DE972216C - Fixative for reductively treated hair - Google Patents
Fixative for reductively treated hairInfo
- Publication number
- DE972216C DE972216C DESCH11367A DESC011367A DE972216C DE 972216 C DE972216 C DE 972216C DE SCH11367 A DESCH11367 A DE SCH11367A DE SC011367 A DESC011367 A DE SC011367A DE 972216 C DE972216 C DE 972216C
- Authority
- DE
- Germany
- Prior art keywords
- catalyst
- fixative
- treated hair
- agent according
- fixing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/362—Polycarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/04—Preparations for permanent waving or straightening the hair
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Description
AUSGEGEBEN AM 4. JUNI 1959ISSUED JUNE 4, 1959
Sch 11367IV a j 30 hSch 11367IV a j 30 h
Es ist bekannt, daß menschliches Haar durch Behandlung mit schwefelhaltigen reduzierenden Substanzen in seiner Form verändert werden kann, sei es zum Zwecke der Haarwellung oder der Glättung von krausen Haaren.It is known that human hair by treatment with sulfur-containing reducing Substances can be changed in its shape, be it for the purpose of hair curling or straightening of frizzy hair.
Anschließend an eine derartige reduktive Haarbehandlung erfolgt eine oxydative Nachbehandlung, wobei ein Oxydationsmittel, wie z. B. Wasserstoffperoxyd, Anlagerungsverbindungen des Wasserstoffperoxyds oder Alkalisalze der Sauerstoffsäuren der Halogene verwendet werden.This type of reductive hair treatment is followed by an oxidative post-treatment, wherein an oxidizing agent, such as. B. hydrogen peroxide, addition compounds of hydrogen peroxide or alkali salts of the oxo acids of the halogens can be used.
Fixierlösungen, die Salze der Halogensauerstoffsäuren, ζ. B. Bromate, enthalten, neigen bei einem pH-Wert unter 7 zur Zersetzung unter Abscheidung des Halogens. Diese Zersetzung ist bei Bromaten bedingt durch Spuren von Bromid, welche stets in technischem Bromat vorhanden sind. Aus diesem Grunde sind nur neutral oder alkalisch eingestellte Bromatlösungen haltbar.Fixing solutions, the salts of the halogenated oxygen acids, ζ. B. bromates contain, tend at a pH value below 7 for decomposition with separation of the halogen. In bromates, this decomposition is due to traces of bromide, which are always present in technical bromate. For this reason, only bromate solutions that are neutral or alkaline can be kept.
Es zeigte sich nun, daß in gebrauchsfertigen Fixierlösungen Bromate besser geeignet sind als Wasserstoffperoxyd, da letzteres im Gegensatz zu Bromat gegen Wärmeeinflüsse nicht beständig ist. Es besteht die Gefahr, daß Wasserstoffperoxydlösungen durch Abspalten von Sauerstoff an Gehalt an wirksamem Wasserstoffperoxyd verlieren und somit die Wirksamkeit nachläßt.It has now been found that bromates are more suitable than ready-to-use fixing solutions Hydrogen peroxide, as the latter, unlike bromate, is not resistant to the effects of heat. There is a risk that hydrogen peroxide solutions will lose their content by splitting off oxygen lose effective hydrogen peroxide and thus the effectiveness decreases.
Alkalisalze der Halogensauerstoffsäuren haben aber den Nachteil, daß der Fixiervorgang, d. h. das restlose Vernichten aller reduzierenden Sub-Alkali salts of the halogenated oxygen acids have the disadvantage that the fixing process, d. H. the complete annihilation of all reducing sub-
909 525/45909 525/45
stanz, längere Zeit in Anspruch nimmt, als es bei Verwendung von WasserstofiEperoxyd oder dieses abspaltenden Verbindungen der Fall ist.punch, takes longer than when using hydrogen peroxide or this separating compounds is the case.
Dieser Nachteil wurde nun erfindungsgemäß dadurch beseitigt, daß den Fixiermitteln, die Salze der Halogensauerstoffsäure enthalten, wasserlösliche komplexe organische Verbindungen der Schwermetalle der IV. Reihe des Periodischen Systems der Elemente (vgl. Chemie-Lexikon vonThis disadvantage has now been eliminated according to the invention in that the fixing agents, the salts containing the haloacid, water-soluble complex organic compounds of the Heavy metals of the IV series of the Periodic Table of the Elements (cf. Chemie-Lexikon von
ίο Dr. H. Römpp, I.Auflage, 1947, S. 980), welche noch die typischen Reaktionen der genannten Schwermetalle geben, zugesetzt werden. Diese Schwermetallsalze katalysieren schon in geringer Konzentration die Oxydation des reduzierten Haarkeratins sowie des überschüssigen Reduktionsmittels durch Bromat, auch im neutralen und schwach alkalischen Medium.ίο Dr. H. Römpp, 1st edition, 1947, p. 980), which nor give the typical reactions of the heavy metals mentioned, are added. These Heavy metal salts catalyze the oxidation of the reduced one, even in low concentrations Hair keratin as well as the excess reducing agent due to bromate, also in the neutral and weakly alkaline medium.
Aus den bekanntgemachten Unterlagen des Patents 958764 der Klasse 30h war es bekannt, wasserlösliche organische Schwermetallverbindungen der IV. Reihe des Periodischen Systems, z. B. Eisenammoncitrat, reduzierend wirkenden Dauerwellmitteln, z. B. Alkalisulfitlösungen, zur Beschleunigung der Luftoxydation zuzusetzen. Hier handelt es sich somit nicht um Fixiermittel, die nach Abschluß der eigentlichen Dauerwellbehandlung angewendet werden wie beim Erfindungsgegenstand, und nicht um Halogensauerstoffsäuren enthaltende Mittel.From the published documents of the patent 958764 of class 30h it was known water-soluble organic heavy metal compounds of the IV. series of the Periodic Table, z. B. Iron ammonium citrate, reducing permanent waving agents, e.g. B. alkali sulfite solutions, for acceleration to add to air oxidation. It is therefore not a matter of fixing agents that after completion of the actual permanent wave treatment are applied as in the subject of the invention, and not to halogenated oxygen acids containing agents.
Erfindungsgemäß wurde nun weiter gefunden, daß komplexe organische Verbindungen der Schwermetalle, besonders des Eisens, welche die typischen Reaktionen der Schwermetalle zeigen, im Gegensatz zu normalen Eisenverbindungen mit ionogenen Schaum- oder Netzmitteln keine unlöslichen Niederschläge bilden. Als besonders geeignet erwies sich das Ferriammoniumcitrat.According to the invention it has now been found that complex organic compounds of Heavy metals, especially iron, which show the typical reactions of heavy metals, In contrast to normal iron compounds with ionic foaming agents or wetting agents, no insoluble ones Form precipitates. Ferriammonium citrate proved to be particularly suitable.
Es folgen einige Beispiele:Here are a few examples:
Beispiel 1 5,0% Natriumbromat 3,0% Laurylalkoholsulfat 0,3 % Ferriammoniumcitrat 91,7% Wasser.Example 1 5.0% sodium bromate 3.0% lauryl alcohol sulfate, 0.3% ferric ammonium citrate, 91.7% water.
Beispiel 2 5,0% Natriumbromat 3,0 °/o Laurylalkoholsulfat 0,5 % Nickelammoniumtartrat 91,5% Wasser.Example 2 5.0% sodium bromate 3.0% lauryl alcohol sulfate 0.5% nickel ammonium tartrate, 91.5% water.
Beispiel 3 5,0% Natriumbromat 3,0% Laurylalkoholsulfat 0,5 °/o Kobaltammoniumoxalat 91,5% Wasser.Example 3 5.0% sodium bromate 3.0% lauryl alcohol sulfate 0.5% cobalt ammonium oxalate 91.5% water.
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DESCH11367A DE972216C (en) | 1952-12-25 | 1952-12-25 | Fixative for reductively treated hair |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DESCH11367A DE972216C (en) | 1952-12-25 | 1952-12-25 | Fixative for reductively treated hair |
Publications (1)
Publication Number | Publication Date |
---|---|
DE972216C true DE972216C (en) | 1959-06-04 |
Family
ID=7426499
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DESCH11367A Expired DE972216C (en) | 1952-12-25 | 1952-12-25 | Fixative for reductively treated hair |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE972216C (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1160984B (en) * | 1960-04-15 | 1964-01-09 | Oreal | Method of fixing perms |
-
1952
- 1952-12-25 DE DESCH11367A patent/DE972216C/en not_active Expired
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1160984B (en) * | 1960-04-15 | 1964-01-09 | Oreal | Method of fixing perms |
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