DE969494C - Surface treatment of metallic heating surfaces exposed to flue gases, in particular boiler heating surfaces - Google Patents

Surface treatment of metallic heating surfaces exposed to flue gases, in particular boiler heating surfaces

Info

Publication number
DE969494C
DE969494C DEW4153D DEW0004153D DE969494C DE 969494 C DE969494 C DE 969494C DE W4153 D DEW4153 D DE W4153D DE W0004153 D DEW0004153 D DE W0004153D DE 969494 C DE969494 C DE 969494C
Authority
DE
Germany
Prior art keywords
heating surfaces
surface treatment
graphite
flue gases
exposed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DEW4153D
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German (de)
Inventor
Siegfried Hutter
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to DEW4153D priority Critical patent/DE969494C/en
Application granted granted Critical
Publication of DE969494C publication Critical patent/DE969494C/en
Expired legal-status Critical Current

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23MCASINGS, LININGS, WALLS OR DOORS SPECIALLY ADAPTED FOR COMBUSTION CHAMBERS, e.g. FIREBRIDGES; DEVICES FOR DEFLECTING AIR, FLAMES OR COMBUSTION PRODUCTS IN COMBUSTION CHAMBERS; SAFETY ARRANGEMENTS SPECIALLY ADAPTED FOR COMBUSTION APPARATUS; DETAILS OF COMBUSTION CHAMBERS, NOT OTHERWISE PROVIDED FOR
    • F23M5/00Casings; Linings; Walls
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23MCASINGS, LININGS, WALLS OR DOORS SPECIALLY ADAPTED FOR COMBUSTION CHAMBERS, e.g. FIREBRIDGES; DEVICES FOR DEFLECTING AIR, FLAMES OR COMBUSTION PRODUCTS IN COMBUSTION CHAMBERS; SAFETY ARRANGEMENTS SPECIALLY ADAPTED FOR COMBUSTION APPARATUS; DETAILS OF COMBUSTION CHAMBERS, NOT OTHERWISE PROVIDED FOR
    • F23M2700/00Constructional details of combustion chambers
    • F23M2700/005Structures of combustion chambers or smoke ducts

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Description

Oberflächenbehandlung von mit Rauchgasen beaufschlagten metallischen Heizflächen, insbesondere von Kesselheizflächen Kessel.'heizflädhen, insbesondere Rohre, sind dadurch besonderen Beanspruchungen ausgesetzt, daß sich auf der vom Rauchgas beaufschlagten Außenseite im Laufe der Betriebszeit Krusten ansetzen, die verhältnismäßig große Dicke besitzen können. Diese Krusten sind schwierig und nur mit besonderen Verfahren, die eine längere Unterbrechung des Kesselbetriebes erfordern, zu entfernen. Die Rohre selbst werden ferner häufig durch in den Rauchgasen enthaltene schweflige Säuren angefressen.Surface treatment of metal exposed to smoke gases Heating surfaces, in particular of boiler heating surfaces Kessel.'heizflädhen, in particular Pipes are exposed to special stresses that on the from Crusts build up on the outside exposed to flue gas in the course of the operating time can have a relatively large thickness. These crusts are difficult and only with special procedures that require a longer interruption of the boiler operation, to remove. The pipes themselves are also often contained in the flue gases corrosive to sulphurous acids.

Die Erfindung hat sich die Aufgabe gestellt, die Oberfläche der Heizflächen derart zu behandeln, daß nicht nur ein Schutz gegen Anfressungen eintritt, sondern auch die Bildung von Krusten verringert und deren Entfernung erleichtert wird. Zur Lösung dieser Aufgabe wird erfindungsgemäß vorgeschlagen, die Heizfläche mit einem aus einem Öl-Graphit-Gemisch bestehenden dünnen Überzug zu versehen. Dieser Überzug kann z. B. mit einer Druckluftpistole aufgespritzt werden. Wird nun der Kessel in Betrieb genommen, so findet eine Erhitzung der Heizflächen statt, wodurch ein Austreiben bzw. Verbrennen der flüchtigen Bestandteile des Öls eintritt. Es ist auch möglich, dieses Abbrennen durch eine besondere Holz- oder Gasfeuerung zu erreichen.The invention has the task of improving the surface of the heating surfaces to be treated in such a way that not only protection against corrosion occurs, but the formation of crusts is also reduced and their removal is facilitated. To the Solution to this problem is proposed according to the invention, the heating surface with a to provide a thin coating consisting of an oil-graphite mixture. This coating can e.g. B. be sprayed with a compressed air gun. If the boiler is now in Put into operation, the heating surfaces are heated, causing them to be expelled or burning of the volatile constituents of the oil occurs. It is also possible, to achieve this burning through a special wood or gas furnace.

Durch das Verfahren nach der Erfindung brennen sich die feinen Graphitteilchen fest in die Poren und Unebenheiten der Oberfläche ein, und es entsteht darüber hinaus eine hauchdünne puderartige Schicht von Graphit, welche das Ansetzen von Krusten aus den Rauchgasen von vornherein erschwert, andererseits aber auch das Entfernen solcher Krusten stark erleichtert. Diese dünne Graphitschicht wirkt hierbei gewissermaßen als »Trennschicht«.By the method of the invention, the fine graphite particles burn firmly into the pores and unevenness of the surface, and it arises In addition, a very thin powder-like layer of graphite, which the attachment from the start made difficult by crusts from the smoke gases, but also on the other hand the removal of such crusts is greatly facilitated. This thin graphite layer works here, as it were, as a »separating layer«.

Es ist an sich bekannt, Rohre von Heizflächen mit einem graphithaltigen Überzug zu versehen. Hierbei handelt es sich aber um die Herstellung von Überzügen in Form einer Glasur (beispielsweise durch Auftragen eines Gemisches von Graphit mit in Wasser löslichen Silikaten - Wasserglas -). Diese bekannten Verfahren haben den Nachteil, daß bei Wärmedehnungen die Glasur zerspringt, so daß Teile davon abplatzen. An diesen Stellen setzen sich dann die Krusten aus den Rauchgasen in besonders starkem Maße an. Bei dem Gegenstand der Erfindung wird die Bildung einer Glasur vermieden.It is known per se, tubes of heating surfaces with a graphite To provide coating. However, this involves the production of coatings in the form of a glaze (for example, by applying a mixture of graphite with water-soluble silicates - water glass -). These known methods have the disadvantage that the glaze cracks during thermal expansion, so that parts of it flake off. At these points, the crusts from the flue gases are particularly strong Dimensions. The object of the invention avoids the formation of a glaze.

Zu keinem Erfolg haben auch Versuche geführt, Kesselrohre mit in Wasser aufgelöstem Graphit zu überziehen, weil nach Verdampfen des Wassers der Graphit sofort verschwand.Attempts to put boiler tubes in water have also been unsuccessful to coat dissolved graphite, because after evaporation of the water the graphite immediately disappeared.

Bei Versuchen hat sich gezeigt, daß durch die erfindungsgemäß vorgesehene Behandlung der Heizflächen eine zwei- bis vierfach längere Betriebszeit zwischen den einzelnen Reinigungen (Entfernung der Krusten) erreicht wurde.Tests have shown that the inventively provided by the Treatment of the heating surfaces for a two to four times longer operating time between the individual cleanings (removal of the crusts) has been achieved.

In vielen Fällen kann man die Krusten einfach durch Rußbläser oder in sonstiger Weise durch Preßluft entfernen, da sich der Belag verhältnismäßig leicht von der Schutzschicht abheben läßt. Es ist also nicht mehr erforderlich, den Belag durch mechanische Mittel abzukratzen oder ihn durch besondere, z. B. mit Dampf arbeitende Verfahren aufzuweichen.In many cases the crusts can be removed simply by sootblowers or remove it in any other way using compressed air, as the covering is relatively easy to remove can stand out from the protective layer. So it is no longer necessary to use the topping scraped off by mechanical means or by special, e.g. B. working with steam Process to soften up.

Für die Herstellung des Öl-Graphit-Gemisches kann man Öle beliebiger Art, insbesondere billige Mineralöle (Abfallöle) verwenden. Der Graphit soll möglichst in Puderform benutzt werden. Man kann dem ö1-Graphit-Gemisch auch Terpentin zusetzen. Zweckmäßig setzt man dem Öl-Graphit-Gemisch eine geringe Menge Petroleum zu, wodurch das Abbrennen erleichtert wird. Das Verfahren nach der Erfindung ist für alle Heizflächen anwendbar, die von Rauchgasen beaufschlagt werden, z. B. also auch bei Gaslufterhitzern. Soweit Kesselanlagen in Betracht kommen, eignet sich das Verfahren nicht nur für die eigentlichen Kesselrohre selbst, sondern auch für Überhitzer sowie Wasser- und Luftvo.rwärmer.Any oils can be used for the production of the oil-graphite mixture Kind, especially use cheap mineral oils (waste oils). The graphite should if possible be used in powder form. Turpentine can also be added to the oil-graphite mixture. A small amount of petroleum is expediently added to the oil-graphite mixture, as a result of which burning is facilitated. The method according to the invention is for all heating surfaces applicable, which are acted upon by smoke gases, z. B. So also with gas air heaters. As far as boiler systems come into consideration, the process is not only suitable for the actual boiler tubes themselves, but also for superheaters as well as water and Air heater.

Durch die Glättung der Oberfläche tritt auch eine Verminderung des den Rauchgasen gebotenen Widerstandes ein, die sich besonders. dann bemerkbar macht, wenn es sich um gegossene Kesselteile handelt, die meist eine sehr rauhe Oberfläche haben.The smoothing of the surface also reduces the resistance offered by the smoke gases, which are particularly. then makes noticeable when it comes to cast boiler parts, which usually have a very rough surface to have.

Claims (2)

PATENTANSPRÜCHE: i. Oberflächenbehandlung von mit Rauchgasen beaufschlagten metallischen Heizflächen, insbesondere von Kesselheizflächen, durch Aufbringen eines graphithaltigen Überzuges, dadurch gekennzeichnet, daß die Heizflächen mit einem aus einem Öl-Graphit-Gemisch bestehenden dünnen Überzug versehen werden. PATENT CLAIMS: i. Surface treatment of exposed to smoke gases metallic heating surfaces, in particular boiler heating surfaces, by applying a graphite-containing coating, characterized in that the heating surfaces with a a thin coating consisting of an oil-graphite mixture. 2. Oberflächenbehandlung nach Anspruch i, dadurch gekennzeichnet, daß dem Öl-Graphit-Gemisch eine geringe Menge Petroleum oder ein anderer leicht brennbarer Stoff zugesetzt wird. In Betracht gezogene Druckschriften: Deutsche Patentschrift Nr. 487 o65; britische Patentschrift Nr. 284218; französische Patentschrift Nr. 684 351; »Archiv für Wärmewirtschaft und Dampfkesselwesen«, 1934, S. 146; »Brennstoff- und Wärmewirtschaft«, 19,33, S. 50; »Feuerungstechnik«, 192c8, S. 248.2. Surface treatment according to claim i, characterized in that a small amount of petroleum or another easily combustible substance is added to the oil-graphite mixture. Considered publications: German Patent No. 487 o65; British Patent No. 284218; French Patent No. 684,351; "Archives for Heat Industry and Steam Boilers", 1934, p. 146; "Fuel and Heat Industry", 19, 33, p. 50; "Feuerungstechnik", 192c8, p. 248.
DEW4153D 1939-05-21 1939-05-21 Surface treatment of metallic heating surfaces exposed to flue gases, in particular boiler heating surfaces Expired DE969494C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
DEW4153D DE969494C (en) 1939-05-21 1939-05-21 Surface treatment of metallic heating surfaces exposed to flue gases, in particular boiler heating surfaces

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DEW4153D DE969494C (en) 1939-05-21 1939-05-21 Surface treatment of metallic heating surfaces exposed to flue gases, in particular boiler heating surfaces

Publications (1)

Publication Number Publication Date
DE969494C true DE969494C (en) 1958-06-12

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Family Applications (1)

Application Number Title Priority Date Filing Date
DEW4153D Expired DE969494C (en) 1939-05-21 1939-05-21 Surface treatment of metallic heating surfaces exposed to flue gases, in particular boiler heating surfaces

Country Status (1)

Country Link
DE (1) DE969494C (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB284218A (en) * 1900-01-01
FR684351A (en) * 1929-11-04 1930-06-25 Babcock & Wilcox Co Improvements to good heat conductor mortars for hearth blocks
DE487065C (en) * 1926-05-27 1932-05-03 Reinhard Wussow Process for lining combustion chamber walls with carbon lining, especially for coal dust, oil and gas firing

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB284218A (en) * 1900-01-01
DE487065C (en) * 1926-05-27 1932-05-03 Reinhard Wussow Process for lining combustion chamber walls with carbon lining, especially for coal dust, oil and gas firing
FR684351A (en) * 1929-11-04 1930-06-25 Babcock & Wilcox Co Improvements to good heat conductor mortars for hearth blocks

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