DEP0050340DA - Process of derivatives of dithiobiuret. - Google Patents
Process of derivatives of dithiobiuret.Info
- Publication number
- DEP0050340DA DEP0050340DA DEP0050340DA DE P0050340D A DEP0050340D A DE P0050340DA DE P0050340D A DEP0050340D A DE P0050340DA
- Authority
- DE
- Germany
- Prior art keywords
- thiobiuret
- crystals
- colorless crystals
- derivatives
- dithiobiuret
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 3
- JIRRNZWTWJGJCT-UHFFFAOYSA-N carbamothioylthiourea Chemical class NC(=S)NC(N)=S JIRRNZWTWJGJCT-UHFFFAOYSA-N 0.000 title 1
- 239000013078 crystal Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 2
- YCLDXRHGQVDVJR-UHFFFAOYSA-N carbamothioylurea Chemical compound NC(=O)NC(N)=S YCLDXRHGQVDVJR-UHFFFAOYSA-N 0.000 claims 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims 2
- 229910052742 iron Inorganic materials 0.000 claims 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 101100042649 Bombyx mori Siwi gene Proteins 0.000 description 1
- 241001633942 Dais Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- YNPNZTXNASCQKK-UHFFFAOYSA-N Phenanthrene Natural products C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 1
- LEHOTFFKMJEONL-UHFFFAOYSA-N Uric Acid Chemical compound N1C(=O)NC(=O)C2=C1NC(=O)N2 LEHOTFFKMJEONL-UHFFFAOYSA-N 0.000 description 1
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
Description
Clemens Xiifrter j,1· Wuppertal -Ernst Ganerv leTeClemens Xiifrter j, 1 · Wuppertal -Ernst Ganerv leTe
22= JuIl22 = July
Verfahren, al?.' BersteiltaigProcedure, al ?. ' Bersteilaig
n ι. · -i^ftT) »■ * ^"^ t3 n ι. · -I ^ ftT) »■ * ^" ^ t3
Vpn; .Derivaten' des .MthiobiVpn ; .Derivatives' of the .Mthiobi
Ss wiird® gefimäen, uiaß isaa durch ÜKsetsimg laoaya.nate mit 'Thittramaoßosulfiaea -su i; gelangt» Diese Beakti&a- is*fc\tifcsrra-ä.CiieBSs wiird® gefimä, uiaß isaa by ÜKsetsimg laoaya.nate with 'Thittramaoßosulfiaea -su i; arrives »This Beakti & a- is * fc \ tifcsrra-ä.CiieB
iae-s, Sie. .be'kanntliofe durcfe 'Söi '■.aus Sen ' Ttiiuraiaäiaulf idea' erhalten, werä.ens iae-s, you. .be'knowledliofe were allowed to get 'Söi' .from Sen 'Ttiiuraiaäiaulf idea', see p
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Unroll' Erhitzen der Ausgangakompone'zitsn mit' oder öh mittel- erhält sas äie neiiea Yerblnaiüigen in: 'guter;Unroll 'heating the initial components with' or uh medium- sas äie neiiea Yerblnaiüigen in: 'good;
■■ 1)14 -ao erbältliöhes J^Ary.l^ditliiobiiirete. steiles ar&lcsf j gut 'kris^ailleiereiide- Verbindiingan /äar» -Sie■■ 1) 14 -ao inherited J ^ Ary.l ^ ditliiobiiirete. steep ar & lcsf j gut 'kris ^ ailleiereiide-verbindiingan / äar »-you
sollen ale Heilmittel9 ' öOfk^^IingsbeJrämpfnngesLittel, Hilfsmittel für die Kunst* feoffiadua Sri© ¥$τψ&ί äving finden oder 8 la «wiB-etenproduirt® für die Here teilung der vorgenannten iiittel oder Sie Heret3llung τολ Far!)stoffe» aiall remedies should be found 9 'öOfk ^^ IingsbeJrämpfnngesLittel, aids for art * feoffiadua Sri © ¥ $ τψ & ί äving or 8 la «wiB-etenproduirt® for the division of the aforementioned products or you manufacture τολ Far!) materials» ai
jaimt werden "$ Bf>unü,<$n auf - 110° G-aseBtwiekimng -geht die üsapg laoli dem ErJcaltsn /wlrS die. SeKjäeljse .la :rofOKEs, gelöst rmii ■ das B@ak'tiossprödiikt' du :iWaseKbes.£Xii In krlstelliner Forsi gefällt« ans, fasolibeBsini uad Metlianoi w|.rä es .weiter jaimt become "$ Bf> unü, <$ n to - 110 ° G-aseBtwiekimng-goes the üsapg laoli dem ErJcaltsn / wlrS die. SeKjäeljse .la: rofOKEs, solved rmii ■ the B @ ak'tiossprödiikt 'du : iWaseKbes. £ Xii In krlstelliner Forsi like «ans, fasolibeBsini uad Metlianoi would like to continue
Kri.atall.en iföfi Fp. !13°Kri.atall.en iföfi Fp. ! 13 °
..■■ -.,■ 5T g ^jI^i.. ■■ -., ■ 5T g ^ jI ^ i
aiilf Iö, (äugt des. Bisulf id ^ 4mrch So'&#ef @lents'Gg iait ','EG alß" rotbraunes j sähe© öj ©r-Miltlich) weMss'in 50 ;sem -Glilpr ü@naol gelSs-tf .mit 20 g/Phenaiilf Iö, (eyes des. Bisulf id ^ 4mrch So '&# ef @ lents'Gg iait', 'EG alß "red-brown j would see © öj © r-Miltlich) weMss'in 50 ; sem -Glilpr ü @ naol gelSs- tf. with 20 g / phen
dea auf 2 JO " ^^hltsiüo laofe-'aea Abdampf es: desdea on 2 JO "^^ hltsiüo laofe-'aea exhaust steam es : des
..verriebe]!!Ä wo&ei er -kristallin: wixaio ZiW -yg wird das Produkt S'us;l©tfca3aolv ]iBd Aceton ;emgelSst,i :3üfistalle Ip.. 144° ο.. triturate] !! Ä where & ei er -crystalline: wixaio ZiW -yg the product S'us; l © tfca3aolv] iBd acetone ; emgelSst, i: 3üfistalle Ip .. 144 ° ο
26 g F9I;!9 Siä9=»Bis-i;stra/tietti(7len«'tiiliiramsoiiosia.lfid Si Kit 13 £ Pll eiiyli socialist 5 Sfonden lang auf 120 "bis26 g F 9 I ;! 9 S iä 9 = »Bis-i; stra / t ietti ( 7len« 'tiiliiramsoiiosia.lfid Si Kit 13 £ Pll eiiyli socialist 5 Sfonden long on 120 "bis
IJO ©pfeifest. Die erst flüssige Sonmslse isij naoh äieserIJO © whistle. The first liquid sun solution is naoh higher
iieit kriscallin erstarrt· Barch UiElöser. aas Aceton Kristall© toki Fp6 I76C siieit kris callin freezes · Barch UiElöser. aas acetone crystal © toki mp 6 I76 C s
fid, VXLa 13 if Pbenylisoc^enat werden 3 Stunden &\pg 120 130 erhitsto 3i® eoV'Oia la ö.ev Eitsie krietallis iaielize wird durch lös^s In Ckloroforiiis Fällen mitfid, VXLa 13 if Pbenylisoc ^ enat are 3 hours & \ pg 120 130 erhitsto 3i® eoV'Oia la ö.ev Eitsie krietallis iaielize is made by sol ^ s In Ckloroforiii s cases with
T22i<3 Ilmlöeefi dar FM2.2img a^s Alkohol gereinigt· lose Iristalle Pp. 161°.T22i <3 Ilmlöeefi dar FM2.2img a ^ s alcohol purified · loose iris crystals pp. 161 °.
4ns 35S2 g B'9F*«=Dl_pliejayl-IitIft'=»diji(etliy2«thiura3E=» fia uric' 15 g Pheiiylisocgmnst duroM dreistündiges E ea aiaT 3 20 ois 25C° hergestellt wi£ durch UsilSsen aus Aceton grereini^-Sj, bilctefe di^s© ?er^ir.<1ang gelbliche Ie von· Fp. 2&0°o4ns 35S2 g B ' 9 F * «= Dl_pliejayl-Ii t If t ' =» diji (etliy2 «thiura3E =» fia uric '15 g Pheiiylisocgmnst duroM three hours E ea aiaT 3 20 ois 25C ° produced by UsilSsen from acetone ^ -Sj, bilctefe di ^ s ©? Er ^ ir. <1ang yellowish Ie of · mp. 2 & 0 ° o
la gleicher ¥®isa Isssen sieh s.Bo herstellen·:For the same ¥ ®isa Isssen, see how to make:
Claims (1)
Family
ID=
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