DK200101392A - Polypropylene fiber and its manufacture - Google Patents

Polypropylene fiber and its manufacture Download PDF

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Publication number
DK200101392A
DK200101392A DK200101392A DKPA200101392A DK200101392A DK 200101392 A DK200101392 A DK 200101392A DK 200101392 A DK200101392 A DK 200101392A DK PA200101392 A DKPA200101392 A DK PA200101392A DK 200101392 A DK200101392 A DK 200101392A
Authority
DK
Denmark
Prior art keywords
polypropylene fiber
fiber
manufacture
polypropylene
index
Prior art date
Application number
DK200101392A
Other languages
Danish (da)
Inventor
Pyung Yul Park
Jun Won Chey
Original Assignee
Pyung Yul Park
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR10-1999-0049610A external-priority patent/KR100401246B1/en
Priority claimed from KR10-2000-0013319A external-priority patent/KR100401248B1/en
Application filed by Pyung Yul Park filed Critical Pyung Yul Park
Publication of DK200101392A publication Critical patent/DK200101392A/en
Priority to DK200501079A priority Critical patent/DK176141B1/en
Application granted granted Critical
Publication of DK175963B1 publication Critical patent/DK175963B1/en

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Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/02Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D01F6/04Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
    • D01F6/06Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Artificial Filaments (AREA)
  • Nonwoven Fabrics (AREA)

Description

PATENTKRAV 1. Polypropylenfibre, som tilvejebringes fra en isotaktisk polypropylenhomopolymer med et isotaktisk indeks på 90 til 99% ved smeltespinding eller ved trækning efter smeltespinding, og som udviser to differentielskanningskalorimeter (DSC) endotermiske toppe mellem 155 og 170°C. 2. Polypropylenfiberen ifølge krav 1, hvori de to differentielskanningskalorimetre (DSC) endotermiske toppe er sammensat af en primær endotermisk top, der forekommer ved 160 + 3°C og en sekundær endotermisk top, der forekommer ved 165 + 3°C. 3. Polypropylenfiberen ifølge krav 1, hvori fiberen har et smelteindeks (MIC) på 16,5-80,0. 4. Polypropylenfiberen ifølge krav 1, hvori fiberen har et polydispersitetsindeks (PIC) på 2,1-5,7. 5. Polypropylenfiberen ifølge krav 1, hvori fiberen har en finhed på 1,0-80,0 denier pr. filament. 6. Polypropylenfiberen ifølge krav 4, hvori fiberen har PIC værdien på 2,3-4,5. 7. Polypropylenfiberen ifølge krav 1 yderligere omfattende en stabilisator og/eller en antioxidant i en mængde på 0,03 til 2,0 vægt%. 8. Polypropylenfiberen ifølge krav 7, hvori stabilisatoren og/eller antioxidanten indeholdes i en mængde på 0,03 til 0,7 vægt%. 9. Polypropylenf iberen ifølge krav 8, hvori stabilisatoren og/eller antioxidanten indeholdes i en mængde på 0,03 til 0,4 vægt%. 10. Fremgangsmåde til fremstilling af polypropylenf ibre omfattende trinnene: (a) smeltning af et isotaktisk polypropylenhomopolymer med et isotaktisk indeks på 90-99%, et smelteindeks (MIa) på 10,0-40,0 og et polydispersitetsindeks (PIa) på 2,5-6,0 for at give en smeltet polymer, som har et smelteindeks (MIb) med forholdet af MIb/MIa liggende i intervallet fra 1,01 til 1,50 og et polydispersitetsindeks (PIb) snævrere med 10% eller mindre end PIa værdien; (b) spinding af den smeltede polymer for at frembringe fibre med et smelteindeks (MIC) på 16,5-80,0 og et polydispersitetsindeks (PIC) , som er snævrere med 20% eller mindre end PIa værdien, hvor forholdet af MIc/MIa ligger i intervallet fra 1,65 til 7,50; og (c) eventuelt trækning af fibrene. 11. Fremgangsmåde ifølge krav 10, hvori polypropy-lenhomopolymeren indeholder en stabilisator og/eller en antioxidant i en mængde på 0,03-2,0 vægt% i trin (a). 12. Fremgangsmåde ifølge krav 10, hvori MIa ligger i intervallet fra 10 til 30. 13. Fremgangsmåde ifølge krav 10, hvori PIa ligger i intervallet fra 2,8 til 5,0. 14. Fremgangsmåde ifølge krav 13, hvori PIa ligger i intervallet fra 3,5 til 4,3. 15. Fremgangsmåde ifølge krav 10, hvori fibrene ligger i intervallet for finhed fra 1,0 til 80,0 denier pr. filament. 16. Fremgangsmåde ifølge krav 10, hvori MIb ligger i intervallet fra 10,1 til 41,0. 17. Fremgangsmåde ifølge krav 10, hvori fiberen har PIC værdien på 2,1 til 5,7. 18. Fremgangsmåde ifølge krav 17, hvori fiberen har PIC værdien på 2,3 til 4,5.PATENT REQUIREMENTS 1. Polypropylene fibers obtained from an isotactic polypropylene homopolymer with an isotactic index of 90 to 99% by melt spinning or by melt spinning and exhibiting two differential scanning calorimeter (DSC) endothermic peaks between 155 and 170 ° C. The polypropylene fiber of claim 1, wherein the two differential scanning calorimeters (DSC) endothermic peaks are composed of a primary endothermic peak occurring at 160 + 3 ° C and a secondary endothermic peak occurring at 165 + 3 ° C. The polypropylene fiber of claim 1, wherein the fiber has a melt index (MIC) of 16.5-80.0. The polypropylene fiber of claim 1, wherein the fiber has a polydispersity index (PIC) of 2.1-5.7. The polypropylene fiber of claim 1, wherein the fiber has a fineness of 1.0-80.0 denier per minute. filament. The polypropylene fiber of claim 4, wherein the fiber has the PIC value of 2.3-4.5. The polypropylene fiber of claim 1 further comprising a stabilizer and / or an antioxidant in an amount of 0.03 to 2.0% by weight. The polypropylene fiber of claim 7, wherein the stabilizer and / or antioxidant is contained in an amount of 0.03 to 0.7% by weight. The polypropylene fiber of claim 8, wherein the stabilizer and / or antioxidant is contained in an amount of 0.03 to 0.4% by weight. A process for preparing polypropylene fiber comprising the steps of: (a) melting an isotactic polypropylene homopolymer with an isotactic index of 90-99%, a melt index (MIa) of 10.0-40.0 and a polydispersity index (PIa) of 2 , 5-6.0 to give a molten polymer having a melt index (MIb) with the ratio of MIb / MIa ranging from 1.01 to 1.50 and a polydispersity index (PIb) narrower by 10% or less than The PIa value; (b) spinning the molten polymer to produce fibers having a melt index (MIC) of 16.5-80.0 and a polydispersity index (PIC) which is narrower by 20% or less than the PIa value, wherein the ratio of MIc / The MIa ranges from 1.65 to 7.50; and (c) optionally pulling the fibers. The method of claim 10, wherein the polypropylene homopolymer contains a stabilizer and / or an antioxidant in an amount of 0.03-2.0% by weight in step (a). The method of claim 10, wherein the MIa is in the range of 10 to 30. The method of claim 10, wherein the P1a is in the range of 2.8 to 5.0. The method of claim 13, wherein the PIa is in the range of 3.5 to 4.3. The method of claim 10, wherein the fibers are in the range of fineness from 1.0 to 80.0 denier per minute. filament. The method of claim 10, wherein the MIb is in the range of 10.1 to 41.0. The method of claim 10, wherein the fiber has the PIC value of 2.1 to 5.7. The method of claim 17, wherein the fiber has the PIC value of 2.3 to 4.5.

DK200101392A 1999-11-10 2001-09-25 polypropylene fiber DK175963B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DK200501079A DK176141B1 (en) 1999-11-10 2005-07-21 Polypropylene fiber used as raw material for non-woven fabric production, is formed by melt spinning and drawing isotactic polypropylene homopolymer and has two endothermic peaks at specific temperature

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
KR19990049610 1999-11-10
KR10-1999-0049610A KR100401246B1 (en) 1999-11-10 1999-11-10 Preparation of polyolefin fiber
KR10-2000-0013319A KR100401248B1 (en) 2000-03-16 2000-03-16 Polypropylene fiber and preparation thereof
KR20000013319 2000-03-16
PCT/KR2000/001270 WO2001034884A2 (en) 1999-11-10 2000-11-07 Polypropylene fiber and preparation thereof
KR0001270 2000-11-07

Publications (2)

Publication Number Publication Date
DK200101392A true DK200101392A (en) 2001-09-25
DK175963B1 DK175963B1 (en) 2005-09-19

Family

ID=26636302

Family Applications (1)

Application Number Title Priority Date Filing Date
DK200101392A DK175963B1 (en) 1999-11-10 2001-09-25 polypropylene fiber

Country Status (13)

Country Link
EP (1) EP1234065B1 (en)
CN (1) CN1174129C (en)
AU (1) AU768809B2 (en)
BR (1) BR0010462B1 (en)
CA (1) CA2372453C (en)
DE (1) DE10084374B4 (en)
DK (1) DK175963B1 (en)
ES (1) ES2237983B1 (en)
GB (1) GB2365438B (en)
LU (1) LU90849B1 (en)
MX (1) MXPA02001814A (en)
MY (1) MY120636A (en)
WO (1) WO2001034884A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104389040B (en) * 2014-10-28 2016-03-09 湖北博韬合纤有限公司 The polypropylene dedicated staple fibre processing technology of light GMT plate
KR102251754B1 (en) * 2019-12-24 2021-05-12 도레이첨단소재 주식회사 Non-woven fabric with enhanced mechanical strength

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL6910137A (en) * 1968-07-04 1970-01-06
JPS509810A (en) * 1973-06-04 1975-01-31
JP3070694B2 (en) * 1991-06-11 2000-07-31 三井化学株式会社 Ultra-high molecular weight stretched polypropylene article and method for producing the same
JP2948948B2 (en) * 1991-07-08 1999-09-13 宇部日東化成 株式会社 Thermal adhesive fiber
TW275076B (en) * 1992-12-02 1996-05-01 Hoechst Ag
US5529845A (en) * 1994-06-13 1996-06-25 Montell North America Inc. Fibers suitable for the production of nonwoven fabrics having improved strength and softness characteristics
JP3554433B2 (en) * 1996-04-10 2004-08-18 特種製紙株式会社 Recording sheet for wet electrophotography
JPH10195714A (en) * 1996-12-27 1998-07-28 Mitsui Chem Inc Fiber made of polypropylene
US6416699B1 (en) * 1999-06-09 2002-07-09 Fina Technology, Inc. Reduced shrinkage in metallocene isotactic polypropylene fibers

Also Published As

Publication number Publication date
EP1234065B1 (en) 2006-03-22
GB2365438B (en) 2003-07-16
AU1177801A (en) 2001-06-06
DE10084374B4 (en) 2006-04-06
ES2237983B1 (en) 2006-11-01
BR0010462B1 (en) 2011-03-22
CA2372453A1 (en) 2001-05-17
MXPA02001814A (en) 2002-09-24
MY120636A (en) 2005-11-30
GB2365438A (en) 2002-02-20
EP1234065A2 (en) 2002-08-28
CA2372453C (en) 2004-06-08
ES2237983A1 (en) 2005-08-01
GB0121728D0 (en) 2001-10-31
CN1335901A (en) 2002-02-13
WO2001034884A3 (en) 2001-10-18
EP1234065A4 (en) 2005-06-15
BR0010462A (en) 2003-07-08
CN1174129C (en) 2004-11-03
DK175963B1 (en) 2005-09-19
LU90849B1 (en) 2002-01-24
DE10084374T1 (en) 2002-11-07
AU768809B2 (en) 2004-01-08
WO2001034884A2 (en) 2001-05-17

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Effective date: 20181107