EA009089B1 - Установка и способ удаления кислых газов - Google Patents
Установка и способ удаления кислых газов Download PDFInfo
- Publication number
- EA009089B1 EA009089B1 EA200500950A EA200500950A EA009089B1 EA 009089 B1 EA009089 B1 EA 009089B1 EA 200500950 A EA200500950 A EA 200500950A EA 200500950 A EA200500950 A EA 200500950A EA 009089 B1 EA009089 B1 EA 009089B1
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- hydrogen sulfide
- gas
- solvent
- physical solvent
- absorber
- Prior art date
Links
- 239000002253 acid Substances 0.000 title claims description 55
- 238000000034 method Methods 0.000 title claims description 38
- 239000007789 gas Substances 0.000 claims abstract description 185
- 239000002904 solvent Substances 0.000 claims abstract description 172
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 106
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims abstract description 70
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims abstract description 68
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 53
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 53
- 239000006096 absorbing agent Substances 0.000 claims description 66
- 229930195733 hydrocarbon Natural products 0.000 claims description 24
- 150000002430 hydrocarbons Chemical class 0.000 claims description 23
- 238000001704 evaporation Methods 0.000 claims description 22
- 230000008020 evaporation Effects 0.000 claims description 22
- 239000004215 Carbon black (E152) Substances 0.000 claims description 19
- 238000009434 installation Methods 0.000 claims description 14
- 238000004140 cleaning Methods 0.000 claims description 12
- 230000003247 decreasing effect Effects 0.000 claims description 6
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 5
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 4
- 238000003795 desorption Methods 0.000 claims description 4
- 238000001179 sorption measurement Methods 0.000 claims description 4
- 238000009834 vaporization Methods 0.000 claims description 4
- 230000008016 vaporization Effects 0.000 claims description 4
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 3
- -1 hydrogen sulfide hydrocarbon Chemical class 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 238000001816 cooling Methods 0.000 description 28
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 28
- 238000010521 absorption reaction Methods 0.000 description 11
- 238000012545 processing Methods 0.000 description 11
- 238000011084 recovery Methods 0.000 description 11
- 239000003507 refrigerant Substances 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- 239000003345 natural gas Substances 0.000 description 8
- 150000001412 amines Chemical class 0.000 description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- 230000018044 dehydration Effects 0.000 description 6
- 238000006297 dehydration reaction Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000012528 membrane Substances 0.000 description 6
- 229910052717 sulfur Inorganic materials 0.000 description 6
- 239000011593 sulfur Substances 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- SIXOAUAWLZKQKX-UHFFFAOYSA-N carbonic acid;prop-1-ene Chemical group CC=C.OC(O)=O SIXOAUAWLZKQKX-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 150000001983 dialkylethers Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000009972 noncorrosive effect Effects 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 230000009919 sequestration Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1425—Regeneration of liquid absorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1456—Removing acid components
- B01D53/1462—Removing mixtures of hydrogen sulfide and carbon dioxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/14—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
- B01D53/1493—Selection of liquid materials for use as absorbents
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02C20/00—Capture or disposal of greenhouse gases
- Y02C20/40—Capture or disposal of greenhouse gases of CO2
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Gas Separation By Absorption (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US43325702P | 2002-12-12 | 2002-12-12 | |
| PCT/US2003/039776 WO2004052511A1 (en) | 2002-12-12 | 2003-12-11 | Configurations and methods of acid gas removal |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EA200500950A1 EA200500950A1 (ru) | 2005-12-29 |
| EA009089B1 true EA009089B1 (ru) | 2007-10-26 |
Family
ID=32508029
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EA200500950A EA009089B1 (ru) | 2002-12-12 | 2003-12-11 | Установка и способ удаления кислых газов |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7637987B2 (https=) |
| EP (1) | EP1569740B1 (https=) |
| JP (1) | JP4105697B2 (https=) |
| CN (1) | CN100339150C (https=) |
| AT (1) | ATE505254T1 (https=) |
| AU (1) | AU2003297063B2 (https=) |
| CA (1) | CA2503404C (https=) |
| DE (1) | DE60336752D1 (https=) |
| EA (1) | EA009089B1 (https=) |
| ES (1) | ES2365474T3 (https=) |
| MX (1) | MXPA05006126A (https=) |
| WO (1) | WO2004052511A1 (https=) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2484882C2 (ru) * | 2007-11-01 | 2013-06-20 | Альстом Текнолоджи Лтд | Способ удаления co2 (варианты) |
| US8927450B2 (en) | 2009-10-19 | 2015-01-06 | Mitsubishi Heavy Industries, Ltd. | Reclaiming method |
| RU2630085C1 (ru) * | 2016-11-22 | 2017-09-05 | Андрей Владиславович Курочкин | Устройство для абсорбции кислых газов |
| WO2022032266A1 (en) * | 2020-08-01 | 2022-02-10 | Honeywell International Inc. | Renewable transportation fuel process with thermal oxidation system |
| WO2022032267A1 (en) * | 2020-08-04 | 2022-02-10 | Honeywell International Inc. | Pitch destruction processes using thermal oxidation system |
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| DE10324694A1 (de) * | 2003-05-28 | 2004-12-23 | Uhde Gmbh | Verfahren zur Entfernung von Sauergasen aus unter Druck befindlichem, mit Sauergasverbindungen verunreinigtem Erdgas und Gewinnung der entfernten Sauergase auf erhöhtem Druckniveau |
| NZ544796A (en) * | 2003-07-22 | 2009-09-25 | Dow Global Technologies Inc | Regeneration of acid gas-containing treatment fluids |
| ATE428486T1 (de) * | 2003-09-09 | 2009-05-15 | Fluor Corp | Verbesserte lösungsmittelverwendung und regenration |
| MX2007001367A (es) | 2004-08-06 | 2007-04-10 | Eig Inc | Ultra limpieza de gases de combustion, incluyendo la eliminacion de co2. |
| DE102005025958A1 (de) | 2005-06-03 | 2006-12-07 | Uhde Gmbh | Verfahren zur Abreicherung von Schwefelwasserstoff in Erdgas |
| DE102005030028A1 (de) * | 2005-06-27 | 2006-12-28 | Uhde Gmbh | Verfahren und Vorrichtung zur Absorption von Sauergas aus Erdgas |
| WO2007133595A2 (en) * | 2006-05-08 | 2007-11-22 | The Board Of Trustees Of The University Of Illinois | Integrated vacuum absorption steam cycle gas separation |
| US7883569B2 (en) | 2007-02-12 | 2011-02-08 | Donald Leo Stinson | Natural gas processing system |
| WO2009020473A1 (en) * | 2007-08-09 | 2009-02-12 | Fluor Technologies Corporation | Configurations and methods for fuel gas treatment with total sulfur removal and olefin saturation |
| DE102007048565B3 (de) * | 2007-10-09 | 2009-01-22 | Dge Dr.-Ing. Günther Engineering Gmbh | Verfahren und Anlage zur Regeneration einer bei der Reinigung von Gasen anfallenden aminhaltigen Waschlösung |
| US7892324B2 (en) * | 2007-10-10 | 2011-02-22 | General Electric Company | Systems and methods for carbon dioxide capture |
| US8182577B2 (en) | 2007-10-22 | 2012-05-22 | Alstom Technology Ltd | Multi-stage CO2 removal system and method for processing a flue gas stream |
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| CN101970079B (zh) * | 2008-02-18 | 2013-09-04 | 氟石科技公司 | 再生器构造和具有降低的蒸汽需求的方法 |
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| US20090241778A1 (en) * | 2008-03-26 | 2009-10-01 | Lechnick William J | Use of Solvent Stream as Motive Fluid in Ejector Unit for Regenerating Solvent for Absorption Unit |
| US8696797B2 (en) * | 2008-05-30 | 2014-04-15 | General Electric Company | Carbon dioxide removal from synthesis gas at elevated pressure |
| WO2010005797A2 (en) * | 2008-07-10 | 2010-01-14 | Shell Oil Company | A method of treating a hydrocarbon gas stream having a high carbon dioxide concentration by using a lean solvent containing aqueous ammonia |
| US7846240B2 (en) | 2008-10-02 | 2010-12-07 | Alstom Technology Ltd | Chilled ammonia based CO2 capture system with water wash system |
| EP2337624A4 (en) * | 2008-10-02 | 2012-06-27 | Fluor Tech Corp | CONFIGURATIONS AND METHODS FOR REMOVING ACID GAS AT HIGH PRESSURE |
| EP2181754A1 (de) * | 2008-10-31 | 2010-05-05 | Siemens Aktiengesellschaft | Verfahren und Vorrichtung zum Abtrennen von Kohlendioxid aus einem Abgas einer fossilbefeuerten Kraftwerksanlage |
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- 2003-12-11 US US10/511,408 patent/US7637987B2/en not_active Expired - Lifetime
- 2003-12-11 CA CA002503404A patent/CA2503404C/en not_active Expired - Fee Related
- 2003-12-11 DE DE60336752T patent/DE60336752D1/de not_active Expired - Lifetime
- 2003-12-11 WO PCT/US2003/039776 patent/WO2004052511A1/en not_active Ceased
- 2003-12-11 ES ES03813011T patent/ES2365474T3/es not_active Expired - Lifetime
- 2003-12-11 AU AU2003297063A patent/AU2003297063B2/en not_active Ceased
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Also Published As
| Publication number | Publication date |
|---|---|
| CN1723073A (zh) | 2006-01-18 |
| US7637987B2 (en) | 2009-12-29 |
| AU2003297063B2 (en) | 2008-05-22 |
| MXPA05006126A (es) | 2005-08-16 |
| EA200500950A1 (ru) | 2005-12-29 |
| JP2006509622A (ja) | 2006-03-23 |
| AU2003297063A1 (en) | 2004-06-30 |
| ES2365474T3 (es) | 2011-10-06 |
| EP1569740A1 (en) | 2005-09-07 |
| JP4105697B2 (ja) | 2008-06-25 |
| CA2503404C (en) | 2009-06-02 |
| US20050172807A1 (en) | 2005-08-11 |
| EP1569740B1 (en) | 2011-04-13 |
| DE60336752D1 (de) | 2011-05-26 |
| EP1569740A4 (en) | 2007-03-28 |
| WO2004052511A1 (en) | 2004-06-24 |
| CN100339150C (zh) | 2007-09-26 |
| CA2503404A1 (en) | 2004-06-24 |
| ATE505254T1 (de) | 2011-04-15 |
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