DK3115336T3 - Fremgangsmåde og anlæg til køling af syntesegas - Google Patents

Fremgangsmåde og anlæg til køling af syntesegas Download PDF

Info

Publication number
DK3115336T3
DK3115336T3 DK15400030.1T DK15400030T DK3115336T3 DK 3115336 T3 DK3115336 T3 DK 3115336T3 DK 15400030 T DK15400030 T DK 15400030T DK 3115336 T3 DK3115336 T3 DK 3115336T3
Authority
DK
Denmark
Prior art keywords
gas
heat exchange
synthesis gas
cooling
condensate
Prior art date
Application number
DK15400030.1T
Other languages
English (en)
Other versions
DK3115336T4 (da
Inventor
Yue Chen
Jean-Philippe Tadiello
Original Assignee
Air Liquide
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=54056152&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DK3115336(T3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Air Liquide filed Critical Air Liquide
Application granted granted Critical
Publication of DK3115336T3 publication Critical patent/DK3115336T3/da
Publication of DK3115336T4 publication Critical patent/DK3115336T4/da

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/48—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents followed by reaction of water vapour with carbon monoxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/0013—Controlling the temperature of the process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/506—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification at low temperatures
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465—Composition of the impurity
    • C01B2203/0495—Composition of the impurity the impurity being water
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0883—Methods of cooling by indirect heat exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1288—Evaporation of one or more of the different feed components
    • C01B2203/1294—Evaporation by heat exchange with hot process stream

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Physical Water Treatments (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Claims (9)

1. Fremgangsmåde til afkøling af en syntesegas, som er frembragt ved katalytisk dampreformering afen kulbrinte-indeholdende tilførselsgas og er blevet afkølet ved varmeveksling med kedeltilførselsvand med henblik på dettes omdannelse til damp, med afskillelse af det derved dannede vandige kondensat, og behandling i et anlæg til katalytisk omdannelse af carbonmonoxid med vanddamp til hydrogen og carbondioxid, hvorved afkølingen udføres ved, at gassen passerer gennem et antal serieforbundne afkølingstrin, og omfatter varmeveksling med tilførselsgassen (3), med afgasset og ikke-afgasset kedeltilførselsvand (7) med henblik på fremstilling af den til reformering af dampen nødvendige damp og med omgivelsesluft, og hvorved afkølet kondensat (14), som er dannet efter det sidste afkølingstrin, afskilles fra gassen (17), og gassen (17) bortledes med henblik på yderligere behandling, kendetegnet ved, at, i det mindste efter et yderligere afkølingstrin, som er beliggende lige før det sidste afkølingstrin, et yderligere, varmt, vandigt kondensat (16) afskilles fra gassen.
2. Fremgangsmåde ifølge krav 1, kendetegnet ved, at alt kølevand, som anvendes til afkøling af syntesegassen, efterfølgende benyttes som kedeltilførselsvand.
3. Fremgangsmåde ifølge krav 1 eller 2, kendetegnet ved, at det første afkølingstrin (2) i syntesegassens strømningsretning omfatter varmeveksling med tilførselsgassen (3), det andet trin (4) omfatter varmeveksling med afgasset kedeltilførselsvand (7), det tredje trin (10) omfatter varmeveksling med omgivelsesluften ved hjælp af en luftkøler (10), og det sidste trin (6) omfatter varmeveksling med det ikke-afgassede kedeltilførselsvand (7).
4. Fremgangsmåde ifølge krav 1 eller 2, kendetegnet ved, at det første afkølingstrin (2) i syntesegassens (1) strømningsretning omfatter varmeveksling med tilførselsgassen (3), det andet trin (4) omfatter varmeveksling med afgasset kedeltilførselsvand (7), det tredje trin (6) omfatter varmeveksling med det ikke- afgassede kedeltilførselsvand (7), og det sidste trin (10) omfatter varmeveksling med omgivelsesluften ved hjælp afen luftkøler (10).
5. Fremgangsmåde ifølge krav 3, kendetegnet ved, at det varme, vandige kondensat (16) efter varmevekslingen med omgivelsesluften afskilles fra syntesegassen (1).
6. Fremgangsmåde ifølge et hvilket som helst af de foregående krav, kendetegnet ved, at begge kondensater (14, 16), som er afskilt fra syntesegassen (1), tilføres til kedeltilførselsvand-afgasningen og der føres sammen med friskt kedeltilførselsvand, som er blevet forvarmet ved varmeveksling med syntesegassen.
7. Fremgangsmåde ifølge krav 5, kendetegnet ved, at varmeenergien til afgasning af kedeltilførselsvand i det mindste delvist leveres ved varmeveksling mellem tilførselsvandet (7), som befinder sig i afgasseren (8), og syntesegassen (1), der skal afkøles.
8. Anvendelse af kondensaterne (14, 16), der frembringes ved en fremgangsmåde ifølge et hvilket som helst af kravene 1 til 4, som tilførselsvand med henblik på frembringelse af i det mindste en del af tilførselsdampen, som anvendes til reformering af katalytisk damp, hvorved de to kondensater (14, 16) føres sammen, opvarmes i en forvarmer og efterfølgende fordampes i en proceskondensatfordamper.
9. Anlæg til afkøling af en syntesegas, der er blevet fremstillet ved katalytisk dampreformering af en hydrocarbon-indeholdende tilførselsgas, som ved varmeveksling med kedeltilførselsvand blev afkølet med henblik på omdannelse af sidstnævnte til damp, ved fraskillelse af det derved dannede vandige kondensat, og behandlet i et anlæg til katalytisk omdannelse af carbonmonoxid med vanddamp til hydrogen og carbondioxid, hvilket anlæg omfatter et antal serieforbundne varmevekslere (4, 6) til varmeveksling med tilførselsgassen, med afgasset og ikke-afgasset kedeltilførselsvand med henblik på frembringelse af den nødvendige damp til damp-reformering og med omgivelsesluft (10) og omfattende en efter varmeveksleren i det sidste afkølingstrin anbragt kondensatafskiller (13) til fraskillelse af det opståede, afkølede kondensat, således at gassen (1) ledes bort til videre behandling, kendetegnet ved, at der i det mindste efter en yderligere, foran varmeveksleren i det sidste afkølingstrin placeret, varmeveksler er installeret en yderligere kondensatafskiller (15) til fraskillelse af varmt, vandigt kondensat (16) fra gassen.
DK15400030.1T 2015-07-10 2015-07-10 Fremgangsmåde og anlæg til køling af syntesegas DK3115336T4 (da)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP15400030.1A EP3115336B2 (de) 2015-07-10 2015-07-10 Verfahren und anlage zur kühlung von synthesegas

Publications (2)

Publication Number Publication Date
DK3115336T3 true DK3115336T3 (da) 2018-06-06
DK3115336T4 DK3115336T4 (da) 2022-03-28

Family

ID=54056152

Family Applications (1)

Application Number Title Priority Date Filing Date
DK15400030.1T DK3115336T4 (da) 2015-07-10 2015-07-10 Fremgangsmåde og anlæg til køling af syntesegas

Country Status (10)

Country Link
US (1) US10875767B2 (da)
EP (1) EP3115336B2 (da)
CN (2) CN106335875B (da)
CA (1) CA2992626C (da)
DE (1) DE102015112533A1 (da)
DK (1) DK3115336T4 (da)
EA (1) EA039828B1 (da)
ES (1) ES2669494T5 (da)
PL (1) PL3115336T5 (da)
WO (1) WO2017008915A1 (da)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3418253B1 (de) * 2017-06-20 2020-11-25 L'air Liquide, Société Anonyme Pour L'Étude Et L'exploitation Des Procédés Georges Claude Verfahren zur kühlung von synthesegas
CN108178124A (zh) * 2018-03-09 2018-06-19 山西潞安煤基合成油有限公司 用于干重整工艺的节能装置
CN110986649A (zh) * 2019-12-20 2020-04-10 乔治洛德方法研究和开发液化空气有限公司 合成气热量回收系统
EP4324787A1 (de) * 2022-08-17 2024-02-21 Linde GmbH Verfahren und anlage zur gewinnung eines oder mehrerer verfahrens produkte

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3297408A (en) * 1962-02-28 1967-01-10 Jr Walton H Marshall Process for production of hydrogen
US4101645A (en) * 1976-11-08 1978-07-18 Friedrich Uhde Gmbh Process for the production of hydrogen/deuterium-containing gas
US20030110694A1 (en) * 2001-12-17 2003-06-19 Drnevich Raymond Francis Method for oxygen enhanced syngas production
US7794689B2 (en) * 2005-01-18 2010-09-14 Enquest Power Corporation Method for steam reforming carbonaceous material
US7540893B2 (en) * 2005-12-06 2009-06-02 General Electric Company System and method for producing synthesis gas
DE102006019100A1 (de) * 2006-04-25 2007-10-31 Linde Ag Verfahren zur Produktion von Exportdampf in Dampfreformern
US7850944B2 (en) 2008-03-17 2010-12-14 Air Products And Chemicals, Inc. Steam-hydrocarbon reforming method with limited steam export
EP2233433A1 (en) * 2009-03-24 2010-09-29 Hydrogen Energy International Limited Process for generating electricity and for sequestering carbon dioxide
US8240370B2 (en) 2009-12-18 2012-08-14 Air Products And Chemicals, Inc. Integrated hydrogen production and hydrocarbon extraction
DE102010044939C5 (de) * 2010-09-10 2015-11-19 Thyssenkrupp Industrial Solutions Ag Verfahren und Vorrichtung zur Erzeugung von Prozessdampf und Kesselspeisewasserdampf in einem beheizbaren Reformierreaktor zur Herstellung von Synthesegas
US20120148485A1 (en) * 2010-12-09 2012-06-14 Morrow Jeffrey M Steam methane reforming process
US9290422B2 (en) * 2012-11-27 2016-03-22 Praxair Technology, Inc. Hybrid plant for liquid fuel production
US20140319425A1 (en) * 2013-04-26 2014-10-30 Shrikar Chakravarti Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system using a combined feed stream
WO2014176020A1 (en) * 2013-04-26 2014-10-30 Praxair Technology, Inc. Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system
FR3007510B1 (fr) * 2013-06-20 2015-06-26 Air Liquide Procede utilisant la chaleur fatale d’une installation de production d’hydrogene pour alimenter les reseaux de chaleur urbains en chaleur verte
US8956587B1 (en) * 2013-10-23 2015-02-17 Air Products And Chemicals, Inc. Hydrogen production process with high export steam
ES2687104T3 (es) 2013-10-23 2018-10-23 Air Products And Chemicals, Inc. Procedimiento de producción de hidrógeno con vapor de exportación en alta

Also Published As

Publication number Publication date
DE102015112533A1 (de) 2017-01-12
EP3115336A1 (de) 2017-01-11
EA201890092A1 (ru) 2018-04-30
CA2992626A1 (en) 2017-01-19
ES2669494T3 (es) 2018-05-28
EA039828B1 (ru) 2022-03-17
EP3115336B1 (de) 2018-02-28
US10875767B2 (en) 2020-12-29
DK3115336T4 (da) 2022-03-28
EP3115336B2 (de) 2022-01-05
CA2992626C (en) 2023-05-16
PL3115336T3 (pl) 2018-07-31
ES2669494T5 (es) 2022-04-28
WO2017008915A1 (en) 2017-01-19
PL3115336T5 (pl) 2022-04-25
CN205973771U (zh) 2017-02-22
CN106335875B (zh) 2021-11-09
US20180201506A1 (en) 2018-07-19
CN106335875A (zh) 2017-01-18

Similar Documents

Publication Publication Date Title
DK3115336T3 (da) Fremgangsmåde og anlæg til køling af syntesegas
US8920771B2 (en) Water purification using energy from a steam-hydrocarbon reforming process
RU2013150992A (ru) Способ производства водорода с высоким содержанием отводимого пара
GB1169263A (en) Distillation and power generating method and apparatus
CA2743089A1 (en) Production of process gas by heat recovery from low-temperature waste heat
CN112203973B (zh) Psa缓冲罐内的尾气加热
WO2017182139A1 (en) Process and plant for producing hydrogen by means of catalytic steam reformation of a hydrocarbonaceous feed gas
RU2425796C2 (ru) Генерирование водяного пара в процессах реформинга с водяным паром
US10358349B1 (en) Advanced heat integration in sulfur recovery unit—SafarClaus
US20200239309A1 (en) Advanced Heat Integration in Sulfur Recovery Unit - SafarClaus
US11925895B2 (en) Method and device for cooling a synthesis gas flow
AU2014231976B2 (en) Methanol plant and gasoline synthesis plant
RU2691073C1 (ru) Установка для получения метанола из исходного газа, содержащего метан
CN110719890B (zh) 用于冷却合成气的方法和设备
GB2569841A (en) Emission control system
EP2865640B1 (en) Water purification using energy from a hydrocarbon steam reforming process
RU2646960C1 (ru) Установка получения метанола и способ ее работы
KR20240012459A (ko) 합성 가스의 생성 및 공정 응축수의 발생을 위한 방법 및 플랜트
CN111712460A (zh) 用于改造和提高烃重整工段的能力的方法
EA028058B1 (ru) Установка для получения серной кислоты
KR20170002516U (ko) 합성가스 냉각 어셈블리