DK151854B - APPLICATION OF A WATER-BINDING AGENT FOR THE CONSERVATION OF TREES AND PROCEDURES FOR TREAT TREATMENT - Google Patents

APPLICATION OF A WATER-BINDING AGENT FOR THE CONSERVATION OF TREES AND PROCEDURES FOR TREAT TREATMENT Download PDF

Info

Publication number
DK151854B
DK151854B DK472681A DK472681A DK151854B DK 151854 B DK151854 B DK 151854B DK 472681 A DK472681 A DK 472681A DK 472681 A DK472681 A DK 472681A DK 151854 B DK151854 B DK 151854B
Authority
DK
Denmark
Prior art keywords
wood
water
binding agent
solution
process according
Prior art date
Application number
DK472681A
Other languages
Danish (da)
Other versions
DK472681A (en
DK151854C (en
Inventor
Bernhard Hantschke
Wilfried Hoselmann
Original Assignee
Basf Lacke & Farben
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Lacke & Farben filed Critical Basf Lacke & Farben
Publication of DK472681A publication Critical patent/DK472681A/en
Publication of DK151854B publication Critical patent/DK151854B/en
Application granted granted Critical
Publication of DK151854C publication Critical patent/DK151854C/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/12Impregnating by coating the surface of the wood with an impregnating paste
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34Organic impregnating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34Organic impregnating agents
    • B27K3/36Aliphatic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34Organic impregnating agents
    • B27K3/50Mixtures of different organic impregnating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/08Impregnating by pressure, e.g. vacuum impregnation
    • B27K3/083Impregnating by pressure, e.g. vacuum impregnation along the fibers, i.e. longitudinal impregnation

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Water Treatment By Sorption (AREA)
  • Fertilizers (AREA)

Abstract

1. Process for treating wood, in which a water-absorbing agent in a liquid or pasty form is introduced into a recess or cavity made in the wood, characterised in that a solution of an orthocarboxylic acid ester in an organic solvent is introduced into the cavity and the latter is then tightly sealed.

Description

DK 151854BDK 151854B

Opfindelsen angår anvendelse af et vandbindende middel til konservering af træ.The invention relates to the use of a water-binding agent for preserving wood.

Det er ofte ønskeligt at formindske vandindholdet i træ, hvad enten dette foreligger som bygningsdele el-5 ler i anden tildannet form, eller som kun delvis forarbejdet tømmer.It is often desirable to reduce the water content of wood, whether as building parts or in other molded form, or as only partially processed timber.

Formålet med en sådan nedbringelse af fugtigheds-indholdet kan være at bringe fugtighedsindholdet ned på så lave værdier, at træet er mindre udsat for angreb af 10 ødelæggende mikroorganismer, og/eller at gøre træet egnet til at modtage en beskyttende imprægnering eller overfladebehandling.The purpose of such a reduction in the moisture content may be to bring the moisture content down to such low values that the tree is less susceptible to attack by 10 destructive microorganisms, and / or to render the tree suitable for receiving a protective impregnation or surface treatment.

Der har været foreslået forskellige metoder til at nedbringe træs vandindhold.Various methods have been proposed to reduce the water content of wood.

15 Således kendes fra DE-AS 2812697 en fremgangsmåde til træbehandling, ved hvilken et vandskyende middel i forbindelse med et vandfortrængende middel anbringes i hulrum i træet,, hvorefter disse hulrum lukkes tæt.Thus, from DE-AS 2812697 a method of wood treatment is known, in which a water repellent in connection with a water displacer is placed in cavities in the wood, after which these cavities are closed tightly.

Denne kendte fremgangsmåde har imidlertid den 20 ulempe, at diffusionen af vand i træet og dermed vandets fortrængning sker meget langsomt, og ved træ, der er forsynet med en belægning, f.eks. i form af en lakering eller plastbelægning, er vandets udtræden fra træet kraftigt hæmmet og under visse omstændigheder helt udeluk-25 ket.However, this known method has the disadvantage that the diffusion of water into the wood and thus the displacement of the water takes place very slowly, and in wood that is provided with a coating, e.g. in the form of a lacquer or plastic coating, the water's exit from the tree is severely hampered and, in certain circumstances, completely excluded.

I tysk patent nr.885.177 foreslås det, før imprægnering af bygningsdele med kemiske giftstoffer, at nedbringe bygningsdelenes fugtighed ved opvarmning eller ved anvendelse af adsorberende stoffer, som bringes i 30 kontakt med bygningsdelenes overflade eller ved hjælp af borehuller indføres i det indre af disse. En tilsvarende metode kan anvendes til at nedbringe fugtighedsind-holdet efter tilførslen af det vandopløselige giftstof med henblik på at fjerne opløsningsmidlet fra dette.German Patent No. 885177 proposes, before impregnating building components with chemical toxins, to reduce the moisture of the building parts by heating or by using adsorbents which are brought into contact with the surface of the building parts or by means of boreholes introduced into the interior thereof. A similar method can be used to reduce the moisture content after the application of the water-soluble toxin to remove the solvent from it.

35 Patentskriftet oplyser ikke, hvilke stoffer man har tænkt at anvende som "adsorberende" stof.35 The patent does not specify which substances are intended to be used as "adsorbent" substances.

Fra tysk patentskrift nr. 29 324 er det kendt at tørre træ ved at bringe det i kontakt med fugtsugende 2From German Patent Specification No. 29,324, it is known to dry wood by contacting it with a vacuum cleaner 2

DK 151854BDK 151854B

materialer såsom kogesalt (natriumchlorid), calciumchlo-rid eller blandinger af disse materialer.materials such as boiling salt (sodium chloride), calcium chloride or mixtures of these materials.

Anvendelse af sådanne uorganiske salte til det pågældende formål medfører imidlertid visse ulemper, da 5 en vis del af saltene vil optages i træet og sammen med den resterende vandmængde i dette eller sammen med vand, som senere måtte blive opsuget af træet, danner en elektrolyt. Dette medfører dels, at træets evne til at fastholde en lak- eller malingfilm forringes, idet tendensen 10 til blæredannelse øges, dels at metaldele såsom søm, skruer, beslag og zinkplader, som kommer i kontakt med det behandlede træ, udsættes for en kraftigere korrosion end tilfældet ville være, hvis de pågældende salte ikke var til stede.However, the use of such inorganic salts for that purpose causes certain disadvantages, since a certain part of the salts will be absorbed into the wood and together with the remaining amount of water therein, or together with water which may later be absorbed by the wood, form an electrolyte. This causes, in part, the ability of the wood to retain a varnish or paint film, as the tendency for blistering increases, and secondly, metal parts such as nails, screws, fittings and zinc sheets that come into contact with the treated wood are subjected to more severe corrosion. than would be the case if the salts in question were not present.

15 Det har nu vist sig, at de ovennævnte ulemper und gås ved, ifølge opfindelsen, at anvende en orthocarboxyl-syreester til formindskelse af træfugtighedsindholdet.It has now been found that the above disadvantages are avoided by using, according to the invention, an orthocarboxylic acid ester to reduce the moisture content of wood.

Særligt gode resultater er opnået ved at anvende triethylorthoformiat til formindskelse af træfugtigheds-20 indholdet.Particularly good results have been obtained by using triethyl orthoformate to reduce the wood moisture content.

TLI overflødiggørelse af efterfølgende imprægnering af træværket med træbeskyttelsesmidler er det hensigtsmæssigt, at det vandbindende middel anvendes i kombination med trækonserverende fungicider, baktericider og/eller 25 insekticider.TLI redundancy of subsequent impregnation of the woodwork with wood preservatives, it is convenient that the water-binding agent be used in combination with wood preservative fungicides, bactericides and / or insecticides.

Ved sanering af ældre bygninger foreligger ofte det problem, at vinduesrammer i deres nederste trediedel har forhøjet fugtighedsindhold, hvilket i samvirke med mikroorganismer med tiden fører til en fuldstændig øde-30 læggelse af træet.When renovating older buildings, there is often the problem that window frames in their lower thirds have increased moisture content, which, in conjunction with microorganisms over time, leads to complete destruction of the tree.

Der er behov for en fremgangsmåde, der i sådanne tilfælde muliggør en hurtig nedsættelse af træets fugtigheds indhold, også i de tilfælde, hvor træet et malet eller lakeret.There is a need for a method which in such cases allows a rapid reduction in the moisture content of the wood, even in cases where the wood is painted or varnished.

i 35 Dette behov opfyldes af en fremgangsmåde, ved hvilken et vandbindende middel i flydende eller pastaagtig form på i sig selv kendt måde anbringes i udsparinger eller hulrum i træet, hvorefter disse hulrum luk- 3This need is met by a method in which a liquid or paste-like agent, in a manner known per se, is placed in recesses or cavities in the wood, after which these cavities are closed.

DK 151854 BDK 151854 B

kes tæt, idet fremgangsmåden ifølge opfindelsen er ejendommelig ved, at der som vandbindende middel anbringes en opløsning af en orthocarboxylsyreester i et organisk opløsningsmiddel i hulrummene.The process according to the invention is characterized in that, as a water-binding agent, a solution of an orthocarboxylic acid ester in an organic solvent is placed in the cavities.

5 Egnede orthocarboxylsyreestere er f.eks. trime- thylorthoformiat, trimethylorthoeddikesyreester, tri-ethylorthoeddikesyreester og tilsvarende estere af ortho-propionsyre. Særlig foretrukken er dog en opløsning af triethylorthoformiat, der fordelagtigt har en koncentra-10 tion på 10 til 40 vægts.Suitable orthocarboxylic acid esters are e.g. trimethyl orthoformate, trimethyl ortho acetic ester, tri ethyl ortho acetic ester and corresponding esters of ortho-propionic acid. Particularly preferred, however, is a solution of triethyl orthoformate which advantageously has a concentration of 10 to 40 wt.

En særlig god konservering af træ opnås ved, at opløsningen udover det vandbindende middel indeholder fungicider, baktericider og/eller insekticider. Opløsningen kan f.eks. indeholde tributyltinoxid i en 15 koncentration fra 1 til 10 vægt% og/eller N-dimethyl-N'-phenyl-N'-(fluordichlormethyl)-thiosulfamid i en koncentration fra 0,5 til 40 vægt%.A particularly good preservation of wood is achieved by the fact that in addition to the water-binding agent the solution contains fungicides, bactericides and / or insecticides. The solution may e.g. contain tributyltin oxide at a concentration of 1 to 10% by weight and / or N-dimethyl-N'-phenyl-N '- (fluorodichloromethyl) thiosulfamide at a concentration of 0.5 to 40% by weight.

Til forbedring af den konserverende virkning kan opløsningen indeholde en naturlig eller syntetisk 20 voksart i en koncentration fra 2 til 20 vægt%. Denne voks forhindrer den yderligere indtrængen af fugtighed i træet og understøtter således det vandbindende middels virkning. Egnet er f.eks. en polyethylenvoks med en gennemsnitlig molekylvægt på ca. 2000. Der kan også an-25 vendes parafiner med et smeltepunktområde omkring ca.To enhance the preservative effect, the solution may contain a natural or synthetic wax species at a concentration of 2 to 20% by weight. This wax prevents the further penetration of moisture into the wood and thus supports the action of the water-binding agent. Suitable for example. a polyethylene wax having an average molecular weight of approx. 2000. Paraffins with a melting point range of about ca.

70°C.70 ° C.

Fremgangsmåden ifølge opfindelsen gennemføres med fordel på den måde, at konserveringsmidlet anbringes i borehuller, der er rettet skråt nedad, hvorefter 30 disse borehuller lukkes med en træfyldmasse. Borehullerne lukkes med fordel med en træfyldmasse, der hærdes med et hærdningsmiddel. Sådanne masser er kendte som "tokomponent træfyldmasser". Efter lukningen af borehullet og hærdning af lukkemassen kan det behandlede sted 35 males, således at konserveringsforanstaltningerne ikke efterlader synlige spor.Advantageously, the method according to the invention is carried out in that the preservative is placed in downwardly directed boreholes, after which these bores are closed with a wood filler. The boreholes are advantageously closed with a wood filler which is cured with a curing agent. Such masses are known as "two-component wood fillers". After closure of the borehole and curing of the closure, the treated site 35 can be painted so that the preservation measures leave no visible traces.

DK 151854 BDK 151854 B

44

Anvendelsen af orthocarboxylsyreestere ifølge op- IThe use of orthocarboxylic acid esters according to op

findelsen til formindskelse af fugtighedsindholdet i træ Ithe finding for reducing the moisture content of wood I

er ikke begrænset til den ovenfor beskrevne fremgangsmå- !is not limited to the method described above!

de, ved hvilken en opløsning af en orthocarboxylsyreester 5 indføres i udsparinger eller hulrum i træet. Den ønskede fugtighedsfjernelse kan også opnås ved påføring af or-thocarboxylsyreesteren i flydende eller pastaagtig form Ithose by which a solution of an orthocarboxylic acid ester 5 is introduced into recesses or cavities in the tree. The desired moisture removal can also be achieved by applying the orthocarboxylic acid ester in liquid or paste form I

på træoverfladen, hvis denne er udækket.on the tree surface if uncovered.

Det har vist sig, at der med den omhandlede 10 fremgangsmåde opnås en hurtig og tydelig sænkning af træfugtighedsindholdet. Overraskende fandtes det, at det behandlede træ yderligere bliver fastere. I det følgende belyses opfindelsen nærmere under henvisning til udførelseseksempler.It has been found that the process of the present invention achieves a rapid and clear reduction in the moisture content of the wood. Surprisingly, it was found that the treated wood becomes even firmer. In the following, the invention will be further elucidated with reference to exemplary embodiments.

1515

Eksempel 1Example 1

Fugtighedsindholdet i en vinduesramme, der var forsynet med en påstrygningslag bestemtes ved hjælp af 20 et træfugtighedsmåleapparat, hvis måling beror på bestemmelse af den elektriske ledningsevne. Det udgjorde i rammens nederste trediedel ca. 30%. I rammen boredes i en vinkel på 30° med et 8 mm bor ca. 4 cm dybe nedadrettede åbninger. Åbningerne fyldtes ca. 2/3 med 25 en konserveringsopløsning med den i det følgende angivne sammensætning og lukkedes med en træfyldmasse.The moisture content of a window frame provided with an ironing layer was determined by means of a wood moisture meter, the measurement of which depends on the determination of the electrical conductivity. In the lower third of the frame, this amounted to approx. 30%. The frame was drilled at an angle of 30 ° with an 8 mm bore approx. 4 cm deep downwards openings. The openings were filled approx. 2/3 with 25 a preservative solution of the composition given below and closed with a wood filler.

Efter 2 uger bestemtes fugtighedsindholdet påny.After 2 weeks, the moisture content was again determined.

Det var sunket til en værdi på ca. 20%. Ved dette fugtig-hedsindhold er f.eks. skimmelvækst udelukket. Derudover 30 kunne det fastslås, at det behandlede træ var blevet tydeligt fastere, hvilket viste sig ved, at der til ind-trykning af en hård genstand i træet krævedes en større kraft end før.It had sunk to a value of approx. 20%. At this moisture content, e.g. mold growth excluded. In addition, it could be determined that the treated wood had become significantly firmer, as evidenced by the fact that a greater force was required to press a hard object into the tree.

35 535 5

DK 151854BDK 151854B

Konserveringsopløsningens sammensætning: 20 dele triethylorthoformiat 5 dele tributyltinoxid 10 dele polyethylenvoks 5 2 dele N-dimethyl-N1 -phenyl-N1 - (f.luordichlor- methyl)-thiosulfamid 63 dele tetralin.Composition of the preservative solution: 20 parts triethyl orthoformate 5 parts tributyltin oxide 10 parts polyethylene wax 5 2 parts N-dimethyl-N1-phenyl-N1 - (fluorodichloromethyl) -thiosulfamide 63 parts tetralin.

Eksempel 2Example 2

Konserveringsopløsningens sammensætning: 30 dele triethylorthoformiat 8 dele tributyltinoxid 3 dele N-dimethyl-N'-phenyl-N1-(fluordichlor-methyl)-thiosulfamid - 59 dele dekalinComposition of the preservative solution: 30 parts triethyl orthoformate 8 parts tributyltin oxide 3 parts N-dimethyl-N'-phenyl-N1- (fluorodichloromethyl) thiosulfamide - 59 parts decalin

Eksempel 3Example 3

Konserveringsopløsningens sammensætning: 2o 25 dele triethylorthoformiat 3 dele tributyltinoxid 2 dele N-dimethyl-N'-phenyl-N1-(fluordimethyl)-thiosulfamid 10 dele paraffinvoks (smelteområde 70°C) 25 60 dele tetralinComposition of the preservative solution: 2o 25 parts triethyl orthoformate 3 parts tributyltin oxide 2 parts N-dimethyl-N'-phenyl-N1- (fluorodimethyl) -thiosulfamide 10 parts paraffin wax (melting range 70 ° C) 25 60 parts tetralin

Med konserveringsopløsningerne fra eksempel 2 og 3 gennemførtes fremgangsmåden ifølge opfindelsen på samme måde som i eksempel 1. Træets fugtighedsindhold sank ligeledes fra 30 til 20%.With the preservative solutions of Examples 2 and 3, the process of the invention was carried out in the same manner as in Example 1. The moisture content of the wood also dropped from 30 to 20%.

Claims (11)

1. Anvendelse af et vandbindende middel til konservering af træ, kendetegnet ved, at en or-thocarboxylsyreester anvendes til formindskelse af træ- 5 fugtighedsindholdet.Use of a water binding agent for wood preservation, characterized in that an orthocarboxylic acid ester is used to reduce the moisture content of wood. 2. Anvendelse ifølge krav 1, kendetegnet ved, at der anvendes triethylorthoformiat til formindskelse af træfugtighedsindholdet.Use according to claim 1, characterized in that triethyl orthoformate is used to reduce the wood moisture content. 3. Anvendelse ifølge krav 1 eller 2, kende- 10tegnet ved, at det vandbindende middel anvendes i kombination med trækonserverende fungicider, bakterici-der og/eller insekticider.Use according to claim 1 or 2, characterized in that the water-binding agent is used in combination with wood preservative fungicides, bacteria and / or insecticides. 4. Fremgangsmåde til træbehandling, ved hvilken et vandbindende middel i flydende eller pastaagtig form 15 anbringes i udsparinger eller hulrum i træet, hvorefter disse hulrum lukkes tæt, kendetegnet ved, at i der som vandbindende middel anbringes en opløsning af en orthocarboxylsyreester i et organisk opløsningsmiddel i hulrummene.Method of wood treatment, in which a liquid or paste-like water-binding agent 15 is placed in recesses or cavities in the wood, after which these cavities are closed tightly, characterized in that a solution of an orthocarboxylic acid ester in an organic solvent is applied as a water-binding agent. in the cavities. 5. Fremgangsmåde ifølge krav 4, kendeteg net ved, at der anvendes en opløsning af triethylorthoformiat.Process according to claim 4, characterized in that a solution of triethyl orthoformate is used. 6. Fremgangsmåde ifølge krav 4 eller 5, kendetegnet ved, at opløsningen har et indhold af 25 vandbindende middel på 10 til 40 vægt%.Process according to claim 4 or 5, characterized in that the solution has a water-binding agent content of 10 to 40% by weight. 7. Fremgangsmåde ifølge krav 4 til 6, k e n -detegnet ved, at opløsningen udover det vandbindende middel indeholder fungicider, baktericider og/eller insekticider.Process according to claims 4 to 6, characterized in that the solution contains, in addition to the water-binding agent, fungicides, bactericides and / or insecticides. 8. Fremgangsmåde ifølge krav 1, kendeteg net ved, at opløsningen yderligere indeholder tribu-tyltinoxid i en koncentration fra 1 til 10 vægt% og/eller N-dimethyl-N'phenyl-N'(fluordichlormethyl)-thio-sulfamid i en koncentration fra 0,5 til 4,0 vægt%.Process according to claim 1, characterized in that the solution further contains tributyltin oxide at a concentration of 1 to 10% by weight and / or N-dimethyl-N'phenyl-N '(fluorodichloromethyl) -thiosulfamide at a concentration. from 0.5 to 4.0% by weight. 9. Fremgangsmåde ifølge krav 4 til 8, kende tegnet ved, at opløsningen yderligere indeholder en naturlig eller syntetisk voksart i en koncentration fra 2 til 20 vægt%. DK 151854BProcess according to claims 4 to 8, characterized in that the solution further contains a natural or synthetic wax species at a concentration of 2 to 20% by weight. DK 151854B 10. Fremgangsmåde ifølge krav 4 til 9, kendetegnet ved, at det vandbindende middel anbringes i skråt nedadrettede borehuller, og at disse borehuller derefter lukkes med træfyldningsmasse.Method according to claims 4 to 9, characterized in that the water-binding agent is placed in inclined downward boreholes and then these boreholes are closed with wood filling material. 11. Fremgangsmåde ifølge krav 10, kende te g n e t ved, at borehullerne lukkes med en. hærdende træfyldmasse med hærdningsmiddel.11. A method according to claim 10, characterized in that the boreholes are closed by one. curing wood filler with curing agent.
DK472681A 1980-10-29 1981-10-27 APPLICATION OF A WATER-BINDING AGENT FOR THE CONSERVATION OF TREES AND PROCEDURES FOR TREAT TREATMENT DK151854C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3040623 1980-10-29
DE3040623A DE3040623C2 (en) 1980-10-29 1980-10-29 Method for treating wood and using a water-binding agent

Publications (3)

Publication Number Publication Date
DK472681A DK472681A (en) 1982-04-30
DK151854B true DK151854B (en) 1988-01-11
DK151854C DK151854C (en) 1988-06-06

Family

ID=6115383

Family Applications (1)

Application Number Title Priority Date Filing Date
DK472681A DK151854C (en) 1980-10-29 1981-10-27 APPLICATION OF A WATER-BINDING AGENT FOR THE CONSERVATION OF TREES AND PROCEDURES FOR TREAT TREATMENT

Country Status (5)

Country Link
EP (1) EP0050839B1 (en)
AT (1) ATE7210T1 (en)
DE (2) DE3040623C2 (en)
DK (1) DK151854C (en)
ES (1) ES8300038A1 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE8201542L (en) * 1982-03-11 1983-09-12 Kenogard Ab PROTECTION OF WOODWOOD IN MOUNTED WINDOWS AND SIMILAR
NL8301694A (en) * 1983-05-11 1984-12-03 Woudsma Jacob METHOD FOR TREATING WOOD AND PREPARATION FOR TREATING WOOD
US4719133A (en) * 1985-08-05 1988-01-12 Jacob Woudsma Process for treating wood as well as product for treating wood
GB2271579B (en) * 1992-10-07 1996-04-03 Rekara Mills Treatment of wood

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE29324C (en) * J. A. KOCH in Galvestone (Texas) und W. HERRE in Firma W. HERRE & Co. in Berlin und Potsdam Drying wood using dehydrating substances
DE885177C (en) * 1951-07-20 1953-08-03 Theodor Keller Process for removing sponges and for removing other plant or animal parasites in buildings using physical and chemical agents
NL176533C (en) * 1977-03-29 1985-05-01 Woodcap Bv METHOD FOR TREATING WOOD.

Also Published As

Publication number Publication date
DE3040623A1 (en) 1982-05-06
EP0050839B1 (en) 1984-04-25
EP0050839A1 (en) 1982-05-05
ATE7210T1 (en) 1984-05-15
DK472681A (en) 1982-04-30
DE3163314D1 (en) 1984-05-30
ES506694A0 (en) 1982-10-01
ES8300038A1 (en) 1982-10-01
DK151854C (en) 1988-06-06
DE3040623C2 (en) 1982-12-09

Similar Documents

Publication Publication Date Title
AU638873B2 (en) Wood preservative based on polymeric nitrogen compounds and metal-fixing acids
US5104664A (en) Methods and compositions for retarding and eradicating infestation in trees and tree derived products
US20030118810A1 (en) Method and composition for treating substrates
WO2003037532A1 (en) Method and composition for treating wood
JPH074805B2 (en) How to protect wood
CA2103470A1 (en) Remedial wood preservative
PT2042282E (en) Method for manufacturing of furan polymer impregnated wood
WO1992022405A1 (en) One step process for imparting decay resistance and fire retardancy to wood products
EP0576608B1 (en) Method of quality improvement of wooden articles, such as improved preservation of the wood through impregnation thereof
DK151854B (en) APPLICATION OF A WATER-BINDING AGENT FOR THE CONSERVATION OF TREES AND PROCEDURES FOR TREAT TREATMENT
DK157594B (en) LIQUID FUNGICID AND INSECTICID SUBSTANCES CONTAINING ETHYLENGYLYCOL AS A SUBSTANCE AND A STANDING ACTIVE INGREDIENT FOR APPLICATION OF A POROEST SUBSTANCE EXCEPT AS A PROCEDURE TO BE TAKEN FOR
EP1796852A1 (en) Penetration improvement of copper amine solutions into dried wood by addition of carbon dioxide
BR112020018141A2 (en) TREATMENT OF WOOD MATERIALS
NO153124B (en) PROCEDURE FOR AA PROTECTED WOODWOOD AGAINST MUG AND MIXING WITH UNITED ALIFATIC CARBOXYL ACIDS
US2012976A (en) Composition for impregnating wood
EP2841212A1 (en) Methods for resisting discoloration of wood
US4889771A (en) Method of preserving wood with lanthanide derivatives
US2344019A (en) Composition and method for preserving wood
US3511691A (en) Method for chemically stabilizing and protecting elongate wood strips
Hwang et al. Surface treatment for preventing decay and termite attack in wood using didecyl dimethyl ammonium tetrafluoroborate (DBF) incorporated with acryl-silicon type resin
Da Costa et al. Laboratory evaluation of chromated metallic preservatives against soft rot fungi in beech
US1054756A (en) Process of preserving wood and products thereof.
US3369964A (en) Preservation of wood
US5009937A (en) Sapstain control composition and method
EP0283100B1 (en) A wood preservative and a method of preserving wood

Legal Events

Date Code Title Description
PUP Patent expired