DEP0000459BA - Electrolyte for the galvanic production of coatings from nickel and nickel alloys on metal and non-conductors. - Google Patents

Description

London .- &'ScandinavianMetallurgical'; Go *. 'limited 3-H / liauriston ^ Eoad,, London S, ¥ ..19 »lnglandV ■ ·'. '. ^r /

-2um -galvanic- eyes. von-TJebersuegenvaus ^^ M

ificlEe'llegieruiigen 'a.uf Metall mid- j | iGi "itleit; ern ^j s ^^ Srlii b rIjt ~

■ · ■: Vv ■ The.; Deadly invention: "bezieli" fc sidh to the ¹ galvanic ; ^: <", { Generation of overlays from lieliel. And backing alloys on ■".-_. ; ^: ■■■ '. .?. ~ Metals and -on · Hichtleitern, the major eh any .. "Lekaimten ..Ter- ·:; ■■ zunl go ', echst conducting ^ made are" ^ Th e invention · It is an object, susrunde j; ' create a ver "better grant · electrolyte en,: 4er; -to ^be: V: galvanic nickel: eignet- and especially since] jei \ a strong ₅ v '■■ hard and vers'chleissfeste Ela.ttierung from Hiekel or Hiekel- \ ■. alloys. results _;? ; as che Oeberflae-for the 'of ^{electrically:;} '' produced press molds, die molds and the like / is required. ■■■ ".... ';■'. · .. · .A ordinary ^ back to '' the hanäelsuetlichen Yerjiickelungs- '■ ■" process produced' lickelplattierung ^is; not for ..; -.. '. ;; ^: some useful 'purposes.' / especially 'for the production of; molds by electroplating, because they lack sufficient hardness ? erbe exploited, 'a' relative raaess. · ^: low precipitation _?. and the JTi generated with their help tend to erq ^ itaet and high tensions ^ what the

- piglets. seriously obstructs ,, -Da ¹ S a- \ ^:> - " ^:: ! 0h

is applicable; ^ especially,% if the relationship. · to the structure / relationship - ;;; ■; ■; - ■ '/ S ^. loosely strong-landing encoder: overhangs \ on intricate forms- _; xA: 0 Multiple ^{1s are to be generated over one} another. If one generates the Ueueg'eiS;",-auf-;!" Orm sticks made of non-conductive material, then in particular the mentioned inecliariis ropes / tensions . 'A': Hickel-clad- y- ^; \ "■■%: | '"badj das;']? luoricl ^; .entlia'elt., possesses -a 'very cheap l'iederschiägs-'; power, while it 'at the same time a liiedersoiilag with: niedeii'':';.:': V nieoliani 'see .Spannriigen. results *': 'As a basis for, -the following ": · ^;: ; ^: "The described. founding serves .. dalrer '"' a de? r good es'- Bad., ',. dem. ', the Torisug before. other b; e] ^ amiteii -galyanischeri Teriiiekelüngsbeiedern given · is ^ ¹ ' gr..nP- ^ a j_g ^ iapi.lr.-ni /' - τ ' - - - ^ 1 ·? '- ^ nj ^ . ■ ΐι, Τοτ - ^ - Η ηη t ^ T - ^ en Beg eJchnUIgBl

^: ii - ^^ ^ -U-_ -; t _i ^ _{ji @ i} : ,, JM) ₁ MaJi -..., η, j ^^ l η jH ""'CJi. ^ i ^ sJljj2SM9 ^^ ii -—SJiM.ä ^ · V-: "

- ';.-' -. ^: ϋΐα pear reduction of the -.! extensibility harder, - precipitations; to - ;;: receive en, whose liaerte '. at temperatures above 30 ° C - "is retained", according to the invention "a" cobalt-containing nickel-plating electrolyte; -ϊ '/; is used, because it has "turned out. - that - through the! cobalt". . ' ■ - ■■;.%

? ■ '■ "■' ^: -Mm ^ - '- ..: ■■ -' ■■ ^:: '■■■' -. ''' -.-- ■. ■■ ·' ■ - ' _: , · - '· ^: "' · ·; ·· ■: -. ■■; '■' ■ .. ^'■■:' - ·;. "- ^':': ·:; Λ ^';' .. ■. ';'.;^; addition ^ ϊ ¹ ; Fluoride solution; 'the precipitation force is increased ..''■"..;■' .. · ':'.. '.' ■ .- .. As is well known, the 'addition' of certain organic agents leads to ^ V: ■ ^: z; .Bo from 1.3? 6 "Batrimn-Naiphtal ^ n. Tria-ulmonat, to the at de-r'vga.1- ;. '' _: , Tanis.chen.- Hochglajizvemickelung ^ withiutsten Ba.edern for higher gloss- ^;. and groeseerer- Haerte of, ^{Iiiedersehla.eg-e5:} yet the this ■ '/ ■ :; ! "also achieved flat animal stomachs especially -'- with an ötaerke of.over.-'.- 5/10 'to 3 Ήΐϊϊν often leaflet' and 'gei / oehnlieh' very 'sproede, also ::' ·.

To an 'increased degree pitted j -and -you- "have' the-own-

■ "■ / '-' ■ ■■■ ■; '- ■' ■■ '- ■"'. ■ '. . ' ■ - '. . ^; - : ■ ■ ■ ■■■■ '■ - ■'''.'■■"■■ ■■

scjha.ft, "-that-: your hardness- a 'heat treatment' over 300 ⁰ O- not"; uebersteht.Perner is festsgestellt.'v / orden, - that the addition of _■::;

: '"- ■ ■>■■■.;■' ■ ■■ ^: '·" - "■ ■"' ■. ^Λ '· ^; - · ^ - ■ ■ "■: ': ■.: ■' ■ '.' ■ '■; ■''·■''.' :: ■■ - .. ■ '\ ^: t ■ ■ -: ■ · ■ '■ - ■ ·' ■ ''.'-.' ^{:: /} " ■ '■■';''" ■■ "■ Eobalt 'ZU'.einera Hatriura-HapllEiliii' ErisulmiOnat containing fluorine id .Id ad 'zum', precipitation of an 'initially very ■ high cobalt content." -. " ·

Vlickellegieruhg - a.on the νernickeliiden 'bottle.' leads, and '■■■ ·. '. "■ _: ■' ■ ··. A'iser'cobalt-containing, coating tended to decompose when heated; ': -, ..'.; a ' ^: . ^_:::;: 'v "'Do-'mechanischer tensions in the galvanic ^'1 plating: · ..-, ■ purely else .'Mittel as, the addition of an organic _compound? - - ■ like l'atrium. . ITaphtalen 'Trisulphonat, ■ ^ especially if' it is -the - producing nickel 3J'ormen by, galssnisehe ITiederschlaege "'*-', acted Eliminating such · voltages: is aberfssim ■ ':': '... /, Electroplating of fiber-optic cables of particular importance »It has now. Been found. That. This 'goal can be achieved by'using" ■ '■,'. ■ · ■

· ■■ '■' ■■ '^; ·. '"■' · ■ ■ '■' ■ '.; ■ ·'. ''." - ■ "■ '.. ■' .: n '''' ■■ ' -. · -' ^: ''■' ■ ' ' · ■. ' . ■■■ ''. ■ '''■.' . "■" - '^;': ■ · '.. .. ^: ''^; .-Watri'um-llaphtalin' TrisulpMonth without, .- consideration of ■ .Sc.hwanlcung'en the '"."■; ■ · ■■ '■'': .. "^;'^;' ^: -. "■ ■' · ^:. · '■■■ <* . ■■ ■"■■■■■' ■■ .-. ■ '- ■■ -: · ■' ·. · ■ · '■.' ■■ '■: ■■' r '' ^: ['.'"■ . ·· '·' ■ '·' ■ .. . ■ ■ -, .. ■

Current density within "further ::" limits can be reached. This also applies to .the 'Äuor-id solution -for different' .pH-. Values while. the result. with the well-known. - ''. ■; '· -. ■■ The use of a wetting agent to prevent pitting' ■ -. ', ^{Condition in electroplating is well known. V-:} Di-e. Most.', Known wetting agents increase the '". inner ¹ " tensions of the. galvanic. Plating considerably »'They also replace ■ • under the usual operating conditions, ie in the case of' higher ' _: . ■., Temperature ,; Presence "of oxygen, development, of'hydrogen ν" laÄa ^ .- d ^ iaiii-aäiexiteJa ^ rSSreH ^^ -decomposition product cracks increase, ¹

■ the tension still? / More, "wa.ehren'd; · at the same time- the attachments- ·: special shrink =,. '.." ■ "' _. ¹ ^ ¹ '; ·. ·''■ ■ · · ■ ·. "', · "■,

^: ; ■ '...' ■ '■. - ■■■■■ ■. · '■■ "■■ ■' · '· ■■ -., ·' ■ '' ■. * ■ '■

• ' T) Ie invention is now based on'"the · .knowledge, - ■ that 'hard and " stretchable plastic, t.tierungeil-aus Hickel' and a · nickel alloy of. considerable strength "Without pitted texture" or internal tensions can be achieved if a cobalt-containing plupride bath is used and

organic. Haerte— -unä '^ irlänzerEiaugimg'sraittel · -. zu uegjt ,, ■ das Λ on: '' -

the . "üiücung - from Ifa.tr3 _i ⁱ uffi.-lia.plital4-n ■ tCri s uljELOnat based"; .und if ";mäii; Furthermore, a wetting agent was added at the same time, which can be seen from a sulphonated aliphatic: llkoiiol; "consists ^: dem ^:: in -uetXicher" ¥ eise-- " ^M. ' ^:

ifatriu ice sulfate added; is. · Οΐ3 ^: .der'Siedersehlag- alsvBickel or ^:. /'!?-ν-.ϊ Liickellegierung 'to address \ is ₅ -dependent: .of which together' with the! ^Λy x. Mekel _; dejected .Eobaitinenge ab-, aliso- da, voh ₃ . whether it is '■; ■}. :: -; ΐ ■ just-' about a "trace or a" i ± considerable. Amount 'of'Ko'balt ■ trades. .Fie turned out - ■ turned out ^ h'at, is' particularly "good as -Bene-tzuiigsiaittel ':, ■''das _: unter -äeie : Handelsbez'eic'hnuhg, ⁿ Olaytavon''WM' ^|: on -.dem ^'English:; ■ ■ market available Lüttel that of DER; Clayton.Jaiiline' Go, '■ _^■:': ':; ^:: - Manchester' is produced I) ie aggressively. 'of the alloy. . _5; 'with' ·· "besciiriebeneh bath can be put down 'DEM ₅ amounts ^to:; ■■ ·. ' -annaeheriid ¹ : '5.50 ° Vickers .. Even with ■!' temperatures awi see 300 ,. ' and . .;:.; : 500. .CV as it is called 'operating temperature for injection molding; ■'■;'■. -by iZink / irnd. Aluminum in .Betracht come, remains to this hardness of ■ '■ metallic plating -; eriaalt.eii ·. · · The addition -.der ^two: organic "means -the au cobalt-containing Pluoridbad provides G-ewaehr .for Haert ^ ';■';; and- stability for 'leiiiperätu ^ ren uebei'_, 50p ⁰ ' and for a - ", '· ■' ■ ·. '. substantial ./reduction ", internal mechanical tensions, which otherwise; -: by ^: wetting agents, are increased. =; also becomes. -der- GaI- ^{; /} "vanization avoided, so that" s ^! man · a "'ITi disgusting betwe .. Hicke.1 — E'obalt- ,.' _: Alloy of relative proportions; constant alloy deterioration ^ ■; build ratio lvaU ^^ ß ^ ^ Ι

. . "'■:' _r / While the galvanically 'obtained from the new electrolyte.' ·: Yifiekel has an unusually high stability of the /"Eaert'e"- ,. ^: "';"' • self-'under .the, influence proportionally -' high · "temperatures"'and.'.

■ äureh; [Srhitsuoig; to ^; 5QO ¹³ :, Q not, sproede will. _? ^: occurs "OberliBfelb. -vöii;;.

: '-'^; .ii - .., · '-.' ρ ... '... ■ - · ■' ■ -. '. ■■ '■■■ -. ■ · -. ■ ·. "- ■. ■' - ■■■ -. '-. · ■'^; · ^.: - ■ '■'. ' · .. '■' ■ "; ■ '■' ..- · ■ ■ ·. '■'"■■ · ..": - .; ■ '.'. '. ·', '".''-' Y ':;, ^ QO ^ gYeine., Certain -Spredigkeit: a. ₅ " dieYin mechanical; .Einsicht ^{':: -;} - ^: -

Power can be sublime. In accordance with the invention, ^ now ' ^: '. ,, became, -äass / by '. addition · of .G ad ml to sum, electrolytes ,, would be · .--! t% ' ^: 3öV0ßövdlese Spröe'digkeltVyerittieden is,' ..- and that the v'-V Cadmiums us ät s with "high vSrhltaung ... au. ·; 'one- allsiaehll.clien ^: .'ErJaoehmig' Vv ^!

.the Blidsaiakelt leads-, - without, however, the. Stabllltaet '-dervHaerte Vv - -VVj ziu -'"affect;; and without the -absolute value of the 'Eaerte' for aie ^v V most of the valve-downsenoVi -The above-described ν Z ^{ t \ physical big shafts. '/ Of the Elckels ^ -are Vjecloch v / ohl understoodV

- '■ - ■' ■. ■■■■■ ·· '.-'". ■ '. ■ ·' ■■ '·.' · ■ 'V. ··. ■ · ■. ■■■ .- '■■■ · ■■■' ... ■ · ■. ■■■ '■ .ι ^.: ' .. '''.■■■' ■ - · '■ - ■. ■■■.:. . · ■■■ '.., ^! ·' - ■ ·.:. ·. ■■■. ''. '. ·.'''.-I-^1; .-- ^: '.-. ·. ·: ■■!

not those ,,, which V s'icli -.- wä-elireiad .. der: heating-of the roll-to the specified, V-temperatures- result, but rather the Big enschaft ehv des. HicitelSj-V '& ie. himself naqh; Complete heating 'when re-cooling ^{r ::} V to "Ziniraer temperature; elnsteilen, -J) Ie, Einufueg'ung the two ¹ or-V ^: ;: Vv; ^r ganischeii: -liittel and the' Gadmiraas leads ■ to.- None / Iiera.setsung the V liederschlagslcraf t 'of the cobalt-containing'i'luorldbades, which one ': Innerhall; further VG-stimuli Voh pH- ^ valuesV-can use, "ails''dieVuebllcherL-.' W! ^ ■ liiclre'lbaeder ·., Ol'hie dadur-chVdie ../ H'ei'absetzuiig- der- Tnechanlschen '; ■ '· ■: ■ -': t- W-Spa.nnung ^; by 'the ■ organic · herniation agent- too' impaired = V VV ₁ ^: ν -Vv A; Example of the galvanic: nickel-plating bath -for ^: the '· ..; .. VV; Implementation of the present invention is the following ./ '. · ..'-. :, ^: ; V ■; ■; nickel sulfate; V->VV;. ■ ■ '.220-340 ^; g ■ /../ 'Z ^: λ: -V' .: '

. -. ■ - ... ■ JxU UcL-L u; b 'UJ L ei.- Is ■ - ■' ■. ■ - .. ■ Ό y diLJ "~ c ~ £. Ο"''"■'' ■ ■ '

.'- ■ '': V- boric acid ■ ■ ^; V, V. V 25 _s -2-37 _s 7-V g - '^ - ■ .. ■. :: ■■ .. ··. -vV

• 'V.' ■ ·· .: sodium fluoride; ..- ■ · ■ · ■ '. 6.28-15.70 g '■ ··' -, ''.:.: ^; , '"' Z

^Z:; latrlumchlörid- ...-. . VV. ^ .. ■ · ,. ■ .; i37_i2y56Vg ' ^: - V.; · -'. ;; ·. '■■ V:> ·· ■'.; These substances are dissolved in distilled 'vifessei ¹ , and:>;,understand; the specified quantities Vje liter. . 'Best' will be: V-; öjO44 ^: - 0.22 g / Goi, dmluni.oxyd added ,. 'and-'the resulting ..VV ...- ^: solution then becomes one of the. known ppcydatioiisverfahren 'under? / orj & i S = Bo dem on the. Use of Kai iumpe rßiang ana t berulienden- Yerf ah ^ ^; ·. · ■ "■ '"' ν · '-.V - ■: ■■ "- ■ -' ■: .. ':''-. · ..' .. ν V ^.: " ^: ■. ν · .-. V ^V V .... 'V' -. 'V-' ^:. '·. ■ - · '■■' ■ '.-. "-. ·";, ·';. ·. ·, "■", ■■ ''" TBHy ■ through the Iioes-ung of organic and other 'Yerunrelriigungeri V

Itfacb. ■; This '^ will experience the Xoesiuig gruendlicn .'-.' ■ -V

"f% f. f.

1 ^%

filtered 'and "das --Mltrat" ver se * b2. ±;.; with'ä ,. " ⁱ '' ¹ -, ■; ■ ·: ..--; ■ ^1; ·.,"; ■ ^; · ^: "'■■' ■ · '"■;^::;

■ - ■: -. i_3_5 ^: | Fatriuia-] iEi, ph-taleii 'Iris ulplionate. (IL "to' 5 ^l g per liter liGS. ;; ■ .: \" Clayta.Ton \ W, M; ' ¹ I ^ "to 3 g ^ je / 'L; i ^: ter ^ Loesiing (entiialtend; O ₅ 5 ''' ■: .. "'., '. '■ ;. 1 ₅ ; 5 \ g sulplionierteil.," e.lipiiatiseilen Jlllcoiiols) ». ·; ■ ".". '■ ^· ■ · ■ _^"i;.'. '■', 'V: V''''' ^:: 13ie, ergiTot this .Weise .Loesung preserved '.'.;: the above '...'^■■;; ■ λ erläeuterten Se sul did e, Vienne .man ^:: them as "'-*.' Slelctrolyt sum.." In Yerniclre at... -Eempe-raturen 'zwiscken. 35, and ^^ S ^ - ^' o .- 'lDenendet .-.' And thereby: -eine- - '.

^ e "square centimeters. 4- -Used ..

• IPa t eiitanspiue ch e .;

Claims (1)

> liondon "from -Scandinavian Metallurgical ·: € Ό. ·. · Tiimit'ed.
■ -5-J .liauristonV Eoad, - iondonVSoW.V19 ;, -BnglancL ,,; ■; -: ^r , Patent application i: - '' ¥ e ^ a, ii * ^{r for the} galvanic production of ·. Uetoei? 2ügerj aus-Mclrel and · iiickeilegierringen on ..Metall 'and' Bi cht lei tern.: O- '; electroplating of metals and. "^ ient- ladders ^ with ■ ITiclcel and ^; Hielcellegiermigen lae-e ^;. ^^ iIο_l "El e'k Li> ol, y: ^ p ^ bältiialti.gen ■■]? luo.ridipesun ^ ' ^: der ein örganisci Ea.erte-mid- G-Ianzjiiittel' on: lTa; fcrium-liaplital4n Trisuimionat G-rundlage: Bo ^: as; a ■■ 'Beliet2mlgsmlt.teΓ ■■ aΛls'; Ifatriumg.uifat _l containing 'sulfo-'
ned, .aliphatic ^ alcohol is added »■ '' ^ ■ ^: ',:,;^:; ^: . · /; 2; ... electrolyte: according to- claim, l, .ge.fennzeiohiaß'ti: dü2? _: .Gjiict-en \. ■■■ -.- ■ '-', ·.
^ ^Additional: γοη. :; .3 ·· .: jSleiitrolyte. according to claim 1 or 2, '· "consisting of - ^: -, - ¹ ;; ■■, , '-Hi disgust sulfate ""^; - ^ '"v''^;: ' ■ <'V ·""' 220 - '34 Ö g ^:. "'; ■ ■ ':' :; ^:: Kohaatsulfat ^ V "- ^-:;;; / _Λ::; 6, 28 - 22 _'g; ■ ^..."' -. ■■ · · ^·;:; ■ '{:' \ h I; ,,; - Boric acid: '■ " J ^ :; / ■: ■' ■. '/ 2-5.2 - 37.7 gf'' ^: .... ' ■ '- :. ■ <''' ^: - - ^: .. '■ - yiatrium fluoride ^ ^; ·: .. ■ '· ■ ^ ■ -, ■; ^-:; _: ·. 6 _S 28; - "15.70, g '- ·', -.,;:>'- ; ■ ■; ■■ ^'■■: HatriunichlOrid: - · ■;. ^: 1.57 to 12 ₅ 56'g .. ^_-:: ".. ■ ... ■ '... ■ .; :: ■'" ■■ ·; '■ ^{": r:} \ ■' ■ ■ - ■ "■ -. · ■: · ■ ··. '· ^I; r ■ .-. ■: ■■■: ■' ■■■ '■■ ·'". ■ ■■ '■ ·.' · '■ ^: '"■" ■■ ', ■ "^;■■' · ■■. ■ '''·■■' ■ ■ '-v". · ■' /. ...- 'ι'- "■.' ^: / . · '. [ 1-3-6' ^: 1! Ia'trium-laphtal ^ n-l'risulf onat'i -.-. ' 5-.g *, '. - ■■■■ ■■ _ ■'. Ϊ ·; ■■: '' ■ '. "' ■ -: ■" Sulphonated ^; aliphatic alcoholΊ / 2 - 11/2 g - - ■ .., ·; ': ·;:. · -, ..'. ^ E; liter solution. ■ '■' _: \; ._; ■ · ■■ · '', ·. ■ ...; : ^ - ^: ,; ■■; 4. Electrolyte according to claim 3. » characterized dureh _"the;, additional ■ '"■;' ■■. · .. '■ .' .. ■". '.'''"■■'■■.; ■ ··.' -. '■■■' ■■■. '■ "· ^v ,' -. ^ V '- ■■""■..' ■ '■ .- ^: .. ■■' .- '■ - ■''.' ■ '- '. ■■■ ¹ ^ of · '-'. ■ ;; Oadmium Oxide -! Ία. Ratio: from 0.044 - 0. _? 22 ..g Je IDiterloBsuiig. . ■; ' _ 2 · ■ · -— Blessing _{steaid 3} ·, gekeniiaeiciinet Plattiermig. ₅ - the h one: the t'en äe.r; trolyteni; ··; ;