DE9318715U1 - Hair care products - Google Patents
Hair care productsInfo
- Publication number
- DE9318715U1 DE9318715U1 DE9318715U DE9318715U DE9318715U1 DE 9318715 U1 DE9318715 U1 DE 9318715U1 DE 9318715 U DE9318715 U DE 9318715U DE 9318715 U DE9318715 U DE 9318715U DE 9318715 U1 DE9318715 U1 DE 9318715U1
- Authority
- DE
- Germany
- Prior art keywords
- hair
- high molecular
- acid
- product
- hair care
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 210000004209 hair Anatomy 0.000 title claims description 30
- 239000000203 mixture Substances 0.000 claims description 13
- 239000003380 propellant Substances 0.000 claims description 12
- 229930195733 hydrocarbon Natural products 0.000 claims description 9
- 150000002430 hydrocarbons Chemical class 0.000 claims description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 6
- 150000002605 large molecules Chemical class 0.000 claims description 6
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- -1 galactan Polymers 0.000 description 12
- 239000007789 gas Substances 0.000 description 11
- 238000001035 drying Methods 0.000 description 10
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 9
- 239000008266 hair spray Substances 0.000 description 9
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 7
- 229920002472 Starch Polymers 0.000 description 7
- 238000005507 spraying Methods 0.000 description 7
- 239000008107 starch Substances 0.000 description 7
- 235000019698 starch Nutrition 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 229920002545 silicone oil Polymers 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920006027 ternary co-polymer Polymers 0.000 description 4
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 102000011782 Keratins Human genes 0.000 description 3
- 108010076876 Keratins Proteins 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 125000005250 alkyl acrylate group Chemical group 0.000 description 3
- 244000309464 bull Species 0.000 description 3
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- 239000001913 cellulose Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 3
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- MPDGHEJMBKOTSU-YKLVYJNSSA-N 18beta-glycyrrhetic acid Chemical compound C([C@H]1C2=CC(=O)[C@H]34)[C@@](C)(C(O)=O)CC[C@]1(C)CC[C@@]2(C)[C@]4(C)CC[C@@H]1[C@]3(C)CC[C@H](O)C1(C)C MPDGHEJMBKOTSU-YKLVYJNSSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 235000017788 Cydonia oblonga Nutrition 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910018557 Si O Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000001242 acetic acid derivatives Chemical class 0.000 description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 229920003123 carboxymethyl cellulose sodium Polymers 0.000 description 2
- 229940063834 carboxymethylcellulose sodium Drugs 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 2
- 210000003746 feather Anatomy 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- CRSOQBOWXPBRES-UHFFFAOYSA-N neopentane Chemical compound CC(C)(C)C CRSOQBOWXPBRES-UHFFFAOYSA-N 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 2
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical class CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- UVHQXWILFGUDTA-LNKPDPKZSA-N (z)-4-ethoxy-4-oxobut-2-enoic acid;methoxyethene Chemical compound COC=C.CCOC(=O)\C=C/C(O)=O UVHQXWILFGUDTA-LNKPDPKZSA-N 0.000 description 1
- RPZWNJWLFOVRMX-UHFFFAOYSA-N 1-aminosulfanylpropane-1,1-diol Chemical compound CCC(O)(O)SN RPZWNJWLFOVRMX-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- PTBDIHRZYDMNKB-UHFFFAOYSA-N 2,2-Bis(hydroxymethyl)propionic acid Chemical compound OCC(C)(CO)C(O)=O PTBDIHRZYDMNKB-UHFFFAOYSA-N 0.000 description 1
- NMGPHUOPSWFUEB-UHFFFAOYSA-N 2-(butylamino)ethyl 2-methylprop-2-enoate Chemical compound CCCCNCCOC(=O)C(C)=C NMGPHUOPSWFUEB-UHFFFAOYSA-N 0.000 description 1
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 description 1
- MXRGSJAOLKBZLU-UHFFFAOYSA-N 3-ethenylazepan-2-one Chemical compound C=CC1CCCCNC1=O MXRGSJAOLKBZLU-UHFFFAOYSA-N 0.000 description 1
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- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical class O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
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- 101150065749 Churc1 gene Proteins 0.000 description 1
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- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
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- 229920001277 pectin Polymers 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 229960000292 pectin Drugs 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000010409 propane-1,2-diol alginate Nutrition 0.000 description 1
- 239000000770 propane-1,2-diol alginate Substances 0.000 description 1
- 239000003531 protein hydrolysate Substances 0.000 description 1
- 235000019423 pullulan Nutrition 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/31—Hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
- A61K8/585—Organosilicon compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8164—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
P 92-1348U Haarpflegemittel P 92-1348 U Hair care products
Die vorliegende Erfindung betrifft Haarpflegemittel, die in Form von Haarsprays appliziert werden, insbesondere solche, die bei ■der Anwendung keinen üblen Geruch verursachen und einen verbesserten Festigungseffekt auf die Haarfrisur bei verringerter Trocknungszeit ausüben.The present invention relates to hair care products that are applied in the form of hair sprays, in particular those that do not cause a bad smell when applied and have an improved fixing effect on the hairstyle with a reduced drying time.
Haarsprays werden in weitem Umfang zu dem Zweck benutzt, das Haar zu festigen und der Frisur Halt zu geben. Diese Haarsprays enthalten zur Festigung als Hauptbestandteile üblicherweise filmbildende Harze und zur Verbesserung der Griffigkeit außerdem ein Öl, niedere Alkohole wie Ethanol bzw. Isopropylalkohol als Lösungsmittel, ein Treibgas, usw.Hairsprays are widely used to hold hair and give the hairstyle a certain hold. These hairsprays usually contain film-forming resins as the main ingredients to hold the hair and also an oil to improve the grip, lower alcohols such as ethanol or isopropyl alcohol as a solvent, a propellant gas, etc.
Die Lösungsmittel wie Ethanol sowie das Treibgas verdunsten und verteilen sich in der Luft beim Versprühen des Haarsprays. Das kann wegen des sich dabei einstellenden schlechten und reizenden Geruchs, der durch den Verbraucher wahrgenommen wird, unangenehme Empfindungen hervorrufen. Da Haarsprays jedoch ausgezeichnet geeignet sind, das Haar zu festigen und die Frisur zu erhalten, werden sie vom Verbraucher verbreitet benutzt. Zur Zeit werden zur Geruchsminderung überdeckende Duftstoffe usw. eingesetzt, um den unangenehmen Geruch zu unterdrücken, jedoch ist deren Wirkung bisher unzureichend. In den letzten Jahren wurden auch unparfurnierte Haarsprays auf den Markt gebracht, jedoch konnte der Eigengeruch der Rohstoffe und der niederen Alkohole dadurch nicht wirksam verringert werden.Solvents such as ethanol and propellant gas evaporate and disperse in the air when the hairspray is sprayed. This can cause unpleasant sensations due to the bad and irritating smell that is perceived by the consumer. However, since hairsprays are excellent for holding hair in place and maintaining the hairstyle, they are widely used by consumers. At present, masking fragrances etc. are used to reduce the smell in order to suppress the unpleasant smell, but their effectiveness has so far been inadequate. In recent years, unscented hairsprays have also been brought onto the market, but they have not been able to effectively reduce the inherent smell of the raw materials and the lower alcohols.
In der JP-A 61-161214 wird ein Haarspray beschrieben, das ein bestimmtes organisches Siliconkunstharz, ein flüchtiges Siliconöl und ein Treibgas enthält; die Aufgabe dieses Haarsprays ist jedoch, den festen Halt der Frisur, einen ausgezeichneten Glanz sowie glattes Haar zu erreichen; es gibt keinerlei Hinweis, dadurch eine Unterdrückung des Eigengeruchs der Rohstoffe, insbesondere der niederen Alkohole, erreichen zu können.JP-A 61-161214 describes a hairspray that contains a certain organic silicone resin, a volatile silicone oil and a propellant gas; the purpose of this hairspray, however, is to achieve a firm hold of the hairstyle, an excellent shine and smooth hair; there is no indication that this can be used to suppress the inherent odor of the raw materials, in particular the lower alcohols.
Es ist daher die Aufgabe der vorliegenden Erfindung, ein Haarpflegemittel zu schaffen, das eine zufriedenstellende Festigung des Haares gestattet, ohne einen den Verbraucher irritierenden oder unangenehmen Geruch bei der Anwendung hervorzurufen.It is therefore the object of the present invention to create a hair care product that allows satisfactory fixing of the hair without causing an irritating or unpleasant smell to the consumer during use.
Die Aufgabe wird dadurch gelöst, daß durch die kombinierte Verwendung einer besonderen flüchtigen Substanz, eines speziellen filmbildenden Harzes für die Haarfestigung und eines verflüssigten Gases oder Treibmittels eine Zusammensetzung geschaffen wird, die nicht nur keinen störenden Eigengeruch bei der Anwendung aufweist, sondern auch die Trocknungszeit nach dem Versprühen, die bei Haarsprays eine wichtige Rolle spielt, wesentlich verkürzt, wodurch die Festigung der Frisur sofort eintritt und lange anhält, und die Griffigkeit des behandelten Haares erhöht.The problem is solved by the combined use of a special volatile substance, a special film-forming resin for hair fixation and a liquefied gas or propellant to create a composition that not only has no unpleasant odor when used, but also significantly shortens the drying time after spraying, which plays an important role in hair sprays, so that the hairstyle is fixed immediately and lasts for a long time, and the handle of the treated hair is increased.
Im einzelnen betrifft die vorliegende Erfindung ein Haarpflegemittel, das dadurch gekennzeichnet ist, daß esIn particular, the present invention relates to a hair care product, which is characterized in that it
(A) mindestens ein oder mehrere flüchtige Siliconöle der allgemeinen Formel (I)(A) at least one or more volatile silicone oils of the general formula (I)
CHrCHr
CHo -Si-O-CH2O-Si-O-
CH3 CH3
CHoCHo
Si-O-I Si-O -I
CH3 CH3
CH,CH-CH,
- Si - CH.- Itself.
CH,CH-CH,
wobei m eine Zahl von O bis 5 bedeutet, und/oder der allgemeinen Formel (II)where m is a number from 0 to 5, and/or the general formula (II)
CH,CH-CH,
-Si - O-Si-O
CH,CH-CH,
wobei &eegr; eine Zahl von 3 bis 7 bedeutet, und/oder einen flüchtigen Kohlenwasserstoff mit einem Siedepunkt von O bis 40 0C,where η is a number from 3 to 7, and/or a volatile hydrocarbon having a boiling point of 0 to 40 0 C,
(B) mindestens eine wasserlösliche hochmolekulare Verbindung,(B) at least one water-soluble high molecular weight compound,
undand
(C) mindestens ein Treibgas enthält.(C) contains at least one propellant gas.
Der erfindungsgemäße Bestandteil (A), ein flüchtiges Siliconöl, das durch die obengenannte allgemeine Formel (I) dargestellt wird, ist vorzugsweise Hexamethyldisiloxan (m = O) oder Octamethyltrisiloxan (m = I)/ das flüchtige Siliconöl, dargestellt durch die obengenannte allgemeine Formel (II), ist vorzugsweise Hexamethylcyclotrisiloxan (n = 3) oder Octamethylcyclotetrasiloxan (n = 4).The component (A) of the present invention, a volatile silicone oil represented by the above-mentioned general formula (I), is preferably hexamethyldisiloxane (m = O) or octamethyltrisiloxane (m = I)/ the volatile silicone oil represented by the above-mentioned general formula (II) is preferably hexamethylcyclotrisiloxane (n = 3) or octamethylcyclotetrasiloxane (n = 4).
P 92-1348 4 P92-1348 4
Der weitere mögliche Bestandteil der Komponente (A), der flüchtige Kohlenwasserstoff, ist ein Kohlenwasserstoff mit einem Siedepunkt von 0 bis 40 0C (vorzugsweise 5 bis 40 0C), und/oder ein linearer oder verzweigter Kohlenwasserstoff mit 4 bis 6 Kohlenstoffatomen; Beispiele dazu sind Neopentan (Siedepunkt 9,5 0C), Isopentan (Siedepunkt 27,9 0C) und n-Pentan (Siedepunkt 36,1 0C).The other possible constituent of component (A), the volatile hydrocarbon, is a hydrocarbon having a boiling point of 0 to 40 0 C (preferably 5 to 40 0 C), and/or a linear or branched hydrocarbon having 4 to 6 carbon atoms; examples are neopentane (boiling point 9.5 0 C), isopentane (boiling point 27.9 0 C) and n-pentane (boiling point 36.1 0 C).
Als Bestandteil (A) der vorliegenden Erfindung wird mindestens eine der aufgezählten möglichen Verbindungen eingesetzt; es können aber auch mehrere der erwähnten flüchtigen Siliconöle und/oder flüchtigen Kohlenwasserstoffe verwendet werden.At least one of the possible compounds listed is used as component (A) of the present invention; but several of the volatile silicone oils and/or volatile hydrocarbons mentioned can also be used.
Die Menge des oben erwähnten Bestandteils (A) in dem Haarpflegemittel beträgt vorzugsweise 0,01 bzw. 0,1, vor allem 1 bis 50 Gew.-%, insbesondere 5, vor allem 10 bis 40 Gew.-%, berechnet auf die Gesamtzusammensetzung.The amount of the above-mentioned component (A) in the hair care product is preferably 0.01 or 0.1, especially 1 to 50 wt.%, in particular 5, especially 10 to 40 wt.%, calculated on the total composition.
Als wasserlösliche hochmolekulare Verbindung, die erfindungsgemäß Bestandteil (B) darstellt, kann ein natürliches oder synthetisches Polymeres eingesetzt werden.A natural or synthetic polymer can be used as the water-soluble high molecular compound which represents component (B) according to the invention.
Beispiele für natürliche wasserlösliche hochmolekulare Verbindungen sind hochmolekulare Pflanzenverbindungen wie Gummi arabicum, Tragantgummi, Galactan, Guar Gum, Johannisbrotgummi, Karayagummi, Karragheen, Pektin, Agar-Agar, Quittensamen (Quitte), Glycyrrhetinsäure; Xanthan Gum, Dextran, Bernsteinglucan, Pullulan; sowie hochmolekulare Eiweißhydrolysate wie Keratinhydrolysate.Examples of natural water-soluble high molecular weight compounds are high molecular weight plant compounds such as gum arabic, gum tragacanth, galactan, guar gum, locust bean gum, karaya gum, carrageenan, pectin, agar-agar, quince seeds (quince), glycyrrhetinic acid; xanthan gum, dextran, succinic glucan, pullulan; as well as high molecular weight protein hydrolysates such as keratin hydrolysates.
Die erwähnten Keratxnhydrolysate werden durch deren Aufspaltung entweder durch Oxidation oder Reduktion und folgende Modifikation der Thiolgruppe gewonnen. Keratinausgangsprodukte sind beispielsweise Pelz, Haar, Federn, Nägel, Hornstoffe, Hufe, Schuppen und ähnliches, allerdings werden Wolle, Haar und Federn besonders bevorzugt. Die Derivate in der Thiolgruppe schließen jene ein, die durch die untenstehenden Formeln 3 und 4 dargestellt werden, insbesondere werden diejenigen der Formel 4 bevorzugt.The keratin hydrolysates mentioned are obtained by splitting them either by oxidation or reduction and subsequent modification of the thiol group. Keratin starting products are, for example, fur, hair, feathers, nails, horn, hooves, scales and the like, but wool, hair and feathers are particularly preferred. The derivatives in the thiol group include those represented by formulas 3 and 4 below, in particular those of formula 4 are preferred.
Formel 3:Formula 3:
-SCH2COOH, -SCHCOOH,-SCH 2 COOH, -SCHCOOH,
CHoCOOHCH2COOH
-SCH2CHCOOH, CH3 -SCH 2 CHCOOH, CH 3
-SCH2CH2SO3H,-SCH 2 CH 2 SO 3 H,
-SCH2CH2 -SCH 2 CH 2
-SCH2CH2COOH, -SCHCHoCOOH,-SCH 2 CH 2 COOH, -SCHCHoCOOH,
CH3
-SO3H, -SSO3H, CH3
-SO 3 H, -SSO 3 H,
SO3H, SO3H ,
CH3 CH3
I -SCH2CH2CONHCCH2So3H, I -SCH 2 CH 2 CONHCCH 2 So 3 H,
CH3 -SCH2CH2So2CH2COOH .CH 3 -SCH 2 CH 2 So 2 CH 2 COOH .
P 92-1348P92-1348
Formel 4:Formula 4:
-SCH2COOH, -SCHCOOH-SCH 2 COOH, -SCHCOOH
CH2COOH CH2COOH
Die oben erwähnte chemische Modifikation der Thiolgruppe erfolgt durch bekannte Verfahren, wie sie beispielsweise in "Textile Progress" (N. H. Leon, Band 7, Seite 1, 1975), in "Organic Sulfur Compounds" (Shigeru Daikyo, Kagaku Dojin Publication, 1968), oder in "Polymer Experimentology Course" (Masami Oku, Band 12, veröffentlicht von Kyoritsu Shuppan, 1957) beschrieben werden.The above-mentioned chemical modification of the thiol group is carried out by known methods, such as those described in "Textile Progress" (N. H. Leon, Volume 7, page 1, 1975), in "Organic Sulfur Compounds" (Shigeru Daikyo, Kagaku Dojin Publication, 1968), or in "Polymer Experimentology Course" (Masami Oku, Volume 12, published by Kyoritsu Shuppan, 1957).
Beispiele für wasserlösliche hochmolekulare Verbindungen sind auch hochmolekulare Stärkeprodukte wie Carboxymethylstärke und Methylhydroxypropylstärke; hochmolekulare Celluloseverbindungen wie Methylcellulose, Nitrocellulose, Ethylcellulose, Methylhydroxypropylcellulose, Hydroxyethylcellulose, Natriumcellulosesulfat, Hydroxypropylcellulose, Carboxymethylcellulosenatrium (CMC), kristalline Cellulose und Cellulosepulver; ebenso hochmolekulare Alginatverbindungen wie Natriumalginat und Propylenglycolalginat. Examples of water-soluble high molecular weight compounds are also high molecular weight starch products such as carboxymethyl starch and methylhydroxypropyl starch; high molecular weight cellulose compounds such as methylcellulose, nitrocellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate, hydroxypropylcellulose, carboxymethylcellulose sodium (CMC), crystalline cellulose and cellulose powder; as well as high molecular weight alginate compounds such as sodium alginate and propylene glycol alginate.
Synthetische wasserlösliche hochmolekulare Verbindungen sindSynthetic water-soluble high molecular weight compounds are
auch die folgenden: · \ also the following: · \
IIIIII .·.·
IIII
(1) Hochmolekulare Polyvinylpyrrolidon-Verbindungen: Diese enthalten beispielsweise Polyvinylpyrrolidon und Vinylpyrrolidon-Copolymere mit Vinylacetat, einem Alkylaminoalkyl-(meth)acrylat, etc. wie im Handel erhältliche Produke, einschließlich Luviskol K (ein BASF-Produkt), PVP K (ein GAF-Produkt), usw.; Luviskol VA (ein BASF-Produkt), PVP/VA (ein GAF-Produkt) usw. als Vinylpyrrolidon/Vinylacetat-Copolymerisate; Luviskol VAP (ein BASF-Produkt) usw. als Copolymerisat von Vinylpyrrolidon, Vinylacetat und Vinylpropionat; Copolymer 845 (ein GAF-Produkt) als Copolymerisat aus Vinylpyrrolidon und einem Alkylaminoalkylacrylat; Copolymer VC-713 (ein GAF-Produkt) als ternäres Copolymerisat aus Vinylpyrrolidon, einem Alkylaminoalkylacrylat und Vinylcaprolactam; sowie Vem (ein Produkt von Ban-Stalfort) als Copolymerisat aus Vinylpyrrolidon und Acrylsäure/Methacrylsaure.(1) High molecular weight polyvinylpyrrolidone compounds: These include, for example, polyvinylpyrrolidone and vinylpyrrolidone copolymers with vinyl acetate, an alkylaminoalkyl (meth)acrylate, etc. such as commercially available products, including Luviskol K (a BASF product), PVP K (a GAF product), etc.; Luviskol VA (a BASF product), PVP/VA (a GAF product) etc. as vinylpyrrolidone/vinyl acetate copolymers; Luviskol VAP (a BASF product), etc. as a copolymer of vinylpyrrolidone, vinyl acetate and vinyl propionate; Copolymer 845 (a GAF product) as a copolymer of vinylpyrrolidone and an alkylaminoalkyl acrylate; Copolymer VC-713 (a GAF product) as a ternary copolymer of vinylpyrrolidone, an alkylaminoalkyl acrylate and vinylcaprolactam; and Vem (a product of Ban-Stalfort) as a copolymer of vinylpyrrolidone and acrylic acid/methacrylic acid.
(2) Hochmolekulare Verbindungen aus Vinylether: Diese umfassen beispielsweise niedere Alkylhalbester von Copolymerisaten aus Methylvinylether und Maleinsäureanhydrid; im Handel erhältliche Produkte sind Gantrez ES-225, ES-335, ES-425 und SP-215 (GAF-Produkte).(2) High molecular weight vinyl ether compounds: These include, for example, lower alkyl half esters of copolymers of methyl vinyl ether and maleic anhydride; commercially available products are Gantrez ES-225, ES-335, ES-425 and SP-215 (GAF products).
(3) Saure hochmolekulare Polyvinylacetat-Verbindungen: Diese enthalten beispielsweise Copolymerisate aus Vinylacetat und Crotonsäure; im Handel erhältliche Produkte sind Resin 28-1310 (ein National Starch-Produkt) und Rubiset CA (ein BASF-Produkt) als Copolymerisate aus Vinylacetat und Crotonsäure; Resin 28-2930 (ein National Starch-Produkt) als ternäres Copolymerisat aus Vinylacetat, Crotonsäure und Vinylneodecanat; Rubiset CAP (ein BASF-Produkt) als ternäres Copolymerisat aus Vinylacetat, Crotonsäure und Vinylpropionat; sowie Dewlex als Copolymerisat aus Vinylacetat und N-Vinyl-5-methyl-2-oxazolin.(3) Acidic high molecular weight polyvinyl acetate compounds: These contain, for example, copolymers of vinyl acetate and crotonic acid; commercially available products are Resin 28-1310 (a National Starch product) and Rubiset CA (a BASF product) as copolymers of vinyl acetate and crotonic acid; Resin 28-2930 (a National Starch product) as a ternary copolymer of vinyl acetate, crotonic acid and vinyl neodecanate; Rubiset CAP (a BASF product) as a ternary copolymer of vinyl acetate, crotonic acid and vinyl propionate; and Dewlex as a copolymer of vinyl acetate and N-vinyl-5-methyl-2-oxazoline.
(4) Saure hochmolekulare Acry!verbindungen: Diese umfassen beispielsweise Copolymerisate aus Acrylsäure und/oder Methacrylsäure mit einem Alkylacrylat und/oder Alkylmethacrylat, und Copolymerisate aus Acrylsäure, einem Alkylacrylat und einem N-Alkylacrylamid; im Handel erhältliche Produkte sind Plasize L-53P (ein Produkt von Gao Kagaku Co.) und Ultrahold 8 (ein BASF-Produkt).(4) Acidic high molecular weight acrylic compounds: These include, for example, copolymers of acrylic acid and/or methacrylic acid with an alkyl acrylate and/or alkyl methacrylate, and copolymers of acrylic acid, an alkyl acrylate and an N-alkylacrylamide; commercially available products are Plasize L-53P (a product of Gao Kagaku Co.) and Ultrahold 8 (a product of BASF).
(5) Amphotere hochmolekulare Acrylverbindungen: Diese schließen beispielsweise Substanzen ein, die durch Copolymerisation eines Dialkylaminoethylmethacrylats, Dialkylaminoethylacrylats oder Diacetonacrylamids usw. mit Acrylsäure,(5) Amphoteric high molecular weight acrylic compounds: These include, for example, substances obtained by copolymerizing a dialkylaminoethyl methacrylate, dialkylaminoethyl acrylate or diacetoneacrylamide, etc. with acrylic acid,
P 92-1348 9P92-1348 9
Methacrylsäure, einem Alkylacrylat oder Alkylmethacrylat usw. erhalten und danach mit halogenierter Essigsäure amphoter eingestellt wurden; im Handel erhältliche Produkte sind Yukaphomer AM75/R205 und AM75S/SM (Produkte von Mitsubishi Yuka Inc.)· Außerdem sind ternäre Copolymerisate von Hydroxypropylacrylat, Butylaminoethylmethacrylat und Octylamidoacrylat usw., im Handel erhältlich z. B. unter der Handelsbezeichnung Amphomer 28-4910 und LV-71 (Produkte von National Starch), geeignet. methacrylic acid, an alkyl acrylate or alkyl methacrylate, etc., and then amphotericized with halogenated acetic acid; commercially available products are Yukaphomer AM75/R205 and AM75S/SM (products of Mitsubishi Yuka Inc.) · In addition, ternary copolymers of hydroxypropyl acrylate, butylaminoethyl methacrylate and octylamidoacrylate, etc., commercially available e.g. under the trade name of Amphomer 28-4910 and LV-71 (products of National Starch), are suitable.
(6) Basische hochmolekulare Acrylverbindungen: Diese umfassen beispielsweise Copolymerisate aus Alkylacrylamiden, Acrylaten, Alkylaminoalkylacrylamiden und Polyethylenglycolmethacrylat (z. B. die wasserlösliche polymere Verbindung, die in der JP-A 2-180911 beschrieben ist).(6) Basic high molecular weight acrylic compounds: These include, for example, copolymers of alkylacrylamides, acrylates, alkylaminoalkylacrylamides and polyethylene glycol methacrylate (e.g. the water-soluble polymeric compound described in JP-A 2-180911).
Bei den obengenannten wasserlöslichen hochmolekularen Verbindungen ist es vom Standpunkt der Verbesserung der Haarwaschleistung und des Griffes vorzuziehen, diejenigen teilweise oder vollständig zu neutralisieren, die eine Säuregruppe enthalten. Die zur Neutralisierung zu verwendenden Alkalien sind nicht spezifisch beschränkt; die Säuregruppe in der hochmolekularen Verbindung kann ein Alkalimetallsalz von Natrium, Kalium, usw., ein Ammoniumsalz oder ein organisches basisches Salz von Ethanolamin, Diethanolamin, Triethanolamin, 2-Amino-2-methylpropanol, 2-Amino-2-methyl-l,3-propandiol, Aminomercaptopropandiol, Triisopropanolamin, Glycin, Histidin, Alginin, usw. enthalten. VonAmong the above-mentioned water-soluble high molecular compounds, it is preferable to partially or completely neutralize those containing an acid group from the standpoint of improving hair washing performance and feel. The alkalis to be used for neutralization are not specifically limited; the acid group in the high molecular compound may contain an alkali metal salt of sodium, potassium, etc., an ammonium salt or an organic basic salt of ethanolamine, diethanolamine, triethanolamine, 2-amino-2-methylpropanol, 2-amino-2-methyl-1,3-propanediol, aminomercaptopropanediol, triisopropanolamine, glycine, histidine, alginine, etc.
P 92-1348 10P92-1348 10
diesen sind die Salze des 2-Amino-2-methylpropanols und 2-Amino-2-methyl-l,3-propandiols besonders vorzuziehen.The salts of 2-amino-2-methylpropanol and 2-amino-2-methyl-1,3-propanediol are particularly preferable.
Außerdem ist ebenso vorzuziehen, die basischen Gruppen derjenigen hochmolekularen Verbindungen, die basisch sind, teilweise oder vollständig zu neutralisieren. Die zur Neutralisation zu verwendende Säure ist nicht sonderlich eingeschränkt, es werden jedoch beispielsweise Salzsäure, Schwefelsäure, Phosphorsäure usw. unter den anorganischen Säuren sowie Essigsäure, Milchsäure, Glycolsäure, Dxmethylolpropionsäure, Weinsäure, Citronensäure, Maleinsäure, Apfelsäure, usw. unter den organischen Säuren bevorzugt.In addition, it is also preferable to partially or completely neutralize the basic groups of those high molecular weight compounds that are basic. The acid to be used for neutralization is not particularly limited, but for example, hydrochloric acid, sulfuric acid, phosphoric acid, etc. are preferred among inorganic acids, and acetic acid, lactic acid, glycolic acid, dimethylolpropionic acid, tartaric acid, citric acid, maleic acid, malic acid, etc. are preferred among organic acids.
Der Anteil des oben definierten Bestandteils (B) im erfindungsgemäßen Haarpflegemittel beträgt vorzugsweise 0,1 bis 20 Gew.-%, insbesondere 1, vor allem 5 bis 10 Gew.-%, berechnet auf die Gesamtzusammensetzung. The proportion of the above-defined component (B) in the hair care product according to the invention is preferably 0.1 to 20% by weight, in particular 1, especially 5 to 10% by weight, calculated on the total composition.
Als Treibgas, das in der erfindungsgemäßen Zusammensetzung als Bestandteil (C) bezeichnet wird, sind Kohlenwasserstoffe wie verflüssigte Alkane, usw. zu nennen, hauptsächlich Propan, &eegr;-Butan, Isobutan, usw.; verflüssigte Gase sind Ether wie Dimethylether, Methylethylether, Diethylether, usw.; und komprimierte Gase, beispielsweise CO2, N2, N2O, usw. Diese Treibgase können allein oder in Verbindung miteinander verwendet werden;As the propellant gas referred to as component (C) in the composition of the invention, there may be mentioned hydrocarbons such as liquefied alkanes, etc., mainly propane, η-butane, isobutane, etc.; liquefied gases are ethers such as dimethyl ether, methyl ethyl ether, diethyl ether, etc.; and compressed gases such as CO 2 , N 2 , N 2 O, etc. These propellants may be used alone or in combination with one another;
P 92-1348 11 P92-1348 11
deren Anteil in der erfindungsgemäßen Zusammensetzung beträgt vorzugsweise 30 bis 70 Gew.-%, insbesondere 40 bis 60 Gew.-% bei verflüssigten Treibmitteln, und vorzugsweise 0,1 bis 10 Gew.-%, insbesondere 0,3 bis 5 Gew.-% im Falle eines komprimierten Gases.their proportion in the composition according to the invention is preferably 30 to 70 wt.%, in particular 40 to 60 wt.% in the case of liquefied propellants, and preferably 0.1 to 10 wt.%, in particular 0.3 to 5 wt.% in the case of a compressed gas.
In der erfindungsgemäßen haarkosmetischen Zusammensetzung kann auch ein Lösungsmittel verwendet werden, um die Kompatibilität der obengenannten Bestandteile (A) bis (C) zu verbessern; hierfür geeignete Lösungsmittel sind insbesondere lineare oder verzweigte Alkohole mit 1 bis 4 Kohlenstoffatomen (vorzugsweise Ethanol) und/oder Wasser. Der Anteil des genannten Lösungsmittels im erfindungsgemäßen Haarpflegemittel beträgt vorzugsweise 1 bis 55 Gew.-%, insbesondere 3 bis 50 Gew.-%, berechnet auf die Gesamtzusammensetzung.In the hair cosmetic composition according to the invention, a solvent can also be used to improve the compatibility of the above-mentioned components (A) to (C); solvents suitable for this purpose are in particular linear or branched alcohols with 1 to 4 carbon atoms (preferably ethanol) and/or water. The proportion of said solvent in the hair care product according to the invention is preferably 1 to 55% by weight, in particular 3 to 50% by weight, calculated on the total composition.
Je nach Verwendungszweck und so lange die Wirkung der vorliegenden Erfindung nicht beeinträchtigt wird, können auch alle anderen üblicherweise in haarkosmetischen Produkten verwendeten Bestandteile der erfindungsgemäßen Zusammensetzung zugesetzt werden. Solche sind beispielsweise Aromastoffe, Tenside (anionische, nichtionische, kationische), Schaumbildner, Stabilisierungsmittel, Konservierungsmittel, Pigmente, Färbemittel, Verdickungsmittel, Emulgatoren, höhere Alkohole, Wachse, StoffeDepending on the intended use and as long as the effect of the present invention is not impaired, all other ingredients usually used in hair cosmetic products can also be added to the composition according to the invention. These include, for example, flavorings, surfactants (anionic, non-ionic, cationic), foaming agents, stabilizers, preservatives, pigments, colorants, thickeners, emulsifiers, higher alcohols, waxes, substances
P 92-1348 12P92-1348 12
zur Regulierung von Schuppenbildung, Bakterizide, Reduktionsmittel, UV-Absorber, Pflanzenextrakte, Farbstoffe, Suspendiermittel, flüssiges Paraffin, Squalan, Lanolinderivate, Öle in Form von Esterölen, weitere Siliconöle, Polyalkylenglycole, Polyether und deren Oligocarboxylatverbindungen, Perlglanzmittel sowie Terpenkohlenwasserstoffe.to regulate dandruff formation, bactericides, reducing agents, UV absorbers, plant extracts, dyes, suspending agents, liquid paraffin, squalane, lanolin derivatives, oils in the form of ester oils, other silicone oils, polyalkylene glycols, polyethers and their oligocarboxylate compounds, pearlescent agents and terpene hydrocarbons.
Die Erfindung wird in den folgenden Beispielen illustriert. Beispiel 1 The invention is illustrated in the following examples. Example 1
Es werden erfindungsgemäße haarkosmetische Zusammensetzungen Nr. 1 bis 6 gemäß der nachstehenden Tabelle 1 hergestellt und dabei folgendes Verfahren verwendet.Hair cosmetic compositions Nos. 1 to 6 according to the invention are prepared as shown in Table 1 below using the following method.
Danach werden die Zusammensetzungen Nr. 1 - 3 im Vergleich zu einem im Handel erhältlichen Spray (A) nach Geruch, Festigungskraft und Trocknungszeit nach dem im folgenden beschriebenen Verfahren beurteilt.Compositions Nos. 1 - 3 are then evaluated in comparison with a commercially available spray (A) for odor, setting power and drying time according to the procedure described below.
Die Ergebnisse werden in Tabelle 2 zusammengefaßt.The results are summarized in Table 2.
P 92-1348 13P92-1348 13
Zunächst werden die Bestandteile, Treibgas ausgenommen, miteinander vermischt oder ineinander aufgelöst, um eine Stammlösung zuzubereiten, die in einen Druckbehälter gegeben wird, in den das Treibgas eingefüllt wird, wodurch sich die fertige haarkosmetische Zusammensetzung ergibt.First, the components, excluding the propellant gas, are mixed or dissolved together to prepare a stock solution, which is placed in a pressure vessel into which the propellant gas is poured, thus resulting in the finished hair cosmetic composition.
Die Intensität des Geruchs zum Zeitpunkt des Versprühens, der unangenehme Geruch zum Zeitpunkt des Versprühens, und die Intensität des verbleibenden Duftes nach dem Versprühen werden auf der Grundlage der folgenden Benotung beurteilt:The intensity of the odor at the time of spraying, the unpleasant odor at the time of spraying, and the intensity of the remaining odor after spraying are assessed based on the following rating:
K)J = sehr schwachK)J = very weak
O ■■
O ~ &Dgr; -O ~ Δ -
/\ = mäßig
X = stark /\ = moderate
X = strong
schwachweak
normalnormal
P 92-1348 14 P92-1348 14
Verfahren zur Beurteilung der
Festiqungskraft (Grad der Festigung): Procedure for assessing the
Strength (degree of strength):
Eine Haarsträhne von 18 cm Länge und 1,5 g Gewicht wird mit Wasser befeuchtet, dann um einen Stab von 2 cm Durchmesser gewickelt und zum Trocknen an der Luft belassen. Nach der Trocknung wird der Stab aus dem gelockten Haar entfernt und das Haarpflegemittel aus einem Abstand von 15 cm aufgesprüht. Nach dem Trocknen wird das Haar 30 Minuten in einem thermohygrostatischen Gerät (bei 20 0C und 98 % Raumfeuchte) aufgehängt, wobei die Verlängerung der Locken beobachtet wird, um den Grad der Festigung (in %) zu bestimmen. Der Grad der Festigung beträgt in dem Falle 35 %, in dem kein Haarpflegepräparat auf das Haar aufgesprüht wird (unbehandelt).A lock of hair 18 cm long and weighing 1.5 g is moistened with water, then wrapped around a rod 2 cm in diameter and left to air dry. After drying, the rod is removed from the curled hair and the hair product is sprayed from a distance of 15 cm. After drying, the hair is hung in a thermohygrostatic device (at 20 0 C and 98% humidity) for 30 minutes, observing the lengthening of the curls to determine the degree of fixation (in %). The degree of fixation is 35% in the case where no hair product is sprayed onto the hair (untreated).
Haar, das auf einer Nachbildung des menschlichen Kopfes (Perücke) aufgesetzt ist, wird eingelegt und aus einer Entfernung von 15 cm mit Haarpflegemittel besprüht/ sofort anschließend wird eine organoleptische Untersuchung des Ausmaßes der Trocknung in festgelegten Zeitabständen durchgeführt.Hair, which is placed on a replica of the human head (wig), is placed and sprayed with hair care product from a distance of 15 cm/ immediately afterwards an organoleptic examination of the degree of drying is carried out at specified intervals.
P 92-1348 15P92-1348 15
(Qj = schnell iy = ziemlich schnell(Qj = fast iy = fairly fast
= normal= normal
/ \ = ziemlich langsam S\ = langsam / \ = quite slow S\ = slow
■ · • *■ · • *
■ ·· • *■ ·· • *
1616
ProdukteInventive
Products
Yukaphomer AM75*5 Amphomer LV-71* 4
Yukaphomer AM75* 5
hochmolekulare
VerbindungWater-soluble
high molecular
Connection
010
0
010
0
010
0
010
0
010
0
010
0
• ♦ « · · a•♦ « · · a
1717
In der obigen Tabelle bedeuten *1 bis *8:In the table above, *1 to *8 mean:
*1 Hexamethyldisiloxan*1 Hexamethyldisiloxane
*2 Octamethyltrisiloxan*2 Octamethyltrisiloxane
*3 Octamethylcyclotetrasiloxan*3 Octamethylcyclotetrasiloxane
*4 amphotere polymere Acrylverbindung, dargestellt durch die*4 amphoteric polymeric acrylic compound, represented by the
untenstehende Formel (ein National Starch-Produkt) *5 amphotere polymere Acrylverbindung, dargestellt durch dieformula below (a National Starch product) *5 amphoteric polymeric acrylic compound represented by the
untenstehende Formel (ein Mitsubishi Yuka-Produkt) *6 Vinylacetat/Etherpolymerisat, dargestellt durch dieformula below (a Mitsubishi Yuka product) *6 Vinyl acetate/ether polymer, represented by the
untenstehende Formel (ein GAF-Produkt) *7 wasserlösliche hochmolekulare Verbindung, wie in derformula below (a GAF product) *7 water-soluble high molecular compound as in the
JP-A 2-180911 beschrieben
*8 ot-MonoisostearylglyceryletherJP-A 2-180911 described
*8 ot-monoisostearylglyceryl ether
Formel 5:Formula 5:
■f CH2CH Y5 ■f CH 2 CH Y 5
CONHC8H27 CONHC 8 H 27
CO2EtCO 2 Et
CO2CH2CH2NHBuCO 2 CH 2 CH 2 NHBu
COOHCOOH
Formel 6:Formula 6:
CH-CH-
-(-CH2C)-(- CH2C )
CO2RCO 2 R
CH,CH-CH,
CH:CH:
CO2CH2CH2^ NCH2CO2 CO 2 CH 2 CH 2 ^ NCH 2 CO 2
CH-CH-
Formel 7Formula 7
OCH -OCH-
(CHCH)15 (CHCH) 15
CO2H CO2H
CO2RCO 2 R
Erfindungsgemäße Musterbeispiele 12 3Inventive examples 12 3
Im Handel erhältliches Spray ACommercially available spray A
GeruchOdor
Geruch während des VersprühensOdor during spraying
Unangenehmer Geruch während d.SprühensUnpleasant smell during spraying
Ausmaß des verbleibenden Duftes nach dem SprühenExtent of remaining fragrance after spraying
OO O OOOOOOOO
O OOOO
&Dgr; &Dgr;Δ Δ
Festigungskraft (Grad der Haltbarkeit in %)Strength (degree of durability in %)
90 8290 82
Trocknungszeit:Drying time:
Co) (&dgr;) (o>Co) (&dgr;) (o>
&Ogr;~&Dgr;Ω~ΔΩ
Wie aus den Ergebnissen in Tabelle 2 ersichtlich, zeigen alle erfindungsgemäßen Muster keinen charakteristischen unangenehmen und schlechten Geruch während der Anwendung, ebenso sind die Festigungseigenschaften und Trocknungszeiten dem Bezugsprodukt überlegen.As can be seen from the results in Table 2, all samples according to the invention show no characteristic unpleasant and bad smell during application, and the setting properties and drying times are superior to the reference product.
Claims (2)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP34826792A JPH06199640A (en) | 1992-12-28 | 1992-12-28 | Hair cosmetic |
Publications (1)
Publication Number | Publication Date |
---|---|
DE9318715U1 true DE9318715U1 (en) | 1994-04-28 |
Family
ID=18395886
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19934341652 Withdrawn DE4341652A1 (en) | 1992-12-28 | 1993-12-07 | Hairspray having reduced unpleasant odour - contg propellant(s), high molecular wt cpd(s) and volatile silicones and/or low b.pt. hydrocarbon |
DE9318715U Expired - Lifetime DE9318715U1 (en) | 1992-12-28 | 1993-12-07 | Hair care products |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19934341652 Withdrawn DE4341652A1 (en) | 1992-12-28 | 1993-12-07 | Hairspray having reduced unpleasant odour - contg propellant(s), high molecular wt cpd(s) and volatile silicones and/or low b.pt. hydrocarbon |
Country Status (2)
Country | Link |
---|---|
JP (1) | JPH06199640A (en) |
DE (2) | DE4341652A1 (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19702156C1 (en) * | 1997-01-22 | 1998-08-06 | Wella Ag | Hair styling product giving good elasticity, bounce and shininess |
FR2853244B1 (en) * | 2003-04-04 | 2008-11-07 | Oreal | COSMETIC COMPOSITION COMPRISING A VOLATILE FATTY PHASE |
US20040197284A1 (en) | 2003-04-04 | 2004-10-07 | Frederic Auguste | Cosmetic composition comprising a volatile fatty phase |
FR2853227B1 (en) * | 2003-04-04 | 2009-05-08 | Oreal | COSMETIC COMPOSITION COMPRISING A VOLATILE FATTY PHASE |
EP1658045A1 (en) * | 2003-07-08 | 2006-05-24 | L'oreal | Perfume composition |
FR2857260A1 (en) * | 2003-07-08 | 2005-01-14 | Oreal | A perfume composition comprising as a solvent a mixture of polydimethylsiloxanes comprising 30 wt.% hexamethyldisiloxane and 70 wt.% octamethyltrisiloxane |
DE102007048290A1 (en) * | 2007-10-08 | 2009-04-09 | Henkel Ag & Co. Kgaa | Use of cyclic polydimethylsiloxanes to create a matte effect |
SG11201804918SA (en) * | 2015-12-11 | 2018-07-30 | Kao Corp | Hair cosmetic |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2132653B (en) * | 1982-12-07 | 1985-12-18 | Dow Corning | Hair treatment compositions |
EP0116207A3 (en) * | 1982-12-15 | 1986-03-12 | Beecham Group Plc | Cosmetic formulation |
-
1992
- 1992-12-28 JP JP34826792A patent/JPH06199640A/en active Pending
-
1993
- 1993-12-07 DE DE19934341652 patent/DE4341652A1/en not_active Withdrawn
- 1993-12-07 DE DE9318715U patent/DE9318715U1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
DE4341652A1 (en) | 1994-06-30 |
JPH06199640A (en) | 1994-07-19 |
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