yields for naphtha catalytic cracking

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4379123A (en) * 1979-10-30 1983-04-05 Mobil Oil Corporation Fluid catalyst conversion of alcohols and oxygenates to hydrocarbons
US6023005A (en) * 1997-07-03 2000-02-08 Exxon Chemicals Patents Inc. Process for converting oxygenates to olefins using molecular sieve catalysts comprising desirable carbonaceous deposits
US6137022A (en) * 1997-12-03 2000-10-24 Exxon Chemical Patents Inc Process for increasing the selectivity of a reaction to convert oxygenates to olefins
US6444868B1 (en) 1999-02-17 2002-09-03 Exxon Mobil Chemical Patents Inc. Process to control conversion of C4+ and heavier stream to lighter products in oxygenate conversion reactions
CN1078094C (zh) * 1999-04-23 2002-01-23 中国石油化工集团公司 一种用于流化催化转化的提升管反应器
US6166282A (en) * 1999-08-20 2000-12-26 Uop Llc Fast-fluidized bed reactor for MTO process
US7232936B1 (en) * 2000-02-22 2007-06-19 Exxonmobil Chemical Patents Inc. Conversion of oxygenate to olefins with staged injection of oxygenate
US6613290B1 (en) * 2000-07-14 2003-09-02 Exxonmobil Research And Engineering Company System for fluidized catalytic cracking of hydrocarbon molecules

Also Published As

Publication number Publication date
US7619127B2 (en) 2009-11-17
CN1898361A (zh) 2007-01-17
ATE419319T1 (de) 2009-01-15
EP1702026B1 (en) 2008-12-31
ES2319905T3 (es) 2009-05-14
CN1898361B (zh) 2010-05-26
US20050137439A1 (en) 2005-06-23
EP1702026A1 (en) 2006-09-20
DE602004018830D1 (de) 2009-02-12
WO2005066312A1 (en) 2005-07-21
EA009365B1 (ru) 2007-12-28

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Legal Events

Date Code Title Description
MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG MD TJ TM

MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): RU