DK148956B - WOOD PROTECTIVE EQUIPMENT AND PROCEDURE TO USE THEREOF - Google Patents

WOOD PROTECTIVE EQUIPMENT AND PROCEDURE TO USE THEREOF Download PDF

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Publication number
DK148956B
DK148956B DK478578AA DK478578A DK148956B DK 148956 B DK148956 B DK 148956B DK 478578A A DK478578A A DK 478578AA DK 478578 A DK478578 A DK 478578A DK 148956 B DK148956 B DK 148956B
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Prior art keywords
wood
protection
bracket
hole
molten
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DK478578AA
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Danish (da)
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DK478578A (en
DK148956C (en
Inventor
Carl Christian Bechgaard
Joseph Dulat
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Wood Slimp Gmbh
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    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01BPERMANENT WAY; PERMANENT-WAY TOOLS; MACHINES FOR MAKING RAILWAYS OF ALL KINDS
    • E01B31/00Working rails, sleepers, baseplates, or the like, in or on the line; Machines, tools, or auxiliary devices specially designed therefor
    • E01B31/20Working or treating non-metal sleepers in or on the line, e.g. marking, creosoting
    • E01B31/26Inserting or removing inserts or fillings for holes in sleepers, e.g. plugs, sleeves
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01BPERMANENT WAY; PERMANENT-WAY TOOLS; MACHINES FOR MAKING RAILWAYS OF ALL KINDS
    • E01B3/00Transverse or longitudinal sleepers; Other means resting directly on the ballastway for supporting rails
    • E01B3/02Transverse or longitudinal sleepers; Other means resting directly on the ballastway for supporting rails made from wood
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/16Inorganic impregnating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/16Inorganic impregnating agents
    • B27K3/163Compounds of boron

Description

148956148956

Denne opfindelse angår et træbeskyttelsesmiddel, der er udformet som et legeme, der er fast ved brugstemperaturen og formet til at passe til et borehul i træ. Soln eksempel på anvendelsen af denne opfindelse kan nævnes beskyttelse af jernbanesveller, trædøre og vinduesrammer, træbroer og træbåde. Opfindelsen angår også en fremgangsmåde til beskyttelse af en jernbanesvelle med skinnebeslag ved hjælp af et træbeskyttelsesmiddel ifølge opfindelsen.This invention relates to a wood preservative designed as a body which is fixed at the operating temperature and shaped to fit a wood borehole. One example of the application of this invention is the protection of railway sleepers, wooden doors and window frames, wooden bridges and wooden boats. The invention also relates to a method for protecting a rail sleep with rail fittings by means of a wood preservative according to the invention.

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Det er normal praksis at beskytte strukturtræ ved imprægnering med en træbeskyttelse såsom metalsalte eller kreosot, men denne metode bliver med tiden ineffektiv. Mangelfuld beskyttelse bliver først synlig i dele af strukturen, hvor fugt, regn eller kondens med størst sandsynlighed samles.It is normal practice to protect structural wood by impregnating with a wood protection such as metal salts or creosote, but this method becomes ineffective over time. Defective protection only becomes visible in parts of the structure where moisture, rain or condensation is most likely to accumulate.

F.eks. starter råddannelsen i jernbanesveller, efter at disse har været nedlagt i nogle år under beslagene, som bærer jernbanesporene.Eg. starts the formation of rail sleepers after they have been closed down for a few years under the brackets which carry the railroad tracks.

Afsvampningsmidler såsom natriumfluorid og natriumborat har også været brugt som træbeskyttelsesmiddel, f.eks. ved indførelse af et pulver i huller boret i træet.Antifungal agents such as sodium fluoride and sodium borate have also been used as wood preservatives, e.g. by introducing a powder into holes drilled in the tree.

Fra beskrivelsen til dansk patent nr. 50.778 og engelsk patent nr. 912.381 kendes træbeskyttelseslegemer, som er fremstillet ved presning, og som kan indføres i et hulrum i et træemne.From the specification of Danish Patent No. 50,778 and English Patent No. 912,381 are known wood protection bodies which are manufactured by pressing and which can be inserted into a cavity in a wood blank.

Sådanne fremstillede legemer lider imidlertid af visse mangler, især er koncentrationen af det aktive materiale i legemet ikke maksimalt, idet komprimeringen af materialet har visse praktiske grænser. Endvidere optager eventuelle bindemidler plads, hvorfor koncentrationen af det aktive materiale reduceres tilsvarende.However, such manufactured bodies suffer from certain deficiencies, in particular the concentration of the active material in the body is not maximal, since the compression of the material has certain practical limits. Furthermore, any binders take up space, and therefore the concentration of the active material is reduced accordingly.

Sådanne fremstillede legemer kan derfor ikke altid anvendes, uden at det giver problemer, når der skal laves huller i konstruktionsdele, såsom bærende konstruktioner, hvor der kun må ske en meget begrænset nedsættelse af styrken i trædelene. For eksempel ved jernbanesveller, hvor rådangrebet sker inde under skinnebeslaget, netop der, hvor belastningen er størst.Therefore, such manufactured bodies cannot always be used without causing problems when making holes in structural parts, such as supporting structures, where there is only a very limited reduction in the strength of the wooden parts. For example, at railway sleepers, where the raid attack occurs under the rail bracket, precisely where the load is greatest.

Endvidere er de komprimerede emner tilbøjelige til at krumme 148956 3 før indsætningen i huller, hvorfor der må laves huller i overstørrelse, for at de kan indføres.Furthermore, the compressed blanks are prone to curvature before insertion into holes, which is why oversized holes must be made for insertion.

Endelig er der en tendens til, at emnerne falder ud, da de ikke har nogen særlig formstabilitet, ligesom der kan fremkomme uensartetheder i fordelingen af de aktive stoffer i emnerne.Finally, there is a tendency for the blanks to fall out as they have no particular shape stability, as well as differences in the distribution of the active substances in the blanks.

Pra beskrivelsen til US patent nr. 4.042.402 kendes endvidere brugen af knust boroxid som svampe- og insektdræbende middel i malinger. Her udnyttes boroxidet som et additiv til overfladebeskyttende maling for træemner, i en ikke særlig koncentreret form.Further, from the disclosure of U.S. Patent No. 4,042,402, the use of crushed boron oxide as a fungicide and insecticide in paints is known. Here, the boron oxide is used as an additive for surface protection paints for woodpieces, in a not very concentrated form.

I modsætning hertil angår ansøgningen et træbeskyttelsesmiddel, der er udformet som et legeme, der er fast ved brugstemperaturen og formet til at passe i et borehul i træ, hvilket træbeskyttelsesmiddel er ejendommeligt ved, at legemet består af boroxid, som er smeltet og udstøbt i den ønskede form, og som kan indeholde mindre mængder af et materiale, der regulerer opløsningshastigheden.In contrast, the application relates to a wood preservative formed as a body which is fixed at the operating temperature and shaped to fit in a wood bore, which wood property is peculiar in that the body consists of boron oxide, which is melted and cast into it. desired form, and which may contain smaller amounts of a material which controls the rate of dissolution.

Sådanne stænger eller propper vil indeholde det maksimale kvantum aktivt stof, og endvidere vil de være helt homogene.Such rods or plugs will contain the maximum amount of active substance, and furthermore they will be completely homogeneous.

Den høje koncentration af aktive stoffer betyder, at man ikke behøver at udbore i overstørrelse, hvorfor den størst mulige styrke bevares i træemnet. Der kan på denne måde indføres det størst mulige kvantum aktivt stof pr. hul.The high concentration of active substances means that there is no need to drill in excess size, which is why the greatest possible strength is retained in the woodpile. In this way, the largest possible amount of active ingredient per day can be introduced. hole.

Hertil kommer en god formstabilitet, som gør det muligt at inddrive emner i en stram pasning, og da der ved fugtoptagelse vil ske en kvælning af emnets overflade, vil det blive presset ind mod hullets sider og derved forankres i hullet.In addition, a good shape stability which allows objects to be recovered in a tight fit, and as moisture will suffocate the surface of the workpiece, it will be pressed into the sides of the hole and thereby anchored in the hole.

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Det har vist sig, at skønt en sammenpresset, men usmeltet stav af boroxid opløses ret hurtigt i fugt i træ, der er udsat for vejr og vind, så opløses en smeltet stav langsommere og giver således en beskyttelse i længere tid.It has been found that although a compressed but unmelted rod of boron oxide dissolves rather quickly in moisture in wood exposed to weather and wind, a molten rod dissolves more slowly and thus provides protection for a longer time.

De andre materialer, som kan indeholdes i træbeskyttelsesmidlet ifølge opfindelsen, vil normalt bestå af mindre dele metaloxider, som virker på den ene eller begge af de følgende måder: (i) Styring af opløsningshastigheden i vand.The other materials which may be contained in the wood preservative of the invention will usually consist of minor portions of metal oxides acting in one or both of the following ways: (i) Controlling the rate of dissolution in water.

(ii) Forøgelse af den beskyttende effekt af borsyre.(ii) Increasing the protective effect of boric acid.

Typiske eksempler på (i) er alkali metaloxider (som forøger opløsningshastigheden) og jordalkalimetaller eller siliciumoxider (som formindsker opløsningshastigheden). Kiseldioxid,Typical examples of (i) are alkali metal oxides (which increase the dissolution rate) and alkaline earth metals or silicon oxides (which decrease the dissolution rate). Kiseldioxid,

SiC>2, er særlig god til forsinkelse af opløsningen af boroxid .SiC> 2, is particularly good for delaying the solution of boron oxide.

Typiske eksempler på (ii) er kobberoxid, tinoxid, zinkoxid.Typical examples of (ii) are copper oxide, tin oxide, zinc oxide.

Nogle afsvampningsmidler styres mest effektivt ved hjælp af kobberoxid eller en af de andre metaloxidér med borsyre.Some antifouling agents are most effectively controlled by copper oxide or one of the other metal oxides with boric acid.

Det smeltede legeme ifølge denne opfindelse er formet som en prop til at passe med et tilsvarende formet hul boret i træet. Den mest bekvemme propform er en stav eller cylinder, f.eks. en cirkulær cylinder med en længde, der er længere end dens største diameter. Alternative former omfatter blokke, piller og kugler. Disse i forvejen tildannede legemer kan laves ved extrudering af træbeskyttelsen i smeltet tilstand eller ved formning eller presning af partikelformede materialer i en form, og så smelte dem ved varme til en sammenhængende struktur. Til boroxid foretrækkes at smelte partikelformet materiale.The molten body of this invention is shaped like a plug to fit with a corresponding shaped hole drilled in the wood. The most convenient plug form is a rod or cylinder, e.g. a circular cylinder having a length longer than its largest diameter. Alternative forms include blocks, pills and bullets. These pre-formed bodies can be made by extruding the wood protection in a molten state or by forming or pressing particulate materials in a mold, and then melting them by heat into a cohesive structure. For boron oxide, it is preferred to melt particulate material.

5 1489565 148956

Efter at legemet er blevet indført i hullet/ kan hullet lukkes til for at undgå direkte indtrængning af fugt. Der kan indsættes mere end et sådant formet legeme, som vist nedenfor med et eksempel med jernbanesveller.After the body has been inserted into the hole / hole, the hole can be closed to avoid direct ingress of moisture. More than one such shaped body can be inserted, as shown below with an example of rail sleepers.

Brug af et smeltet legeme ifølge opfindelsen har mange fordele i forhold til brug af andre træbeskyttelser. Efter smeltning har proppen en høj tæthed således, at volumenet for en given vægt af træbeskyttelsen er mindre end for et partikelformet materiale. Som følge deraf er hulrummene, hvori proppen er placeret, mindre, således at den mekaniske svækkelse af træet er mindre. Det er også billigere og hurtigere at bore et lille hul end et stort hul. Ydermere opløses det smeltede materiale langsommere i fugt i træet, end det samme materiale på partikelform gør, og alligevel kan det stadig opløses tilstrækkelig hurtigt til at opretholde den ønskede koncentration af afsvampningsmiddel i det område af træet, der er mest udsat for svampeangreb.Using a molten body according to the invention has many advantages over the use of other wood protectors. After melting, the plug has a high density such that the volume for a given weight of the tree protection is less than that of a particulate material. As a result, the voids in which the plug is located are smaller, so that the mechanical weakening of the wood is less. It is also cheaper and faster to drill a small hole than a large hole. Furthermore, the molten material dissolves more slowly in the moisture in the wood than does the same particulate material, and yet it can still dissolve sufficiently quickly to maintain the desired concentration of antifungal agent in the area of the wood most exposed to fungal attack.

Boroxid opløses i fugt i træ ved dannelse af borsyre, som i sig selv er den aktive bestanddel. Borsyren diffunderer ind i træet med en hastighed, som er bestemt af mængden af tilgængeligt frit vand, d.v.s. at jo fugtigere træet er, jo hurtigere bevæger beskyttelsen sig ind i træet. 1 ml smeltet boroxid danner 3 ml borsyre.Boron oxide dissolves in moisture in wood by forming boric acid, which is itself the active ingredient. The boric acid diffuses into the tree at a rate determined by the amount of free water available, i.e. the more moist the tree, the faster the protection moves into the tree. 1 ml of molten boric oxide forms 3 ml of boric acid.

Ifølge opfindelsen foretrækkes det, at legemet yderligere indeholder SiC>2, da opløsningen af boroxid-proppen derved især kan forsinkes for at give proppen en længere levetid.According to the invention, it is preferred that the body further contains SiC> 2, since the solution of the boron oxide plug can thereby be delayed especially to give the plug a longer service life.

Under betingelser, hvor levetiden for borsyre-pasta kunne forventes at være fem år, kan levetiden for proppen ifølge opfindelsen forventes at være 12-15 år.Under conditions where the life of boric acid paste could be expected to be five years, the life of the plug according to the invention can be expected to be 12-15 years.

Ved en anden foretrukken udførelsesform for opfindelsen 6 148956 indeholder legemet et alkalimetalorid, som har vist sig særlig velegnet til at forøge opløsningen af legemet, når dette ønskes for at få en hurtig virkning.In another preferred embodiment of the invention, the body contains an alkali metaloride which has been found to be particularly suitable for increasing the dissolution of the body when desired for rapid action.

Idet de smeltede propper er mindre for en given vægt af træbeskyttelse, behøver de kun små huller og bevirker således mindre mekanisk skade og svækkelse af træet. Hvis en tresbeskyttelse, . der er lettere opløselig i vand end boroxid, er til stede sammen med boroxid i det smeltede legeme ifølge opfindelsen, vil den også kun diffundere langsomt, fordi den er indkapslet i den mindre opløselige boroxid.As the molten plugs are smaller for a given weight of wood protection, they only need small holes and thus cause less mechanical damage and weakening of the wood. If a sixty protection,. which is more readily soluble in water than boric oxide, present with boric oxide in the molten body of the invention, will also only diffuse slowly because it is encapsulated in the less soluble boric oxide.

Opfindelsen angår også en fremgangsmåde til beskyttelse af en jernbanesvelle med skinnebeslag, ved hjælp af træbeskyttelsesmidlet ifølge opfindelsen, hvilken fremgangsmåde er ejendommelig ved, at der anbringes et eller flere legemer i borehuller tæt ved beslagets ene side, hvilke huller forlø-ber skråt ind under beslaget. Herved opnås, at legemer anbringes, så at de udøver deres beskyttende virkning netop der, hvor der er størst risiko for angreb uden at man svækker træet mekanisk i væsentlig grad.The invention also relates to a method for protecting a rail sleeve with rail fittings, by means of the wood preservative according to the invention, which is characterized in that one or more bodies are placed in boreholes close to one side of the bracket which extend obliquely under the bracket. . Hereby, bodies are placed so that they exert their protective effect precisely where there is the greatest risk of attack without significantly weakening the wood.

Efter indsættelsen af de beskyttende -propper i træet kan de forsegles med en kapsel af plast eller andet passende materiale. Når beskyttelsen er diffunderet gennem træet, kan hulrummene simpelt hen fyldes igen med frisk beskyttelse ved fjernelse af kapslen og indsættelse af yderligere propper.After inserting the protective plugs into the wood, they can be sealed with a plastic capsule or other suitable material. Once the protection is diffused through the wood, the cavities can simply be filled again with fresh protection by removing the capsule and inserting additional plugs.

Opfindelsen forklares nærmere under henvisning til et eksempel på beskyttelse af jernbanesveller. Opfindelsen er naturligvis lige anvendelig til andre trækonstruktioner, som anført nedenfor.The invention is further explained with reference to an example of protection of railway sleepers. Of course, the invention is equally applicable to other wood structures as set forth below.

148956 7148956 7

Skønt levetiden for jernbanesveller på et spor, som kun bruges lidt, kan være adskillige årtier, behøver de fleste sveller behandling med træbeskyttelse efter omkring 10-15 år, hvis de skal vedblive at være slidstærke.Although the life of rail sleepers on a track that is only slightly used can be several decades, most sleepers need treatment with tree protection after about 10-15 years if they are to remain durable.

Råd i jernbanesveller forekommer i begyndelsen omkring fastgørelsesbeslaget for sporet, især i området tæt ved skruehullerne, hvor beslaget er fastgjort til svellen.Advice in rail sleepers initially occurs around the attachment bracket for the track, especially in the area close to the screw holes where the bracket is attached to the sleepers.

En typisk prop ifølge opfindelsen til brug i jernbanesveller er en cirkulær cylinder, der er 80 mm lang og 12 mm i diameter. Denne har en masse på omkring 16 g.A typical plug according to the invention for use in railway sleepers is a circular cylinder 80 mm long and 12 mm in diameter. This one has a mass of about 16 g.

Hulrum, normalt 8 med 2 placeret på hver side af hvert rektangulært beslag, bores til en dybde, der ikke er mere end halvdelen af svellens tykkelse. Hvert hul er netop stort nok til at modtage en prop og skråner nedad mod et sted under den midterste del af beslaget, som vist på den medfølgende tegning. Hullerne er boret i retning imod en position under beslaget for at træbeskyttelsen kan placeres direkte i området, der er mest udsat for råd. Ydermere er dette område bedst beskyttet med hensyn til udvaskning af vandopløselig beskyttelse, hvis svellerne ligger i områder med megen regn. Området under beslaget indeholder mest fugt, på grund af kondensvand under beslaget, hvilket fremmer diffunderingen af træbeskyttelsen gennem svellen.Cavities, usually 8 by 2 located on each side of each rectangular bracket, are drilled to a depth no more than half the thickness of the swelling. Each hole is just large enough to receive a plug and slopes downward toward a location below the middle portion of the bracket, as shown in the accompanying drawing. The holes are drilled in a direction towards a position below the bracket so that the tree protection can be placed directly in the area that is most exposed. Furthermore, this area is best protected in terms of leaching of water-soluble protection if the sleepers are in areas with heavy rainfall. The area under the bracket contains the most moisture, due to condensation water beneath the bracket, which promotes the diffusion of the tree protection through the sleep.

På tegningen viser fig. 1 en del af en svelle set fra oven, hvorpå der er monteret et beslag, fig. 2 svellen set fra siden, og 8 148956 fig. 3 svellen set fra enden.In the drawing, FIG. 1 is a plan view of a part of a swell on which a bracket is mounted; FIG. 2 is the side view, and FIG. 3 the sleep from the end.

Svellen 10 bærer beslaget 11. Detaljerne af beslaget med dets fjedrende fastgørelse til sporet, der er skitseret som 12, er ikke vist, da det ikke udgør en del af denne opfindelse. Beslaget er fastgjort til svellen med fire skruer, som hver er benævnt 13.The sleeper 10 carries the bracket 11. The details of the bracket with its resilient attachment to the groove outlined as 12 are not shown as it does not form part of this invention. The bracket is fastened to the sleep with four screws, each referred to as 13.

Hullerne, som er boret til propperne ifølge opfindelsen, er benævnt 14. Hældningen af hulrummene ses i fig. 2 og 3, og i fig. 1 er retningen af hulrummene vist med stiplet linie.The holes drilled for the plugs of the invention are referred to as 14. The inclination of the cavities is shown in FIG. 2 and 3, and in FIG. 1, the direction of the cavities is shown in dotted line.

En prop ifølge opfindelsen indsættes derefter i hvert hul, som derefter kan tilkapsles. Hvis hullerne er boret til en længde, der er større end 150-200 mm, som kan være nødvendigt, hvis de skråner meget fra lodret, kan to eller tre propper bruges i hvert hul. Mens et pulver eller en pasta af træbeskyttelse er tilbøjelig til at blive presset ud af trykket, som bliver overført gennem træsvellen ved passage af tog, forbliver den smeltede prop urokkeligt på plads.·A plug according to the invention is then inserted into each hole, which can then be encapsulated. If the holes are drilled to a length greater than 150-200 mm which may be necessary if they are sloped much from the vertical, two or three plugs can be used in each hole. While a powder or paste of wood protection tends to be squeezed out of the pressure, which is passed through the wood sleeper when passing trains, the molten plug remains firmly in place.

En' yderligere interessant fordel ved smeltede legemer ifølge opfindelsen er, at de ikke forøger træets ledeevne. Dette er i nogle tilfælde vigtigt, når træet indgår i et automatisk signalsystem.A further interesting advantage of molten bodies according to the invention is that they do not increase the conductivity of the wood. This is sometimes important when the tree is part of an automatic signal system.

Størrelsen af det formede legeme ifølge opfindelsen afhænger af den tilsigtede anvendelse. Til jernbanesveller er en cylindrisk stang med en masse på 10-100 g passende. Til vinduesrammer og døre er en cylindrisk stang med en masse på 1-10 g passende, f.eks. 18 mm lang og 9 mm i diameter med en masse på 2-2½ g.The size of the shaped body according to the invention depends on the intended use. For railway sleepers, a cylindrical rod with a mass of 10-100 g is suitable. For window frames and doors, a cylindrical bar with a mass of 1-10 g is suitable, e.g. 18 mm long and 9 mm in diameter with a mass of 2-2½ g.

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Toppen af træpæle er udsat for råd, som kan standses ved indsættelse af en stor smeltet pille eller stang på f.eks.The top of wooden piles are exposed to tips which can be stopped by inserting a large molten pill or rod on e.g.

100 g af træbeskyttelse såsom boroxid i et hul boret i pælen eller direkte i det af råd blødgjorte træ.100g of wood protection such as boron oxide in a hole drilled in the pile or directly in the softened wood.

I træbroer, hvor det er vigtigt at begrænse den mekaniske svækkelse, som er forårsaget af boring af huller, anbefales det at anvende stænger med de samme egenskaber som for jernbanesveller.In wooden bridges where it is important to limit the mechanical impairment caused by drilling holes, it is recommended to use rods with the same characteristics as for railway sleepers.

DK478578A 1977-11-11 1978-10-27 WOOD PROTECTIVE EQUIPMENT AND PROCEDURE TO USE THEREOF DK148956C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB4713877 1977-11-11
GB4713877 1977-11-11
GB4713777 1977-11-11
GB4713777 1977-11-11

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DK478578A DK478578A (en) 1979-05-12
DK148956B true DK148956B (en) 1985-12-02
DK148956C DK148956C (en) 1986-05-20

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AU (1) AU527240B2 (en)
BR (1) BR7807344A (en)
CA (1) CA1103856A (en)
DE (1) DE2822461A1 (en)
DK (1) DK148956C (en)
FR (1) FR2408441A1 (en)
GB (1) GB2008640B (en)
NL (1) NL189364C (en)
SE (1) SE429210B (en)
SU (1) SU1087062A3 (en)

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FR2408441B1 (en) 1983-09-30
GB2008640A (en) 1979-06-06
JPS5484003A (en) 1979-07-04
DK478578A (en) 1979-05-12
SE429210B (en) 1983-08-22
DE2822461C2 (en) 1988-12-29
DE2822461A1 (en) 1979-05-17
NL7810841A (en) 1979-05-15
CA1103856A (en) 1981-06-30
AU4147278A (en) 1979-05-17
FR2408441A1 (en) 1979-06-08
NL189364C (en) 1993-03-16
GB2008640B (en) 1982-03-24
BR7807344A (en) 1979-07-24
JPS6242763B2 (en) 1987-09-10
SU1087062A3 (en) 1984-04-15
NL189364B (en) 1992-10-16
SE7810771L (en) 1979-05-12
DK148956C (en) 1986-05-20
AU527240B2 (en) 1983-02-24

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