DK2702403T3 - Analyse af reservoirfluider under tryk - Google Patents
Analyse af reservoirfluider under tryk Download PDFInfo
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- DK2702403T3 DK2702403T3 DK12724189T DK12724189T DK2702403T3 DK 2702403 T3 DK2702403 T3 DK 2702403T3 DK 12724189 T DK12724189 T DK 12724189T DK 12724189 T DK12724189 T DK 12724189T DK 2702403 T3 DK2702403 T3 DK 2702403T3
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- gas
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- chromatographic
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- reservoir fluid
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- 238000004458 analytical method Methods 0.000 title claims description 76
- 239000007789 gas Substances 0.000 claims description 173
- 239000012530 fluid Substances 0.000 claims description 100
- 239000000203 mixture Substances 0.000 claims description 38
- 238000004587 chromatography analysis Methods 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 21
- 229930195733 hydrocarbon Natural products 0.000 claims description 15
- 150000002430 hydrocarbons Chemical class 0.000 claims description 14
- 238000009833 condensation Methods 0.000 claims description 11
- 230000005494 condensation Effects 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
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- 239000012159 carrier gas Substances 0.000 description 30
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 22
- 239000007791 liquid phase Substances 0.000 description 17
- 239000003921 oil Substances 0.000 description 16
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 14
- 239000012808 vapor phase Substances 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 11
- 238000012546 transfer Methods 0.000 description 11
- 238000005259 measurement Methods 0.000 description 10
- 239000002808 molecular sieve Substances 0.000 description 9
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 9
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- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000004817 gas chromatography Methods 0.000 description 5
- 239000001307 helium Substances 0.000 description 5
- 229910052734 helium Inorganic materials 0.000 description 5
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 5
- 239000003345 natural gas Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 238000005070 sampling Methods 0.000 description 5
- 230000008016 vaporization Effects 0.000 description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000001514 detection method Methods 0.000 description 4
- AAOVKJBEBIDNHE-UHFFFAOYSA-N diazepam Chemical compound N=1CC(=O)N(C)C2=CC=C(Cl)C=C2C=1C1=CC=CC=C1 AAOVKJBEBIDNHE-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 4
- 238000011002 quantification Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 238000009834 vaporization Methods 0.000 description 4
- -1 C20 hydrocarbons Chemical class 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 239000008246 gaseous mixture Substances 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
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- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- CBFCDTFDPHXCNY-UHFFFAOYSA-N icosane Chemical compound CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 231100000331 toxic Toxicity 0.000 description 2
- 230000002588 toxic effect Effects 0.000 description 2
- 229910000619 316 stainless steel Inorganic materials 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 230000005679 Peltier effect Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000011208 chromatographic data Methods 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000012864 cross contamination Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 150000001923 cyclic compounds Chemical class 0.000 description 1
- 238000011161 development Methods 0.000 description 1
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- 235000013305 food Nutrition 0.000 description 1
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- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000006798 recombination Effects 0.000 description 1
- 238000005215 recombination Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
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- 230000007704 transition Effects 0.000 description 1
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Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/04—Preparation or injection of sample to be analysed
- G01N30/06—Preparation
- G01N30/12—Preparation by evaporation
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/88—Integrated analysis systems specially adapted therefor, not covered by a single one of the groups G01N30/04 - G01N30/86
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/24—Earth materials
- G01N33/241—Earth materials for hydrocarbon content
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
- G01N33/2823—Raw oil, drilling fluid or polyphasic mixtures
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/88—Integrated analysis systems specially adapted therefor, not covered by a single one of the groups G01N30/04 - G01N30/86
- G01N2030/8809—Integrated analysis systems specially adapted therefor, not covered by a single one of the groups G01N30/04 - G01N30/86 analysis specially adapted for the sample
- G01N2030/884—Integrated analysis systems specially adapted therefor, not covered by a single one of the groups G01N30/04 - G01N30/86 analysis specially adapted for the sample organic compounds
- G01N2030/8854—Integrated analysis systems specially adapted therefor, not covered by a single one of the groups G01N30/04 - G01N30/86 analysis specially adapted for the sample organic compounds involving hydrocarbons
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N30/00—Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography or field flow fractionation
- G01N30/02—Column chromatography
- G01N30/88—Integrated analysis systems specially adapted therefor, not covered by a single one of the groups G01N30/04 - G01N30/86
- G01N2030/8881—Modular construction, specially adapted therefor
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Environmental & Geological Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Remote Sensing (AREA)
- Sampling And Sample Adjustment (AREA)
- Other Investigation Or Analysis Of Materials By Electrical Means (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
Claims (15)
1. Analysesystem (100), der omfatter: et fælles hus, der omfatter: 5 et flash-apparat (104) , der er konfigureret til delvis fordampning af en reservoirfluid under tryk ved hjælp af reduktion af trykket over en ventil til opnåelse af en fordampet gas og en reservoirvæske; et første kromatografisk delsystem (500), der omfatter en 10 første kromatografisøjle og en første prøvesløjfe (504), hvor den første prøvesløjfe (504) er fluidforbundet til flash- apparatet (104) og konfigureret til at modtage den fordampede gas fra flash-apparatet (104); et andet kromatografisk delsystem (520), der omfatter en anden 15 kromatografisøjle og en anden prøvesløjfe (524), hvor den anden prøvesløjfe (524) er fluidisk forbundet til den første prøvesløjfe (504) og konfigureret til at modtage den fordampede gas fra flash-apparatet (104) via den første prøvesløjfe (504), hvor den første kromatografisøjle i det 20 første kromatografiske delsystem (500) og den anden kromatografisøjle i det andet kromatografiske delsystem (520) er konfigureret til at blive aktiveret samtidigt til påvisning af bestanddele i reservoirfluiden under tryk; et enkelt dataopsamlingssystem (122), der er koblet til det 25 første kromatografiske delsystem (500), det andet kromatografiske delsystem (520) og flash-apparatet (104) , hvor det enkelte dataopsamlingssystem (122) er konfigureret til at opsamle data, der er relateret til sammensætningen af reservoirfluid under tryk, der tilføres flash-apparatet (104); 30 og en mikroprocessor (124) , der er koblet til dataopsamlingssystemet (122), hvor mikroprocessoren (124) er i stand til at bestemme gas:olie-forholdet i reservoirfluid under tryk, der tilføres flash-apparatet (104), baseret på 35 data opsamlet af dataopsamlingssystemet (122).
2. Analysesystem ifølge krav 1, hvor det første kromatografiske delsystem (500) er konfigureret til at påvise bundne gasser.
3. Analysesystem ifølge krav 1 eller krav 2, hvor det andet kromatografiske delsystem (520) er konfigureret til at påvise Cl til C5-carbonhydrider.
4. Analysesystem ifølge et hvilket som helst af kravene 1 til og med 3, hvor huset yderligere omfatter et tredje kromatografisk (540) delsystem, og det tredje kromatografiske delsystem (540) omfatter en kromatografisøjle, der er konfigureret til at påvise Cl til C20-carbonhydrider.
5. Analysesystem ifølge krav 4, hvor det tredje kromatografiske delsystem (540) omfatter en flammeioniseringsdetektor (312).
6. Analysesystem ifølge krav 5, der yderligere omfatter: en gasanalytisk kapillarsøjle; en væskeanalytisk kapillarsøjle; og en skifteventil, hvor den gasanalytiske kapillarsøjle og den væskeanalytiske kapillarsøjle er koblet til flammeioniseringsdetektoren (312) via skifteventilen.
7. Analysesystem ifølge krav 6, hvor det tredje kromatografiske delsystem (540) omfatter den gasanalytiske kapillarsøj le.
8. Analysesystem ifølge et hvilket som helst af kravene 1 til og med 7, hvor det første kromatografiske delsystem (500) omfatter en første varmekonduktivitetsdetektor (510), og det andet kromatografiske delsystem (520) omfatter en anden varmekonduktivitetsdetektor (530).
9. Analysesystem ifølge et hvilket som helst af kravene 1 til og med 8, der yderligere omfatter en ledning, der er konfigureret til at transportere fordampet gas fra flash-apparatet (104) til det første kromatografiske delsystem (500), hvor temperaturen i ledningen kontrolleres ved anvendelse af tilgængelig varme i analysesystemet.
10. Analysesystem ifølge et hvilket som helst af kravene 1 til og med 9, hvor flash-apparatet (104) er konfigureret til delvist at fordampe reservoirfluid under tryk til opnåelse af frit vand sammen med fordampet gas og reservoirvæske.
11. Analysesystem ifølge et hvilket som helst af kravene 1 til og med 10, hvor flash-apparatet (104) er konfigureret til delvist at fordampe reservoirfluid under tryk til opnåelse af en ækvilibreret reservoirvæske.
12. Fremgangsmåde, der omfatter: delvis fordampning af en reservoirfluid under tryk til frembringelse af en fordampet gas og en reservoirvæske; hindring af kondensering af den fordampede gas, hvor hindring af kondensering af den fordampede gas omfatter opvarmning af den fordampede gas; automatisk tilførsel af en enkelt prøve af den opvarmede, fordampede gas til en første prøvesløjfe (504) i et første kromatografisk delsystem (500) og en anden prøvesløjfe (524) i et andet kromatografisk delsystem (520) i serie og aktivering af en første kromatografisøjle i det første kromatografiske delsystem (500) og en anden kromatografisøjle i det andet kromatografiske delsystem (520) samtidigt til påvisning af bestanddele i den opvarmede, fordampede gas; opsamling af data, der er relateret til sammensætningen af den opvarmede, fordampede gas, fra de to kromatografiske delsystemer (500, 520) med et enkelt dataopsamlingssystem (122) ; kvantificering af sammensætningen af reservoirvæsken baseret på data opsamlet af det enkelte dataopsamlingssystem (122); og bestemmelse af et vægtforhold mellem den fordampede gas og reservoirvæsken.
13. Fremgangsmåde ifølge krav 12, der yderligere omfatter automatisk tilførsel af en del af den enkelte prøve af den fordampede gas til et tredje kromatografisk delsystem (540) i serie med de to kromatografiske delsystemer (500, 520).
14. Fremgangsmåde ifølge krav 12 eller krav 13, der yderligere omfatter: tilførsel af en del af reservoirvæsken til et tredje kromatografisk delsystem (540); opsamling af data, der er relateret til sammensætningen af reservoirvæsken, fra det tredje kromatografiske delsystem (540) med det enkelte dataopsamlingssystem (122); kombinering af dataene, der er relateret til sammensætningen af reservoirvæsken, og dataene, der er relateret til sammensætningen af den fordampede gas; og kvantificering af sammensætningen af reservoirfluiden under tryk baseret på data opsamlet af det enkelte dataopsamlingssystem (122).
15. Fremgangsmåde ifølge et hvilket som helst af kravene 12 til og med 14, hvor hindring af kondensering af den fordampede gas omfatter opvarmning af den fordampede gas med tilgængelig varme.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201161480017P | 2011-04-28 | 2011-04-28 | |
| US13/455,688 US8991233B2 (en) | 2011-04-28 | 2012-04-25 | Analysis of pressurized reservoir fluids |
| PCT/US2012/035445 WO2012149310A1 (en) | 2011-04-28 | 2012-04-27 | Analysis of pressurized reservoir fluids |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DK2702403T3 true DK2702403T3 (da) | 2015-05-04 |
Family
ID=47066846
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DK12724189T DK2702403T3 (da) | 2011-04-28 | 2012-04-27 | Analyse af reservoirfluider under tryk |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US8991233B2 (da) |
| EP (1) | EP2702403B1 (da) |
| CN (1) | CN103688167B (da) |
| AU (1) | AU2012249502B2 (da) |
| BR (1) | BR112013027897B1 (da) |
| CO (1) | CO6801656A2 (da) |
| CY (1) | CY1116382T1 (da) |
| DK (1) | DK2702403T3 (da) |
| ES (1) | ES2535830T3 (da) |
| HR (1) | HRP20150447T1 (da) |
| MX (1) | MX2013012556A (da) |
| MY (1) | MY173028A (da) |
| PE (1) | PE20141782A1 (da) |
| RU (1) | RU2589768C2 (da) |
| SA (1) | SA112330483B1 (da) |
| WO (1) | WO2012149310A1 (da) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PE20121270A1 (es) | 2009-07-30 | 2012-10-07 | Sgs North America Inc | Analisis de presion-volumen-temperatura de fluidos presurizados |
| CN103221819B (zh) | 2010-07-19 | 2015-09-16 | Sgs北美股份有限公司 | 加压储层流体的自动分析 |
| RU2635611C2 (ru) | 2012-01-27 | 2017-11-14 | ЭсДжиЭс НОРТ АМЕРИКА ИНК. | Составной пробоотбор текучих сред |
| CN103412075B (zh) * | 2013-08-27 | 2015-06-03 | 贵州电力试验研究院 | 变压器油色谱全自动进样装置及操作方法 |
| US9624769B2 (en) * | 2013-11-11 | 2017-04-18 | Halliburton Energy Services, Inc. | Determination of fluid compositions |
| CA2939078C (en) | 2014-02-12 | 2020-07-07 | Mustang Sampling, Llc | Natural gas liquid pressure regulating vaporizer sampling system |
| US10605797B2 (en) | 2014-02-12 | 2020-03-31 | Schlumberger Technology Corporation | Fluid analysis methods and apparatus for determining gas-oil ratio |
| RU2662497C1 (ru) * | 2017-06-21 | 2018-07-26 | Общество с ограниченной ответственностью "ЛУКОЙЛ-Инжиниринг" (ООО "ЛУКОЙЛ-Инжиниринг") | Способ оценки воздействия техногенных факторов на изменение компонентного состава и свойств пластового флюида в призабойной зоне пласта |
| RU2681665C1 (ru) * | 2017-11-14 | 2019-03-12 | Игорь Геннадиевич Лапшин | Способ хроматографического анализа смеси углеводородов и газовый хроматограф для его осуществления |
| US12000720B2 (en) | 2018-09-10 | 2024-06-04 | Marathon Petroleum Company Lp | Product inventory monitoring |
| US10613006B1 (en) | 2018-09-24 | 2020-04-07 | Mustang Sampling, LLC. | Liquid vaporization device and method |
| US12031676B2 (en) | 2019-03-25 | 2024-07-09 | Marathon Petroleum Company Lp | Insulation securement system and associated methods |
| US11975316B2 (en) | 2019-05-09 | 2024-05-07 | Marathon Petroleum Company Lp | Methods and reforming systems for re-dispersing platinum on reforming catalyst |
| US12013381B2 (en) * | 2020-06-24 | 2024-06-18 | Frontier Laboratories Ltd. | Gas phase component analysis device and gas phase component analysis method |
| US11852616B2 (en) * | 2021-01-07 | 2023-12-26 | Saudi Arabian Oil Company | High pressure high temperature direct fluid injection to gas chromatography in a PVT system |
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| US12013387B2 (en) | 2021-03-11 | 2024-06-18 | Saudi Arabian Oil Company | Determining reservoir fluid composition to pentatetracontanes plus |
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| US12018216B2 (en) | 2021-10-10 | 2024-06-25 | Marathon Petroleum Company Lp | Methods and systems for enhancing processing of hydrocarbons in a fluid catalytic cracking unit using plastic |
| US20230273176A1 (en) * | 2022-02-28 | 2023-08-31 | Saudi Arabian Oil Company | Method to prepare virtual assay using high pressure liquid chromatography |
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-
2012
- 2012-04-25 US US13/455,688 patent/US8991233B2/en active Active
- 2012-04-27 PE PE2013002423A patent/PE20141782A1/es active IP Right Grant
- 2012-04-27 WO PCT/US2012/035445 patent/WO2012149310A1/en active Application Filing
- 2012-04-27 CN CN201280030381.7A patent/CN103688167B/zh not_active Expired - Fee Related
- 2012-04-27 RU RU2013152754/28A patent/RU2589768C2/ru active
- 2012-04-27 MX MX2013012556A patent/MX2013012556A/es active IP Right Grant
- 2012-04-27 ES ES12724189.1T patent/ES2535830T3/es active Active
- 2012-04-27 BR BR112013027897-8A patent/BR112013027897B1/pt active IP Right Grant
- 2012-04-27 AU AU2012249502A patent/AU2012249502B2/en active Active
- 2012-04-27 DK DK12724189T patent/DK2702403T3/da active
- 2012-04-27 EP EP12724189.1A patent/EP2702403B1/en active Active
- 2012-04-27 MY MYPI2013003921A patent/MY173028A/en unknown
- 2012-04-28 SA SA112330483A patent/SA112330483B1/ar unknown
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2013
- 2013-10-28 CO CO13255068A patent/CO6801656A2/es active IP Right Grant
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2015
- 2015-04-27 CY CY20151100388T patent/CY1116382T1/el unknown
- 2015-04-27 HR HRP20150447TT patent/HRP20150447T1/hr unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US8991233B2 (en) | 2015-03-31 |
| AU2012249502B2 (en) | 2015-07-09 |
| CN103688167A (zh) | 2014-03-26 |
| BR112013027897A2 (pt) | 2017-01-10 |
| HRP20150447T1 (hr) | 2015-07-31 |
| EP2702403A1 (en) | 2014-03-05 |
| AU2012249502A1 (en) | 2013-11-28 |
| SA112330483B1 (ar) | 2015-10-29 |
| CN103688167B (zh) | 2015-11-25 |
| BR112013027897B1 (pt) | 2020-09-01 |
| PE20141782A1 (es) | 2014-12-07 |
| RU2589768C2 (ru) | 2016-07-10 |
| MY173028A (en) | 2019-12-19 |
| MX2013012556A (es) | 2014-06-23 |
| EP2702403B1 (en) | 2015-01-28 |
| RU2013152754A (ru) | 2015-06-10 |
| CO6801656A2 (es) | 2013-11-29 |
| WO2012149310A1 (en) | 2012-11-01 |
| ES2535830T3 (es) | 2015-05-18 |
| CY1116382T1 (el) | 2017-02-08 |
| US20120272715A1 (en) | 2012-11-01 |
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