CN1174129C - Polypropylene fiber and preparation thereof - Google Patents
Polypropylene fiber and preparation thereof Download PDFInfo
- Publication number
- CN1174129C CN1174129C CNB008024685A CN00802468A CN1174129C CN 1174129 C CN1174129 C CN 1174129C CN B008024685 A CNB008024685 A CN B008024685A CN 00802468 A CN00802468 A CN 00802468A CN 1174129 C CN1174129 C CN 1174129C
- Authority
- CN
- China
- Prior art keywords
- fiber
- polypropylene
- index
- polypropylene fibre
- melt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 91
- -1 Polypropylene Polymers 0.000 title claims abstract description 42
- 239000004743 Polypropylene Substances 0.000 title claims abstract description 42
- 229920001155 polypropylene Polymers 0.000 title claims abstract description 42
- 238000002360 preparation method Methods 0.000 title description 4
- 238000002074 melt spinning Methods 0.000 claims abstract description 12
- 229920005629 polypropylene homopolymer Polymers 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims description 19
- 238000000113 differential scanning calorimetry Methods 0.000 claims description 18
- 238000009987 spinning Methods 0.000 claims description 18
- 229920000642 polymer Polymers 0.000 claims description 9
- 239000000155 melt Substances 0.000 claims description 8
- 239000003963 antioxidant agent Substances 0.000 claims description 7
- 230000003078 antioxidant effect Effects 0.000 claims description 7
- 239000003381 stabilizer Substances 0.000 claims description 7
- 230000004927 fusion Effects 0.000 claims description 5
- 238000009960 carding Methods 0.000 abstract description 9
- 239000004745 nonwoven fabric Substances 0.000 abstract description 3
- 239000004744 fabric Substances 0.000 description 48
- 230000000704 physical effect Effects 0.000 description 10
- 238000001816 cooling Methods 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 6
- 238000013461 design Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 206010013786 Dry skin Diseases 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 235000007164 Oryza sativa Nutrition 0.000 description 2
- 210000002659 acromion Anatomy 0.000 description 2
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 2
- 238000003490 calendering Methods 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 235000009566 rice Nutrition 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 229920000433 Lyocell Polymers 0.000 description 1
- 241001274660 Modulus Species 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 159000000009 barium salts Chemical class 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000013213 extrapolation Methods 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000003252 repetitive effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/02—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D01F6/04—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins
- D01F6/06—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolymers obtained by reactions only involving carbon-to-carbon unsaturated bonds from polyolefins from polypropylene
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Nonwoven Fabrics (AREA)
Abstract
Description
The embodiment numbering | Material | Melt | Fiber | MI b/MI a | MI c/MI a | |||
MI a | PI a | MI b | PI b | MI c | PI c | |||
1 | 17.2 | 4.1 | 18.2 | 3.9 | 52.0 | 3.8 | 1.1 | 3.0 |
2 | 22 | 3.2 | 23.0 | 3.1 | 56.0 | 2.9 | 1.0 | 2.5 |
3 | 12.2 | 5.5 | 18.0 | 5.1 | 57.0 | 4.5 | 1.5 | 4.7 |
4 | 12.2 | 6.0 | 17.0 | 5.5 | 36.5 | 4.9 | 1.4 | 3.0 |
5 | 13.2 | 4.3 | 15.0 | 3.9 | 45.0 | 3.6 | 1.1 | 3.4 |
6 | 11.0 | 3.8 | 14.6 | 3.6 | 46.0 | 3.5 | 1.3 | 4.2 |
7 | 11.0 | 5.8 | 13.6 | 5.6 | 31.2 | 4.9 | 1.2 | 2.8 |
C1 | 12.2 | 2.4 | 17.0 | 2.3 | 24.3 | 2.2 | 1.4 | 2.0 |
C2 | 17.1 | 10.8 | 29.2 | 9.5 | 106.5 | 6.5 | 1.7 | 6.2 |
C3 | 3.9 | 6.5 | 5.6 | 6.4 | 32.5 | 5.1 | 1.4 | 8.3 |
C4 | 12.2 | 5.5 | 15.4 | 4.9 | 80.2 | 4.7 | 1.3 | 6.6 |
C5 | 8.1 | 5.6 | 11.6 | 5.1 | 28.0 | 4.2 | 1.4 | 3.5 |
C6 | 10.8 | 12.0 | 19.1 | 11.0 | 39.5 | 10.2 | 1.8 | 3.7 |
C7 | 42.5 | 5.9 | 62.4 | 5.7 | 698.0 | 5.1 | 1.5 | 4.7 |
The embodiment numbering | {1-(PI b/PI a)} ×100(%) | {1-(PI c/PI a)} ×100(%) | The DSC endothermic peak of spun yarn (℃) | |
1′ | 2′ | |||
1 | 4.9 | 7.3 | 159.6 | 164.2 |
2 | 3.1 | 9.4 | 160.2 | 164.5 |
3 | 7.3 | 18.2 | 159.8 | 165.2 |
4 | 8.3 | 18.3 | 158.9 | 164.8 |
5 | 9.3 | 16.3 | 160.1 | 163.9 |
6 | 5.3 | 7.9 | 160.0 | 166.2 |
7 | 3.4 | 15.5 | 159.5 | 164.2 |
C1 | 4.2 | 8.3 | 159.8 | - |
C2 | 12.0 | 39.8 | 160.2 | - |
C3 | 1.5 | 21.5 | 160.2 | - |
C4 | 10.9 | 14.5 | 159.2 | - |
C5 | 8.9 | 25.0 | 160.0 | - |
C6 | 8.3 | 15.0 | 159.9 | - |
C7 | 8.4 | 13.6 | 159.8 | - |
The embodiment numbering | MIc | PIc | Fibre strength (gram/dawn) | Crispation number | The DSC endothermic peak of staple fibre (℃) | |||
The fiber that spinning forms | The staple fibre of spinning after-drawing | The fiber that spinning forms | The staple fibre of spinning after-drawing | 1′ | 2′ | |||
1 | 52.0 | 51.0 | 3.8 | 3.7 | 1.9 | 7.7 | 159.4 | 164.2 |
2 | 56.0 | 55.0 | 2.9 | 2.8 | 2.2 | 6.2 | 160.1 | 164.5 |
3 | 57.0 | 57.6 | 4.5 | 4.5 | 2.3 | 6.4 | 159.7 | 165.8 |
4 | 36.5 | 36.9 | 4.9 | 5.0 | 1.9 | 6.4 | 158.9 | 165.1 |
5 | 45.0 | 44.0 | 3.6 | 3.8 | 2.4 | 7.2 | 160.2 | 164.1 |
6 | 46.0 | 47.3 | 3.5 | 3.4 | 2.2 | 6.2 | 159.8 | 165.8 |
7 | 31.2 | 33.0 | 4.9 | 4.8 | 2.6 | 5.9 | 159.9 | 163.7 |
C1 | 24.3 | 24.3 | 2.2 | 2.3 | 2.2 | 7.5 | 160.1 | - |
C2 | 106.5 | 104.2 | 6.5 | 6.5 | 1.7 | 7.6 | 160.2 | - |
C3 | 32.3 | 33.6 | 5.1 | 5.2 | 2.2 | 6.5 | 160.3 | - |
C4 | 80.2 | 81.2 | 4.7 | 4.9 | 1.9 | 8.1 | 160.4 | - |
C5 | 28.0 | 29.3 | 4.2 | 4.3 | 2.1 | 6.9 | 160.1 | - |
C6 | 39.6 | 41.2 | 10.2 | 10.3 | 1.6 | 7.2 | 160.2 | - |
C7 | 201.0 | 197.0 | 5.1 | 5.2 | 1.7 | 6.5 | 160.1 | - |
The embodiment numbering | Combing | Intensity (kilogram/5 centimetres) | TBI | Pliability | Note | |||
Machine | Speed (rice/minute) | Design weight (gram/rice 2) | MD | CD | ||||
1 | THIBEAU | 180 | 21.0 | 5.3 | 1.4 | 2.6 | 5 | - |
2 | SPINNBAU | 175 | 19.0 | 5.2 | 1.2 | 2.6 | 4 | - |
3 | SPINNBAU | 100 | 19.5 | 7.2 | 2.6 | 4.4 | 5 | - |
4 | SPINNBAU | 210 | 17.8 | 6.2 | 1.5 | 3.4 | 4 | - |
5 | HERGETH | 95 | 20.1 | 4.9 | 1.8 | 3.0 | 5 | - |
6 | HERGETH | 95 | 22.1 | 6.8 | 1.8 | 3.2 | 4 | - |
7 | HERGETH | 180 | 20.3 | 3.9 | 1.4 | 2.3 | 4 | - |
C1 | SPINNBAU | 100 | 20.2 | 3.2 | 0.9 | 1.7 | 1 | Coarse |
C2 | HERGETH | 150 | 21.0 | 3.5 | 0.8 | 1.6 | 3 | TBI descends |
C3 | SPINNBAU | 150 | 20.3 | 3.4 | 0.9 | 1.7 | 1 | TBI descends |
C4 | SPINNBAU | 160 | 20.4 | 3.5 | 1.0 | 1.8 | 2 | TBI descends |
C5 | SPINNBAU | 100 | 19.8 | 3.8 | 0.9 | 1.9 | 2 | Coarse |
C6 | SPINNBAU | 105 | 18.9 | 3.9 | 0.8 | 1.9 | 2 | Coarse |
C7 | SPINNBAU | 90 | 19.5 | 3.8 | 0.9 | 1.9 | 3 | Difficulty, NEP is many |
Claims (17)
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-1999-0049610A KR100401246B1 (en) | 1999-11-10 | 1999-11-10 | Preparation of polyolefin fiber |
KR1999/49610 | 1999-11-10 | ||
KR10-2000-0013319A KR100401248B1 (en) | 2000-03-16 | 2000-03-16 | Polypropylene fiber and preparation thereof |
KR2000/13319 | 2000-03-16 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1335901A CN1335901A (en) | 2002-02-13 |
CN1174129C true CN1174129C (en) | 2004-11-03 |
Family
ID=26636302
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB008024685A Expired - Lifetime CN1174129C (en) | 1999-11-10 | 2000-11-07 | Polypropylene fiber and preparation thereof |
Country Status (13)
Country | Link |
---|---|
EP (1) | EP1234065B1 (en) |
CN (1) | CN1174129C (en) |
AU (1) | AU768809B2 (en) |
BR (1) | BR0010462B1 (en) |
CA (1) | CA2372453C (en) |
DE (1) | DE10084374B4 (en) |
DK (1) | DK175963B1 (en) |
ES (1) | ES2237983B1 (en) |
GB (1) | GB2365438B (en) |
LU (1) | LU90849B1 (en) |
MX (1) | MXPA02001814A (en) |
MY (1) | MY120636A (en) |
WO (1) | WO2001034884A2 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104389040B (en) * | 2014-10-28 | 2016-03-09 | 湖北博韬合纤有限公司 | The polypropylene dedicated staple fibre processing technology of light GMT plate |
KR102251754B1 (en) * | 2019-12-24 | 2021-05-12 | 도레이첨단소재 주식회사 | Non-woven fabric with enhanced mechanical strength |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL6910137A (en) * | 1968-07-04 | 1970-01-06 | ||
JPS509810A (en) * | 1973-06-04 | 1975-01-31 | ||
JP3070694B2 (en) * | 1991-06-11 | 2000-07-31 | 三井化学株式会社 | Ultra-high molecular weight stretched polypropylene article and method for producing the same |
JP2948948B2 (en) * | 1991-07-08 | 1999-09-13 | 宇部日東化成 株式会社 | Thermal adhesive fiber |
TW275076B (en) * | 1992-12-02 | 1996-05-01 | Hoechst Ag | |
US5529845A (en) * | 1994-06-13 | 1996-06-25 | Montell North America Inc. | Fibers suitable for the production of nonwoven fabrics having improved strength and softness characteristics |
JP3554433B2 (en) * | 1996-04-10 | 2004-08-18 | 特種製紙株式会社 | Recording sheet for wet electrophotography |
JPH10195714A (en) * | 1996-12-27 | 1998-07-28 | Mitsui Chem Inc | Fiber made of polypropylene |
US6416699B1 (en) * | 1999-06-09 | 2002-07-09 | Fina Technology, Inc. | Reduced shrinkage in metallocene isotactic polypropylene fibers |
-
2000
- 2000-10-18 MY MYPI20004879A patent/MY120636A/en unknown
- 2000-11-07 WO PCT/KR2000/001270 patent/WO2001034884A2/en active IP Right Grant
- 2000-11-07 DE DE10084374T patent/DE10084374B4/en not_active Expired - Fee Related
- 2000-11-07 EP EP00973247A patent/EP1234065B1/en not_active Expired - Lifetime
- 2000-11-07 CA CA002372453A patent/CA2372453C/en not_active Expired - Fee Related
- 2000-11-07 ES ES200250025A patent/ES2237983B1/en not_active Expired - Fee Related
- 2000-11-07 BR BRPI0010462-0A patent/BR0010462B1/en not_active IP Right Cessation
- 2000-11-07 AU AU11778/01A patent/AU768809B2/en not_active Ceased
- 2000-11-07 CN CNB008024685A patent/CN1174129C/en not_active Expired - Lifetime
- 2000-11-07 MX MXPA02001814A patent/MXPA02001814A/en active IP Right Grant
- 2000-11-07 GB GB0121728A patent/GB2365438B/en not_active Expired - Fee Related
-
2001
- 2001-09-25 DK DK200101392A patent/DK175963B1/en not_active IP Right Cessation
- 2001-10-10 LU LU90849A patent/LU90849B1/en active
Also Published As
Publication number | Publication date |
---|---|
EP1234065B1 (en) | 2006-03-22 |
GB2365438B (en) | 2003-07-16 |
AU1177801A (en) | 2001-06-06 |
DE10084374B4 (en) | 2006-04-06 |
DK200101392A (en) | 2001-09-25 |
ES2237983B1 (en) | 2006-11-01 |
BR0010462B1 (en) | 2011-03-22 |
CA2372453A1 (en) | 2001-05-17 |
MXPA02001814A (en) | 2002-09-24 |
MY120636A (en) | 2005-11-30 |
GB2365438A (en) | 2002-02-20 |
EP1234065A2 (en) | 2002-08-28 |
CA2372453C (en) | 2004-06-08 |
ES2237983A1 (en) | 2005-08-01 |
GB0121728D0 (en) | 2001-10-31 |
CN1335901A (en) | 2002-02-13 |
WO2001034884A3 (en) | 2001-10-18 |
EP1234065A4 (en) | 2005-06-15 |
BR0010462A (en) | 2003-07-08 |
DK175963B1 (en) | 2005-09-19 |
LU90849B1 (en) | 2002-01-24 |
DE10084374T1 (en) | 2002-11-07 |
AU768809B2 (en) | 2004-01-08 |
WO2001034884A2 (en) | 2001-05-17 |
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Effective date of registration: 20200317 Address after: 213 Gongtuan Road, Jinquan City, North Qingshang Road, South Korea Patentee after: Cologne fiber Address before: Han Guojingjidao Patentee before: KOLON GLOTECH, Inc. |
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