DE94080C - - Google Patents
Info
- Publication number
- DE94080C DE94080C DENDAT94080D DE94080DA DE94080C DE 94080 C DE94080 C DE 94080C DE NDAT94080 D DENDAT94080 D DE NDAT94080D DE 94080D A DE94080D A DE 94080DA DE 94080 C DE94080 C DE 94080C
- Authority
- DE
- Germany
- Prior art keywords
- acid
- mol
- amidonaphthol
- dyes
- tetrazo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002253 acid Substances 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 3
- JRBJSXQPQWSCCF-UHFFFAOYSA-N 3,3'-Dimethoxybenzidine Chemical compound C1=C(N)C(OC)=CC(C=2C=C(OC)C(N)=CC=2)=C1 JRBJSXQPQWSCCF-UHFFFAOYSA-N 0.000 claims description 2
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims description 2
- 239000000975 dye Substances 0.000 description 7
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- HFACYLZERDEVSX-UHFFFAOYSA-N Benzidine Chemical compound C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- -1 benzoyl compound Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 230000004927 fusion Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B35/00—Disazo and polyazo dyes of the type A<-D->B prepared by diazotising and coupling
- C09B35/02—Disazo dyes
- C09B35/039—Disazo dyes characterised by the tetrazo component
- C09B35/08—Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of biphenyl
- C09B35/20—Disazo dyes characterised by the tetrazo component the tetrazo component being a derivative of biphenyl from two coupling compounds of different types
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Ink Jet (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
in BERLIN.in Berlin.
naphtol - a2 - sulfosäure.naphtol - a 2 - sulfonic acid.
In der Patentschrift Nr. 63074 werden blaue Substantive Farbstoffe beschrieben, welche aus gewissen Tetrazokörpern durch Combination mit der Benzoylverbindung derjenigen Ct1 c^-Amidonaphtolmonosulfosä'ure entstehen, die durch Verschmelzen der ci^-Naphtylamindisulfosäure S dargestellt wird. Es wird in der Patentschrift angegeben, dafs diese Ct1 c^-Amidonaphtolmonosulfosäure selbst sich zur Darstellung blauer substantiver Farbstoffe nicht eigne, da sie mit den Tetrazoverbindungen des Benzidins und ähnlicher Basen — ebenso wie die durch Sulfuriren von Ct1 ci4-Amidonaphtol entstehende Sulfosäure — nur Farbstoffe von stumpfem Ton und geringem Werth liefern soll.In the patent specification No. 63074 blue nouns dyes are described, which are formed from certain tetrazo bodies by combining with the benzoyl compound of that Ct 1 c ^ -amidonaphthol monosulphonic acid, which is produced by fusing the ci ^ -naphtylamine disulphonic acid. It is stated in the patent that this Ct 1 c ^ amidonaphthol monosulphonic acid itself is unsuitable for the preparation of blue substantive dyes, since it reacts with the tetrazo compounds of benzidine and similar bases - just like the sulphonic acid formed by sulphurizing Ct 1 ci 4 amidonaphthol - should only provide dyes of dull tone and of little value.
Im Gegensatz hierzu hat sich nun ergeben, dafs gerade die durch Verschmelzen der a - Naphtylamindisulfosäure S erhaltene Ct1 c^-Amidonaphtolmonosulfosäure mit gewissen Tetrazoverbindungen, wie Tetrazoditolyl und Tetrazodianisol brauchbare Farbstoffe liefert; ferner hat sich gezeigt, dafs die genannte' Ci1 Ci4 - Amidonaphtolmonosulfosäure mit den erwähnten Tetrazokörpern ein Zwischenproduct zu liefern im Stande ist, welches noch eine freie Diazogruppe enthält und daher noch mit ι Mol. eines Amins, Phenols bezw. deren Sulfosäuren combinirt werden kann.In contrast, now has arisen, that just by fusion of a - provides Naphtylamindisulfosäure S obtained Ct 1 c ^ -Amidonaphtolmonosulfosäure with certain Tetrazoverbindungen as Tetrazoditolyl and Tetrazodianisol useful dyes; It has also been shown that the said 'Ci 1 Ci 4 - amidonaphtolmonosulfonic acid is able to deliver an intermediate product with the tetrazo bodies mentioned, which still contains a free diazo group and therefore still contains ι mol. of an amine, phenol or. the sulfonic acids of which can be combined.
Von besonderem technischen Werth erwies sich derjenige gemischte Farbstoff, welcher aus ι Mol. Tetrazodianisol, 1 Mol. Ct1 ai - Amidonaphtolmonosulfosäure und ι Mol. ß-napbtoldisulfosaurem Natron R entsteht.. Of particular industrial value is the one mixed dye, which from ι Tetrazodianisol mol, 1 mol proved Ct 1 a i -. Amidonaphtolmonosulfosäure and ι mole of ß-R napbtoldisulfosaurem soda is produced..
Bei der Darstellung des Farbstoffes verfährt man wie folgt:The procedure for displaying the dye is as follows:
24,4 kg Dianisidin werden in bekannter Weise in die Tetrazoverbindung übergeführt; die Lösung der letzteren giebt man zu einer durch ,Soda alkalisch gehaltenen Lösung von 23,9 kg Ct1 a4-Amidonaphtolmonosulfosäure; das Zwischenproduct scheidet sich in Form eines blauschwarzen Niederschlages ab. Sobald die Bildung desselben beendet ist, fügt man eine Lösung von 34,8 kg β - naphtoldisulfosaurem Natron R zu und läfst die Mischung längere Zeit rühren. Alsdann wird angewärmt, der Farbstoff mit Salzwasser ausgefällt und abfiltrirt, geprefst und getrocknet. Er färbt ungeheizte Baumwolle im Seifen- oder Salzbade prachtvoll grünstichig 'blau.24.4 kg of dianisidine are converted into the tetrazo compound in a known manner; the solution of the latter is added to a solution, kept alkaline by soda, of 23.9 kg of Ct 1 a 4 amidonaphthol monosulfonic acid; the intermediate product is deposited in the form of a blue-black precipitate. As soon as the formation of the same has ended, a solution of 34.8 kg of β-naphthol-disulfo-acid sodium R is added and the mixture is left to stir for a long time. Then it is warmed up, the dye is precipitated with salt water and filtered off, pressed and dried. It dyes unheated cotton in a soap or salt bath with a magnificent greenish tinge of blue.
Claims (1)
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE94080C true DE94080C (en) |
Family
ID=365459
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT94080D Active DE94080C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE94080C (en) |
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0
- DE DENDAT94080D patent/DE94080C/de active Active
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