DEV0000199MA - Means for producing keratin-containing fiber material that has been intentionally changed in shape, in particular permanent waves - Google Patents
Means for producing keratin-containing fiber material that has been intentionally changed in shape, in particular permanent wavesInfo
- Publication number
- DEV0000199MA DEV0000199MA DEV0000199MA DE V0000199M A DEV0000199M A DE V0000199MA DE V0000199M A DEV0000199M A DE V0000199MA
- Authority
- DE
- Germany
- Prior art keywords
- shape
- fiber material
- ferments
- oxidation
- catalase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 102000011782 Keratins Human genes 0.000 title claims description 8
- 108010076876 Keratins Proteins 0.000 title claims description 8
- 239000002657 fibrous material Substances 0.000 title claims description 7
- 102000016938 Catalase Human genes 0.000 claims description 11
- 108010053835 Catalase Proteins 0.000 claims description 11
- 125000000446 sulfanediyl group Chemical group *S* 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 239000003755 preservative agent Substances 0.000 claims description 4
- 239000000284 extract Substances 0.000 claims description 3
- 235000011389 fruit/vegetable juice Nutrition 0.000 claims description 3
- 239000012141 concentrate Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- -1 mercapto fatty acids Chemical class 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- 102000000634 Cytochrome c oxidase subunit IV Human genes 0.000 description 1
- 108050008072 Cytochrome c oxidase subunit IV Proteins 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- SPAGIJMPHSUYSE-UHFFFAOYSA-N Magnesium peroxide Chemical compound [Mg+2].[O-][O-] SPAGIJMPHSUYSE-UHFFFAOYSA-N 0.000 description 1
- 108700020962 Peroxidase Proteins 0.000 description 1
- 102000003992 Peroxidases Human genes 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 102000003425 Tyrosinase Human genes 0.000 description 1
- 108060008724 Tyrosinase Proteins 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 229960004995 magnesium peroxide Drugs 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 125000005342 perphosphate group Chemical group 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 210000002966 serum Anatomy 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Description
Es ist bekannt, dass keratinhaltiges Fasermaterial insbesondere Haar durch Einwirkung von Thioverbindungen wie Thioglycolsäure oder Mercaptanen, vorzugsweise in alkalischer Lösung, formverändert werden kann. Besonders geeignet hierzu sind (alpha)- oder (beta)- oder (gamma)-Mercaptofettsäuren oder deren Thiolactone, ferner Mercaptozucker bzw. Mercaptoalkohole.It is known that keratin-containing fiber material, in particular hair, can be changed in shape by the action of thio compounds such as thioglycolic acid or mercaptans, preferably in an alkaline solution. Particularly suitable for this purpose are (alpha) or (beta) or (gamma) mercapto fatty acids or their thiolactones, and also mercaptosugars or mercapto alcohols.
Die Fixierung der veränderten Form kann dabei durch Oxydationsmittel, insbesondere Perverbindungen wie Peroxyde z.B. Wasserstoffsuperoxyd, Persulfat, Perborat, Perphosphat, Percarbonat, Magnesiumperoxyd, Natrium, Kalium- oder Ba- riumperoxyd, Fettalkoholpersulfate oder Fettalkoholperphosphate erfolgen.The fixation of the changed shape can be done by oxidizing agents, in particular per compounds such as peroxides e.g. hydrogen peroxide, persulfate, perborate, perphosphate, percarbonate, magnesium peroxide, sodium, potassium or Ba- rium peroxide, fatty alcohol persulphates or fatty alcohol perphosphates.
Es wurde schon früher vorgeschlagen, zur Nachbehandlung der Wasserstoffsuperoxyd-Oxydation zwecks Zersetzung von Wasserstoffsuperoxyd-Rückständen Katalase in wässriger Aufschwemmung zu verwenden, wodurch angeblich die Haltbarkeit der Formveränderung verstärkt werden soll. Dabei bestand immer die Gefahr, dass durch Verwendung von zu heißen Wassers beim Spülen des Fasermaterials oder beim Aufschwemmen des katalasehaltigen Ferments die Wirksamkeit desselben herabgesetzt oder zerstört wurde. Andererseits kann die Katalase ihr Oxydations- bzw. Verkettungsvermögen auf das reduzierte Keratin - S Na (resp. -S N H(sub)4) nur entfalten in Gegenwart einer Perverbindung, wie z.B. H(sub)2O(sub)2. Diese Letztere wurde aber bei der bisherigen Methode (spülen mit Wasser zwischen Oxydation mit der Perverbindung und Katalaseanwendung) bis auf Spuren ausgewaschen.It has already been proposed earlier to use catalase in aqueous suspension for the aftertreatment of hydrogen peroxide oxidation for the purpose of decomposing hydrogen peroxide residues, which is said to increase the durability of the change in shape. There was always the risk that the use of excessively hot water when rinsing the fiber material or when floating the catalase-containing ferment reduced or destroyed the effectiveness of the same. On the other hand, the catalase can only develop its oxidizing or linking capacity to the reduced keratin - S Na (or -S N H (sub) 4) in the presence of a per compound, such as H (sub) 2O (sub) 2. This latter was washed out to traces with the previous method (rinsing with water between oxidation with the per compound and catalase application).
Es wurde nun gefunden, dass ein Zusatz von oxydationsfördernde Fermente den Thioverbindungen die nachfolgende Oxydation durch die oben genannten Peroxyde wesentlich verstärkt, beschleunigt, verdeutlicht und einen größeren Sicherheitskoeffizienten ergibt, indem die Thioverbindungen vollständig oxydiert werden.It has now been found that the addition of oxidation-promoting ferments to the thio compounds significantly strengthens, accelerates, and clarifies the subsequent oxidation by the above-mentioned peroxides and results in a greater safety coefficient in that the thio compounds are completely oxidized.
Vorliegende Erfindung betrifft nun ein Mittel zur Erzeugung von absichtlich formveränderten keratinhaltigenThe present invention relates to a means for producing keratin-containing keratin that have been intentionally changed in shape
Fasermaterial, insbesondere von Dauerwellen, das dadurch gekennzeichnet ist, dass es außer den die Formveränderung bewirkenden Thioverbindungen, oxydationsfördernde Fermente, wie Katalase oder katalasehaltiges Material, bzw. oxydationsfördernde Fermente enthaltende Extrakte, Presssäfte oder Konzentrate gegebenenfalls zusammen mit proteinabbauenden Fermenten oder solche enthaltenden Stoffe, sowie verträglichen Konservierungsmitteln enthält.Fiber material, in particular of permanent waves, which is characterized in that it contains, in addition to the thio compounds causing the change in shape, oxidation-promoting ferments such as catalase or catalase-containing material, or extracts, pressed juices or concentrates containing protein-degrading ferments or substances containing them, as well as contains compatible preservatives.
Als oxydationsfördernde Fermente eignen sich Katalase oder diese enthaltendes Material, wie Bakterien- oder Pflanzenzellen, Spaltpilze, Blütenpollenstaub, Pflanzenkaltpresssaft oder Extrakte, z.B. Tierblutserum.Catalase or material containing it, such as bacterial or plant cells, split fungi, pollen dust, cold pressed plant juice or extracts, e.g. animal blood serum, are suitable as oxidation-promoting ferments.
Tatsächlich haben praktische Versuche von mehreren Monaten Dauer, auch nach öfterem Waschen des absichtlich formveränderten keratinhaltigen Fasermaterials eine wesentlich bessere Formbeständigkeit desselben ergeben. Ferner hat sich eine erhebliche Zeitersparnis gezeigt, da bei vorheriger Zugabe des katalasehaltigen Materials zur Thioverbindung, diese ohne Zwischenspülung mit Wasser direkt auf der Faser oxydiert werden kann. Aus diesen Ausführungen geht hervor, dass das vorliegende Verfahren gegenüber den bisher üblichen Methoden einen technischen Fortschritt bedeutet. Es ist denkbar, dass andere oxydationsfördernde Begleitfermente wie Peroxydasen, Cytochromoxydasen, Tyrosinasen, sowie Schutzkolloide des katalasehaltigen Materials am erreichten günstigen Effekt Anteil haben.In fact, practical tests lasting several months, even after repeated washing of the keratin-containing fiber material, which has been deliberately changed in shape, have shown a significantly better dimensional stability of the same. Furthermore, a considerable time saving has been shown, since if the catalase-containing material is added to the thio compound beforehand, it can be oxidized directly on the fiber without intermediate rinsing with water. From these statements it can be seen that the present process represents a technical advance compared to the methods customary up to now. It is conceivable that other oxidation-promoting accompanying ferments such as peroxidases, cytochrome oxidases, tyrosinases and protective colloids of the catalase-containing material contribute to the favorable effect achieved.
Die Mischung aus Thioverbindung und Ferment kann gewünschtenfalls mit Konservierungsmitteln, die mit den Komponenten verträglich sind, versehen oder sonst einer konservierenden Behandlung unterworfen und so in den Handel gebracht werden.The mixture of thio compound and ferment can, if desired, be provided with preservatives which are compatible with the components or otherwise subjected to a preservative treatment and thus be placed on the market.
Es wurde ferner gefunden, dass ein Zusatz von proteinabbauenden Fermenten zu den genannten Thioverbindungen vor der Oxydation, deren Formveränderungsvermögen für das keratinhaltige Fasermaterial begünstigt, indem sich die Formveränderung nach der Oxydierung als intensiver, stabiler und dauerhafter erweist.It was also found that the addition of protein-degrading ferments to the thio compounds mentioned before the oxidation promotes their ability to change shape for the keratin-containing fiber material, in that the change in shape after the oxidation proves to be more intense, more stable and more permanent.
Infolge des katalytischen Charakters der oxydationsfördernden und proteinabbauenden Fermente brauchen diese nur in sehr kleinen Mengen angewandt zu werden.Due to the catalytic character of the oxidation-promoting and protein-degrading ferments, they only need to be used in very small quantities.
Claims (1)
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