DK164588B - Gasket element for storage of galvanic air oxygen cells. - Google Patents

Gasket element for storage of galvanic air oxygen cells. Download PDF

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Publication number
DK164588B
DK164588B DK416887A DK416887A DK164588B DK 164588 B DK164588 B DK 164588B DK 416887 A DK416887 A DK 416887A DK 416887 A DK416887 A DK 416887A DK 164588 B DK164588 B DK 164588B
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DK
Denmark
Prior art keywords
foil
air
film
cup
packing element
Prior art date
Application number
DK416887A
Other languages
Danish (da)
Other versions
DK416887A (en
DK164588C (en
DK416887D0 (en
Inventor
Ullrich Costenoble
Original Assignee
Varta Batterie
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Filing date
Publication date
Application filed by Varta Batterie filed Critical Varta Batterie
Publication of DK416887D0 publication Critical patent/DK416887D0/en
Publication of DK416887A publication Critical patent/DK416887A/en
Publication of DK164588B publication Critical patent/DK164588B/en
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Publication of DK164588C publication Critical patent/DK164588C/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D75/00Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
    • B65D75/28Articles or materials wholly enclosed in composite wrappers, i.e. wrappers formed by associating or interconnecting two or more sheets or blanks
    • B65D75/30Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding
    • B65D75/32Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding one or both sheets or blanks being recessed to accommodate contents
    • B65D75/325Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding one or both sheets or blanks being recessed to accommodate contents one sheet being recessed, and the other being a flat not- rigid sheet, e.g. puncturable or peelable foil
    • B65D75/327Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding one or both sheets or blanks being recessed to accommodate contents one sheet being recessed, and the other being a flat not- rigid sheet, e.g. puncturable or peelable foil and forming several compartments
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D2585/00Containers, packaging elements or packages specially adapted for particular articles or materials
    • B65D2585/68Containers, packaging elements or packages specially adapted for particular articles or materials for machines, engines, or vehicles in assembled or dismantled form
    • B65D2585/86Containers, packaging elements or packages specially adapted for particular articles or materials for machines, engines, or vehicles in assembled or dismantled form for electrical components
    • B65D2585/88Batteries

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  • Chemical & Material Sciences (AREA)
  • Composite Materials (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Packages (AREA)
  • Respiratory Apparatuses And Protective Means (AREA)
  • Apparatus Associated With Microorganisms And Enzymes (AREA)
  • Laminated Bodies (AREA)
  • Hybrid Cells (AREA)
  • Battery Mounting, Suspending (AREA)

Abstract

The package (1), which is impermeable to air and water vapour and is intended, in particular, for zinc/air hearing aid batteries of the button cell type, is formed partially from a tear-resistant, preferably transparent film (2) of PVC or polyvinylidene chloride with cup-shaped elevations (3) for accommodating the button cells and partially from an aluminium closure foil (5) which is sealed flatly onto said film. To remove a button cell (4), the latter needs only to be pressed from the outside through the easily tearable aluminium foil. In the case of particularly reliable packages for despatch to areas with an extremely humid or dry climate, both the cup film and the closure foil can be based on a multi-layered plastic/metal composite material. <IMAGE>

Description

iin

DK 164588 BDK 164588 B

Opfindelsen angår et pakningselement til lagring af galvaniske 1 uftoxygenceller under lufttæt tillukning, indtil de skal tages i brug. Sådanne 1 uftoxygencel1 er er f.eks. anvendt i forbindelse med høreapparater.The present invention relates to a packing element for storing galvanic 1 uftoxygen cells during airtight closure until they are put into service. Such 1 uftoxygencel1 is e.g. used in conjunction with hearing aids.

55

Genopladelige Ni/Cd-knapcel1 er eller Ag20/Zn eller HgO/Zn knapceller leveres for det meste til brugeren i forholdsvis dyre pakninger, jf. US patentskrift nr. 3.414.161. Disse pakninger består af to runde plastskaller, af hvilke den ene har 10 et rundt hulrum til optagelse af en knapcelle. Skallerne er således sammenføjet, at den ene skal kan drejes i forhold til den anden. Knapcellerne afdækkes derved en efter en, hvorefter de vil kunne udtages ved oplukning af en lukkelaske.Rechargeable Ni / Cd button cells or Ag20 / Zn or HgO / Zn button cells are mostly supplied to the user in relatively expensive packages, cf. US Patent No. 3,414,161. These seals consist of two round plastic shells, one of which has a round cavity for receiving a button cell. The shells are joined together so that one shell can be rotated relative to the other. The button cells are thereby uncovered one by one, after which they can be removed by opening a closure bag.

15 Ved pakning af zink/1uftknapce11 er opstod der imidlertid et problem, idet lufttilgangsåbninger i katodebægeret skulle beskyttes mod indtrængning af luft fra omgivelserne. Ud over at ilt kan reagere med den negative elektrode og omsætte denne til inaktivt zinkoxid, vil en indtrængende kuldioxid også 20 kunne gøre den basiske elektrolyt uanvendelig som følge af carbonatdanneIser. Endvidere kan der trænge vand ind i cellen, hvis den relative fugtighed af omgivelsernes luft er højere end fugtigheden over elektrolytten, eller elektrolytten vil kunne udtørre, hvis den relative fugtighed af omgivelsernes 25 luft er mindre end fugtigheden over elektrolytten. Cellens kapacitet kan derved blive reduceret under lagring.15 However, when packing zinc / 1 air button 11, a problem arose, as air inlet openings in the cathode cup had to be protected from air penetration from the surroundings. In addition to oxygen being able to react with the negative electrode and convert it to inert zinc oxide, an ingress of carbon dioxide could also render the basic electrolyte unusable due to carbonate formation. Furthermore, water may enter the cell if the relative humidity of the ambient air is higher than the humidity above the electrolyte or the electrolyte may dry out if the relative humidity of the ambient air is less than the humidity above the electrolyte. The capacity of the cell can thereby be reduced during storage.

Fra US patentskrift nr. 4.015.708 kendes en batteri pakn i ng, der løser dette problem ved hjælp af et foldeetui. Etuiet har 30 et fladt indlæg af f.eks. stift karton med et antal runde udsparinger til optagelse af zink/1uft-cel1 er og en bagvæg i form af en polyesterfolie, idet cellerne vil kunne fastklæbes til folien ved hjælp af klæbemiddel. Polyesterfolien hindrer en indtrængning af oxygen, kultveilte og fugt via åbningerne i 35 bunden af det enkelte cellebæger. Hydrogen vil imidlertid kunne trænge ind i et sådant omfang, at der kan opstå et overtryk, hvorved polyesterfolien vil kunne adskilles fra bunden af cellebægeret.From U.S. Patent No. 4,015,708, a battery pack is known which solves this problem by means of a folding case. The case has a flat insert of e.g. rigid cardboard with a number of circular recesses for receiving zinc / 1uft cell 1 and a back wall in the form of a polyester film, the cells being able to be adhered to the film by adhesive. The polyester foil prevents the penetration of oxygen, carbon dioxide and moisture through the openings in the bottom of the individual cell cup. However, hydrogen will be able to penetrate to such an extent that an overpressure may occur whereby the polyester film can be separated from the bottom of the cell cup.

DK 164588 BDK 164588 B

22

Det er også kendt at klæbe etiketter på bunden af det enkelte cellebæger. Disse etiketter udgøres af en tolaget laminatpoly-esterfolie samt et lag trykt papir med kautschukklæbemiddel over hele fladen.It is also known to stick labels on the bottom of the individual cell cup. These labels consist of a two-layered laminate polyester film and a layer of printed paper with rubber shock adhesive all over the surface.

55

En sådan etikettering har imidlertid flere svage punkter. Ved knapceller, der har ligget på lager i 6-24 måneder, kan kaut-schukklæbemidlet være ændret, og vedhæftningen kan være reduceret. I klæbemidlet kan der derved dannes luftkanaler, hvil-10 ket kan forårsage udfald af celler. Klæbemiddel lagene kan også have fejlsteder i form af klæbefri linier og huller, der allerede fra begyndelsen muliggør en lufttilgang. Bægerbunde med urenheder, såsom fedtstoffer og olierester reducerer også ved-hæftningen af klæbemidlet. En yderligere ulempe ved det nævnte 15 klæbemiddel er desuden, at det kun ved et passende tryk giver en optimal vedhæftning. Endvidere behøver klæbemidlet en forholdsvis stor kontaktflade. Eventuelle prægninger på bægeret må derfor reduceres til et minimum for ikke at reducere kontaktf 1 aden.However, such labeling has several weaknesses. For button cells that have been in storage for 6-24 months, the cautious shock adhesive may have changed and the adhesion may have been reduced. Air ducts can thereby be formed in the adhesive, which can cause cell failure. The adhesive layers may also have defect points in the form of adhesive-free lines and holes, which from the outset enable an air supply. Cup bottoms with impurities such as fats and oil residues also reduce the adhesion of the adhesive. A further disadvantage of said adhesive is that it provides only an optimal adhesion at an appropriate pressure. Furthermore, the adhesive needs a relatively large contact surface. Therefore, any imprints on the cup must be reduced to a minimum so as not to reduce the contact surface.

2020

Fra tysk offentliggørelsesskrift nr. 2.335.123 kendes en "verbundfolie" til fremstilling af gennemtrykspakninger. Der er imidlertid kun anvendt en aluminiumsdækfolie på den ene side af gennemtrykspakningen.German publication specification No. 2,335,123 discloses a "compound foil" for the production of pressure seals. However, only one aluminum cover film is used on one side of the pressure seal.

2525

Formålet med opfindelsen er at anvise et pakningselement til 1 uftoxygencel1 er, især til anvendelse i høreapparater, og som er luft- og damptæt, og som ikke har de ovennævnte ulemper, og som desuden muliggør en fuldautomatisk pakning.The object of the invention is to provide a gasket element for 1 uftoxygen cell 1, especially for use in hearing aids, which are air and vapor tight and which do not have the disadvantages mentioned above, and which furthermore enable a fully automatic gasket.

3030

Et pakningselement af den indledningsvis nævnte art er ifølge opfindelsen ejendommeligt ved, at det består af en til cellens ydre mål i det væsentlige tilpasset skålformet beholder af et laminat bestående af en plastfolie og en metalfolie, der er 35 uigennemtrængeligt for luft og vanddamp, på hvilket laminat der er forseglet en lukkefolie af metal eller af forbundne plast- og metalfolier, der ligeledes er uigennemtrængelige for luft og vanddamp, og som kan afrives eller frigøres.According to the invention, a packing element of the kind mentioned in the invention is characterized in that it consists of a substantially adapted bowl-shaped container of a laminate consisting of a plastic film and a metal film impervious to air and water vapor, on which laminate which is sealed a metal sealing film or of associated plastic and metal foils which are also impermeable to air and water vapor and which can be peeled off or released.

DK 164588BDK 164588B

33

Pakningselementet er derved sammensat af to folier, af hvilke i hvert fald det ene gennem sin formgivning fungerer som beholder, og den anden lukker denne beholder. Ved en forsegling med varmekontakt, varmeimpulsti 1førsel, højfrekvens, ultralyd 5 eller friktionsvarme, bliver pakningselementets to folier forbundet indbyrdes, hvorved lukkefolien i regelen kommer til at ligge glat over den folie, der fungerer som beholder for cel-1 en.The packing element is thereby composed of two sheets, at least one of which, through its shaping, acts as a container and the other closes this container. In a sealing with heat contact, heat impulse path, high frequency, ultrasonic 5 or frictional heat, the two foils of the packing element are interconnected, whereby the closing foil will generally lie smoothly over the foil which serves as the container for the cell-1.

10 De anvendte folier skulle, ud fra materialevalg og tykkelse, være ubetinget uigennemtrængelige for luft og vanddamp.10 The films used should, based on material selection and thickness, be unconditionally impermeable to air and water vapor.

Selv om folierne med skålformede fordybninger består af et laminat af metal og plastmateriale, er den forseglede lukkefolie 15 fortrinsvis en metalfolie, fortrinsvis en aluminiumsfolie med et klæbelag.Although the foil-shaped foil films consist of a metal and plastic laminate, the sealed foil 15 is preferably a metal foil, preferably an aluminum foil with an adhesive layer.

Egnede plastmaterialer til den skålformede folie er f.eks. po-lyvinylchlorid (PVC), og polyvinyl idenchlorid (PVDC), af hvi 1 -20 ke sidstnævnte udmærker sig ved en god spærreevne over for vanddamp.Suitable plastics materials for the bowl-shaped foil are e.g. polyvinyl chloride (PVC) and polyvinyl idene chloride (PVDC), of which 1 -20 ke the latter are distinguished by a good water vapor barrier.

Formningen af disse folier, der i udgangstilstand har en tykkelse på 0,2-0,5 mm, sker ved varmdybtrækning.The molding of these foils, which in the initial state has a thickness of 0.2-0.5 mm, is done by hot dip.

25 I modsætning til den seje og brudfaste skålformede del, som har en vis stivhed, er den forseglede lukkefolie forholdsvis tynd og kan let afrives eller frigøres. En passende lukkefolie i form af en aluminiumsfolie har en tykkelse på ca. 0,02-0,03 30 mm.25 Unlike the tough and fracture-shaped bowl-shaped portion which has some stiffness, the sealed closure film is relatively thin and can be easily torn off or released. A suitable sealing foil in the form of an aluminum foil has a thickness of approx. 0.02-0.03 30 mm.

En celle i pakningselementet trykkes let ud gennem aluminiumsfolien, da denne let brydes.A cell in the gasket element is easily pushed out through the aluminum foil as it is easily broken.

35 Til forsendelse og lagring af 1 uftoxygenceller i klimazoner med ekstrem høj henholdsvis ekstrem lav luftfugtighed, kan beskyttelsesvirkningen af pakningselementet forbedres ved anven-For shipping and storing 1 uftoxygen cells in climate zones with extremely high and extremely low humidity, the protective effect of the packing element can be enhanced by the use of

DK 164588 BDK 164588 B

4 delse af forbundne plast- og metalfolier, såvel på beholdersiden som på afdækningssiden. En absolut damptæt skålformet del er f.eks. sammensat af fem lag, nemlig en piast-beskyttel-sesfolie, et første klæbelag, en aluminiumsfolie, et andet klæ-5 belag, samt en forseglelig plastfolie, og er gennem denne opbygning forholdsvis stiv. En fleksibel skålformet del kan f.eks. bestå af en forbindelse af en plastfolie, et klæbelag og en aluminiumsfolie, idet der til aluminiumsiden er tilføjet et varmforsegleligt lag, der kan forbindes med lukkefolien.4 for bonded plastic and metal foils, both on the container side and on the cover side. An absolutely vapor-proof bowl-shaped portion is e.g. composed of five layers, namely a piast protective film, a first adhesive layer, an aluminum foil, a second adhesive coating, and a sealable plastic film, and are relatively rigid throughout this structure. A flexible bowl-shaped part can e.g. consist of a connection of a plastic film, an adhesive layer and an aluminum foil, a heat-sealable layer which can be connected to the closure foil is added to the aluminum side.

1010

Lukkefolien kan dannes ved en tilsvarende forbindelse af lag.The closure foil can be formed by a corresponding layer of layers.

I dette tilfælde må der dog skæres i pakningen til udtagning af indholdet, da plastkomponenterne øger den mekaniske modstandsstyrke af lukkefolien, således at denne ikke længere er 15 let at bryde.In this case, however, the packing must be cut to remove the contents as the plastic components increase the mechanical resistance of the closure foil so that it is no longer easy to break.

I en yderligere udførelsesform bliver pakningselementet dannet af to på hinanden forseglede beholderfolier, hvis skålformede dele ligger over for hinanden til afgrænsning af en hermetisk 20 tæt kapsel.In a further embodiment, the packing element is formed by two sealed container foils, the bowl-shaped portions of which are opposite one another to define a hermetically sealed capsule.

Ved de skålformede forbundne plast- og aluminiumsfolier anvendes en passende strækretning.A suitable stretching direction is used for the bowl-shaped plastic and aluminum foils.

25 Den store fordel ved pakningselementet ifølge opfindelsen ligger i varmforseglingen, der er påklæbningen af etiketter stærkt overlegen i henseende til sikkerhed. Den på metal folierne påførte varmforseglingsklæber smelter ved en varmekontakt på 90eC eller derover. I hærdet tilstand ved stuetemperatur har 30 den en væsentlig højere klæbeevne end kontaktklæberen.The great advantage of the packaging element according to the invention lies in the heat seal, which is the adhesive of labels strongly superior for safety. The heat sealing adhesives applied to the metal foil melt at a heat contact of 90 ° C or more. When cured at room temperature, it has a substantially higher adhesive capacity than the contact adhesive.

Et eksempel på et pakningselement ifølge opfindelsen er vist på tegningen.An example of a packing element according to the invention is shown in the drawing.

35 Ved det på tegningen viste pakningselement i form af en fire-stykspakke 6 er to ens ved trækning formede laminater bestående af en plastfolie og en aluminiumsfolie 7 forseglet til hin-In the drawing element shown in the drawing, in the form of a four-piece package 6, two similarly drawn laminates consisting of a plastic film and an aluminum foil 7 are sealed to each other.

Claims (4)

1. Pakningselement til lagring af galvaniske luftoxygenceller under lufttæt tillukning, indtil de skal tages i brug, kendetegnet ved, at det består af en til cellens (4) ydre 10 mål i det væsentlige tilpasset skålformet beholder (7) af et laminat bestående af en plastfolie og en metalfolie, der er uigennemtrængelig for luft og vanddamp, på hvilket laminat der er forseglet en lukkefolie af metal eller af forbundne plast-og metalfolier, der ligeledes er uigennemtrængelige for luft 15 og vanddamp, og som kan afrives eller frigøres.Packing element for storing galvanic air oxygen cells during airtight closure until they are put into use, characterized in that it consists of a substantially 10-sized bowl-shaped container (7) of a laminate consisting of plastic foil and a metal foil impervious to air and water vapor, on which laminate is sealed a metal closure foil or of associated plastic and metal foils which are also impervious to air and water vapor and which can be peeled or released. 2. Pakningselement ifølge krav 1, kendetegnet ved, at den forseglede folie er en metalfolie (7), fortrinsvis en a 1 umi niumsfo 1 ie. 20Packing element according to claim 1, characterized in that the sealed foil is a metal foil (7), preferably an aluminum foil. 20 3. Pakningselement ifølge krav 1 eller 2, k e n d e t e g -net ved, at begge folierne (7) er skålformede.Packing element according to claim 1 or 2, characterized in that both foils (7) are cup-shaped. 4. Pakningselement ifølge krav 1-3, kendetegnet 25 ved, at plastmaterialet af beholderen (7) er polyvinylchlorid eller polyviny 1 idench1 or id. 30 35Packing element according to claims 1-3, characterized in that the plastic material of the container (7) is polyvinyl chloride or polyvinyl chloride or id. 30 35
DK416887A 1986-09-11 1987-08-11 Gasket element for storage of galvanic air oxygen cells. DK164588C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19863630926 DE3630926A1 (en) 1986-09-11 1986-09-11 PACKING ELEMENT FOR THE STORAGE OF GALVANIC OXYGEN ELEMENTS
DE3630926 1986-09-11

Publications (4)

Publication Number Publication Date
DK416887D0 DK416887D0 (en) 1987-08-11
DK416887A DK416887A (en) 1988-03-12
DK164588B true DK164588B (en) 1992-07-20
DK164588C DK164588C (en) 1992-12-07

Family

ID=6309361

Family Applications (1)

Application Number Title Priority Date Filing Date
DK416887A DK164588C (en) 1986-09-11 1987-08-11 Gasket element for storage of galvanic air oxygen cells.

Country Status (5)

Country Link
EP (1) EP0259574B1 (en)
JP (1) JPS6376259A (en)
AT (1) ATE62201T1 (en)
DE (2) DE3630926A1 (en)
DK (1) DK164588C (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE9011626U1 (en) * 1990-08-09 1990-10-31 Ende-Pichler, Gabriele von, 8019 Glonn Composites as packaging material
DE4128248A1 (en) * 1991-08-26 1993-03-04 Varta Batterie SALES AND STOCK PACK FOR ZINC / AIR CELLS
JP2585670Y2 (en) * 1993-04-08 1998-11-25 株式会社フジシール Battery packaging
DE4326268A1 (en) * 1993-08-05 1995-02-09 Hoefliger Verpackungsforsch Packaging device for tablets or the like
US7010137B1 (en) * 1997-03-12 2006-03-07 Sarnoff Corporation Hearing aid
EP1077375B1 (en) 1997-03-21 2012-06-20 Ngk Spark Plug Co., Ltd Method and apparatus for measuring NOx gas concentration
DE29712139U1 (en) * 1997-07-10 1997-09-18 Varta Batterie Ag, 30419 Hannover Sales packaging for button cells
US6252061B1 (en) 1998-03-23 2001-06-26 Reliable Biopharmaceutical, Inc. Process for the production of 2-halo-6-aminopurine derivatives
US7285334B1 (en) * 1999-04-08 2007-10-23 Dai Nippon Printing Co., Ltd. Material for packaging cell, bag for packaging cell, and its production method
JP4659181B2 (en) * 1999-07-30 2011-03-30 株式会社フジシールインターナショナル Button battery packaging
DE20120503U1 (en) 2001-12-19 2003-04-30 Varta Microbattery Gmbh Sales and stock pack for zinc / air cells
DE10345564A1 (en) * 2003-09-30 2005-04-28 Bullith Batteries Ag Packaging with electrochemical cell in gas-tight casing, includes sealing region extending predominantly into tray
DE102009025471A1 (en) 2009-06-12 2010-12-16 Varta Microbattery Gmbh Sales and storage pack for zinc / air button cells
EP3121132A1 (en) 2015-07-21 2017-01-25 Renata AG Blister pack for button battery
DE202019101861U1 (en) 2019-04-01 2019-04-09 Varta Microbattery Gmbh Sales and supply pack of blister card type for button cells
EP4116217A1 (en) * 2021-07-09 2023-01-11 VARTA Microbattery GmbH Packaging unit for at least two button cells and method

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2155047B2 (en) * 1971-11-05 1973-08-16 PACKAGING MADE OF HEAT SEALABLE PLASTIC FILM FOR BALL BEARINGS
GB1571119A (en) * 1976-11-19 1980-07-09 Gould Inc Packaging of cells
JPS60165044A (en) * 1984-02-07 1985-08-28 Seiko Instr & Electronics Ltd Blister pack packaging material for lithium battery

Also Published As

Publication number Publication date
DK416887A (en) 1988-03-12
JPS6376259A (en) 1988-04-06
EP0259574B1 (en) 1991-04-03
ATE62201T1 (en) 1991-04-15
EP0259574A2 (en) 1988-03-16
DK164588C (en) 1992-12-07
EP0259574A3 (en) 1989-04-19
DK416887D0 (en) 1987-08-11
DE3630926A1 (en) 1988-03-24
DE3769048D1 (en) 1991-05-08

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