DK1954923T3 - Strålingskøler til syntesegas - Google Patents

Strålingskøler til syntesegas Download PDF

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Publication number
DK1954923T3
DK1954923T3 DK06836565.9T DK06836565T DK1954923T3 DK 1954923 T3 DK1954923 T3 DK 1954923T3 DK 06836565 T DK06836565 T DK 06836565T DK 1954923 T3 DK1954923 T3 DK 1954923T3
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DK
Denmark
Prior art keywords
synthesis gas
gas cooler
cooler according
liquid
cooled
Prior art date
Application number
DK06836565.9T
Other languages
English (en)
Inventor
Dave L Kraft
Kiplin C Alexander
Steven R Fry
Thomas E Doyle
Melvin J Albrecht
Original Assignee
Babcock & Wilcox Co
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Publication of DK1954923T3 publication Critical patent/DK1954923T3/da

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/86—Other features combined with waste-heat boilers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46—Gasification of granular or pulverulent flues in suspension
    • C10J3/48—Apparatus; Plants
    • C10J3/52—Ash-removing devices
    • C10J3/526—Ash-removing devices for entrained flow gasifiers
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/74—Construction of shells or jackets
    • C10J3/76—Water jackets; Steam boiler-jackets
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/82—Gas withdrawal means
    • C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
    • C10J3/845—Quench rings
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/04—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
    • C10K1/10—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids
    • C10K1/101—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors with aqueous liquids with water only
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22—STEAM GENERATION
    • F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00—Methods of steam generation characterised by form of heating method
    • F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/18—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22—STEAM GENERATION
    • F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00—Methods of steam generation characterised by form of heating method
    • F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/18—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
    • F22B1/1838—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines the hot gas being under a high pressure, e.g. in chemical installations
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22—STEAM GENERATION
    • F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B1/00—Methods of steam generation characterised by form of heating method
    • F22B1/02—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers
    • F22B1/18—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines
    • F22B1/1838—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines the hot gas being under a high pressure, e.g. in chemical installations
    • F22B1/1846—Methods of steam generation characterised by form of heating method by exploitation of the heat content of hot heat carriers the heat carrier being a hot gas, e.g. waste gas such as exhaust gas of internal-combustion engines the hot gas being under a high pressure, e.g. in chemical installations the hot gas being loaded with particles, e.g. waste heat boilers after a coal gasification plant
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22—STEAM GENERATION
    • F22B—METHODS OF STEAM GENERATION; STEAM BOILERS
    • F22B21/00—Water-tube boilers of vertical or steeply-inclined type, i.e. the water-tube sets being arranged vertically or substantially vertically
    • F22B21/02—Water-tube boilers of vertical or steeply-inclined type, i.e. the water-tube sets being arranged vertically or substantially vertically built-up from substantially straight water tubes
    • F22B21/04—Water-tube boilers of vertical or steeply-inclined type, i.e. the water-tube sets being arranged vertically or substantially vertically built-up from substantially straight water tubes involving a single upper drum and a single lower drum, e.g. the drums being arranged transversely
    • F22B21/06—Water-tube boilers of vertical or steeply-inclined type, i.e. the water-tube sets being arranged vertically or substantially vertically built-up from substantially straight water tubes involving a single upper drum and a single lower drum, e.g. the drums being arranged transversely the water tubes being arranged annularly in sets, e.g. in abutting connection with drums of annular shape
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/16—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation
    • F28D7/163—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation with conduit assemblies having a particular shape, e.g. square or annular; with assemblies of conduits having different geometrical features; with multiple groups of conduits connected in series or parallel and arranged inside common casing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/16—Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18—Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]

Claims (30)

1. Syntesegaskøler (10) til ekstraktion af varme fra syntesegas (12), der dannes ved en forgasningsproces, som omfatter: en kappe (44) med et syntesegasindløb (14) og et syntesegasudløb (38); en væskekølet trækkanal (26), der er indeholdt i kappen til modtagelse af syntesegas; et forseglingsplademiddel (64) i syntesegaskøleren til at forhindre, at syntesegas trænger ind i et område mellem kappen og trækkanalen, hvilket forseglingsplademiddel omfatter et trykudligningsmiddel (72), der er tilvejebragt i forseglingsplademidlet, til reducering af muligheden for skade på forseglingsplademidlet, som kunne forekomme som følge af, at et tryk på den ene side af forseglingsplademidlet er større end et tryk på en modsat side af forseglingsplademidlet; væskekølet strålingsvarmeoverførselsflade (30), der strækker sig delvist ind i trækkanalen, til køling af syntesegassen; og et middel (56, 60) til at transportere syntesegassen fra trækkanalen til syntesegasudløbet.
2. Syntesegaskøler ifølge krav 1, der omfatter et vandbadområde (34) i en nedre del af syntesegaskøleren til modtagelse og nedkøling af faststoffer, der er indeholdt i syntesegassen, og et faststofudløb (54) til fjernelse af faststofferne fra syntesegaskøleren.
3. Syntesegaskøler ifølge krav 1, hvor den væskekølede trækkanal består af en indeslutningsvæg (28) fremstillet af væskekølede rør.
4. Syntesegaskøler ifølge krav 1, hvor den væskekølede stålingsvarmeoverførselsflade består af en eller flere væskekølede skillevægsflader, der er ophængt indvendigt i syntesegaskøleren, således at en signifikant del af skillevægsfladerne er eksponeret for den indkommende syntesegas.
5. Syntesegaskøler ifølge krav 4, hvor hver af den ene eller de flere skillevægsflader består af en plan række af rør, der er anbragt tilstødende til hinanden.
6. Syntesegaskøler ifølge krav 1, hvor en bunddel af trækkanalen omfatter et tragtmiddel (46).
7. Syntesegaskøler ifølge krav 6, der yderligere omfatter et middel til transport af syntesegassen fra tragtmidlet til vandbadområdet.
8. Syntesegaskøler ifølge krav 7, hvor midlet til transport af syntesegassen fra tragtmidlet til vandbadområdet omfatter et stigrør (56) med et udløb tæt på vandbadområdet.
9. Syntesegaskøler ifølge krav 8, der yderligere omfatter et middel (60) til frembringelse af en passage til transport af syntesegassen fra udløbet af stigrøret mod syntesegasudløbet.
10. Syntesegaskøler ifølge krav 9, hvor midlet til frembringelse af en passage til transport af syntesegassen fra udløbet af stigrøret mod syntesegasudløbet omfatter et faldrør omkring stigrøret.
11. Syntesegaskøler ifølge krav 1 og krav 6, hvor forseglingsplademidlet strækker sig mellem kappen og et middel til transport af syntesegassen fra tragtmidlet til vandbadområdet.
12. Syntesegaskøler ifølge krav 1, hvor kappen og forseglingsplademidlet delvist definerer et syntesegasudløbsområde (36).
13. Syntesegaskøler ifølge krav 12, hvor syntesegasudløbsområdet transporterer syntesegas fra vandbadområdet til syntesegasudløbet.
14. Syntesegaskøler ifølge krav 11, der omfatter et ekspansionssamlingsmiddel (66) til tilvejebringelse af relativ bevægelse mellem forseglingsplademidlet og tragtmidlet.
15. Syntesegaskøler ifølge krav 1, der yderligere omfatter et bratkølingsmiddel (68) til injektion af væske i syntesegassen.
16. Syntesegaskøler ifølge krav 7, hvor tragtmidlet har en keglestubform og et indsnævringsområde (48) tilstødende midlet til transport af syntesegassen mod vandbadområdet.
17. Syntesegaskøler ifølge krav 1, der omfatter et nedløbsrør (18) til fremføring af væske til den væskekølede trækkanal og stålingsvarmeoverførselsflade og en stigeledning (20) til transport af væske derfra.
18. Syntesegaskøler ifølge krav 1, der omfatter et ekspansionssamlingsmiddel til tilvejebringelse af relativ bevægelse mellem kappen og mindst den ene af indeslutningsvæggene for den væskekølede trækkanal og den væskekølede stålingsvarmeoverførselsflade.
19. Syntesegaskøler ifølge krav 1, hvor den væskekølede trækkanal og de væskekølede stålingsvarmeoverførselsflader er konfigureret til at ekstrahere tilstrækkelig varme fra syntesegassen under normal funktion af syntesegaskøleren til induktion af naturlig cirkulation gennem den væskekølede trækkanal og de væskekølede stålingsvarmeoverførselsflader.
20. Syntesegaskøler ifølge krav 1, hvor trykudligningsmidlet omfatter mindst én åbning (74) i forseglingsplademidlet og et middel (76) til blokering af strømning gennem åbningen, indtil trykket på den ene eller den anden side af forseglingsplademidlet overstiger en trykindstillingsværdi, ved hvilken værdi strømningsblokeringsmidlet vil muliggøre strømning gennem åbningen, indtil trykket ikke længere overstiger trykindstillingsværdien.
21. Syntesegaskøler ifølge krav 1, der omfatter et parabolsk kegleformet indløb i en topdel of syntesegaskøleren til muliggørelse af indløb af syntesegassen ind i syntesegaskøleren, således at faststoffer, der er indeholdt i syntesegassen, fortrinsvis ledes nedad til reducering af direkte indvirkning af de indeholdte faststoffer på den væskekølede stålingsvarmeoverførselsflade.
22. Syntesegaskøler ifølge krav 1, hvor den væskekølede stålingsvarmeoverførselsflade, der strækker sig delvist inde i trækkanalen, til nedkøling af syntesegassen, er placeret, således at direkte indvirkning af syntesegassen og faststoffer indeholdt deri på den væskekølede stålingsvarmeoverførselsflade reduceres.
23. Syntesegaskøler ifølge krav 5, hvor en bunddel af trækkanalen omfatter et tragtmiddel (46), og den ene eller de flere plane skillevægsflader har varierende form til reducering af slaggedeponering derpå, idet dele af skillevægsfladerne, der er tættere på syntesegasindløbet, er radialt længere væk fra en længdegående akse af syntesegaskøleren, og dele af skillevægsfladerne, der er tættere på tragtmidlet, er radialt tættere på den længdegående akse.
24. Syntesegaskøler ifølge krav 23, hvor skillevægsfladerne er forsynet med en membranvægkonstruktion og den varierende skillevægsformen er tilvejebragt ved at variere bredden af membranen mellem tilstødende rør.
25. Syntesegaskøler ifølge krav 8, der yderligere omfatter konvektionsvarmeoverførselsflader (70) placeret tilstødende stigrøret, som ekstraherer yderligere varme fra syntesegassen før transport af syntesegassen gennem syntesegasudløbet.
26. Syntesegaskøler ifølge krav 25, hvor konvektionsvarmeoverførselsfladen omfatter en eller flere rækker af rør, der er anbragt, således at syntesegassen strømmer over ydersiden af rørene.
27. Syntesegaskøler ifølge kravene 8 og 15, hvor bratkølingsmidlet er placeret i stigrøret.
28. Syntesegaskøler ifølge krav 17, hvor noget af nedløbsmidlet opvarmes, idet det udgør en del af væggene i den væskekølede trækkanal, og nedløbsmidlet er tilvejebragt fra og understøttes af et fælles ringsamlerør, der er placeret i en øvre del af syntesegaskøleren.
29. Syntesegaskøler ifølge krav 1, hvor den væskekølede trækkanal og de væskekølede stålingsvarmeoverførselsflader består af kompositrør.
30. Syntesegaskøler ifølge krav 29, hvor kompositrørene har et ydre lag af en højt krom/nikkel-legering over et basisrør af Croloy-materiale.
DK06836565.9T 2005-11-03 2006-10-27 Strålingskøler til syntesegas DK1954923T3 (da)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US73309705P 2005-11-03 2005-11-03
PCT/US2006/041958 WO2007055930A2 (en) 2005-11-03 2006-10-27 Radiant syngas cooler

Publications (1)

Publication Number Publication Date
DK1954923T3 true DK1954923T3 (da) 2017-07-24

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Country Status (7)

Country Link
US (1) US7587995B2 (da)
EP (1) EP1954923B1 (da)
CN (1) CN101351622B (da)
DK (1) DK1954923T3 (da)
ES (1) ES2625929T3 (da)
PL (1) PL1954923T3 (da)
WO (1) WO2007055930A2 (da)

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US20070119577A1 (en) 2007-05-31
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CN101351622B (zh) 2014-04-23
PL1954923T3 (pl) 2017-10-31

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